Abstract: Mercury is a natural occurring element and present in
various concentrations in the environment. Due to its toxic effects, it
is desirable to research mercury sensitive materials to adsorb
mercury. This paper describes the preparation of Au nanoparticles for
mercury adsorption by using a microwave (MW)-polyol method in
the presence of three different Sodium Chloride (NaCl)
concentrations (10, 20 and 30 mM). Mixtures of spherical, triangular,
octahedral, decahedral particles and 1-D product were obtained using
this rapid method. Sizes and shapes was found strongly depend on the
concentrations of NaCl. Without NaCl concentration, spherical,
triangular plates, octahedral, decahedral nanoparticles and 1D
product were produced. At the lower NaCl concentration (10 mM),
spherical, octahedral and decahedral nanoparticles were present,
while spherical and decahedral nanoparticles were preferentially form
by using 20 mM of NaCl concentration. Spherical, triangular plates,
octahedral and decahedral nanoparticles were obtained at the highest
NaCl concentration (30 mM). The amount of mercury adsorbed using
20 ppm mercury solution is the highest (67.5 %) for NaCl
concentration of 30 mM. The high yield of polygonal particles will
increase the mercury adsorption. In addition, the adsorption of
mercury is also due to the sizes of the particles. The sizes of particles
become smaller with increasing NaCl concentrations (size ranges, 5-
16 nm) than those synthesized without addition of NaCl (size ranges
11-32 nm). It is concluded that NaCl concentrations affects the
formation of sizes and shapes of Au nanoparticles thus affects the
mercury adsorption.
Abstract: New nondestructive technique, namely an inverse technique based on vibration tests, to characterize nonlinear mechanical properties of adhesive layers in sandwich composites is developed. An adhesive layer is described as a viscoelastic isotropic material with storage and loss moduli which are both frequency dependent values in wide frequency range. An optimization based on the planning of experiments and response surface technique to minimize the error functional is applied to decrease considerably the computational expenses. The developed identification technique has been tested on aluminum panels and successfully applied to characterize viscoelastic material properties of 3M damping polymer ISD-112 used as a core material in sandwich panels.
Abstract: In this article, a high vacuum system for the evaporation of organic semiconductors is introduced and a mathematical model is given. Based on the exact input output linearization a deposition rate controller is designed and tested with different evaporation materials.
Abstract: This research is to design and implement a new kind
of agitators called differential agitator. The Differential Agitator is an
electro- mechanic set consists of two shafts. The first shaft is the
bearing axis while the second shaft is the axis of the quartet upper
bearing impellers group and the triple lower group which are called
as agitating group. The agitating group is located inside a cylindrical
container equipped especially to contain square directors for the
liquid entrance and square directors called fixing group for the liquid
exit. The fixing group is installed containing the agitating group
inside any tank whether from upper or lower position. The agitating
process occurs through the agitating group bearing causing a lower
pressure over the upper group leading to withdrawing the liquid from
the square directors of the liquid entering and consequently the liquid
moves to the denser place under the quartet upper group. Then, the
liquid moves to the so high pressure area under the agitating group
causing the liquid to exit from the square directors in the bottom of
the container. For improving efficiency, parametric study and shape
optimization has been carried out. A numerical analysis,
manufacturing and laboratory experiments were conducted to design
and implement the differential agitator. Knowing the material
prosperities and the loading conditions, the FEM using ANSYS11
was used to get the optimum design of the geometrical parameters of
the differential agitator elements while the experimental test was
performed to validate the advantages of the differential agitators to
give a high agitation performance of lime in the water as an example.
In addition, the experimental work has been done to express the
internal container shape in the agitation efficiency. The study ended
up with conclusions to maximize agitator performance and optimize
the geometrical parameters to be used for manufacturing the
differential agitator
Abstract: The steam cracking reactions are always accompanied with the formation of coke which deposits on the walls of the tubular reactors. The investigation has attempted to control catalytic coking by the applying aluminum, zinc and ceramic coating like aluminum-magnesium by thermal spray and pack cementation method. Rate of coke formation during steam cracking of naphtha has been investigated both for uncoated stainless steel (with different alloys) and metal coating constructed with thermal Spray and pack cementation method with metal powders of Aluminum, Aluminum-Magnesium, zinc, silicon, nickel and chromium. The results of the study show that passivating the surface of SS321 with a coating of Aluminum and Aluminum-Magnesium can significantly reduce the rate of coke deposition during naphtha pyrolysis. SEM and EDAX techniques (Philips XL Series) were used to examine the coke deposits formed by the metal-hydrocarbon reactions. Our objective was to separate the different stages by identifying the characteristic morphologies.
