Abstract: Ionic liquids consisting of a phosphonium cationic
moiety and a saccharinate anion are synthesized and compared with
their precursors, phosphonium chlorides, in reference to their
extraction efficiency towards L-lactic acid. On the base of
measurements of the acid and the water partitioning in the
equilibrium biphasic systems, the molar ratios between acid, water
and ionic liquid are estimated which allows to deduce the lactic acid
extractive pathway. The effect of a salting-out addition that
strengthens hydrophobicity in both phases is studied in view to reveal
the best biphasic system with respect to IL low toxicity and high
extraction efficiency.
Abstract: This article discusses ways to implement a
differentiated approach to developing academic motivation for
mathematical studies which relies on defining the primary structural
characteristics of motivation. The following characteristics are
considered: features of realization of cognitive activity, meaningmaking
characteristics, level of generalization and consistency of
knowledge acquired by personal experience. The assessment of the
present level of individual student understanding of each component
of academic motivation is the basis for defining the relevant
educational strategy for its further development.
Abstract: Modern Portfolio Theory (MPT) according to
Markowitz states that investors form mean-variance efficient
portfolios which maximizes their utility. Markowitz proposed the
standard deviation as a simple measure for portfolio risk and the
lower semi-variance as the only risk measure of interest to rational
investors. This paper uses a third volatility estimator based on
intraday data and compares three efficient frontiers on the Croatian
Stock Market. The results show that range-based volatility estimator
outperforms both mean-variance and lower semi-variance model.
Abstract: This study aimed to examine the management and
development of forest tourism Kamchanoad. Ban Dung, Udon Thani
sustainability. Data were collected by means of qualitative research
including in-depth interviews, semi- structured, and then the data
were summarized and discussed in accordance with the objectives.
And make a presentation in the form of lectures. The target
population for the study consisted of 16 people, including
representatives from government agencies, community leaders and
the community. The results showed that Guidelines for the
Management and Development of Forest Tourism Kamchanoad
include management of buildings and infrastructure such as roads,
water, electricity, toilets. Other developments are the establishment
of a service center that provides information and resources to
facilitate tourists.; nature trails and informative signage to educate
visitors on the path to the jungle Kamchanoad; forest activities for
tourists who are interested only in occasional educational activities
such as vegetation, etc.; disseminating information on various aspects
of tourism through various channels in both Thailand and English, as
well as a web site to encourage community involvement in the
planning and management of tourism together with the care and
preservation of natural resources and preserving the local cultural
tourist area of Kamchanoad.
Abstract: To determine the potential of a low cost Irish
engineered timber product to replace high cost solid timber for use in
bending active structures such as gridshells a single Irish engineered
timber product in the form of orientated strand board (OSB) was
selected. A comparative study of OSB and solid timber was carried
out to determine the optimum properties that make a material suitable
for use in gridshells. Three parameters were identified to be relevant
in the selection of a material for gridshells. These three parameters
are the strength to stiffness ratio, the flexural stiffness of
commercially available sections, and the variability of material and
section properties. It is shown that when comparing OSB against
solid timber, OSB is a more suitable material for use in gridshells that
are at the smaller end of the scale and that have tight radii of
curvature. Typically, for solid timber materials, stiffness is used as an
indicator for strength and engineered timber is no different. Thus, low
flexural stiffness would mean low flexural strength. However, when
it comes to bending active gridshells, OSB offers a significant
advantage. By the addition of multiple layers, an increased section
size is created, thus endowing the structure with higher stiffness and
higher strength from initial low stiffness and low strength materials
while still maintaining tight radii of curvature. This allows OSB to
compete with solid timber on large scale gridshells. Additionally, a
preliminary sustainability study using a set of sustainability indicators
was carried out to determine the relative sustainability of building a
large-scale gridshell in Ireland with a primary focus on economic
viability but a mention is also given to social and environmental
aspects. For this, the Savill garden gridshell in the UK was used as
the functional unit with the sustainability of the structural roof
skeleton constructed from UK larch solid timber being compared
with the same structure using Irish OSB. Albeit that the advantages of
using commercially available OSB in a bending active gridshell are
marginal and limited to specific gridshell applications, further study
into an optimised engineered timber product is merited.
