Abstract: Contamination of aromatic compounds in water can
cause severe long-lasting effects not only for biotic organism but also
on human health. Several alternative technologies for remediation of
polluted water have been attempted. One of these is adsorption
process of aromatic compounds by using organic modified clay
mineral. Porous structure of clay is potential properties for molecular
adsorptivity and it can be increased by immobilizing hydrophobic
structure to attract organic compounds. In this work natural
montmorillonite were modified with cetyltrimethylammonium
(CTMA+) and was evaluated for use as adsorbents of aromatic
compounds: benzene, toluene, and 2-chloro phenol in its single and
multicomponent solution by ethanol:water solvent. Preparation of
CTMA-montmorillonite was conducted by simple ion exchange
procedure and characterization was conducted by using x-day
diffraction (XRD), Fourier-transform infra red (FTIR) and gas
sorption analysis. The influence of structural modification of
montmorillonite on its adsorption capacity and adsorption affinity of
organic compound were studied. It was shown that adsorptivity of
montmorillonite was increased by modification associated with
arrangements of CTMA+ in the structure even the specific surface
area of modified montmorillonite was lower than raw
montmorillonite. Adsorption rate indicated that material has affinity
to adsorb compound by following order: benzene> toluene > 2-chloro
phenol. The adsorption isotherms of benzene and toluene showed 1st
order adsorption kinetic indicating a partition phenomenon of
compounds between the aqueous and organophilic CTMAmontmorillonite.
Abstract: The pavement constructions on soft and expansive soils are not durable and unable to sustain heavy traffic loading. As a result, pavement failures and settlement problems will occur very often even under light traffic loading due to cyclic and rolling effects. Geotechnical engineers have dwelled deeply into this matter, and adopt various methods to improve the engineering characteristics of soft fine-grained soils and expansive soils. The problematic soils are either replaced by good and better quality material or treated by using chemical stabilization with various binding materials. Increased the strength and durability are also the part of the sustainability drive to reduce the environment footprint of the built environment by the efficient use of resources and waste recycle materials. This paper presents a series of laboratory tests and evaluates the effect of cement and fly ash on the strength and drainage characteristics of soil in Miri. The tests were performed at different percentages of cement and fly ash by dry weight of soil. Additional tests were also performed on soils treated with the combinations of fly ash with cement and lime. The results of this study indicate an increase in unconfined compression strength and a decrease in hydraulic conductivity of the treated soil.
Abstract: In this paper, we propose a novel time-frequency distribution (TFD) for the analysis of multi-component signals. In particular, we use synthetic as well as real-life speech signals to prove the superiority of the proposed TFD in comparison to some existing ones. In the comparison, we consider the cross-terms suppression and the high energy concentration of the signal around its instantaneous frequency (IF).
Abstract: In this paper, we study the existence of solution of
the four-point boundary value problem for second-order differential
equations with impulses by using leray-Schauder theory:
Abstract: A piston cylinder based high pressure differential
thermal analyzer system is developed to investigate phase
transformations, melting, glass transitions, crystallization behavior of
inorganic materials, glassy systems etc., at ambient to 4 GPa and at
room temperature to 1073 K. The pressure is calibrated by the phase
transition of bismuth and ytterbium and temperature is calibrated
by using thermocouple data chart. The system developed is
calibrated using benzoic acid, ammonium nitrate and it has a
pressure and temperature control of ± 8.9 x 10 -4 GPa , ± 2 K
respectively. The phase transition of Asx Te100-x chalcogenides,
ferrous oxide and strontium boride are studied using the
indigenously developed system.
Abstract: Monitoring of ecological systems is one of the major
issues in ecosystem research. The concepts and methodology of
mathematical systems theory provide useful tools to face this
problem. In many cases, state monitoring of a complex ecological
system consists in observation (measurement) of certain state
variables, and the whole state process has to be determined from the
observed data. The solution proposed in the paper is the design of an
observer system, which makes it possible to approximately recover
the state process from its partial observation. The method is
illustrated with a trophic chain of resource – producer – primary
consumer type and a numerical example is also presented.
