Abstract: The first laboratory synthesis of hard materials such as
diamond proceeded to attack of developing materials with high
hardness to compete diamond. Boron rich solids are good candidates
owing to their short interatomic bond lengths and strong covalent
character. Boron containing hard material was synthesized by modifiedmicrowave
method under nitrogen atmosphere by using a fuel
(glycine or urea), amorphous boron and/or boric acid in appropriate
molar ratio. Characterizations were done by x-ray diffraction (XRD),
Fourier transform infrared (FTIR) spectroscopy, scanning electron
microscopy/energy dispersive analyze (SEM/EDS), thermo
gravimetric/differential thermal analysis (TG/DTA).
Abstract: High temperature Fischer-Tropsch synthesis process
use fixed fluidized bed as a reactor. In order to understand the flow
behavior in the fluidized bed better, the research of how the radial
velocity affects the entire flow field is necessary. Laser Doppler
Velocimetry (LDV) was used to study the radial velocity distribution
along the diameter direction of the cross-section of the particle in a
fixed fluidized bed. The velocity in the cross-section is fluctuating
within a small range. The direction of the speed is a random
phenomenon. In addition to r/R is 1, the axial velocity are more than 6
times of the radial velocity, the radial velocity has little impact on the
axial velocity in a fixed fluidized bed.
Abstract: This paper discusses the general methods to saturation
in the steady-state, two axis (d & q) frame models of synchronous
machines. In particular, the important role of the magnetic coupling
between the d-q axes (cross-magnetizing phenomenon), is
demonstrated. For that purpose, distinct methods of saturation
modeling of dumper synchronous machine with cross-saturation are
identified, and detailed models synthesis in d-q axes. A number of
models are given in the final developed form. The procedure and the
novel models are verified by a critical application to prove the
validity of the method and the equivalence between all developed
models is reported. Advantages of some of the models over the
existing ones and their applicability are discussed.
Abstract: As a by-product of the biodiesel industries, glycerol
has been vastly generated which surpasses the market demand. It is
imperative to develop an efficient glycerol valorization processes in
minimizing the net energy requirement and intensifying the biodiesel
production. In this study, base-catalyzed transesterification of
glycerol with dimethyl carbonate using microwave irradiation as
heating method to produce glycerol carbonate was conducted by
varying grades of glycerol, i.e. 70%, 86% and 99% purity, that is
obtained from biodiesel plant. Metal oxide catalysts were used with
varying operating parameters including reaction time, DMC/glycerol
molar ratio, catalyst weight %, temperature and stirring speed. From
the study on the effect of different operating parameters it was found
that the type of catalyst used has the most significant effect on the
transesterification reaction. Amidst the metal oxide catalysts
examined, CaO gave the best performance. This study indicates the
feasibility of producing glycerol carbonate using different grade of
glycerol in both conventional thermal activation and microwave
irradiation with CaO as catalyst. Microwave assisted
transesterification (MAT) of glycerol into glycerol carbonate has
demonstrated itself as an energy efficient route by achieving 94.2%
yield of GC at 65°C, 5 minutes reaction time, 1 wt% CaO and
DMC/glycerol molar ratio of 2. The advantages of MAT
transesterification route has made the direct utilization of bioglycerol
from biodiesel production without the need of purification. This has
marked a more economical and less-energy intensive glycerol
carbonate synthesis route.
Abstract: The access to relevant information that is adapted to
user’s needs, preferences and environment is a challenge in many
applications running. That causes an appearance of context-aware
systems. To facilitate the development of this class of applications, it
is necessary that these applications share a common context
metamodel. In this article, we will present our context metamodel
that is defined using the OMG Meta Object facility (MOF).This
metamodel is based on the analysis and synthesis of context concepts
proposed in literature.
Abstract: Below-knee amputees commonly experience
asymmetrical gait patterns. It is generally believed that ischemia is
related to the formation of pressure sores due to uneven distribution
of forces. Micro-vascular responses can reveal local malnutrition.
Changes in local skin blood supply under various external loading
conditions have been studied for a number of years. Radionuclide
clearance, photo-plethysmography, trans-cutaneous oxygen tension
along with other studies showed that the blood supply would be
influenced by the epidermal forces, and the rate and the amount of
blood supply would decrease with increased epidermal loads being
shear forces or normal forces. Several cases of socket designs were
investigated using Finite Element Model (FEM) and Design of
Experiment (DOE) to increase flexibility and minimize the pressure
at the limb/socket interface using ultra high molecular weight
polyethylene (UHMWPE) and polyamide 6 (PA6) or Duraform. The
pressure reliefs at designated areas where reducing thickness is
involved are seen to be critical in determination of amputees’ comfort
and are very important to clinical applications. Implementing a hole
between the Patellar Tendon (PT) and Distal Tibia (DT) would
decrease stiffness and increase prosthesis range of motion where
flexibility is needed. In addition, displacement and prosthetic energy
storage increased without compromising mechanical efficiency and
prosthetic design integrity.