Abstract: Nitrogen fertilizer is the most used and often the most
mismanaged nutrient input. Nitrogen management has tremendous
implications on crop productivity, quality and environmental
stewardship. Sufficient nitrogen is needed to optimum yield and
quality. Soil and in-season plant tissue testing for nitrogen status are
a time consuming and expensive process. Real time sensing of plant
nitrogen status can be a useful tool in managing nitrogen inputs. The
objectives of this project were to assess the reliability of remotely
sensed non-destructive plant nitrogen measurements compared to wet
chemistry data from sampled plant tissue, develop in-season nitrogen
recommendations based on remotely sensed data for improved
nitrogen use efficiency and assess the potential for determining yield
and quality from remotely sensed data. Very good correlations were
observed between early-season remotely sensed crop nitrogen status
and plant nitrogen concentrations and subsequent in-season fertilizer
recommendations. The transmittance/absorbance type meters gave
the most accurate readings. Early in-season fertilizer recommendation
would be to apply 40 kg nitrogen per hectare plus 15 kg nitrogen per
hectare for each unit difference measured with the SPAD meter
between the crop and reference area or 25 kg plus 13 kg per hectare
for each unit difference measured with the CCM 200. Once the crop
was sufficiently fertilized meter readings became inconclusive and
were of no benefit for determining nitrogen status, silage yield and
quality and grain yield and protein.
Abstract: The Al-MoO3-P-CdTe-Al MOS sandwich structures
were fabricated by vacuum deposition method on cleaned glass
substrates. Capacitance versus voltage measurements were performed
at different frequencies and sweep rates of applied voltages for oxide
and semiconductor films of different thicknesses. In the negative
voltage region of the C-V curve a high differential capacitance of the
semiconductor was observed and at high frequencies (
Abstract: The capability of CNC gantry milling machines in
manufacturing long components has caused the expanded use of such
machines. On the other hand, the machines’ gantry rigidity can
reduce under severe loads or vibration during operation. Indeed, the
quality of machining is dependent on the machine’s dynamic
behavior throughout the operating process. For this reason, these
types of machines have always been used widely and are not
efficient. Therefore, they can usually be employed for rough
machining and may not produce adequate surface finishing. In this
paper, a CNC gantry milling machine with the potential to produce
good surface finish has been designed and analyzed. The lowest
natural frequency of this machine is 202 Hz corresponding to 12000
rpm at all motion amplitudes with a full range of suitable frequency
responses. Meanwhile, the maximum deformation under dead loads
for the gantry machine is 0.565*m, indicating that this machine tool
is capable of producing higher product quality.
Abstract: In this work, we begin with the presentation of the
Tθ family of usual similarity measures concerning multidimensional
binary data. Subsequently, some properties of these measures are
proposed. Finally the impact of the use of different inter-elements
measures on the results of the Agglomerative Hierarchical Clustering
Methods is studied.
Abstract: In the present work, fly ash geopolymer based
composites including polyester (PES) waste were studied. Specimens
of three compositions were prepared: (a) fly ash geopolymer with 5%
PES waste; (b) fly ash geopolymer mortar with 5% PES waste; (c) fly
ash geopolymer mortar with 6.25% PES waste. Compressive and
bending strength measurements, water absorption test and
determination of thermal conductivity coefficient were performed.
The results showed that the addition of sand in a mixture of
geopolymer with 5% PES content led to higher compressive strength,
while it increased water absorption and reduced thermal conductivity
coefficient. The increase of PES addition in geopolymer mortars
resulted in a more dense structure, indicated by the increase of
strength and thermal conductivity and the decrease of water
absorption.
