Abstract: Polymer-like organic thin films were deposited on both
aluminum alloy type 6061 and glass substrates at room temperature by
Plasma Enhanced Chemical Vapor Deposition (PECVD) methodusing
benzene and hexamethyldisiloxane (HMDSO) as precursor materials.
The surface and physical properties of plasma-polymerized organic
thin films were investigated at different r.f. powers. The effects of
benzene/argon ratio on the properties of plasma polymerized benzene
films were also investigated. It is found that using benzene alone
results in a non-coherent and non-adherent powdery deposited
material. The chemical structure and surface properties of the asgrown
plasma polymerized thin films were analyzed on glass
substrates with FTIR and contact angle measurements. FTIR spectra
of benzene deposited film indicated that the benzene rings are
preserved when increasing benzene ratio and/or decreasing r.f.
powers. FTIR spectra of HMDSO deposited films indicated an
increase of the hydrogen concentration and a decrease of the oxygen
concentration with the increase of r.f. power. The contact angle (θ) of
the films prepared from benzene was found to increase by about 43%
as benzene ratio increases from 10% to 20%. θ was then found to
decrease to the original value (51°) when the benzene ratio increases
to 100%. The contact angle, θ, for both benzene and HMDSO
deposited films were found to increase with r.f. power. This signifies
that the plasma polymerized organic films have substantially low
surface energy as the r.f power increases. The corrosion resistance of
aluminum alloy substrate both bare and covered with plasma
polymerized thin films was carried out by potentiodynamic
polarization measurements in standard 3.5 wt. % NaCl solution at
room temperature. The results indicate that the benzene and HMDSO
deposited films are suitable for protection of the aluminum substrate
against corrosion. The changes in the processing parameters seem to
have a strong influence on the film protective ability. Surface
roughness of films deposited on aluminum alloy substrate was
investigated using scanning electron microscopy (SEM). The SEM
images indicate that the surface roughness of benzene deposited films
increase with decreasing the benzene ratio. SEM images of benzene
and HMDSO deposited films indicate that the surface roughness
decreases with increasing r.f. power. Studying the above parameters
indicate that the films produced are suitable for specific practical
applications.
Abstract: The aim of this study is to analyze influence of
differences of heat insulation methods on indoor thermal environment and comfort of apartment buildings.
This study analyzes indoor thermal environment and comfort on units of apartment buildings using calculation software "THERB" and
compares three different kinds of heat insulation methods. Those are
outside insulation on outside walls, inside insulation on outside walls and interior insulation. In terms of indoor thermal environment, outside insulation is the best to stabilize room temperature. In winter, room temperature on
outside insulation after heating is higher than other and it is kept 3-5 degrees higher through all night. But the surface temperature with
outside insulation did not dramatically increase when heating was used, which was 3 to 5oC lower than the temperature with other
insulation. The PMV of interior insulation fall nearly range of comfort when the heating and cooling was use.
Abstract: This paper studies the optimum design for reducing
optical loss of an 8x8 mechanical type optical switch due to the
temperature change. The 8x8 optical switch is composed of a base, 8
input fibers, 8 output fibers, 3 fixed mirrors and 17 movable mirrors.
First, an innovative switch configuration is proposed with
thermal-compensated design. Most mechanical type optical switches
have a disadvantage that their precision and accuracy are influenced
by the ambient temperature. Therefore, the thermal-compensated
design is to deal with this situation by using materials with different
thermal expansion coefficients (α). Second, a parametric modeling
program is developed to generate solid models for finite element
analysis, and the thermal and structural behaviors of the switch are
analyzed. Finally, an integrated optimum design program, combining
Autodesk Inventor Professional software, finite element analysis
software, and genetic algorithms, is developed for improving the
thermal behaviors that the optical loss of the switch is reduced. By
changing design parameters of the switch in the integrated design
program, the final optimum design that satisfies the design constraints
and specifications can be found.
Abstract: This study fabricates p-type Ni1−xO:Li/n-Si heterojunction solar cells (P+/n HJSCs) by using radio frequency (RF) magnetron sputtering and investigates the effect of substrate temperature on photovoltaic cell properties. Grazing incidence x-ray diffraction, four point probe, and ultraviolet-visible-near infrared discover the optoelectrical properties of p-Ni1-xO thin films. The results show that p-Ni1-xO thin films deposited at 300 oC has the highest grain size (22.4 nm), average visible transmittance (~42%), and electrical resistivity (2.7 Ωcm). However, the conversion efficiency of cell is shown only 2.33% which is lower than the cell (3.39%) fabricated at room temperature. This result can be mainly attributed to interfacial layer thickness (SiOx) reduces from 2.35 nm to 1.70 nm, as verified by high-resolution transmission electron microscopy.
