Abstract: Interaction between mixing and crystallization is often
ignored despite the fact that it affects almost every aspect of the
operation including nucleation, growth, and maintenance of the
crystal slurry. This is especially pronounced in multiple impeller
systems where flow complexity is increased. By choosing proper
mixing parameters, what closely depends on the knowledge of the
hydrodynamics in a mixing vessel, the process of batch cooling
crystallization may considerably be improved. The values that render
useful information when making this choice are mixing time and
power consumption. The predominant motivation for this work was
to investigate the extent to which radial dual impeller configuration
influences mixing time, power consumption and consequently the
values of metastable zone width and nucleation rate. In this research,
crystallization of borax was conducted in a 15 dm3 baffled batch
cooling crystallizer with an aspect ratio (H/T) of 1.3. Mixing was
performed using two straight blade turbines (4-SBT) mounted on the
same shaft that generated radial fluid flow. Experiments were
conducted at different values of N/NJS ratio (impeller speed/
minimum impeller speed for complete suspension), D/T ratio
(impeller diameter/crystallizer diameter), c/D ratio (lower impeller
off-bottom clearance/impeller diameter), and s/D ratio (spacing
between impellers/impeller diameter). Mother liquor was saturated at
30°C and was cooled at the rate of 6°C/h. Its concentration was
monitored in line by Na-ion selective electrode. From the values of
supersaturation that was monitored continuously over process time, it
was possible to determine the metastable zone width and
subsequently the nucleation rate using the Mersmann’s nucleation
criterion. For all applied dual impeller configurations, the mixing
time was determined by potentiometric method using a pulse
technique, while the power consumption was determined using a
torque meter produced by Himmelstein & Co. Results obtained in
this investigation show that dual impeller configuration significantly
influences the values of mixing time, power consumption as well as
the metastable zone width and nucleation rate. A special attention
should be addressed to the impeller spacing considering the flow
interaction that could be more or less pronounced depending on the
spacing value.
Abstract: The UK has had its fair share of the shale gas
revolutionary waves blowing across the global oil and gas industry at
present. Although, its exploitation is widely agreed to have been
delayed, shale gas was looked upon favorably by the UK Parliament
when they recognized it as genuine energy source and granted
licenses to industry to search and extract the resource. This, although
a significant progress by industry, there yet remains another test the
UK fracking resource must pass in order to render shale gas
extraction feasible – it must be economically extractible and
sustainably so. Developing unconventional resources is much more
expensive and risky, and for shale gas wells, producing in
commercial volumes is conditional upon drilling horizontal wells and
hydraulic fracturing, techniques which increase CAPEX. Meanwhile,
investment in shale gas development projects is sensitive to gas price
and technical and geological risks. Using a Two-Factor Model, the
economics of the Bowland shale wells were analyzed and the
operational conditions under which fracking is profitable in the UK
was characterized. We find that there is a great degree of flexibility
about Opex spending; hence Opex does not pose much threat to the
fracking industry in the UK. However, we discover Bowland shale
gas wells fail to add value at gas price of $8/ Mmbtu. A minimum gas
price of $12/Mmbtu at Opex of no more than $2/ Mcf and no more
than $14.95M Capex are required to create value within the present
petroleum tax regime, in the UK fracking industry.
Abstract: The source of the jet noise is generated by rocket exhaust plume during rocket engine testing. A domain decomposition approach is applied to the jet noise prediction in this paper. The aerodynamic noise coupling is based on the splitting into acoustic sources generation and sound propagation in separate physical domains. Large Eddy Simulation (LES) is used to simulate the supersonic jet flow. Based on the simulation results of the flow-fields, the jet noise distribution of the sound pressure level is obtained by applying the Ffowcs Williams-Hawkings (FW-H) acoustics equation and Fourier transform. The calculation results show that the complex structures of expansion waves, compression waves and the turbulent boundary layer could occur due to the strong interaction between the gas jet and the ambient air. In addition, the jet core region, the shock cell and the sound pressure level of the gas jet increase with the nozzle size increasing. Importantly, the numerical simulation results of the far-field sound are in good agreement with the experimental measurements in directivity.
