Abstract: Impurity metals such as manganese and cadmium
from high-tenor cobalt electrolyte solution were selectively removed
by solvent extraction method using Co-D2EHPA after converting the functional group of D2EHPA with Co2+ ions. The process parameters
such as pH, organic concentration, O/A ratio, kinetics etc. were
investigated and the experiments were conducted by batch tests in the laboratory bench scale. Results showed that a significant amount
of manganese and cadmium can be extracted using Co-D2EHPA for the optimum processing of cobalt electrolyte solution at equilibrium pH about 3.5. The McCabe-Thiele diagram, constructed from the
extraction studies showed that 100% impurities can be extracted through four stages for manganese and three stages for cadmium
using O/A ratio of 0.65 and 1.0, respectively. From the stripping study, it was found that 100% manganese and cadmium can be stripped from the loaded organic using 0.4 M H2SO4 in a single
contact. The loading capacity of Co-D2EHPA by manganese and cadmium were also investigated with different O/A ratio as well as
with number of stages of contact of aqueous and organic phases. Valuable information was obtained for the designing of an impurities
removal process for the production of pure cobalt with less trouble in the electrowinning circuit.
Abstract: It is important to remove manganese from water
because of its effects on human and the environment. Human
activities are one of the biggest contributors for excessive manganese
concentration in the environment. The proposed method to remove
manganese in aqueous solution by using adsorption as in carbon
nanotubes (CNT) at different parameters: The parameters are CNT
dosage, pH, agitation speed and contact time. Different pHs are pH
6.0, pH 6.5, pH 7.0, pH 7.5 and pH 8.0, CNT dosages are 5mg,
6.25mg, 7.5mg, 8.75mg or 10mg, contact time are 10 min, 32.5 min,
55 min, 87.5 min and 120 min while the agitation speeds are 100rpm,
150rpm, 200rpm, 250rpm and 300rpm. The parameters chosen for
experiments are based on experimental design done by using Central
Composite Design, Design Expert 6.0 with 4 parameters, 5 levels and
2 replications. Based on the results, condition set at pH 7.0, agitation
speed of 300 rpm, 7.5mg and contact time 55 minutes gives the
highest removal with 75.5%. From ANOVA analysis in Design
Expert 6.0, the residual concentration will be very much affected by
pH and CNT dosage. Initial manganese concentration is 1.2mg/L
while the lowest residual concentration achieved is 0.294mg/L,
which almost satisfy DOE Malaysia Standard B requirement.
Therefore, further experiments must be done to remove manganese
from model water to the required standard (0.2 mg/L) with the initial
concentration set to 0.294 mg/L.
Abstract: Contact centres have been exemplars of scientific management in the discipline of operations management for more than a decade now. With the movement of industries from a resource based economy to knowledge based economy businesses have started to realize the customer eccentricity being the key to sustainability amidst high velocity of the market. However, as technologies have converged and advanced, so have the contact centres. Contact Centres have redirected the supply chains and the concept of retailing is highly diminished due to over exaggeration of cost reduction strategies. In conditions of high environmental velocity together with services featuring considerable information intensity contact centres will require up to date and enlightened agents to satisfy the demands placed upon them by those requesting their services. In this paper we examine salient factors such as Power Distance, Knowledge structures and the dynamics of job specialisation and enlargement to suggest critical success factors in the domain of contact centres.
Abstract: Chatter vibration has been a troublesome problem
for a machine tool toward the high precision and high speed machining.
Essentially, the machining performance is determined by the dynamic
characteristics of the machine tool structure and dynamics of cutting
process, which can further be identified in terms of the stability lobe
diagram. Therefore, realization on the machine tool dynamic behavior
can help to enhance the cutting stability. To assess the dynamic
characteristics and machining stability of a vertical milling system
under the influence of a linear guide, this study developed a finite
element model integrated the modeling of linear components with the
implementation of contact stiffness at the rolling interface. Both the
finite element simulations and experimental measurements reveal that
the linear guide with different preload greatly affects the vibration
behavior and milling stability of the vertical column spindle head
system, which also clearly indicate that the predictions of the
machining stability agree well with the cutting tests. It is believed that
the proposed model can be successfully applied to evaluate the
dynamics performance of machine tool systems of various
configurations.
Abstract: A new tool path planning method for 5-axis flank
milling of a globoidal indexing cam is developed in this paper. The
globoidal indexing cam is a practical transmission mechanism due
to its high transmission speed, accuracy and dynamic performance.