Abstract: In this paper, an approach for finding optimized
layouts for connecting PV units delivering maximum array output
power is suggested. The approach is based on considering the
different varying parameters of PV units that might be extracted from
a general two-diode model. These are mainly, solar irradiation,
reverse saturation currents, ideality factors, series and shunt
resistances in addition to operating temperature. The approach has
been tested on 19 possible 2×3 configurations and allowed to
determine the optimized configurations as well as examine the effects
of the different units- parameters on the maximum output power.
Thus, using this approach, standard arrays with n×m units can be
configured for maximum generated power and allows designing PV
based systems having reduced surfaces to fit specific required power,
as it is the case for solar cars and other mobile systems.
Abstract: In the gas refineries of Iran-s South Pars Gas
Complex, Sulfrex demercaptanization process is used to remove
volatile and corrosive mercaptans from liquefied petroleum gases by
caustic solution. This process consists of two steps. Removing low
molecular weight mercaptans and regeneration exhaust caustic. Some
parameters such as LPG feed temperature, caustic concentration and
feed-s mercaptan in extraction step and sodium mercaptide content in
caustic, catalyst concentration, caustic temperature, air injection rate
in regeneration step are effective factors. In this paper was focused on
temperature factor that play key role in mercaptans extraction and
caustic regeneration. The experimental results demonstrated by
optimization of temperature, sodium mercaptide content in caustic
because of good oxidation minimized and sulfur impurities in
product reduced.
Abstract: In the Northern hemisphere, sheep reproduction is
seasonal (September-November). Among several natural factors
influencing the reproduction status of rams, we studied the daylight
length and temperature. Rams from different breeds were studied:
Merinos de Palas (half-precocious), Karakul de Botosani (halfbelated)
and Turcana (belated breed, low reproductive plasticity). In
Merinos de Palas, ejaculate volume during sexual repose is 51.3%
from normal quantity. When autumn climate was experimentally
induced, ejaculate volume reached 98.45% (Merinos), 94.97%
(Karakul) and 97.59% (Turcana). Semen density increased from
1.031-1.033 till 1.035 after exposition to artificial light and
temperature conditions. Spermatozoids mobility and sperm pH
improved, passing over 82% and 6.75, values identical to those in the
natural reproduction season. Behaviour analysis after
photoperiodicity indicated that over 83.3% Merinos and Karakul
males and all Turcana rams exteriorised normal and intense sexual
reflexes. Certain effort and reduced expenses brought rams in good
condition, producing higher quantity and quality sperm.
Abstract: Noble metal participation in nanostructured
semiconductor catalysts has drawn much interest because of their
improved properties. Recently, it has been discussed by many
researchers that Ag participation in TiO2, CuO, ZnO semiconductors
showed improved photocatalytic and optical properties. In this
research, Ag/ZnO nanocomposite particles were prepared by
Ultrasonic Spray Pyrolysis(USP) Method. 0.1M silver and zinc
nitrate aqueous solutions were used as precursor solutions. The
Ag:Zn atomic ratio of the solution was selected 1:1. Experiments
were taken place under constant air flow of 400 mL/min at 800°C
furnace temperature. Particles were characterized by X-Ray
Diffraction (XRD), Scanning Electron Microscope (SEM) and
Energy Dispersive Spectroscopy (EDS). The crystallite sizes of Ag
and ZnO in composite particles are 24.6 nm, 19.7 nm respectively.
Although, spherical nanocomposite particles are in a range of 300-
800 nm, these particles are formed by the aggregation of primary
particles which are in a range of 20-60 nm.
Abstract: In the last decade, carbohydrates have attracted great
attention as renewable resources for the chemical industry.
Carbohydrates are abundantly found in nature in the form of
monomers, oligomers and polymers, or as components of
biopolymers and other naturally occurring substances. As natural
products, they play important roles in conferring certain physical,
chemical, and biological properties to their carrier molecules.The
synthesis of this particular carbohydrate glycomonomer is part of our
work to obtain biodegradable polymers. Our current paper describes
the synthesis and characterization of a novel carbohydrate
glycomonomer starting from D-glucose, in several synthesis steps,
that involve the protection/deprotection of the D-glucose ring via
acetylation, tritylation, then selective deprotection of the aromaticaliphatic
protective group, in order to obtain 1,2,3,4-tetra-O-acetyl-
6-O-allyl-β-D-glucopyranose. The glycomonomer was then obtained
by the allylation in drastic conditions of 1,2,3,4-tetra-O-acetyl-6-Oallyl-
β-D-glucopyranose with allylic alcohol in the presence of
stannic chloride, in methylene chloride, at room temperature. The
proposed structure of the glycomonomer, 2,3,4-tri-O-acetyl-1,6-di-
O-allyl-β-D-glucopyranose, was confirmed by FTIR, NMR and
HPLC-MS spectrometry. This glycomonomer will be further
submitted to copolymerization with certain acrylic or methacrylic
monomers in order to obtain competitive plastic materials for
applications in the biomedical field.