Abstract: Cerium-doped lanthanum bromide LaBr3:Ce(5%)
crystals are considered to be one of the most advanced scintillator
materials used in PET scanning, combining a high light yield, fast
decay time and excellent energy resolution. Apart from the correct
choice of scintillator, it is also important to optimise the detector
geometry, not least in terms of source-to-detector distance in order to
obtain reliable measurements and efficiency. In this study a
commercially available 25 mm x 25 mm BrilLanCeTM 380 LaBr3: Ce
(5%) detector was characterised in terms of its efficiency at varying
source-to-detector distances. Gamma-ray spectra of 22Na, 60Co, and
137Cs were separately acquired at distances of 5, 10, 15, and 20cm. As
a result of the change in solid angle subtended by the detector, the
geometric efficiency reduced in efficiency with increasing distance.
High efficiencies at low distances can cause pulse pile-up when
subsequent photons are detected before previously detected events
have decayed. To reduce this systematic error the source-to-detector
distance should be balanced between efficiency and pulse pile-up
suppression as otherwise pile-up corrections would need to be
necessary at short distances. In addition to the experimental
measurements Monte Carlo simulations have been carried out for the
same setup, allowing a comparison of results. The advantages and
disadvantages of each approach have been highlighted.
Abstract: Quality of 2D and 3D cross-sectional images produce
by Computed Tomography primarily depend upon the degree of
precision of primary and secondary X-Ray intensity detection.
Traditional method of primary intensity detection is apt to errors.
Recently the X-Ray intensity measurement system along with smart
X-Ray sensors is developed by our group which is able to detect
primary X-Ray intensity unerringly. In this study a new smart X-Ray
sensor is developed using Light-to-Frequency converter TSL230
from Texas Instruments which has numerous advantages in terms of
noiseless data acquisition and transmission. TSL230 construction is
based on a silicon photodiode which converts incoming X-Ray
radiation into the proportional current signal. A current to frequency
converter is attached to this photodiode on a single monolithic CMOS
integrated circuit which provides proportional frequency count to
incoming current signal in the form of the pulse train. The frequency
count is delivered to the center of PICDEM FS USB board with
PIC18F4550 microcontroller mounted on it. With highly compact
electronic hardware, this Demo Board efficiently read the smart
sensor output data. The frequency output approaches overcome
nonlinear behavior of sensors with analog output thus un-attenuated
X-Ray intensities could be measured precisely and better
normalization could be acquired in order to attain high resolution.
Abstract: This paper presents a heuristic to solve large size 0-1 Multi constrained Knapsack problem (01MKP) which is NP-hard. Many researchers are used heuristic operator to identify the redundant constraints of Linear Programming Problem before applying the regular procedure to solve it. We use the intercept matrix to identify the zero valued variables of 01MKP which is known as redundant variables. In this heuristic, first the dominance property of the intercept matrix of constraints is exploited to reduce the search space to find the optimal or near optimal solutions of 01MKP, second, we improve the solution by using the pseudo-utility ratio based on surrogate constraint of 01MKP. This heuristic is tested for benchmark problems of sizes upto 2500, taken from literature and the results are compared with optimum solutions. Space and computational complexity of solving 01MKP using this approach are also presented. The encouraging results especially for relatively large size test problems indicate that this heuristic can successfully be used for finding good solutions for highly constrained NP-hard problems.
Abstract: Concrete performance is strongly affected by the
particle packing degree since it determines the distribution of the
cementitious component and the interaction of mineral particles. By
using packing theory designers will be able to select optimal
aggregate materials for preparing concrete with low cement content,
which is beneficial from the point of cost. Optimum particle packing
implies minimizing porosity and thereby reducing the amount of
cement paste needed to fill the voids between the aggregate particles,
taking also the rheology of the concrete into consideration. For
reaching good fluidity superplasticizers are required. The results from
pilot tests at Luleå University of Technology (LTU) show various
forms of the proposed theoretical models, and the empirical approach
taken in the study seems to provide a safer basis for developing new,
improved packing models.
