Abstract: The paper presents a computational tool developed for
the evaluation of technical and economic advantages of an innovative
cleaning and conditioning technology of fluidized bed steam/oxygen
gasifiers outlet product gas. This technology integrates into a single
unit the steam gasification of biomass and the hot gas cleaning and
conditioning system. Both components of the computational tool,
process flowsheet and economic evaluator, have been developed
under IPSEpro software. The economic model provides information
that can help potential users, especially small and medium size
enterprises acting in the regenerable energy field, to decide the
optimal scale of a plant and to better understand both potentiality and
limits of the system when applied to a wide range of conditions.
Abstract: The separation of dissolved gas including dissolved oxygen can be used in breathing for a human under water. When one is suddenly wrecked or meets a tsunami, one is instantly drowned and cannot breathe under water. To avoid this crisis, when we meet waves, the dissolved gas separated from water by wave is used, while air can be used to breathe when we are about to escape from water. In this thesis, we investigated the separation characteristics of dissolved gas using the pipe type of hollow fiber membrane with polypropylene and the nude type of one with polysulfone. The hollow fiber membranes with good characteristics under water are used to separate the dissolved gas. The hollow fiber membranes with good characteristics in an air are used to transfer air. The combination of membranes with good separation characteristics under water and good transferring one in an air is used to breathe instantly under water to be alive at crisis. These results showed that polypropylene represented better performance than polysulfone under both of air and water conditions.
Abstract: The research object was wheat bread. Experiments
were carried out at the Faculty of Food Technology of the Latvia
University of Agriculture. An active packaging in combination with
modified atmosphere (MAP, CO2 60% and N2 40%) was examined
and compared with traditional packaging in air ambiance. Polymer
Multibarrier 60, PP and OPP bags were used. Influence of iron based
oxygen absorber in sachets of 100 cc obtained from Mitsubishi Gas
Chemical Europe Ageless® was tested on the quality during the shelf
of wheat bread. Samples of 40±4 g were packaged in polymer
pouches (110 mm x 120 mm), hermetically sealed by MULTIVAC
C300 vacuum chamber machine, and stored in room temperature
+21.0±0.5 °C. The physiochemical properties – weight losses,
moisture content, hardness, pH, colour, changes of atmosphere
content (CO2 and O2) in headspace of packs, and microbial
conditions were analysed before packaging and in the 7th, 14th, 21st
and 28th days of storage.
Abstract: Hydrogenated biodiesel is one of the most promising
renewable fuels. It has many advantages over conventional biodiesel,
including higher cetane number, higher heating value, lower
viscosity, and lower corrosiveness due to its absence of oxygen.
From previous work, Pd/TiO2 gave high conversion and selectivity in
hydrogenated biodiesel. In this work, the effect of biomass feedstocks
(i.e. beef fat, chicken fat, pork fat, and jatropha oil) on the production
of hydrogenated biodiesel over Pd/TiO2 has been studied. Biomass
feedstocks were analyzed by ICP-OES (inductively coupled plasma
optical emission spectrometry) to identify the content of impurities
(i.e. P, K, Ca, Na, and Mg). The deoxygenation catalyst, Pd/TiO2,
was prepared by incipient wetness impregnation (IWI) and tested in a
continuous flow packed-bed reactor at 500 psig, 325°C, H2/feed
molar ratio of 30, and LHSV of 4 h-1 for its catalytic activity and
selectivity in hydrodeoxygenation. All feedstocks gave high
selectivity in diesel specification range hydrocarbons and the main
hydrocarbons were n-pentadecane (n-C15) and n-heptadecane (n-
C17), resulting from the decarbonylation/decarboxylation reaction.
Intermediates such as oleic acid, stearic acid, palmitic acid, and esters
were also detected in minor amount. The conversion of triglycerides
in jatropha oil is higher than those of chicken fat, pork fat, and beef
fat, respectively. The higher concentration of metal impurities in
feedstock, the lower conversion of feedstock.