Abstract: Thisresearch paper is dedicated to an actual issue in Latvia and in the whole European Union – development of the secondary materials management. The goal of this paper is to research the development of the secondary materials management in Latvia as a result to point out its main positive aspects and problems. In this research paper the author regards following issues: significance of the secondary materials management, current situation of the waste generation and utilization in Latvia comparing with other EU Member States, main problems and positive aspects of the secondary materials management in Latvia. The research author concludes that in last ten years a great work is done to develop the secondary materials market. Nevertheless following improvements are necessary: implementation of the packaging deposit system, development of the separate waste collection, increasing of the recycling capacity.
Abstract: Adsorption of methanol and ethanol over mesoporous
siliceous material are studied in the current paper. The pure
mesoporous silica is prepared using tetraethylorthosilicate (TEOS) as
silica source and dodecylamine as template at low pH. The prepared
material was characterized using nitrogen adsorption,nX-ray
diffraction (XRD) and scanning electron microscopy (SEM). The
adsorption kinetics of methanol and ethanol from aqueous solution
were studied over the prepared mesoporous silica material. The
percent removal of alcohol was calculated per unit mass of adsorbent
used. The 1st order model is found to be in agreement with both
adsorbates while the 2nd order model fit the adsorption of methanol
only.
Abstract: In this study, the dispersion of heavy particles line in
an isotropic and incompressible three-dimensional turbulent flow has
been studied using the Kinematic Simulation techniques to find out
the evolution of the line fractal dimension. The fractal dimension of
the line is found in the case of different particle gravity (in practice,
different values of particle drift velocity) in the presence of small
particle inertia with a comparison with that obtained in the diffusion
case of material line at the same Reynolds number. It can be
concluded for the dispersion of heavy particles line in turbulent flow
that the particle gravity affect the fractal dimension of the line for
different particle gravity velocities in the range 0.2 < W < 2. With
the increase of the particle drift velocity, the fractal dimension of the
line decreases which may be explained as the particles pass many
scales in their journey in the direction of the gravity and the particles
trajectories do not affect by these scales at high particle drift
velocities.
Abstract: In this paper, for the first time, a two-dimensional
(2D) analytical drain current model for sub-100 nm multi-layered
gate material engineered trapezoidal recessed channel (MLGMETRC)
MOSFET: a novel design is presented and investigated using
ATLAS and DEVEDIT device simulators, to mitigate the large gate
leakages and increased standby power consumption that arise due to
continued scaling of SiO2-based gate dielectrics. The twodimensional
(2D) analytical model based on solution of Poisson-s
equation in cylindrical coordinates, utilizing the cylindrical
approximation, has been developed which evaluate the surface
potential, electric field, drain current, switching metric: ION/IOFF
ratio and transconductance for the proposed design. A good
agreement between the model predictions and device simulation
results is obtained, verifying the accuracy of the proposed analytical
model.
Abstract: Online learning with Intelligent Tutoring System (ITS) is becoming very popular where the system models the student-s learning behavior and presents to the student the learning material (content, questions-answers, assignments) accordingly. In today-s distributed computing environment, the tutoring system can take advantage of networking to utilize the model for a student for students from other similar groups. In the present paper we present a methodology where using Case Based Reasoning (CBR), ITS provides student modeling for online learning in a distributed environment with the help of agents. The paper describes the approach, the architecture, and the agent characteristics for such system. This concept can be deployed to develop ITS where the tutor can author and the students can learn locally whereas the ITS can model the students- learning globally in a distributed environment. The advantage of such an approach is that both the learning material (domain knowledge) and student model can be globally distributed thus enhancing the efficiency of ITS with reducing the bandwidth requirement and complexity of the system.
Abstract: Polyurethanes (PURs) are very versatile polymeric
materials with a wide range of physical and chemical properties.