Abstract: This paper deals with a new way for designing
external fixators applied in traumatology and orthopaedics. These
fixators can be applied in the treatment of open and unstable
fractures or for lengthening human or animal bones etc. The new
design is based on the development of Ilizarov and other techniques
(i.e. shape and weight optimalization based on composite materials,
application of smart materials, nanotechnology, low x-ray absorption,
antibacterial protection, patient's comfort, reduction in the duration
of the surgical treatment, and cost).
Abstract: Many well-known interconnection networks, such as kary n-cubes, recursive circulant graphs, generalized recursive circulant graphs, circulant graphs and so on, are shown to belong to the family of cycle composition networks. Recently, various studies about mutually independent hamiltonian cycles, abbreviated as MIHC-s, on interconnection networks are published. In this paper, using an improved construction method, we obtain MIHC-s on cycle composition networks with a much weaker condition than the known result. In fact, we established the existence of MIHC-s in the cycle composition networks and the result is optimal in the sense that the number of MIHC-s we constructed is maximal.
Abstract: The state-of-the-art Bag of Words model in Content-
Based Image Retrieval has been used for years but the relevance
feedback strategies for this model are not fully investigated. Inspired
from text retrieval, the Bag of Words model has the ability to use the
wealth of knowledge and practices available in text retrieval. We
study and experiment the relevance feedback model in text retrieval
for adapting it to image retrieval. The experiments show that the
techniques from text retrieval give good results for image retrieval
and that further improvements is possible.
Abstract: The use of bioindicators plants (lichens, bryophytes
and Sphagnum....) in monitoring pollution by heavy metals has been
the subject of several works. However, few studies have addressed
the impact of specific type-s pollutants (fertilizers, pesticides.) on
these organisms.
We propose in this work to make the highlighting effect of NPKs
(NPK: nitrogen-phosphate-potassium-sulfate (NP2O5K2O) (15,15,15),
at concentrations of 10, 20, 30 , 40 and 50mM/L) on the activity of
detoxification enzymes (GSH/GST, CAT, APX and MDA) of plant
bioindicators (mosses and lichens) after treatment for 3 and 7 days.
This study shows the important role of the defense system in the
accumulation and tolerance to chemical pollutants through the
activation of enzymatic (GST (glutathione-S-transferase, APX
(ascorbat peroxidase), CAT (catalase)) and nonenzymatic biomarkers
(GSH (glutathione), MDA (malondialdehyde)) against oxidative
stress generated by the NPKs.
Abstract: In a wireless communication system, a
predistorter(PD) is often employed to alleviate nonlinear distortions
due to operating a power amplifier near saturation, thereby improving
the system performance and reducing the interference to adjacent
channels. This paper presents a new adaptive polynomial digital
predistorter(DPD). The proposed DPD uses Coordinate Rotation
Digital Computing(CORDIC) processors and PD process by pipelined
architecture. It is simpler and faster than conventional adaptive
polynomial DPD. The performance of the proposed DPD is proved by
MATLAB simulation.
Abstract: Seismic design may require non-conventional
concept, due to the fact that the stiffness and layout of the structure
have a great effect on the overall structural behaviour, on the seismic
load intensity as well as on the internal force distribution. To find an
economical and optimal structural configuration the key issue is the
optimal design of the lateral load resisting system. This paper focuses
on the optimal design of regular, concentric braced frame (CBF)
multi-storey steel building structures. The optimal configurations are
determined by a numerical method using genetic algorithm approach,
developed by the authors. Aim is to find structural configurations
with minimum structural cost. The design constraints of objective
function are assigned in accordance with Eurocode 3 and Eurocode 8
guidelines. In this paper the results are presented for various building
geometries, different seismic intensities, and levels of energy
dissipation.