Abstract: Three sulphonic acid-doped polyanilines were
synthesized through chemical oxidation at low temperature (0-5 oC)
and potential of these polymers as sensing agent for O2 gas detection
in terms of fluorescence quenching was studied. Sulphuric acid,
dodecylbenzene sulphonic acid (DBSA) and camphor sulphonic acid
(CSA) were used as doping agents. All polymers obtained were dark
green powder. Polymers obtained were characterized by Fourier
transform infrared spectroscopy, ultraviolet-visible absorption
spectroscopy, thermogravimetry analysis, elemental analysis,
differential scanning calorimeter and gel permeation
chromatography. Characterizations carried out showed that polymers
were successfully synthesized with mass recovery for sulphuric aciddoped
polyaniline (SPAN), DBSA-doped polyaniline (DBSA-doped
PANI) and CSA-doped polyaniline (CSA-doped PANI) of 71.40%,
75.00% and 39.96%, respectively. Doping level of SPAN, DBSAdoped
PANI and CSA-doped PANI were 32.86%, 33.13% and
53.96%, respectively as determined based on elemental analysis.
Sensing test was carried out on polymer sample in the form of
solution and film by using fluorescence spectrophotometer. Samples
of polymer solution and polymer film showed positive response
towards O2 exposure. All polymer solutions and films were fully
regenerated by using N2 gas within 1 hour period. Photostability
study showed that all samples of polymer solutions and films were
stable towards light when continuously exposed to xenon lamp for 9
hours. The relative standard deviation (RSD) values for SPAN
solution, DBSA-doped PANI solution and CSA-doped PANI
solution for repeatability were 0.23%, 0.64% and 0.76%,
respectively. Meanwhile RSD values for reproducibility were 2.36%,
6.98% and 1.27%, respectively. Results for SPAN film, DBSAdoped
PANI film and CSA-doped PANI film showed the same
pattern with RSD values for repeatability of 0.52%, 4.05% and
0.90%, respectively. Meanwhile RSD values for reproducibility were
2.91%, 10.05% and 7.42%, respectively. The study on effect of the
flow rate on response time was carried out using 3 different rates
which were 0.25 mL/s, 1.00 mL/s and 2.00 mL/s. Results obtained
showed that the higher the flow rate, the shorter the response time.
Abstract: Oxygen and carbon isotopes records of multi-species planktonic, benthic foraminifera and bulk carbonate sample from Central Java Indonesia demonstrate that warm sea surface temperature occurred during the Miocene. Planktonic δ18O values from this study consistently lighter (-4 to -3 ‰PDB) than previous studies that indicate sea surface temperature during Miocene in this area was warm than tropical/equatorial localities. A surprising decrease of oxygen isotopic composition was recorded at ±14 Ma where the maximum of δ18O values is -4.87 ‰PDB for Orbulina universa, -5.02 ‰PDB for Globigerinoides sacculifer and -4.30 ‰PDB for Globoquadrina dehiscens, this event we predict as Middle Miocene Optimum. Warming of sea surface temperature we interpret as related to the development of Western Pacific Warm Pool where warm water from Pacific Ocean through the Indonesian seaway appears to remain during Miocene. Our result also show increasing suddenly of oxygen isotope values of planktic, benthic and bulk carbonate sample from ± 12 Ma, the increasing cooled surface water relatively high degree with Late Miocene global cooling climate or we predict that due to closing of Indonesian Gateway.
Abstract: In this study Vitaton (an organic supplement which
contains fermentative β-carotene) and synthetic astaxanthin
(CAROPHYLL® Pink) were evaluated as pro-growth factors in
Rainbow trout diet. An 8 week feeding trial was conducted to
determine the effects of Vitaton versus astaxanthin on rearing factors,
survival rate and visual flesh color of Rainbow trout
(Oncorhnchynchus mykiss) with initial weight of 196±5. Four
practical diets were formulated to contain 50 and 80 (ppm) of β-
carotene and astaxanthin and also a control diet was prepared without
any pigment. Each diet was fed to triplicate groups of fish rearing in
fresh water. Fish were fed twice daily. The water temperature
fluctuated from 12 to 15 (C˚) and also dissolved oxygen content was
between 7 to 7.5 (mg/lit) during the experimental period. At the end
of the experiment, growth and food utilization parameters and
survival rate were unaffected by dietary treatments (p>0.05). Also,
there was no significant difference between carcass yield within
treatments (p>0.05). No significant difference recognized between
visual flesh color (SalmoFan score) of fish fed Vitaton-containing
diets. On the contrary, feeding on diets containing 50 and 80 (ppm)
of astaxanthin, increased SalmoFan score (flesh astaxanthin
concentration) from
Abstract: Oxidative stress makes up common incidents in
eukaryotic metabolism. The presence of diverse components
disturbing the equilibrium during oxygen metabolism increases
oxidative damage unspecifically in living cells. Body´s own
ubiquinone (Q10) seems to be a promising drug in defending the
heightened appearance of reactive oxygen species (ROS). Though, its
lipophilic properties require a new strategy in drug formulation to
overcome their low bioavailability. Consequently, the manufacture of
heterogeneous nanodispersions is in focus for medical applications.
