Abstract: Gypsum (CaSO4.2H2O) is a mineral that is found in
large quantities in the Turkey and in the World. In this study, the
dissolution of this mineral in the diammonium hydrogen phosphate
solutions has been studied. The dissolution and dissolution kinetics of
gypsum in diammonium hydrogen phosphate solutions will be useful
for evaluating of solid wastes containing gypsum. Parameters such as
diammonium hydrogen phosphate concentration, temperature and
stirring speed affecting on the dissolution rate of the gypsum in
diammonium hydrogen phosphate solutions were investigated. In
experimental studies have researched effectiveness of the selected
parameters. The dissolution of gypsum were examined in two parts at
low and high temperatures. The experimental results were
successfully correlated by linear regression using Statistica program.
Dissolution curves were evaluated shrinking core models for solidfluid
systems. The activation energy was found to be 34.58 kJ/mol
and 44.45 kJ/mol for the low and the high temperatures. The
dissolution of gypsum was controlled by chemical reaction both low
temperatures and high temperatures.
Abstract: Incineration of municipal solid waste (MSW) is one of
the key scopes in the global clean energy strategy. A computational
fluid dynamics (CFD) model was established in order to reveal these
features of the combustion process in a fixed porous bed of MSW.
Transporting equations and process rate equations of the waste bed
were modeled and set up to describe the incineration process,
according to the local thermal conditions and waste property
characters. Gas phase turbulence was modeled using k-ε turbulent
model and the particle phase was modeled using the kinetic theory of
granular flow. The heterogeneous reaction rates were determined
using Arrhenius eddy dissipation and the Arrhenius-diffusion
reaction rates. The effects of primary air flow rate and temperature in
the burning process of simulated MSW are investigated
experimentally and numerically. The simulation results in bed are
accordant with experimental data well. The model provides detailed
information on burning processes in the fixed bed, which is otherwise
very difficult to obtain by conventional experimental techniques.
Abstract: A three-dimensional numerical model of
thermoelectric generator (TEG) modules attached to a large chimney
plate is proposed and solved numerically using a control volume based
finite difference formulation. The TEG module consists of a
thermoelectric generator, an elliptical pin-fin heat sink, and a cold
plate for water cooling. In the chimney, the temperature of flue gases is
450-650K. Although the TEG hot-side temperature and thus the
electric power output can be increased by inserting an elliptical pin-fin
heat sink into the chimney tunnel to increase the heat transfer area, the
pin fin heat sink would cause extra pumping power at the same time.
The main purpose of this study is to analyze the effects of geometrical
parameters on the electric power output and chimney pressure drop
characteristics. The effects of different operating conditions, including
various inlet velocities (Vin= 1, 3, 5 m/s), inlet temperatures (Tgas = 450,
550, 650K) and different fin height (0 to 150 mm) are discussed in
detail. The predicted numerical data for the power vs. current (P-I)
curve are in good agreement (within 11%) with the experimental data.
Abstract: This paper introduces an original method for
guaranteed estimation of the accuracy for an ensemble of Lipschitz
classifiers. The solution was obtained as a finite closed set of
alternative hypotheses, which contains an object of classification with
probability of not less than the specified value. Thus, the
classification is represented by a set of hypothetical classes. In this
case, the smaller the cardinality of the discrete set of hypothetical
classes is, the higher is the classification accuracy. Experiments have
shown that if cardinality of the classifiers ensemble is increased then
the cardinality of this set of hypothetical classes is reduced. The
problem of the guaranteed estimation of the accuracy for an ensemble
of Lipschitz classifiers is relevant in multichannel classification of
target events in C-OTDR monitoring systems. Results of suggested
approach practical usage to accuracy control in C-OTDR monitoring
systems are present.
Abstract: Machining of hard materials is a recent technology for
direct production of work-pieces. The primary challenge in
machining these materials is selection of cutting tool inserts which
facilitates an extended tool life and high-precision machining of the
component. These materials are widely for making precision parts for
the aerospace industry. Nickel-based alloys are typically used in
extreme environment applications where a combination of strength,
corrosion resistance and oxidation resistance material characteristics
are required. The present paper reports the theoretical and
experimental investigations carried out to understand the influence of
machining parameters on the response parameters. Considering the
basic machining parameters (speed, feed and depth of cut) a study has
been conducted to observe their influence on material removal rate,
surface roughness, cutting forces and corresponding tool wear.