Abstract: This paper presents the performance characteristics of
Darrieus-type vertical axis wind turbine (VAWT) with NACA airfoil
blades. The performance of Darrieus-type VAWT can be
characterized by torque and power. There are various parameters
affecting the performance such as chord length, helical angle, pitch
angle and rotor diameter. To estimate the optimum shape of Darrieustype
wind turbine in accordance with various design parameters, we
examined aerodynamic characteristics and separated flow occurring
in the vicinity of blade, interaction between flow and blade, and
torque and power characteristics derived from it. For flow analysis,
flow variations were investigated based on the unsteady RANS
(Reynolds-averaged Navier-Stokes) equation. Sliding mesh algorithm
was employed in order to consider rotational effect of blade. To
obtain more realistic results we conducted experiment and numerical
analysis at the same time for three-dimensional shape. In addition,
several parameters (chord length, rotor diameter, pitch angle, and
helical angle) were considered to find out optimum shape design and
characteristics of interaction with ambient flow. Since the NACA
airfoil used in this study showed significant changes in magnitude of
lift and drag depending on an angle of attack, the rotor with low drag,
long cord length and short diameter shows high power coefficient in
low tip speed ratio (TSR) range. On the contrary, in high TSR range,
drag becomes high. Hence, the short-chord and long-diameter rotor
produces high power coefficient. When a pitch angle at which airfoil
directs toward inside equals to -2° and helical angle equals to 0°,
Darrieus-type VAWT generates maximum power.
Abstract: The present study investigates the effectiveness of
newly designed clayey pellets (fired clay pellets diameter sizes of 5
and 8 mm, and unfired clay pellets with the diameter size of 15 mm)
as the beds in the column adsorption process. The adsorption
experiments in the batch mode were performed before the column
experiment with the purpose to determine the order of adsorbent
package in the column which was to be designed in the investigation.
The column experiment was performed by using a known mass of the
clayey beds and the volume of the waste printing developer, which
was purified. The column was filled in the following order: fired clay
pellets of the diameter size of 5 mm, fired clay pellets of the diameter
size of 8 mm, and unfired clay pellets of the diameter size of 15 mm.
The selected order of the adsorbents showed a high removal
efficiency for zinc (97.8%) and copper (81.5%) ions. These
efficiencies were better than those in the case of the already existing
mode adsorption. The obtained experimental data present a good
basis for the selection of an appropriate column fill, but further
testing is necessary in order to obtain more accurate results.
Abstract: Nanofibers are defined as fibers with diameters less
than 100 nanometers. In this study, behaviours of activated carbon
nanofiber (ACNF), carbon nanofiber (CNF), polyacrylonitrile/ carbon
nanotube (PAN/CNT), polyvinyl alcohol/nanosilver (PVA/Ag) in
proton exchange membrane (PEM) fuel cells are investigated
experimentally. This material was used as gas diffusion layer (GDL)
in PEM fuel cells. In this study, the electrical conductivities of
nanofiber and nanofiber/nanoparticles have been studied to
understand their effects on PEM fuel cell performance. According to
the experimental results, the maximum electrical conductivity
performance of the fuel cell with nanofiber was found to be at
PVA/Ag (at UConn condition). The electrical conductivities of CNF,
ACNF, PAN/CNT are lower for PEM. The resistance of cell with
PVA/Ag is lower than the resistance of cell with PAN/CNT, ACNF,
CNF.
Abstract: This research work is an experimental study, through
development of an adhesive from Prosopis africana endosperm. The
prosopis seed for this work were obtained from Enugu State in the
South East part of Nigeria. The seeds were prepared by separating the
endosperm from the seed coat and cotyledon. Three methods were
used to separate them, which are acidic method, roasting method and
boiling method. 20g of seed were treated with different
concentrations (25, 40, 55, 70, and 85% w/w) at 100°C and constant
time (30 minutes), under continuous stirring with magnetic stirrer.
Also 20g of seed were treated with sulphuric acid of concentrations
40% w/w at 100°C with different time (10, 15, 20, 25, 30 minutes),
under continuous stirring with magnetic stirrer. Finally, 20g of seed
were treated with sulphuric acid of concentrations 40% w/w at
different temperature (20°C, 40°C, 60°C, 80°C, and 100°C) with
constant time (30 minutes), under continuous stirring with magnetic
stirrer. The whole endosperm extracted was adhesive. The physical
properties of the adhesive were determined (appearance, odour, taste,
solubility, pH, size, and binding strength). The percentage of the
adhesive yield makes the commercialization of the seed in Nigeria
possible and profitable. The very high viscosity attained at low
concentrations makes prosopis adhesive an excellent thickener in the
food industry.