PURs have desirable properties such as high abrasion resistance, tear
strength, shock absorption, flexibility and elasticity. Although they
have relatively poor thermal stability, this can be improved by using
treated clay. Polyurethane/clay nanocomposites have been
synthesized from renewable sources. A polyol for the production of
polyurethane by reaction with an isocyanate was obtained by the
synthesis of palm oil-based oleic acid with glycerol. Dodecylbenzene
sulfonic acid (DBSA) was used as catalyst and emulsifier. The
unmodified clay (kunipia-F) was treated with cetyltrimethyl
ammonium bromide (CTAB-mont) and octadodecylamine (ODAmont).
The d-spacing in CTAB-mont and ODA-mont were 1.571 nm
and 1.798 nm respectively and larger than that of the pure-mont
(1.142 nm). The organoclay was completely intercalated in the
polyurethane, as confirmed by a wide angle x-ray diffraction
(WAXD) pattern.
The results showed that adding clay demonstrated better thermal
stability in comparison with the virgin polyurethane. Onset
degradation of pure PU is at 200oC, and is lower than that of the
CTAB-mont PU and ODA-mont PU which takes place at about
318oC and 330oC, respectively. The mechanical properties (including
the dynamic mechanical properties) of pure polyurethane (PU) and
PU/clay nanocomposites, were measured. The modified organoclay
had a remarkably beneficial effect on the strength and elongation at
break of the nanocomposites, which both increased with increasing
clay content with the increase of the tensile strength of more than
214% and 267% by the addition of only 5 wt% of the
montmorillonite CTAB-mont PU and ODA-mont PU, respectively.
Abstract: Industrial surveys shows that manufacturing
companies define the qualities of thermal removing process based on
the dimension and physical appearance of the cutting material
surface. Therefore, the roughness of the surface area of the material
cut by the plasma arc cutting process and the rate of the removed
material by the manual plasma arc cutting machine was importantly
considered. Plasma arc cutter Selco Genesis 90 was used to cut
Standard AISI 1017 Steel of 200 mm x100 mm x 6 mm manually
based on the selected parameters setting. The material removal rate
(MRR) was measured by determining the weight of the specimens
before and after the cutting process. The surface roughness (SR)
analysis was conducted using Mitutoyo CS-3100 to determine the
average roughness value (Ra). Taguchi method was utilized to
achieve optimum condition for both outputs studied. The
microstructure analysis in the region of the cutting surface is
performed using SEM. The results reveal that the SR values are
inversely proportional to the MRR values. The quality of the surface
roughness depends on the dross peak that occurred after the cutting
process.
Abstract: Cassava is one of the top five crops in Cameroon. Its
evolution has remained constant since the independence period and
the production has more than tripled. It is a crop with multiple
industrial capacities but the sector-s business opportunities are
underexploited. Using Strengths, Weaknesses, Opportunities and
Threats analysis method, this paper examines the cassava actual state.
It appraises the sector-s strengths (S), considers suitable measures to
strengthen weaknesses (W), evaluates strategies to fully benefit from
the sector numerous business opportunities (O) and explore means to
convert threats (T) into opportunities. Data were collected from the
ministry of agriculture and rural development and different actors.
The results show that cassava sector embodies many business
opportunities and stands as a raw material provider for many
industries but ultimately requires challenges to be tackled
appropriately.
Abstract: In determining the electromagnetic properties of
magnetic materials, hysteresis modeling is of high importance. Many
models are available to investigate those characteristics but they tend
to be complex and difficult to implement. In this paper a new
qualitative hysteresis model for ferromagnetic core is presented,
based on the function approximation capabilities of adaptive neuro
fuzzy inference system (ANFIS). The proposed ANFIS model
combined the neural network adaptive capabilities and the fuzzy
logic qualitative approach can restored the hysteresis curve with a
little RMS error. The model accuracy is good and can be easily
adapted to the requirements of the application by extending or
reducing the network training set and thus the required amount of
measurement data.
Abstract: One of the most important parts of a cement factory is
the cement rotary kiln which plays a key role in quality and quantity of produced cement. In this part, the physical exertion and bilateral
movement of air and materials, together with chemical reactions take
place. Thus, this system has immensely complex and nonlinear dynamic equations. These equations have not worked out yet. Only
in exceptional case; however, a large number of the involved parameter were crossed out and an approximation model was
presented instead. This issue caused many problems for designing a
cement rotary kiln controller. In this paper, we presented nonlinear predictor and simulator models for a real cement rotary kiln by using
nonlinear identification technique on the Locally Linear Neuro-
Fuzzy (LLNF) model. For the first time, a simulator model as well as
a predictor one with a precise fifteen minute prediction horizon for a
cement rotary kiln is presented. These models are trained by
LOLIMOT algorithm which is an incremental tree-structure
algorithm. At the end, the characteristics of these models are expressed. Furthermore, we presented the pros and cons of these
models. The data collected from White Saveh Cement Company is used for modeling.