Abstract: To calculate the temperature distribution of the slab in
a hot rolled reheating furnace a mathematical model has been
developed by considering the thermal radiation in the furnace and
transient conduction in the slab. The furnace is modeled as radiating
medium with spatially varying temperature. Radiative heat flux within
the furnace including the effect of furnace walls, combustion gases,
skid beams and buttons is calculated using the FVM and is applied as
the boundary condition of the transient conduction equation of the
slab. After determining the slab emissivity by comparison between
simulation and experimental work, variation of heating characteristics
in the slab is investigated in the case of changing furnace temperature
with various time and the slab residence time is optimized with this
evaluation.
Abstract: Temperature is one of the most principle factors affects aquaculture system. It can cause stress and mortality or superior environment for growth and reproduction. This paper presents the control of pond water temperature using artificial intelligence technique. The water temperature is very important parameter for shrimp growth. The required temperature for optimal growth is 34oC, if temperature increase up to 38oC it cause death of the shrimp, so it is important to control water temperature. Solar thermal water heating system is designed to supply an aquaculture pond with the required hot water in Mersa Matruh in Egypt. Neural networks are massively parallel processors that have the ability to learn patterns through a training experience. Because of this feature, they are often well suited for modeling complex and non-linear processes such as those commonly found in the heating system. Artificial neural network is proposed to control water temperature due to Artificial intelligence (AI) techniques are becoming useful as alternate approaches to conventional techniques. They have been used to solve complicated practical problems. Moreover this paper introduces a complete mathematical modeling and MATLAB SIMULINK model for the aquaculture system. The simulation results indicate that, the control unit success in keeping water temperature constant at the desired temperature by controlling the hot water flow rate.
Abstract: Dehydration process was carried out for tomato slices of var. Avinash after giving different pre-treatments such as calcium chloride (CaCl2), potassium metabisulphite (KMS), calcium chloride and potassium metabisulphite (CaCl2 +KMS), and sodium chloride (NaCl). Untreated samples served as control. Solar drier and continuous conveyor (tunnel) drier were used for dehydration. Quality characteristics of tomato slices viz. moisture content, sugar, titratable acidity, lycopene content, dehydration ratio, rehydration ratio and non-enzymatic browning as affected by dehydration process were studied. Storage study was also carried out for a period of six months for tomato powder packed into different types of packaging materials viz. metalized polyester (MP) film and low density poly ethylene (LDPE). Changes in lycopene content and non-enzymatic browning (NEB) were estimated during storage at room temperature. Pretreatment of 5 mm thickness of tomato slices with calcium chloride in combination with potassium metabisulphite and drying using a tunnel drier with subsequent storage of product in metalized polyester bags was selected as the best process.
Abstract: The concerns about clean environment and high oil
prices driving forces for the research on alternative fuels. The
research efforts directed towards improving the performance of C.I
engines using vegetable oil as fuel. The paper deals results of
performance of a four stroke, single cylinder C.I. engine by preheated
neat Karanja oil is done from 30
o
C to 100
o
C. The performance of the
engine was studied for a speed range between 1500 to 4000 rpm, with
the engine operated under full load conditions. The performance
parameters considered for comparing are brake specific fuel
consumption, thermal efficiency, brake power, Nox emission of the
engine. The engine offers lower thermal efficiency when it is
powered by preheated neat Karanja oil at higher speed. The power
developed and Nox emission increase with the increase in the fuel
inlet temperature and the specific fuel consumption is higher than
diesel fuel operation at all elevated fuel inlet temperature.
Abstract: Ti-6Al-4V alloy has demonstrated a high strength to
weight ratio as well as good properties at high temperature. The
successful application of the alloy in some important areas depends
on suitable joining techniques. Friction welding has many
advantageous features to be chosen for joining Titanium alloys. The
present work investigates the feasibility of producing similar metal
joints of this Titanium alloy by rotary friction welding method. The
joints are produced at three different speeds and the performances of
the welded joints are evaluated by conducting microstructure studies,
Vickers Hardness and tensile tests at the joints. It is found that the
weld joints produced are sound and the ductile fractures in the tensile
weld specimens occur at locations away from the welded joints. It is
also found that a rotational speed of 1500 RPM can produce a very
good weld, with other parameters kept constant.