Abstract: This study aimed to identify the alignment of
understanding and assessment practices among secondary school
teachers. The study was carried out using quantitative descriptive
study. The sample consisted of 164 teachers who taught Form 1 and 2
from 11 secondary schools in the district of North Kinta, Perak,
Malaysia. Data were obtained from 164 respondents who answered
Expectation Alignment Understanding and Practices of School
Assessment (PEKDAPS) questionnaire. The data were analysed
using SPSS 17.0+. The Cronbach’s alpha value obtained through
PEKDAPS questionnaire pilot study was 0.86. The results showed
that teachers' performance in PEKDAPS based on the mean value
was less than 3, which means that perfect alignment does not occur
between the understanding and practices of school assessment. Two
major PEKDAPS sub-constructs of articulation across grade and age
and usability of the system were higher than the moderate alignment
of the understanding and practices of school assessment (Min=2.0).
The content focused of PEKDAPs sub-constructs which showed
lower than the moderate alignment of the understanding and practices
of school assessment (Min=2.0). Another two PEKDAPS subconstructs
of transparency and fairness and the pedagogical
implications showed moderate alignment (2.0). The implications of
the study is that teachers need to fully understand the importance of
alignment among components of assessment, learning and teaching
and learning objectives as strategies to achieve quality assessment
process.
Abstract: Urban Search and Rescue (USAR) is a functional
capability that has been developed to allow the United Kingdom Fire
and Rescue Service to deal with ‘major incidents’ primarily involving
structural collapse. The nature of the work undertaken by USAR
means that staying out of a damaged or collapsed building structure is
not usually an option for search and rescue personnel. As a result
there is always a risk that they themselves could become victims. For
this paper, a systematic and investigative review using desk research
was undertaken to explore the role which structural engineering can
play in assisting search and rescue personnel to conduct structural
assessments when in the field. The focus is on how search and rescue
personnel can assess damaged and collapsed building structures, not
just in terms of structural damage that may been countered, but also
in relation to structural stability. Natural disasters, accidental
emergencies, acts of terrorism and other extreme events can vary
significantly in nature and ferocity, and can cause a wide variety of
damage to building structures. It is not possible or, even realistic, to
provide search and rescue personnel with definitive guidelines and
procedures to assess damaged and collapsed building structures as
there are too many variables to consider. However, understanding
what implications damage may have upon the structural stability of a
building structure will enable search and rescue personnel to better judge
and quantify risk from a life-safety standpoint. It is intended that this
will allow search and rescue personnel to make informed decisions
and ensure every effort is made to mitigate risk, so that they
themselves do not become victims.
Abstract: The building sector is responsible, in many
industrialized countries, for about 40% of the total energy
requirements, so it seems necessary to devote some efforts in this
area in order to achieve a significant reduction of energy
consumption and of greenhouse gases emissions.
The paper presents a study aiming at providing a design
methodology able to identify the best configuration of the system
building/plant, from a technical, economic and environmentally point
of view.
Normally, the classical approach involves a building's energy
loads analysis under steady state conditions, and subsequent selection
of measures aimed at improving the energy performance, based on
previous experience made by architects and engineers in the design
team. Instead, the proposed approach uses a sequence of two wellknown
scientifically validated calculation methods (TRNSYS and
RETScreen), that allow quite a detailed feasibility analysis.
To assess the validity of the calculation model, an existing,
historical building in Central Italy, that will be the object of
restoration and preservative redevelopment, was selected as a casestudy.
The building is made of a basement and three floors, with a
total floor area of about 3,000 square meters.
The first step has been the determination of the heating and
cooling energy loads of the building in a dynamic regime by means,
which allows simulating the real energy needs of the building in
function of its use. Traditional methodologies, based as they are on
steady-state conditions, cannot faithfully reproduce the effects of
varying climatic conditions and of inertial properties of the structure.
With this model is possible to obtain quite accurate and reliable
results that allow identifying effective combinations building-HVAC
system.
The second step has consisted of using output data obtained as
input to the calculation model, which enables to compare different
system configurations from the energy, environmental and financial
point of view, with an analysis of investment, and operation and
maintenance costs, so allowing determining the economic benefit of
possible interventions.
The classical methodology often leads to the choice of
conventional plant systems, while our calculation model provides a
financial-economic assessment for innovative energy systems and
low environmental impact.