Abstract: This paper describes a platform that faces the main
research areas for e-learning educational contents. Reusability tackles
the possibility to use contents in different courses reducing costs and
exploiting available data from repositories. In our approach the
production of educational material is based on templates to reuse
learning objects. In terms of interoperability the main challenge lays
on reaching the audience through different platforms. E-learning
solution must track social consumption evolution where nowadays
lots of multimedia contents are accessed through the social networks.
Our work faces it by implementing a platform for generation of
multimedia presentations focused on the new paradigm related to
social media. The system produces videos-courses on top of web
standard SMIL (Synchronized Multimedia Integration Language)
ready to be published and shared. Regarding interfaces it is
mandatory to satisfy user needs and ease communication. To
overcome it the platform deploys virtual teachers that provide natural
interfaces while multimodal features remove barriers to pupils with
disabilities.
Abstract: An implementation of a design for a game based
virtual learning environment is described. The game is developed for a course in analogue electronics, and the topic is the design of a
power supply. This task can be solved in a number of different ways, with certain constraints, giving the students a certain amount of
freedom, although the game is designed not to facilitate trial-and error approach. The use of storytelling and a virtual gaming environment provides the student with the learning material in a
MMORPG environment. The game is tested on a group of second
year electrical engineering students with good results.
Abstract: In this article, the authors reviewed and analyzed the survey materials similarities ornament proto-Turkic and northern Indians. The study examined the materials scientists - geneticists, archaeologists, anthropologists. Numerous studies of scientists from different directions once again prove the relevance of the topic. The authors approached the subject from an artistic side. The study authors have made the appropriate conclusions. This publication is based on the proceedings of the investigation.
Abstract: Ovshinsky initiated scientific research in the field of
amorphous and disordered materials that continues to this day. The
Ovshinsky Effect where the resistance of thin GST films is
significantly reduced upon the application of low voltage is of
fundamental importance in phase-change - random access memory
(PC-RAM) devices.GST stands for GdSbTe chalcogenide type
glasses.However, the Ovshinsky Effect is not without controversy.
Ovshinsky thought the resistance of GST films is reduced by the
redistribution of charge carriers; whereas, others at that time including
many PC-RAM researchers today argue that the GST resistance
changes because the GST amorphous state is transformed to the
crystalline state by melting, the heat supplied by external heaters. In
this controversy, quantum mechanics (QM) asserts the heat capacity of
GST films vanishes, and therefore melting cannot occur as the heat
supplied cannot be conserved by an increase in GST film
temperature.By precluding melting, QM re-opens the controversy
between the melting and charge carrier mechanisms. Supporting
analysis is presented to show that instead of increasing GST film
temperature, conservation proceeds by the QED induced creation of
photons within the GST film, the QED photons confined by TIR. QED
stands for quantum electrodynamics and TIR for total internal
reflection. The TIR confinement of QED photons is enhanced by the
fact the absorbedheat energy absorbed in the GST film is concentrated
in the TIR mode because of their high surface to volume ratio. The
QED photons having Planck energy beyond the ultraviolet produce
excitons by the photoelectric effect, the electrons and holes of which
reduce the GST film resistance.
Abstract: This paper presents the utilizing of ferroelectric
material on antenna application. There are two different ferroelectric
had been used on the proposed antennas which include of Barium
Strontium Titanate (BST) and Bismuth Titanate (BiT), suitable for
Access Points operating in the WLAN IEEE 802.11 b/g and WiMAX
IEEE 802.16 within the range of 2.3 GHz to 2.5 GHz application.
BST, which had been tested to own a dielectric constant of εr = 15
while BiT has a dielectric constant that higher than BST which is εr =
21 and both materials are in rectangular shaped. The influence of
various parameters on antenna characteristics were investigated
extensively using commercial electromagnetic simulations software
by Communication Simulation Technology (CST). From theoretical
analysis and simulation results, it was demonstrated that ferroelectric
material used have not only improved the directive emission but also
enhanced the radiation efficiency.