Experiments are designed and conducted with the help of Central
Composite Rotatable Design technique. The results reveals that for a
given range of process parameters, material removal rate is favorable
for higher depths of cut and low feed rate for cutting forces. Low feed
rates and high values of rotational speeds are suitable for better finish
and higher tool life.
Abstract: If teamwork is the key to organizational learning,
productivity and growth, then, why do some teams succeed in
achieving these, while others falter at different stages? Building
teams in higher education institutions has been a challenge and an
open-ended constructivist approach was considered on an
experimental basis for this study to address this challenge. For this
research, teams of students from the MBA program were chosen to
study the effect of teamwork in learning, the motivation levels among
student team members, and the effect of collaboration in achieving
team goals. The teams were built on shared vision and goals,
cohesion was ensured, positive induction in the form of faculty
mentoring was provided for each participating team and the results
have been presented with conclusions and suggestions.
Abstract: The key role in phenomenological modelling of cyclic
plasticity is good understanding of stress-strain behaviour of given
material. There are many models describing behaviour of materials
using numerous parameters and constants. Combination of individual
parameters in those material models significantly determines whether
observed and predicted results are in compliance. Parameter
identification techniques such as random gradient, genetic algorithm
and sensitivity analysis are used for identification of parameters using
numerical modelling and simulation. In this paper genetic algorithm
and sensitivity analysis are used to study effect of 4 parameters of
modified AbdelKarim-Ohno cyclic plasticity model. Results
predicted by Finite Element (FE) simulation are compared with
experimental data from biaxial ratcheting test with semi-elliptical
loading path.
Abstract: In Jordan having deficit atmospheric precipitation, an
increase in water demand occurs during summer months. Jordan can
be regarded with a relatively high potential for wastewater recycling
and reuse. The main purpose of this paper was to investigate the
removal of total suspended solids (TSS) and chemical oxygen
demand (COD) for olive mill wastewater (OMW) by
electrocoagulation (EC) process. In the combination of
electrocoagulation by using coupled iron–aluminum electrodes, the
optimum working pH was found to be around 6. Results indicated
that the electrocoagulation process allowed removal of TSS and COD
of about 82.5% and 47.5%, respectively at 45 mA/cm2 after 70
minutes by using coupled iron–aluminum electrodes. It was
demonstrated that the maximum TSS and COD removals were
obtained at some optimum experimental parameters for current
density, pH, and reaction time.
Abstract: Interaction of Schiff base complexes of Iron and
Manganese: Iron [N, N’ Bis (5- (triphenyl phosphonium methyl)
salicylidene) -1, 2 ethanediamine) chloride, [Fe Salen]Cl; Manganese
[N, N’ Bis (5- (triphenyl phosphonium methyl) salicylidene) -1, 2
ethanediamine) acetate, were investigated by spectroscopic and
isothermal titration calorimetry techniques (ITC).
The absorbance spectra of complexes have shown hyper and
hypochromism in the presence of DNA that is indication of
interaction of complexes with DNA. The linear dichroism (LD)
measurements confirmed the bending of DNA in the presence of
complexes.
Furthermore, Isothermal titration calorimetry experiments
approved that complexes bound to DNA on the base of both
electrostatic and hydrophobic interactions. More, ITC profile exhibits
the existence of two binding phases for the complexes. Antibacterial
activity of ligand and complexes were tested in vitro to evaluate their
activity against the gram positive and negative bacteria.
Abstract: Two finite element (FEM) models are presented in
this paper to address the random nature of the response of glued
timber structures made of wood segments with variable elastic
moduli evaluated from 3600 indentation measurements. This total
database served to create the same number of ensembles as was the
number of segments in the tested beam. Statistics of these ensembles
were then assigned to given segments of beams and the Latin
Hypercube Sampling (LHS) method was called to perform 100
simulations resulting into the ensemble of 100 deflections subjected
to statistical evaluation. Here, a detailed geometrical arrangement of
individual segments in the laminated beam was considered in the
construction of two-dimensional FEM model subjected to in fourpoint
bending to comply with the laboratory tests. Since laboratory
measurements of local elastic moduli may in general suffer from a
significant experimental error, it appears advantageous to exploit the
full scale measurements of timber beams, i.e. deflections, to improve
their prior distributions with the help of the Bayesian statistical
method. This, however, requires an efficient computational model
when simulating the laboratory tests numerically. To this end, a
simplified model based on Mindlin’s beam theory was established.