Abstract: This article developed an ion thruster optic system
sputter erosion depth numerical 3D model by IFE-PIC (Immersed
Finite Element-Particle-in-Cell) and Mont Carlo method, and
calculated the downstream surface sputter erosion rate of accelerator
grid; compared with LIPS-200 life test data. The results of the
numerical model are in reasonable agreement with the measured data.
Finally, we predicted the lifetime of the 20cm diameter ion thruster via
the erosion data obtained with the model. The ultimate result
demonstrated that under normal operating condition, the erosion rate
of the grooves wears on the downstream surface of the accelerator grid
is 34.6μm⁄1000h, which means the conservative lifetime until
structural failure occurring on the accelerator grid is 11500 hours.
Abstract: Highly stable and homogeneously dispersed amino
acid coated silver nanoparticles (ANP) of ≈ 10 nm diameter, ranging
from 420 to 430 nm are prepared on AgNO3 solution addition to gum
of Azadirachta indica solution at 373.15 K. The amino acids were
selected based on their polarity. The synthesized nanoparticles were
characterized by UV-Vis, FTIR spectroscopy, HR-TEM, XRD, SEM
and 1H-NMR. The coated nanoparticles were used as catalyst for the
reduction of methylene blue dye in presence of Sn(II) in aqueous,
anionic and cationic micellar media. The rate of reduction of dye was
determined by measuring the absorbance at 660 nm,
spectrophotometrically and followed the order: Kcationic > Kanionic >
Kwater. After 12 min and in absence of the ANP, only 2%, 3% and 6%
of the dye reduction was completed in aqueous, anionic and cationic
micellar media respectively while, in presence of ANP coated by
polar neutral amino acid with non-polar -R group, the reduction
completed to 84%, 95% and 98% respectively. The ANP coated with
polar neutral amino acid having non-polar -R group, increased the
rate of reduction of the dye by 94, 3205 and 6370 folds in aqueous,
anionic and cationic micellar media respectively. Also, the rate of
reduction of the dye increased by three folds when the micellar media
was changed from anionic to cationic when the ANP is coated by a
polar neutral amino acid having a non-polar -R group.
Abstract: This study investigated the effects of thermal
treatment on Tualang honey sample in terms of honey colour and
heat-induced small metabolites. The heating process was carried out
in a temperature controlled water batch at 90oC for 4 hours. The
honey samples were put in cylinder tubes with the dimension of 1 cm
diameter and 10 cm length for homogenous heat transfer. The results
found that the thermal treatment produced not only
hydroxylmethylfurfural, but also other harmful substances such as
phthalic anhydride and radiolytic byproducts. The degradation of
honey protein was due to the detection of free amino acids such as
cysteine and phenylalanine in heat-treated honey samples. Sugar
dehydration was also occurred because fragmented di-galactose was
identified based on the presence of characteristic ions in the mass
fragmentation pattern. The honey colour was found getting darker as
the heating duration was increased up to 4 hours. Approximately, 60
mm PFund of increment was noticed for the honey colour with the
colour change rate of 14.8 mm PFund per hour. Based on the
principal component analysis, the score plot clearly shows that the
chemical profile of Tualang honey was significantly altered after 2
hours of heating at 90oC.
Abstract: A three-dimensional numerical simulation of flow
through mini and microchannels with designed roughness is
conducted here. The effect of the roughness height (surface
roughness), geometry, Reynolds number on the friction factor, and
Nusselt number is investigated. The study is carried out by
employing CFD software, CFX. Our work focuses on a water flow
inside a circular mini-channel of 1 mm and microchannels of 500 and
100 m in diameter. The speed entry varies from 0.1 m/s to 20 m/s.
The general trend can be observed that bigger sizes of roughness
element lead to higher flow resistance. It is found that the friction
factor increases in a nonlinear fashion with the increase in obstruction
height. Particularly, the effect of roughness can no longer be ignored
at relative roughness height higher than 3%. A significant increase in
Poiseuille number is detected for all configurations considered. The
same observation can be done for Nusselt number. The transition
zone between laminar and turbulent flow depends on the channel
diameter.