Abstract: Recently, lots of researchers are attracted to retrieving
multimedia database by using some impression words and their values.
Ikezoe-s research is one of the representatives and uses eight pairs of
opposite impression words. We had modified its retrieval interface and
proposed '2D-RIB'. In '2D-RIB', after a retrieval person selects a
single basic music, the system visually shows some other music
around the basic one along relative position. He/she can select one of
them fitting to his/her intention, as a retrieval result. The purpose of
this paper is to improve his/her satisfaction level to the retrieval result
in 2D-RIB. One of our extensions is to define and introduce the
following two measures: 'melody goodness' and 'general acceptance'.
We implement them in different five combinations. According to an
evaluation experiment, both of these two measures can contribute to
the improvement. Another extension is three types of customization.
We have implemented them and clarified which customization is
effective.
Abstract: The primary cause of Total Hip Replacement (THR)
failure for younger patients is aseptic loosening. This complication is
twice more likely to happen in acetabular cup than in femoral stem.
Excessive micromotion between bone and implant will cause
loosening and it depends in patient activities, age and bone. In this
project, the effects of different metal back design of press fit on
osseointegration of the acetabular cup are carried out. Commercial
acetabular cup designs, namely Spiked, Superfix and Quadrafix are
modelled and analyzed using commercial finite element software.
The diameter of acetabular cup is based on the diameter of acetabular
rim to make sure the component fit to the acetabular cavity. A new
design of acetabular cup are proposed and analyzed to get better
osseointegration between the bones and implant interface. Results
shows that the proposed acetabular cup designs are more stable
compared to other designs with respect to stress and displacement
aspects.
Abstract: The present research was designed to investigate the
anti-microbial activity of aristolochic acid from the root of
Aristolochia bracteata. From the methanolic & ethyl extract extracts
of Aristolochia bracteata aristolochic acid I was isolated and
conformed through IR, NMR & MS. The percentage purity of
aristolochic acid I was determined by UV & HPLC method. Antibacterial
activity of extracts of Aristolochia bracteata and the
isolated compound was determined by disc diffusion method. The
results reveled that the isolated aristolochic acid from methanolic
extract was more pure than the compound from ethyl acetate extract.
The various extracts (500μg/disc) of Aristolochia bracteata showed
moderate antibacterial activity with the average zone of inhibition of
7-18 mm by disc diffusion method. Among the extracts, ethyl acetate
& methanol extracts were shown good anti-microbial activity and the
growth of E.coli (18 mm) was strongly inhibited. Microbial assay of
isolated compound (Aristolochic acid I) from ethyl acetate &
methanol extracts were shown good antimicrobial activity and the
zone of inhibition of both at higher concentration 50 μg/ml was
similar with the standard aristolochic acid. It may be concluded that
the isolated compound of aristolochic acid I has good anti-bacterial
activity.
Abstract: Lipases are enzymes particularly amenable for
immobilization by entrapment methods, as they can work equally
well in aqueous or non-conventional media and long-time stability of
enzyme activity and enantioselectivity is needed to elaborate more
efficient bioprocesses. The improvement of Pseudomonas
fluorescens (Amano AK) lipase characteristics was investigated by
optimizing the immobilization procedure in hybrid organic-inorganic
matrices using ionic liquids as additives. Ionic liquids containing a
more hydrophobic alkyl group in the cationic moiety are beneficial
for the activity of immobilized lipase. Silanes with alkyl- or aryl
nonhydrolizable groups used as precursors in combination with
tetramethoxysilane could generate composites with higher
enantioselectivity compared to the native enzyme in acylation
reactions of secondary alcohols. The optimal effect on both activity
and enantioselectivity was achieved for the composite made from
octyltrimethoxysilane and tetramethoxysilane at 1:1 molar ratio (60%
increase of total activity following immobilization and enantiomeric
ratio of 30). Ionic liquids also demonstrated valuable properties as
reaction media for the studied reactions, comparable with the usual
organic solvent, hexane.