The improved posterior distributions show that the most significant
change of the Young’s modulus distribution takes place in laminae in
the most strained zones, i.e. in the top and bottom layers within the
beam center region. Posterior distributions of moduli of elasticity
were subsequently utilized in the 2D FEM model and compared with
the original simulations.
Abstract: An experimental study was performed to investigate
the behavior and strength of proposed technique to connect
reinforced concrete (RC) beam to steel or composite columns. This
approach can practically be used in several types of building
construction. In this technique, the main beam of the frame consists
of a transfer part (part of beam; Tr.P) and a common reinforcement
concrete beam. The transfer part of the beam is connected to the
column, whereas the rest of the beam is connected to the transfer part
from each side. Four full-scale beam-column connections were tested
under static loading. The test parameters were the length of the
transfer part and the column properties. The test results show that
using of the transfer part technique leads to modify the deformation
capabilities for the RC beam and hence it increases its resistance
against failure. Increase in length of the transfer part did not
necessarily indicate an enhanced behavior. The test results contribute
to the characterization of the connection behavior between RC beam -
steel column and can be used to calibrate numerical models for the
simulation of this type of connection.
Abstract: Array-based gene expression analysis is a powerful
tool to profile expression of genes and to generate information on
therapeutic effects of new anti-cancer compounds. Anti-apoptotic
effect of thymoquinone was studied in MCF7 breast cancer cell line
using gene expression profiling with cDNA microarray. The purity
and yield of RNA samples were determined using RNeasyPlus Mini
kit. The Agilent RNA 6000 NanoLabChip kit evaluated the quantity
of the RNA samples. AffinityScript RT oligo-dT promoter primer
was used to generate cDNA strands. T7 RNA polymerase was used to
convert cDNA to cRNA. The cRNA samples and human universal
reference RNA were labelled with Cy-3-CTP and Cy-5-CTP,
respectively. Feature Extraction and GeneSpring softwares analysed
the data. The single experiment analysis revealed involvement of 64
pathways with up-regulated genes and 78 pathways with downregulated
genes. The MAPK and p38-MAPK pathways were
inhibited due to the up-regulation of PTPRR gene. The inhibition of
p38-MAPK suggested up-regulation of TGF-ß pathway. Inhibition of
p38-MAPK caused up-regulation of TP53 and down-regulation of
Bcl2 genes indicating involvement of intrinsic apoptotic pathway.
Down-regulation of CARD16 gene as an adaptor molecule regulated
CASP1 and suggested necrosis-like programmed cell death and
involvement of caspase in apoptosis. Furthermore, down-regulation
of GPCR, EGF-EGFR signalling pathways suggested reduction of
ER. Involvement of AhR pathway which control cytochrome P450
and glucuronidation pathways showed metabolism of Thymoquinone.
The findings showed differential expression of several genes in
apoptosis pathways with thymoquinone treatment in estrogen
receptor-positive breast cancer cells.
Abstract: In the past few decades, the field of chemistry
education has grown tremendously and researches indicated that after
traditional chemistry instruction students often lacked deep
conceptual understanding and failed to integrate their ideas into
coherent conceptual framework. For several concepts in chemistry,
students at all levels have demonstrated difficulty in changing their
initial perceptions. Their perceptions are most often wrong and don't
agree with correct scientific concepts. This study explored the
effectiveness of intervention discussion sections for a college general
chemistry course designed to apply research on students
preconceptions, knowledge integration and student explanation.
Three interventions discussions lasting three hours on bond energy
and spontaneity were done tested and intervention (treatment)
students’ performances were compared with that of control group
which did not use the experimental pedagogy. Results indicated that
this instruction which was capable of identifying students'
misconceptions, initial conceptions and integrating those ideas into
class discussion led to enhanced conceptual understanding and better
achievement for the experimental group.