Abstract: The aim of this study is to investigate the relationship
between expectation, satisfaction and loyalty of South Korean
tourists visiting Turkey. In the research, a questionnaire was used as a
data collecting tool. The questionnaires are filled by South Korean
tourists coming to Turkey through package tours and individual. The
survey was conducted in 2014 in Nevsehir (Cappadocia Region) and
Istanbul. Tourist guides and agency staff have helped the
implementation of surveys. The survey questions are composed of 4
parts, which are “demographic characteristics of tourists”, “travel
behavior characteristics”, “perception of expectations on destination
attributes” and “perception of destination loyalty”. 5-point Likert
type scale including 28 destination attributes was used to measure the
expectations of South Korean tourists coming to Turkey. Questions
were directed to the tourists to measure the destination loyalty. The
questions relating to destination loyalty are “Talking about Turkey to
others”, “Recommendation Turkey to others” and “Tourists’
intentions to revisit Turkey”. The basic hypothesis of the research is
that there is a statistically significant relationship among
expectations, satisfactions and destination loyalty of South Korean
tourists coming to Turkey. The results indicated that the expectation
had a significant effect on overall satisfaction. In addition it was seen
that between overall satisfaction of tourists and destination loyalty
had a significant relationship. Based on findings, some suggestions
for tour operators and travel agencies were made.
Abstract: Standard Gibbs energy of formation ΔGfor(298.15) of
lanthanide-iron double oxides of garnet-type crystal structure
R3Fe5O12 - RIG (R – are rare earth ions) from initial oxides are
evaluated. The calculation is based on the data of standard entropies
S298.15 and standard enthalpies ΔH298.15 of formation of compounds
which are involved in the process of garnets synthesis. Gibbs energy
of formation is presented as temperature function ΔGfor(T) for the
range 300-1600K. The necessary starting thermodynamic data were
obtained from calorimetric study of heat capacity – temperature
functions and by using the semi-empirical method for calculation of
ΔH298.15 of formation. Thermodynamic functions for standard
temperature – enthalpy, entropy and Gibbs energy - are
recommended as reference data for technological evaluations.
Through the structural series of rare earth-iron garnets the correlation
between thermodynamic properties and characteristics of lanthanide
ions are elucidated.
Abstract: Synthesis of gold nanoparticles has attracted much
attention since the pioneering discovery of the high catalytic activity
of supported gold nanoparticles in the reaction of CO oxidation at
low temperature. In this research field, we used Na-montmorillonite
for gold nanoparticles stabilization; various gold loading percentage
1, 2 and 5% were used for gold nanoparticles preparation. The gold
nanoparticles were obtained using chemical reduction method using
NaBH4 as reductant agent. The obtained gold nanoparticles stabilized
in Na-montmorillonite were used as catalysts for the reduction of 4-
nitrophenol to aminophenol with sodium borohydride at room
temperature. The UV-Vis results confirmed directly the gold
nanoparticles formation. The XRD and N2 adsorption results showed
the formation of gold nanoparticles in the pores of montmorillonite
with an average size of 5 nm obtained on samples with 2% gold
loading percentage. The gold particles size increased with the
increase of gold loading percentage. The reduction reaction of 4-
nitrophenol into 4-aminophenol with NaBH4 catalyzed by Au-Namontmorillonite
catalyst exhibits remarkably a high activity; the
reaction was completed within 9 min for 1%Au-Na-montmorillonite
and within 3 min for 2%Au-Na-montmorillonite.
Abstract: Based on the hypothesis that disaster risk is
constructed socially and historically, this article shows the
importance of keeping alive the historical memory of disaster by
means of architectural and urban heritage conservation. This is
illustrated with three examples of Latin American World Heritage
cities, where disasters like floods and earthquakes have shaped urban
form. Therefore, the study of urban form or "Urban Morphology" is
proposed as a tool to understand and analyze urban transformations
with the documentation of the occurrence of disasters. Lessons
learned from such cities may be useful to reduce disasters risk in
contemporary built environments.
Abstract: This paper presents a power control for a Doubly Fed
Induction Generator (DFIG) using in Wind Energy Conversion
System (WECS) connected to the grid. The proposed control strategy
employs two nonlinear controllers, Backstipping (BSC) and slidingmode
controller (SMC) scheme to directly calculate the required
rotor control voltage so as to eliminate the instantaneous errors of
active and reactive powers. In this paper the advantages of BSC and
SMC are presented, the performance and robustness of this two
controller’s strategy are compared between them. First, we present a
model of wind turbine and DFIG machine, then a synthesis of the
controllers and their application in the DFIG power control.