Machining the cam profile is a complex and precise task. The profile
surface of the globoidal cam is generated by the conjugate contact
motion of the roller. The generated complex profile surface is usually
machined by 5-axis point-milling method. The point-milling method
is time-consuming compared with flank milling. The tool path for
5-axis flank milling of globoidal cam is developed to improve the
cutting efficiency. The flank milling tool path is globally optimized
according to the minimum zone criterion, and high accuracy is
guaranteed. The computational example and cutting simulation finally
validate the developed method.
Abstract: In accordance with environmental impacts contended in Kyoto Protocol, the study aims to explore the different administrative and non-administrative measurements that industrial countries, such as America, German, Japan, Korea, Holland and British take to face with the increasing Global Warming phenomena. By large, these measurements consist of versatile dimensions, including of education and advocating, economical instruments, research developments and instances, restricted instruments, voluntary contacts, exchangeable permit for carbon-release and public investments. The results of discussion for the study are as follows: both economical impacts as well as reformations for nations that are affected via Kyoto Protocol, and human testifying for variables of global surroundings in the age of Kyoto Protocol.
Abstract: The ability of pomelo peel, a natural biosorbent, to remove Cd(II) ions from aqueous solution by biosorption was investigated. The experiments were carried out by batch method at 25 °C. The influence of solution pH, initial cadmium ion concentrations and contact times were evaluated. Cadmium ion removal increased significantly as the pH of the solution increased from pH 1 to pH 5. At pH 5, the cadmium ion removal reached a maximum value. The equilibrium process was described well by the Langmuir isotherm model, with a maximum biosorption capacity of 21.83 mg/g. The biosorption was relatively quick, (approx. 20 min). Biosorption kinetics followed a pseudo-second-order model. The result showed that pomelo peel was effective as a biosorbent for removing cadmium ions from aqueous solution. It is a low cost material that shows potential to be applied in wastewater technology for remediation of heavy metal contamination.
Abstract: Acute toxicity of nano SiO2, ZnO, MCM-41 (Meso
pore silica), Cu, Multi Wall Carbon Nano Tube (MWCNT), Single
Wall Carbon Nano Tube (SWCNT) , Fe (Coated) to bacteria Vibrio
fischeri using a homemade luminometer , was evaluated. The values
of the nominal effective concentrations (EC), causing 20% and 50%
inhibition of biouminescence, using two mathematical models at two
times of 5 and 30 minutes were calculated. Luminometer was
designed with Photomultiplier (PMT) detector. Luminol
chemiluminescence reaction was carried out for the calibration graph.
In the linear calibration range, the correlation coefficients and
coefficient of Variation (CV) were 0.988 and 3.21% respectively
which demonstrate the accuracy and reproducibility of the instrument
that are suitable. The important part of this research depends on how
to optimize the best condition for maximum bioluminescence. The
culture of Vibrio fischeri with optimal conditions in liquid media,
were stirring at 120 rpm at a temperature of 150C to 180C and were
incubated for 24 to 72 hours while solid medium was held at 180C
and for 48 hours. Suspension of nanoparticles ZnO, after 30 min
contact time to bacteria Vibrio fischeri, showed the highest toxicity
while SiO2 nanoparticles showed the lowest toxicity. After 5 min
exposure time, the toxicity of ZnO was the strongest and MCM-41
was the weakest toxicant component.
Abstract: The unique structural configuration found in human foot allows easy walking. Similar movement is hard to imitate even for an ape. It is obvious that human ambulation relates to the foot structure itself. Suppose the bones are represented as vertices and the joints as edges. This leads to the development of a special graph that represents human foot. On a footprint there are point-ofcontacts which have contact with the ground. It involves specific vertices. Theoretically, for an ideal ambulation, these points provide reactions onto the ground or the static equilibrium forces. They are arranged in sequence in form of a path. The ambulating footprint follows this path. Having the human foot graph and the path crossbred, it results in a representation that describes the profile of an ideal ambulation. This profile cites the locations where the point-of-contact experience normal reaction forces. It highlights the significant of these points.
Abstract: Today automobile and aerospace industries realise Laser Beam Welding for a clean and non contact source of heating and fusion for joining of sheets. The welding performance is mainly based on by the laser welding parameters. Some concepts related to Artificial Neural Networks and how can be applied to model weld bead geometry and mechanical properties in terms of equipment parameters are reported in order to evaluate the accuracy and compare it with traditional modeling schemes. This review reveals the output features of Titanium and Aluminium weld bead geometry and mechanical properties such as ultimate tensile strength, yield strength, elongation and reduction of the area of the weld using Artificial Neural Network.