Computational analysis can help in the design phase, particularly
in the case of complex structures with centralized plant systems, by
comparing the data returned by the calculation model for different
design options.
Abstract: Attributes and methods are the basic contents of an
object-oriented class. The connectivity among these class members
and the relationship between the class and other classes play an
important role in determining the quality of an object-oriented
system. Class cohesion evaluates the degree of relatedness of class
attributes and methods, whereas class coupling refers to the degree to
which a class is related to other classes. Researchers have proposed
several class cohesion and class coupling measures. However, the
correlation between class coupling and class cohesion measures has
not been thoroughly studied. In this paper, using classes of three
open-source Java systems, we empirically investigate the correlation
between several measures of connectivity-based class cohesion and
coupling. Four connectivity-based cohesion measures and eight
coupling measures are considered in the empirical study. The
empirical study results show that class connectivity-based cohesion
and coupling internal quality attributes are inversely correlated. The
strength of the correlation depends highly on the cohesion and
coupling measurement approaches.
Abstract: Thin-walled elements with a matrix set on a base of
high-valuable Portland cement with dispersed reinforcement from
alkali-resistant glass fibres are used in a range of applications as
claddings of buildings and infrastructure constructions as well as
various architectural elements of residential buildings.
Even though their elementary thickness and therefore total weight
is quite low, architects and building companies demand on even
further decreasing of the bulk density of these fibre-cement elements
for the reason of loading elimination of connected superstructures
and easier assembling in demand conditions.
By the means of various kinds of light-weight aggregates it is
possible to achieve light-weighing of these composite elements.
From the range of possible fillers with different material properties
granulated expanded glass worked the best.
By the means of laboratory testing an effect of two fillers based on
expanded glass on the fibre reinforced cement composite was
verified.
Practical applicability was tested in the production of commonly
manufactured glass fibre reinforced concrete elements, such as
channels for electrical cable deposition, products for urban equipment
and especially various cladding elements.
Even though these are not structural elements, it is necessary to
evaluate also strength characteristics and resistance to environment
for their durability in certain applications.
Abstract: Pulmonary Function Tests are important non-invasive
diagnostic tests to assess respiratory impairments and provides
quantifiable measures of lung function. Spirometry is the most
frequently used measure of lung function and plays an essential role
in the diagnosis and management of pulmonary diseases. However,
the test requires considerable patient effort and cooperation,
markedly related to the age of patients resulting in incomplete data
sets. This paper presents, a nonlinear model built using Multivariate
adaptive regression splines and Random forest regression model to
predict the missing spirometric features. Random forest based feature
selection is used to enhance both the generalization capability and the
model interpretability. In the present study, flow-volume data are
recorded for N= 198 subjects. The ranked order of feature importance
index calculated by the random forests model shows that the
spirometric features FVC, FEF25, PEF, FEF25-75, FEF50 and the
demographic parameter height are the important descriptors. A
comparison of performance assessment of both models prove that, the
prediction ability of MARS with the `top two ranked features namely
the FVC and FEF25 is higher, yielding a model fit of R2= 0.96 and
R2= 0.99 for normal and abnormal subjects. The Root Mean Square
Error analysis of the RF model and the MARS model also shows that
the latter is capable of predicting the missing values of FEV1 with a
notably lower error value of 0.0191 (normal subjects) and 0.0106
(abnormal subjects) with the aforementioned input features. It is
concluded that combining feature selection with a prediction model
provides a minimum subset of predominant features to train the
model, as well as yielding better prediction performance. This
analysis can assist clinicians with a intelligence support system in the
medical diagnosis and improvement of clinical care.