Simulation results on a 1.5MW grid-connected DFIG system are
provided by MATLAB/Simulink.
Abstract: A novel chromium-free protective coating films based
on a zeolite coating was growing onto a FeCrAlloy metal using in –
situ hydrothermal method. The zeolite film was obtained using in-situ
crystallization process that is capable of coating large surfaces with
complex shape and in confined spaces has been developed. The
zeolite coating offers an advantage of a high mechanical stability and
thermal stability. The physicochemical properties were investigated
using X-ray diffraction (XRD), Electron Microscopy (SEM), Energy
Dispersive X–ray Analysis (EDX) and Thermogravimetric Analysis
(TGA). The transition from oxide-on-alloy wires to hydrothermally
synthesised uniformly zeolite coated surfaces was followed using
SEM and XRD. In addition, the robustness of the prepared coating
was confirmed by subjecting these to thermal cycling (ambient to
550oC).
Abstract: The aim of the present study is to investigate
consumers' determinants of intention toward the adoption of Smart
Grid solutions and technologies. Ajzen's Theory of Planned
Behaviour (TPB) model is applied and tested to explain the formation
of such adoption intention. An exogenous variable, taking into
account the resistance to change of individuals, was added to the
basic model. The elicitation study allowed obtaining salient modal
beliefs, which were used, with the support of literature, to design the
questionnaire. After the screening phase, data collected from the
main survey were analysed for evaluating measurement model's
reliability and validity. Consistent with the theory, the results of
structural equation analysis revealed that attitude, subjective norm,
and perceived behavioural control positively, which affected the
adoption intention. Specifically, the variable with the highest estimate
loading factor was found to be the perceived behavioural control,
and, the most important belief related to each construct was
determined (e.g., energy saving was observed to be the most
significant belief linked with attitude). Further investigation indicated
that the added exogenous variable has a negative influence on
intention; this finding confirmed partially the hypothesis, since this
influence was indirect: such relationship was mediated by attitude.
Implications and suggestions for future research are discussed.
Abstract: HR is a department that enhances the power of
employee performance in regard with their services, and to make the
organization strategic objectives. The main concern of HR
department is to organize people, focus on policies and their system.
The empirical study shows the relationship between HRM (Human
Resource Management practices) and their Job Satisfaction. The
Hypothesis is testing on a sample of overall 320 employees of 5
different Pharmaceutical departments of different organizations in
Pakistan. The important thing as Relationship of Job satisfaction with
HR Practices, Impact on Job Satisfaction with HR Practices,
Participation of Staff of Different Departments, HR Practices effects
the Job satisfaction, Recruitment or Hiring and Selection effects the
Job satisfaction, Training and Development, Performance and
Appraisals, Compensation affects the Job satisfaction , and Industrial
Relationships affects the Job satisfaction. After finishing all data
analysis, the conclusion is that lots of Job related activities raise the
confidence of Job satisfaction of employees with their salary and
other benefits.
Abstract: Cross-linked konjac glucomannan and kappa
carrageenan film were prepared by chemical crosslinking using
glutaraldehyde (GA) as the crosslinking agent. The effect
crosslinking on the swelling degree was investigated. Konjac
glucomannan and its mixture with kappa carrageenan film was
immersed in GA solution and then thermally cured. The obtained
cross-linked film was washed and soaked in the ethanol to remove
the unreacted GA. The obtained film was air dried at room
temperature to a constant weight. The infrared spectra and the value
of swelling degree of obtained crosslinked film showed that
glucomannan and kappa carrageenan was able to be cross-linked
using glutaraldehyde by film immersion and curing method without
catalyst. The cross-linked films were found to be pH sensitive,
indicating a potential to be used in drug delivery polymer system.
Abstract: The synthesis of CuFe2O4 spinel powders by an
optimized combustion-like process followed by calcination is
described herein. The samples were characterized using X-ray
diffraction (XRD), differential thermal analysis (TG/DTA), scanning
electron microscopy (SEM), dilatometry and 4-probe DC methods.
Different glycine to nitrate (G/N) ratios of 1 (fuel-deficient), 1.48
(stoichiometric) and 2 (fuel-rich) were employed. Calcining the asprepared
powders at 800 and 1000°C for 5 hours showed that the G/N
ratio of 2 results in the formation of the desired copper spinel single
phase at both calcination temperatures. For G/N=1, formation of
CuFe2O4 takes place in three steps. First, iron and copper nitrates
decompose to iron oxide and pure copper. Then, copper transforms to
copper oxide and finally, copper and iron oxides react with each other
to form a copper ferrite spinel phase. The electrical conductivity and
the coefficient of thermal expansion of the sintered pelletized
samples were 2 S.cm-1 (800°C) and 11×10-6 °C-1 (25-800°C),
respectively.