Abstract: In this project cadmium ions were adsorbed from
aqueous solutions onto either date pits; a cheap agricultural and nontoxic
material, or chemically activated carbon prepared from date pits
using phosphoric acid. A series of experiments were conducted in a
batch adsorption technique to assess the feasibility of using the
prepared adsorbents. The effects of the process variables such as
initial cadmium ions concentration, contact time, solution pH and
adsorbent dose on the adsorption capacity of both adsorbents were
studied. The experimental data were tested using different isotherm
models such as Langmuir, Freundlich, Tempkin and Dubinin-
Radushkevich. The results showed that although the equilibrium data
could be described by all models used, Langmuir model gave slightly
better results when using activated carbon while Freundlich model,
gave better results with date pits.
Abstract: A numerical analysis of a reinforced concrete (RC) wall under missile impact loading is presented in this study. The model created by Technical Research Center of Finland was used. The commercial finite element code, LS-DYNA was used to analyze. The structural components of the reinforced concrete wall, missile and their contacts are fully modeled. The material nonlinearity with strain rate effects considering damage and failure is included in the analysis. The results of analysis were verified with other research results. The case-studies with different reinforcement ratios were conducted to investigate the influence of reinforcement on the punching behavior of walls under missile impact.
Abstract: Polymer-like organic thin films were deposited on both
aluminum alloy type 6061 and glass substrates at room temperature by
Plasma Enhanced Chemical Vapor Deposition (PECVD) methodusing
benzene and hexamethyldisiloxane (HMDSO) as precursor materials.
The surface and physical properties of plasma-polymerized organic
thin films were investigated at different r.f. powers. The effects of
benzene/argon ratio on the properties of plasma polymerized benzene
films were also investigated. It is found that using benzene alone
results in a non-coherent and non-adherent powdery deposited
material. The chemical structure and surface properties of the asgrown
plasma polymerized thin films were analyzed on glass
substrates with FTIR and contact angle measurements. FTIR spectra
of benzene deposited film indicated that the benzene rings are
preserved when increasing benzene ratio and/or decreasing r.f.
powers. FTIR spectra of HMDSO deposited films indicated an
increase of the hydrogen concentration and a decrease of the oxygen
concentration with the increase of r.f. power. The contact angle (θ) of
the films prepared from benzene was found to increase by about 43%
as benzene ratio increases from 10% to 20%. θ was then found to
decrease to the original value (51°) when the benzene ratio increases
to 100%. The contact angle, θ, for both benzene and HMDSO
deposited films were found to increase with r.f. power. This signifies
that the plasma polymerized organic films have substantially low
surface energy as the r.f power increases. The corrosion resistance of
aluminum alloy substrate both bare and covered with plasma
polymerized thin films was carried out by potentiodynamic
polarization measurements in standard 3.5 wt. % NaCl solution at
room temperature. The results indicate that the benzene and HMDSO
deposited films are suitable for protection of the aluminum substrate
against corrosion. The changes in the processing parameters seem to
have a strong influence on the film protective ability. Surface
roughness of films deposited on aluminum alloy substrate was
investigated using scanning electron microscopy (SEM). The SEM
images indicate that the surface roughness of benzene deposited films
increase with decreasing the benzene ratio. SEM images of benzene
and HMDSO deposited films indicate that the surface roughness
decreases with increasing r.f. power. Studying the above parameters
indicate that the films produced are suitable for specific practical
applications.
Abstract: The purpose of this research was to analyze and compare the instability of a contact surface between Copper and Nickel an alloy cathode in vacuum, the different ratio of Copper and Copper were conducted at 1%, 2% and 4% by using the cathode spot model. The transient recovery voltage is predicted. The cathode spot region is recognized as the collisionless space charge sheath connected with singly ionized collisional plasma. It was found that the transient voltage is decreased with increasing the percentage of an amount of Nickel in cathode materials.
Abstract: Iran is one of the greatest producers of date in the
world. However due to lack of information about its viscoelastic
properties, much of the production downgraded during harvesting
and postharvesting processes. In this study the effect of temperature
and moisture content of product were investigated on stress
relaxation characteristics. Therefore, the freshly harvested date
(kabkab) at tamar stage were put in controlled environment chamber
to obtain different temperature levels (25, 35, 45, and 55 0C) and
moisture contents (8.5, 8.7, 9.2, 15.3, 20, 32.2 %d.b.). A texture
analyzer TAXT2 (Stable Microsystems, UK) was used to apply
uniaxial compression tests. A chamber capable to control temperature
was designed and fabricated around the plunger of texture analyzer to
control the temperature during the experiment. As a new approach a
CCD camera (A4tech, 30 fps) was mounted on a cylindrical glass
probe to scan and record contact area between date and disk.