Abstract: In this paper, a robust fault detection and isolation
(FDI) scheme is developed to monitor a multivariable nonlinear
chemical process called the Chylla-Haase polymerization reactor,
when it is under the cascade PI control. The scheme employs a radial
basis function neural network (RBFNN) in an independent mode to
model the process dynamics, and using the weighted sum-squared
prediction error as the residual. The Recursive Orthogonal Least
Squares algorithm (ROLS) is employed to train the model to
overcome the training difficulty of the independent mode of the
network. Then, another RBFNN is used as a fault classifier to isolate
faults from different features involved in the residual vector. Several
actuator and sensor faults are simulated in a nonlinear simulation of
the reactor in Simulink. The scheme is used to detect and isolate the
faults on-line. The simulation results show the effectiveness of the
scheme even the process is subjected to disturbances and
uncertainties including significant changes in the monomer feed rate,
fouling factor, impurity factor, ambient temperature, and
measurement noise. The simulation results are presented to illustrate
the effectiveness and robustness of the proposed method.
Abstract: Production fluids are transported from the platform to
tankers or process facilities through transfer pipelines. Water being
one of the heavier phases tends to settle at the bottom of pipelines
especially at low flow velocities and this has adverse consequences
for pipeline integrity. On restart after a shutdown, this could result in
corrosion and issues for process equipment, thus the need to have the
heavier liquid dispersed into the flowing lighter fluid. This study
looked at the flow regime of low water cut and low flow velocity oil
and water flow using conductive film thickness probes in a large
diameter 4-inch pipe to obtain oil and water interface height and the
interface structural velocity. A wide range of 0.1–1.0 m/s oil and
water mixture velocities was investigated for 0.5–5% water cut. Two
fluid model predictions were used to compare with the experimental
results.
Abstract: The photovoltaic and the semiconductor industries are
in growth and it is necessary to supply a large amount of silicon to
maintain this growth. Since silicon is still the best material for the
manufacturing of solar cells and semiconductor components so the
pure silicon like solar grade and semiconductor grade materials are
demanded. There are two main routes for silicon production:
metallurgical and chemical. In this article, we reviewed the
electrotecnological installations and systems for semiconductor
manufacturing. The main task is to design the installation which can
produce SOG Silicon from river sand by one work unit.
Abstract: In this paper, the 2-D unsteady viscous flow around
two cam shaped cylinders in tandem arrangement is numerically
simulated in order to study the characteristics of the flow in turbulent
regimes. The investigation covers the effects of high subcritical and
supercritical Reynolds numbers and L/D ratio on total drag
coefficient. The equivalent diameter of cylinders is 27.6 mm The
space between center to center of two cam shaped cylinders is define
as longitudinal pitch ratio and it varies in range of 1.5< L/D
Abstract: Recently, many users have begun to frequently share
their opinions on diverse issues using various social media. Therefore,
numerous governments have attempted to establish or improve
national policies according to the public opinions captured from
various social media. In this paper, we indicate several limitations of
the traditional approaches to analyze public opinion on science and
technology and provide an alternative methodology to overcome these
limitations. First, we distinguish between the science and technology
analysis phase and the social issue analysis phase to reflect the fact that
public opinion can be formed only when a certain science and
technology is applied to a specific social issue. Next, we successively
apply a start list and a stop list to acquire clarified and interesting
results. Finally, to identify the most appropriate documents that fit
with a given subject, we develop a new logical filter concept that
consists of not only mere keywords but also a logical relationship
among the keywords. This study then analyzes the possibilities for the
practical use of the proposed methodology thorough its application to
discover core issues and public opinions from 1,700,886 documents
comprising SNS, blogs, news, and discussions.
Abstract: The ultimate purpose of this investigation was to
determine the teachers’ opinions as well as students’ opinions
towards the Adapted English Lessons. The subjects of the study were
5 Thai teachers, who teach English, and 85 Grade 10 mixed-ability
students at Triamudom Suksa Pattanakarn Ratchada School,
Bangkok, Thailand. The research instruments included questionnaires
and the informal interview. The data from the research instruments
was collected and analyzed concerning linguistic principles of
minimal pair and articulatory phonetics as well as teaching
techniques of mimicry-memorization; vocabulary substitution drills,
language pattern drills, reading comprehension exercise, practicing
listening, speaking and writing skill and communicative activities;
informal talk and free writing. The data was statistically compiled
according to an arithmetic percentage. The results showed that the
teachers and students have very highly positive opinions towards
adapting linguistic principles for teaching and learning phonological
accuracy. Teaching techniques provided in the Adapted English
Lessons can be used efficiently in the classroom. The teachers and
students have positive opinions towards them too.