Abstract: The aim of the present study is to detect the chaotic
behavior in monetary economic relevant dynamical system. The
study employs three different forms of Taylor rules: current, forward,
and backward looking. The result suggests the existence of the
chaotic behavior in all three systems. In addition, the results strongly
represent that using expectations in policy rule especially rational
expectation hypothesis can increase complexity of the system and
leads to more chaotic behavior.
Abstract: Superabsorbent polymers received much attention and
are used in many fields because of their superior characters to
traditional absorbents, e.g., sponge and cotton. So, it is very
important but challenging to prepare highly and fast-swelling
superabsorbents. A reliable, efficient and low-cost technique for
removing heavy metal ions from wastewater is the adsorption using
bio-adsorbents obtained from biological materials, such as
polysaccharides-based hydrogels superabsorbents. In this study, novel multi-functional superabsorbent composites
type semi-interpenetrating polymer networks (Semi-IPNs) were
prepared via graft polymerization of acrylamide onto chitosan
backbone in presence of gelatin, CTS-g-PAAm/Ge, using potassium
persulfate and N,N’-methylene bisacrylamide as initiator and
crosslinker, respectively. These hydrogels were also partially
hydrolyzed to achieve superabsorbents with ampholytic properties
and uppermost swelling capacity. The formation of the grafted
network was evidenced by Fourier Transform Infrared Spectroscopy
(ATR-FTIR) and Thermogravimetric Analysis (TGA). The porous
structures were observed by Scanning Electron Microscope (SEM).
From TGA analysis, it was concluded that the incorporation of the Ge
in the CTS-g-PAAm network has marginally affected its thermal
stability. The effect of gelatin content on the swelling capacities of
these superabsorbent composites was examined in various media
(distilled water, saline and pH-solutions). The water absorbency was
enhanced by adding Ge in the network, where the optimum value was
reached at 2 wt. % of Ge. Their hydrolysis has not only greatly
optimized their absorption capacity but also improved the swelling
kinetic.These materials have also showed reswelling ability. We
believe that these super-absorbing materials would be very effective
for the adsorption of harmful metal ions from wastewater.
Abstract: In recent years a new method of combination
treatment for cancer has been developed and studied that has led to
significant advancements in the field of cancer therapy. Hyperthermia
is a traditional therapy that, along with a creation of a medically
approved level of heat with the help of an alternating magnetic AC
current, results in the destruction of cancer cells by heat. This paper
gives details regarding the production of the spherical nanocomposite
PVA/γ-Fe2O3 in order to be used for medical purposes such as tumor
treatment by hyperthermia. To reach a suitable and evenly distributed
temperature, the nanocomposite with core-shell morphology and
spherical form within a 100 to 200 nanometer size was created using
phase separation emulsion, in which the magnetic nano-particles γ-
Fe2O3 with an average particle size of 20 nano-meters and with
different percentages of 0.2, 0.4, 0.5 and 0.6 were covered by
polyvinyl alcohol. The main concern in hyperthermia and heat
treatment is achieving desirable specific absorption rate (SAR) and
one of the most critical factors in SAR is particle size. In this project
all attempts has been done to reach minimal size and consequently
maximum SAR. The morphological analysis of the spherical
structure of the nanocomposite PVA/γ-Fe2O3 was achieved by SEM
analyses and the study of the chemical bonds created was made
possible by FTIR analysis. To investigate the manner of magnetic
nanocomposite particle size distribution a DLS experiment was
conducted. Moreover, to determine the magnetic behavior of the γ-
Fe2O3 particle and the nanocomposite PVA/γ-Fe2O3 in different
concentrations a VSM test was conducted. To sum up, creating
magnetic nanocomposites with a spherical morphology that would be
employed for drug loading opens doors to new approaches in
developing nanocomposites that provide efficient heat and a
controlled release of drug simultaneously inside the magnetic field,
which are among their positive characteristics that could significantly
improve the recovery process in patients.
Abstract: Academicians at the Arab Open University have
always voiced their concern about the efficacy of the blended
learning process. Based on 75% independent study and 25% face-toface
tutorial, it poses the challenge of the predisposition to
adjustment. Being used to the psychology of traditional educational
systems, AOU students cannot be easily weaned from being spoonfed.
Hence they lack the motivation to plunge into self-study. For
better involvement of AOU students into the learning practices, it is
imperative to diagnose the factors that impede or increase their
motivation. This is conducted through an empirical study grounded
upon observations and tested hypothesis and aimed at monitoring and
optimizing the students’ learning outcome. Recommendations of the
research will follow the findings.