Abstract: The Malaysian government had consistently revived
its campaign for “Buy Malaysian Goods” from time to time. The
purpose of the campaign is to remind consumers to be ethnocentric
and patriotic when purchasing product and services. This is necessary
to ensure high demand for local products and services compared to
foreign products. However, the decline of domestic investment in
2012 has triggered concern for the Malaysian economy. Hence, this
study attempts to determine the drivers of actual purchasing behavior,
intention to purchase domestic products and ethnocentrism. The
study employs the cross-sectional primary data, self-administered on
household, selected using stratified random sampling in four
Malaysian regions. A nine factor driver of actual domestic purchasing
behavior (culture openness, conservatism, collectivism, patriotism,
control belief, interest in foreign travel, attitude, ethnocentrism and
intention) were measured utilizing 60 items, using 7-point Likertscale.
From 1000 questionnaires distributed, a sample of 486 were
returned representing 48.6 percent response rate. From the fit
generated structural model (SEM analysis), it was found that the
drivers of actual purchase behavior are collectivism, cultural
openness and patriotism; the drivers of intention to purchase
domestic product are attitude, control belief, collectivism and
conservatism; and drivers of ethnocentrism are cultural openness,
control belief, foreign travel and patriotism. It also shows that
Malaysian consumers scored high in ethnocentrism and patriotism.
The findings are discussed in the perspective of its implication to
Malaysian National Agenda.
Abstract: This work deals with parameter identification of
permanent magnet motors, a class of ac motor which is particularly
important in industrial automation due to characteristics like
applications high performance, are very attractive for applications
with limited space and reducing the need to eliminate because they
have reduced size and volume and can operate in a wide speed range,
without independent ventilation. By using experimental data and
genetic algorithm we have been able to extract values for both the
motor inductance and the electromechanical coupling constant, which
are then compared to measured and/or expected values.
Abstract: This research has been conducted to study the method
of culture and comparing growth and biomass of Gracilaria corticata
cultured on rope and net for 50 days through two treatments (first
treatment: culture of alga on net and the second treatment: culture of
alga on rope and each treatment was repeated by four cases). During
culture period, the water of aquariums was replaced once every two
days for 40-50%. Also, 0.3-0.5 grams of urea fertilizer was added to
the culture environment for fertilization. Moreover, some of the
environmental factors such as pH, salinity and temperature of the
environment were measured on a daily basis. During the culture
period, extent of longitudinal growth of the species of both treatments
was equal. The said length was reached from 8-10 cm to 10.5-13 cm
accordingly. The resulted weight in repetitions of the first treatment
was higher than that of the second treatment in such a way as in the
first treatment, its weight reached from 10 grams to 21.119 grams and
in the second treatment, its weight reached from 10 grams to 17.663
grams. On a whole, it may be stated that that kind of alga being
studied has a considerable growth with respect to its volume. The
results have revealed that the percentage of daily growth and wet
weight at the end of the first treatment was higher than that of the
second treatment and it was registered as 0.934, 6.072 and 811.432 in
the first treatment and 0.797, 4.990 and 758.071 in the second
treatment respectively. This difference is significant (P
Abstract: Over the past four decades, the fatigue behavior of
nickel-based alloys has been widely studied. However, in recent
years, significant advances in the fabrication process leading to grain
size reduction have been made in order to improve fatigue properties
of aircraft turbine discs. Indeed, a change in particle size affects the
initiation mode of fatigue cracks as well as the fatigue life of the
material. The present study aims to investigate the fatigue behavior of
a newly developed nickel-based superalloy under biaxial-planar
loading. Low Cycle Fatigue (LCF) tests are performed at different
stress ratios so as to study the influence of the multiaxial stress state
on the fatigue life of the material. Full-field displacement and strain
measurements as well as crack initiation detection are obtained using
Digital Image Correlation (DIC) techniques. The aim of this
presentation is first to provide an in-depth description of both the
experimental set-up and protocol: the multiaxial testing machine, the
specific design of the cruciform specimen and performances of the
DIC code are introduced. Second, results for sixteen specimens
related to different load ratios are presented. Crack detection, strain
amplitude and number of cycles to crack initiation vs. triaxial stress
ratio for each loading case are given. Third, from fractographic
investigations by scanning electron microscopy it is found that the
mechanism of fatigue crack initiation does not depend on the triaxial
stress ratio and that most fatigue cracks initiate from subsurface
carbides.