The composition of conventional nanodispersions is made up of a
drug-consisting core and a surfactive agent, also named as surfactant.
Long-termed encapsulation of the surfactive components into tissues
might be the consequence of the use during medical therapeutics. The
potential of provoking side-effects is given by their nonbiodegradable
properties. Further improvements during fabrication
process use the incorporation of biodegradable components such as
modified γ-polyglutamic acid which decreases the potential of
prospective side-effects.
Abstract: The nature of adsorbed species on catalytic surface
over an industrial precipitated iron-based high temperature catalyst
during FTS was investigated by in-situ DRIFTS and chemical
trapping. The formulation of the mechanism of oxygenates formation
and key intermediates were also discussed. Numerous oxygenated
precursors and crucial intermediates were found by in-situ DRIFTS,
such as surface acetate, acetyl and methoxide. The results showed that
adsorbed molecules on surface such as methanol or acetaldehyde
could react with basic sites such as lattice oxygen or free surface
hydroxyls. Adsorbed molecules also had reactivity of oxidizing.
Moreover, acetyl as a key intermediate for oxygenates was observed
by investigation of CH3OH + CO and CH3I + CO + H2. Based on the
nature of surface properties, the mechanism of oxygenates formation
on precipitated iron-based high temperature catalyst was discussed.
Abstract: Our results showed that treatment with both
cyclooxygenase (COX1 or COX2) inhibitors impair reproduction
parameters of the medaka. Resveratrol (COX1 inhibitor) caused an
decrease in the number of spawning females at the first week of
feeding fish with experimental diets. In the group treated with NS-
398 (COX2 inhibitor) we found the lowest sperm velocity parameters
and decreased linearity of movement. The ovaries of the medaka fed
feed supplemented with Resveratrol or NS-398 were confirmed to
have a lower share of matured oocytes however during the
experiment (four weeks) the number of eggs spawned by females was
similar. Both inhibitors in fish diet (20 mg/kg body weight/day)
caused a decrease in the embryo survival. Our results revealed that
for the medaka female reproduction, activity of both COX enzymes
might be necessary whereas males reproduction competence, as
expressed by sperm motility parameters, might be related to COX2
activity.
Abstract: Utilization of bagasse ash for silica sources is one of
the most common application for agricultural wastes and valuable
biomass byproducts in sugar milling. The high percentage silica
content from bagasse ash was used as silica source for sodium
silicate solution. Different heating temperature, time and acid
treatment were studies for silica extraction. The silica was
characterized using various techniques including X-ray fluorescence,
X-ray diffraction, Scanning electron microscopy, and Fourier
Transform Infrared Spectroscopy method,. The synthesis conditions
were optimized to obtain the bagasse ash with the maximum silica
content. The silica content of 91.57 percent was achieved from
heating of bagasse ash at 600°C for 3 hours under oxygen feeding
and HCl treatment. The result can be used as value added for bagasse
ash utilization and minimize the environmental impact of disposal
problems.
Abstract: The purpose of this study was to examine and
compare physical fitness values of students engaged in different team
sport branches Totally 60 female, and 60 male athletes, that 20
athletes in each branch which are volleyball, basketball and football
participated the study as a volunteer. The mean ages of female and
male athletes were 21.20 ±1.87 and 21.61 ± 1.61 respectively. Age,
height, body weight, body mass index, flexibility, body fat
percentage, 30m sprint, maximum oxygen consumption capacity
(MaxVO2) and drop jump values were measured. As a result of
measurements, significant differences were found in height, weight,
MaxVO2, shuttle run speed between different sports branches in
female athletes. In male athletes, height, body weight, flexibility,
30m split speed and drop jump values were found significantly
different between sports branches.