Abstract: Targeted drug delivery is a method of delivering
medication to a patient in a manner that increases the concentration
of the medication in some parts of the body relative to others.
Targeted drug delivery seeks to concentrate the medication in the
tissues of interest while reducing the relative concentration of the
medication in the remaining tissues. This improves efficacy of the
while reducing side effects. In the present work, we investigate the
effect of magnetic field, flow rate and particle concentration on the
capturing of magnetic particles transported in a stent implanted
fluidic channel. Iron oxide magnetic nanoparticles (Fe3O4)
nanoparticles were synthesized via co-precipitation method. The
synthesized Fe3O4 nanoparticles were added in the de-ionized (DI)
water to prepare the Fe3O4 magnetic particle suspended fluid. This
fluid is transported in a cylindrical tube of diameter 8 mm with help
of a peristaltic pump at different flow rate (25-40 ml/min). A
ferromagnetic coil of SS 430 has been implanted inside the
cylindrical tube to enhance the capturing of magnetic nanoparticles
under magnetic field. The capturing of magnetic nanoparticles was
observed at different magnetic magnetic field, flow rate and particle
concentration. It is observed that capture efficiency increases from
47-67% at magnetic field 2-5kG, respectively at particle
concentration 0.6mg/ml and at flow rate 30 ml/min. However, the
capture efficiency decreases from 65 to 44% by increasing the flow
rate from 25 to 40 ml/min, respectively. Furthermore, it is observed
that capture efficiency increases from 51 to 67% by increasing the
particle concentration from 0.3 to 0.6 mg/ml, respectively.
Abstract: The objective of this study was to synthesize and
characterize the poly(alkenoic acid)s with different molecular
structures, use these polymers to formulate a dental cement
restorative, and study the effect of molecular structures on reaction
kinetics, viscosity, and mechanical strengths of the formed polymers
and cement restoratives. In this study, poly(alkenoic acid)s with
different molecular structures were synthesized. The purified
polymers were formulated with commercial Fuji II LC glass fillers to
form the experimental cement restoratives. The reaction kinetics was
studied via 1HNMR spectroscopy. The formed restoratives were
evaluated using compressive strength, diametral tensile strength,
flexural strength, hardness and wear-resistance tests. Specimens were
conditioned in distilled water at 37oC for 24 h prior to testing. Fuji II
LC restorative was used as control. The results show that the higher
the arm number and initiator concentration, the faster the reaction
was. It was also found that the higher the arm number and branching
that the polymer had, the lower the viscosity of the polymer in water
and the lower the mechanical strengths of the formed restorative. The
experimental restoratives were 31-53% in compressive strength, 37-
55% in compressive modulus, 80-126% in diametral tensile strength,
76-94% in flexural strength, 4-21% in fracture toughness and 53-96%
in hardness higher than Fuji II LC. For wear test, the experimental
restoratives were only 5.4-13% of abrasive and 6.4-12% of attritional
wear depths of Fuji II LC in each wear cycle. The aging study also
showed that all the experimental restoratives increased their strength
continuously during 30 days, unlike Fuji II LC. It is concluded that
polymer molecular structures have significant and positive impact on
mechanical properties of dental cement restoratives.
Abstract: In this article, the radial displacement error correction
capability of a high precision spindle grinding caused by unbalance
force was investigated. The spindle shaft is considered as a flexible
rotor mounted on two sets of angular contact ball bearing. Finite
element methods (FEM) have been adopted for obtaining the
equation of motion of the spindle. In this paper, firstly, natural
frequencies, critical frequencies, and amplitude of the unbalance
response caused by residual unbalance are determined in order to
investigate the spindle behaviors. Furthermore, an optimization
design algorithm is employed to minimize radial displacement of the
spindle which considers dimension of the spindle shaft, the dynamic
characteristics of the bearings, critical frequencies and amplitude of
the unbalance response, and computes optimum spindle diameters
and stiffness and damping of the bearings. Numerical simulation
results show that by optimizing the spindle diameters, and stiffness
and damping in the bearings, radial displacement of the spindle can
be reduced. A spindle about 4 μm radial displacement error can be
compensated with 2 μm accuracy. This certainly can improve the
accuracy of the product of machining.