Abstract: The main aim of the presented experiments is to
improve behaviour of sandwich structures under dynamic loading,
such as crash or explosion. This paper describes experimental
investigation on the response of new advanced materials to low and
high velocity load. Blast wave energy absorbers were designed using
two types of porous lightweight raw particle materials based on
expanded glass and ceramics with dimensions of 0.5-1 mm,
combined with polymeric binder. The effect of binder amount on the
static and dynamic properties of designed materials was observed.
Prism shaped specimens were prepared and loaded to obtain physicomechanical
parameters – bulk density, compressive and flexural
strength under quasistatic load, the dynamic response was determined
using Split Hopkinson Pressure bar apparatus. Numerical
investigation of the material behaviour in sandwich structure was
performed using implicit/explicit solver LS-Dyna. As the last step,
the developed material was used as the interlayer of blast resistant
litter bin, and it´s functionality was verified by real field blast tests.
Abstract: Power Regeneration in Refrigeration Plant concept
has been analyzed and has been shown to be capable of saving about
25% power in Cryogenic Plants with the Power Regeneration System
(PRS) running under nominal conditions. The innovative component
Compressor Expander Group (CEG) based on turbomachinery has
been designed and built modifying CETT compressor and expander,
both selected for optimum plant performance. Experiments have
shown the good response of the turbomachines to run with R404a as
working fluid. Power saving up to 12% under PRS derated conditions
(50% loading) has been demonstrated. Such experiments allowed
predicting a power saving up to 25% under CEG full load.
Abstract: The dissimilar joint between aluminum/titanium
alloys (Al 6082 and Ti G2) were successfully achieved by CO2 laser
welding with a single pass and without filler material using the
overlap joint design. Laser welding parameters ranges combinations
were experimentally determined using Taguchi approach with the
objective of producing welded joint with acceptable welding profile
and high quality of mechanical properties. In this study a joining of
dissimilar Al 6082 / Ti G2 was resulted in three distinct regions
fusion area in the weldment. These regions are studied in terms of its
microstructural characteristics and microhardness which are directly
affecting the welding quality.
The weld metal was mainly composed of martensite alpha prime.
In two different metals in the two different sides of joint HAZ, grain
growth was detected. The microhardness of the joint distribution also
has shown microhardness increasing in the HAZ of two base metals
and a varying microhardness in fusion zone.
Abstract: The article deals with modelling of the fire
pragmatism in the area of military management and its experimental
verification. Potential approaches are based on the synergy of
mathematical and theoretical ideas, operational and tactical
requirements and the military decision-making process. This issue
has taken on importance in recent times, particularly with the
increasing trend of digitized battlefield, the development of C4ISR
systems and intention to streamline the command and control process
at the lowest levels of command. From fundamental and
philosophical point of view, these new approaches seek to
significantly upgrade and enhance the decision-making process of the
tactical commanders.
Abstract: Customer churn prediction is one of the most useful
areas of study in customer analytics. Due to the enormous amount
of data available for such predictions, machine learning and data
mining have been heavily used in this domain. There exist many
machine learning algorithms directly applicable for the problem of
customer churn prediction, and here, we attempt to experiment on
a novel approach by using a cognitive learning based technique in
an attempt to improve the results obtained by using a combination
of supervised learning methods, with cognitive unsupervised learning
methods.
Abstract: Cemented carbide balls are usually implemented in
industry under the environment of high speed, high temperature,
corrosiveness and strong collisions. However, its application is limited
due to high fabrication cost, processing efficiency and quality. A novel
eccentric lapping method with two rotatable lapping plates was
proposed in this paper. A mathematical model was constructed to
analyze the influence of each design parameter on this lapping method.
To validate this new lapping method, an orthogonal experiment was
conducted with cemented carbide balls (YG6). The simulation model
was verified and the optimal lapping parameters were derived. The
results show that the surface roundness of the balls reaches to 0.65um
from 2um in 1 hour using this lapping method. So, using this novel
lapping method, it can effectively improve the machining precision
and efficiency of cemented carbide balls.
Abstract: This paper shows an experimental testing of a small
unit for combustion of solid fuels, such as charcoal and wood logs,
that can provide electricity. One of the concepts is that the unit does
not require qualified personnel for its operation. The unit itself is
composed of two main parts. The design requires a heat producing
stove and electricity producing thermoelectric generator. After the
construction the unit was tested and the results show that the
emission release is within the legislative requirements for emission
production and environmental protection. That qualifies such unit for
indoor application.