As a conclusion and as a literature, it can be said that structure of
body has to be appropriate with the engaged sports branch. Physical
fitness values that required the sports branches can be expressed
clearly by increasing the number of subjects.
Abstract: Smoke from domestic wood burning has been
identified as a major contributor to air pollution, motivating detailed
emission measurements under controlled conditions. A series of
experiments was performed to characterise the emissions from wood
combustion in a fireplace and in a woodstove of two common species
of trees grown in Spain: Pyrenean oak (Quercus pyrenaica) and
black poplar (Populus nigra). Volatile organic compounds (VOCs) in
the exhaust emissions were collected in Tedlar bags, re-sampled in
sorbent tubes and analysed by thermal desorption-gas
chromatography-flame ionisation detection. Pyrenean oak presented
substantially higher emissions in the woodstove than in the fireplace,
for the majority of compounds. The opposite was observed for
poplar. Among the 45 identified species, benzene and benzenerelated
compounds represent the most abundant group, followed by
oxygenated VOCs and aliphatics. Emission factors obtained in this
study are generally of the same order than those reported for
residential experiments in the USA.
Abstract: In this study, multiwall carbon nanotubes (MWNTs)
were modified with nitric acid chemically and by dielectric barrier
discharge (DBD) plasma in an oxygen-based atmosphere. Used
carbon nanotubes (CNTs) were prepared by chemical vapour
deposition (CVD) floating catalyst method. For removing amorphous
carbon and metal catalyst, MWNTs were exposed to dry air and
washed with hydrochloric acid. Heating purified CNTs under helium
atmosphere caused elimination of acidic functional groups. Fourier
transformed infrared spectroscopy (FTIR) shows formation of
oxygen containing groups such as C=O and COOH. Brunauer,
Emmett, Teller (BET) analysis revealed that functionalization causes
generation of defects on the sidewalls and opening of the ends of
CNTs. Results of temperature-programmed desorption (TPD) and gas
chromatography(GC) indicate that nitric acid treatment create more
acidic groups than plasma treatment.
Abstract: Acid rain occurs when sulphur dioxide (SO2) and
nitrogen oxides (Nox) gases react in the atmosphere with water,
oxygen, and other chemicals to form various acidic compounds. The
result is a mild solution of sulfuric acid and nitric acid. Soil has a
greater buffering capacity than aquatic systems. However excessive
amount of acids introduced by acid rains may disturb the entire soil
chemistry. Acidity and harmful action of toxic elements damage
vegetation while susceptible microbial species are eliminated. In
present study, the effects of simulated sulphuric acid and nitric acid
rains were investigated on crop Glycine max. The effect of acid rain
on change in soil fertility was detected in which pH of control sample
was 6.5 and pH of 1%H2SO4 and 1%HNO3 were 3.5. Nitrogen nitrate
in soil was high in 1% HNO3 treated soil & Control sample.
Ammonium nitrogen in soil was low in 1% HNO3 & H2SO4 treated
soil. Ammonium nitrogen was medium in control and other samples.
The effect of acid rain on seed germination on 3rd day of germination
control sample growth was 7 cm, 0.1% HNO3 was 8cm, and 0.001%
HNO3 & 0.001% H2SO4 was 6cm each. On 10th day fungal growth
was observed in 1% and 0.1%H2SO4 concentrations, when all plants
were dead. The effect of acid rain on crop productivity was
investigated on 3rd day roots were developed in plants. On12th day
Glycine max showed more growth in 0.1% HNO3, 0.001% HNO3 and
0.001% H2SO4 treated plants growth were same as compare to control
plants. On 20th day development of discoloration of plant pigments
were observed on acid treated plants leaves. On 38th day, 0.1, 0.001%
HNO3 and 0.1, 0.001% H2SO4 treated plants and control plants were
showing flower growth. On 42th day, acid treated Glycine max variety
and control plants were showed seeds on plants. In Glycine max
variety 0.1, 0.001% H2SO4, 0.1, 0.001% HNO3 treated plants were
dead on 46th day and fungal growth was observed. The toxicological
study was carried out on Glycine max plants exposed to 1% HNO3
cells were damaged more than 1% H2SO4. Leaf sections exposed to
0.001% HNO3 & H2SO4 showed less damaged of cells and
pigmentation observed in entire slide when compare with control
plant. The soil analysis was done to find microorganisms in HNO3 &
H2SO4 treated Glycine max and control plants. No microorganism
growth was observed in 1% HNO3 & H2SO4 but control plant showed
microbial growth.