Afterwards, pictures were analyzed using image processing toolbox
of Matlab software. Individual date fruit was uniaxially compressed
at speed of 1 mm/s. The constant strain of 30% of thickness of date
was applied to the horizontally oriented fruit. To select a suitable
model for describing stress relaxation of date, experimental data were
fitted with three famous stress relaxation models including the
generalized Maxwell, Nussinovitch, and Pelege. The constant in
mentioned model were determined and correlated with temperature
and moisture content of product using non-linear regression analysis.
It was found that Generalized Maxwell and Nussinovitch models
appropriately describe viscoelastic characteristics of date fruits as
compared to Peleg mode.
Abstract: The previous researches focused on the influence of
anthropogenic greenhouse gases exerting global warming, but not
consider whether desert sand may warm the planet, this could be
improved by accounting for sand's physical and geometric properties.
Here we show, sand particles (because of their geometry) at the desert
surface form an extended surface of up to 1 + π/4 times the planar area
of the desert that can contact sunlight, and at shallow depths of the
desert form another extended surface of at least 1 + π times the planar
area that can contact air. Based on this feature, an enhanced heat
exchange system between sunlight, desert sand, and air in the spaces
between sand particles could be built up automatically, which can
increase capture of solar energy, leading to rapid heating of the sand
particles, and then the heating of sand particles will dramatically heat
the air between sand particles. The thermodynamics of deserts may
thus have contributed to global warming, especially significant to
future global warming if the current desertification continues to
expand.
Abstract: A two-dimensional thin-walled capsule of a flexible
semi-permeable membrane is adhered onto a rigid planar substrate
under adhesive forces (derived from a potential function) in the
presence of osmosis across the membrane. The capsule is immersed
in a hypotonic and diluted binary solution of a non-electrolyte
solute. The Stokes flow problem is solved by the immersed interface
method (IIM) with equal viscosities for the enclosed and
surrounding fluid of the capsule. The numerical results obtained are
verified against two simplified theoretical solutions and the
agreements are good. The osmotic inflation of the adhered capsule is
studied as a function of the solute concentration field, hydraulic
conductivity, and the initial capsule shape. Our findings indicate that
the contact length shrinks in dimension as capsule inflates in the
hypotonic medium, and the equilibrium contact length does not
depend on the hydraulic conductivity of the membrane and the
initial shape of the capsule.
Abstract: In this paper, the application of thermal spray
coatings in high speed shafts by a revolution up to 23000 RPM
has been studied. Gas compressor shafts are worn in contact
zone with journal therefore will be undersized. Wear
mechanisms of compressor shaft were identified. The
predominant wear mechanism is abrasion wear. The worn
surface was coated by hard WC-Co cermets using high
velocity oxy fuel (HVOF) after preparation. The shafts were in
satisfactory service in 8000h period. The metallurgical and
Tribological studies has been made on the worn and coated
shaft using optical microscopy, scanning electron microscopy
(SEM) and X-ray diffraction.
Abstract: The flexible follower response of a translating cam with
four different profiles for rise-dwell-fall-dwell (RDFD) motion is
investigated. The cycloidal displacement motion, the modified
sinusoidal acceleration motion, the modified trapezoidal acceleration
motion, and the 3-4-5 polynomial motion are employed to describe the
rise and the fall motions of the follower and the associated four kinds of
cam profiles are studied. Since the follower flexibility is considered,
the contact point of the roller and the cam is an unknown. Two
geometric constraints formulated to restrain the unknown position are
substituted into Hamilton-s principle with Lagrange multipliers.
Applying the assumed mode method, one can obtain the governing
equations of motion as non-linear differential-algebraic equations. The
equations are solved using Runge-Kutta method. Then, the responses of
the flexible follower undergoing the four different motions are
investigated in time domain and in frequency domain.
Abstract: Contact stress analysis between two spur gear
teeth was considered in different contact positions,
representing a pair of mating gears during rotation. A
programme has been developed to plot a pair of teeth in contact. This programme was run for each 3° of pinion
rotation from the first location of contact to the last location of
contact to produce 10 cases. Each case was represented a
sequence position of contact between these two teeth. The
programme gives graphic results for the profiles of these teeth
in each position and location of contact during rotation. Finite
element models were made for these cases and stress analysis
was done. The results were presented and finite element
analysis results were compared with theoretical calculations,
wherever available.