Abstract: This research is to study the performance of heat
pump dryer for drying of kaffir lime leaves under different media and
to compare the color values and essential oil content of final products
after drying. In the experiments, kaffir lime leaves were dried in the
closed-loop system at drying temperatures of 40, 50 and 60 oC. The
drying media used in this study were hot air, CO2 and N2 gases. The
velocity of drying media in the drying chamber was 0.4 m/s with
bypass ratio of 30%. The initial moisture content of kaffir lime leaves
was approximately 180-190 % d.b. It was dried until down to a final
moisture content of 10% d.b. From the experiments, the results
showed that drying rate, the coefficient of performance (COP) and
specific energy consumption (SEC) depended on drying temperature.
While drying media did not affect on drying rate. The time for kaffir
lime leaves drying at 40, 50 and 60 oC was 10, 5 and 3 hours,
respectively. The performance of the heat pump system decreased
with drying temperature in the range of 2.20-3.51. In the aspect of
final product color, the greenness and overall color had a great
change under drying temperature at 60 oC rather than drying at 40
and 50 oC. When compared among drying media, the greenness and
overall color of product dried with hot air at 60 oC had a great change
rather than dried with CO2 and N2.
Abstract: Nanowire arrays of copper with uniform diameters have
been synthesized by potentiostatic electrochemical metal deposition
(EMD) of copper sulphate and potassium chloride solution within
the nano-channels of porous Indium-Tin Oxide (ITO), also known as
Tin doped Indium Oxide templates. The nanowires developed were
fairly continuous with diameters ranging from 110-140 nm along
the entire length. Single as well as poly-crystalline copper wires
have been prepared by application of appropriate potential during the
EMD process. Scanning electron microscopy (SEM), high resolution
transmission electron microscopy (HRTEM), small angle electron
diffraction (SAED) and atomic force microscopy (AFM) were used
to characterize the synthesized nano wires at room temperature. The
electrochemical response of synthesized products was evaluated by
cyclic voltammetry while surface energy analysis was carried out
using a Goniometer.
Abstract: The copper flotation tailings from Konkola Copper
mine in Nchanga, Zambia were used in the study. The purpose of this
study was to determine the leaching characteristics of the tailings
material prior and after the physical beneficiation process is
employed. The Knelson gravity concentrator (KC-MD3) was used for
the beneficiation process. The copper leaching efficiencies and
impurity co-extraction percentages in both the upgraded and the raw
feed material were determined at different pH levels and temperature.
It was observed that the copper extraction increased with an increase
in temperature and a decrease in pH levels. In comparison to the raw
feed sample, the upgraded sample reported a maximum copper
extraction of 69% which was 9%, higher than raw feed % extractions.
The impurity carry over was reduced from 18% to 4 % on the
upgraded sample. The reduction in impurity co-extraction was as a
result of the removal of the reactive gangue elements during the
upgrading process, this minimized the number of side reaction
occurring during leaching.
Abstract: Nonlinear solitary structures of electron plasma waves
have been investigated by using nonlinear quantum fluid equations for electrons with an arbitrary temperature. It is shown that the electron degeneracy parameter has significant effects on the linear and nonlinear properties of electron plasma waves. Depending on its
value both compressive and rarefactive solitons can be excited in the model plasma under consideration.
Abstract: This paper presents a cold chain monitoring system which focuses on assessment of quality and dynamic pricing information about food in cold chain. Cold chain is composed of many actors and stages; however it can be seen as a single entity since a breakdown in temperature control at any stage can impact the final quality of the product. In a cold chain, the shelf life, quality, and safety of perishable food throughout the supply chain is greatly impacted by environmental factors especially temperature. In this paper, a prototype application is implemented to retrieve timetemperature history, the current quality and the dynamic price setting according to changing quality impacted by temperature fluctuations in real-time.
Abstract: The winding hot-spot temperature is one of the most
critical parameters that affect the useful life of the power
transformers. The winding hot-spot temperature can be calculated as
function of the top-oil temperature that can estimated by using the
ambient temperature and transformer loading measured data. This
paper proposes the estimation of the top-oil temperature by using a
method based on Least Squares Support Vector Machines approach.
The estimated top-oil temperature is compared with measured data of
a power transformer in operation. The results are also compared with
methods based on the IEEE Standard C57.91-1995/2000 and
Artificial Neural Networks. It is shown that the Least Squares
Support Vector Machines approach presents better performance than
the methods based in the IEEE Standard C57.91-1995/2000 and
artificial neural networks.