Abstract: In this work, we consider an application of neural networks in LD converter. Application of this approach assumes a reliable prediction of steel temperature and reduces a reblow ratio in steel work. It has been applied a conventional model to charge calculation, the obtained results by this technique are not always good, this is due to the process complexity. Difficulties are mainly generated by the noisy measurement and the process non linearities. Artificial Neural Networks (ANNs) have become a powerful tool for these complex applications. It is used a backpropagation algorithm to learn the neural nets. (ANNs) is used to predict the steel bath temperature in oxygen converter process for the end condition. This model has 11 inputs process variables and one output. The model was tested in steel work, the obtained results by neural approach are better than the conventional model.
Abstract: The study of effect of laser scanning speed on
material efficiency in Ti6Al4V application is very important because unspent powder is not reusable because of high temperature oxygen
pick-up and contamination. This study carried out an extensive study
on the effect of scanning speed on material efficiency by varying the
speed between 0.01 to 0.1m/sec. The samples are wire brushed and
cleaned with acetone after each deposition to remove un-melted
particles from the surface of the deposit. The substrate is weighed before and after deposition. A formula was developed to calculate the
material efficiency and the scanning speed was compared with the
powder efficiency obtained. The results are presented and discussed.
The study revealed that the optimum scanning speed exists for this study at 0.01m/sec, above and below which the powder efficiency
will drop
Abstract: In this study, a 3D combustion chamber was simulated
using FLUENT 6.32. Aims to obtain accurate information about the
profile of the combustion in the furnace and also check the effect of
oxygen enrichment on the combustion process. Oxygen enrichment is
an effective way to reduce combustion pollutant. The flow rate of air
to fuel ratio is varied as 1.3, 3.2 and 5.1 and the oxygen enriched
flow rates are 28, 54 and 68 lit/min. Combustion simulations
typically involve the solution of the turbulent flows with heat
transfer, species transport and chemical reactions. It is common to
use the Reynolds-averaged form of the governing equation in
conjunction with a suitable turbulence model. The 3D Reynolds
Averaged Navier Stokes (RANS) equations with standard k-ε
turbulence model are solved together by Fluent 6.3 software. First
order upwind scheme is used to model governing equations and the
SIMPLE algorithm is used as pressure velocity coupling. Species
mass fractions at the wall are assumed to have zero normal
gradients.Results show that minimum mole fraction of CO2 happens
when the flow rate ratio of air to fuel is 5.1. Additionally, in a fixed
oxygen enrichment condition, increasing the air to fuel ratio will
increase the temperature peak. As a result, oxygen-enrichment can
reduce the CO2 emission at this kind of furnace in high air to fuel
rates.
Abstract: The paper provides biomasses characteristics by
proximate analysis (volatile matter, fixed carbon and ash) and
ultimate analysis (carbon, hydrogen, nitrogen and oxygen) for the
prediction of the heating value equations. The heating value
estimation of various biomasses can be used as an energy evaluation.
Thirteen types of biomass were studied. Proximate analysis was
investigated by mass loss method and infrared moisture analyzer.
Ultimate analysis was analyzed by CHNO analyzer. The heating
values varied from 15 to 22.4MJ kg-1. Correlations of the calculated
heating value with proximate and ultimate analyses were undertaken
using multiple regression analysis and summarized into three and two
equations, respectively. Correlations based on proximate analysis
illustrated that deviation of calculated heating values from
experimental heating values was higher than the correlations based
on ultimate analysis.
Abstract: Bleeding in the digestive duct is an important diagnostic parameter for patients. Blood in the endoscopic image can be determined by investigating the color tone of blood due to the degree of oxygenation, under- or over- illumination, food debris and secretions, etc. However, we found that how to pre-process raw images obtained from the capsule detectors was very important. We applied various image process methods suitable for the capsule endoscopic image in order to remove noises and unbalanced sensitivities for the image pixels. The results showed that much improvement was achieved by additional pre-processing techniques on the algorithm of determining bleeding areas.