Abstract: Selective oxidation of H2S to elemental sulfur in a
fixed bed reactor over newly synthesized alumina nanocatalysts was
physio-chemically investigated and results compared with a
commercial Claus catalyst. Amongst these new materials, Al2O3-
supported sodium oxide prepared with wet chemical technique and
Al2O3 nanocatalyst prepared with spray pyrolysis method were the
most active catalysts for selective oxidation of H2S to elemental
sulfur. Other prepared nanocatalysts were quickly deactivated,
mainly due to the interaction with H2S and conversion into sulfides.
Abstract: The one of most important objects in implementation
of damage analysis observations is manner of dam break wave
propagation. In this paper velocity and wave height due dam break in
with and without tailwater states for appointment hazardous lands
and flood radius are investigate. In order to modeling above
phenomenon finite volume method of Roe type for solving shallow
water equations is used. Results indicated that in the dry bed state
risk radius due to dam break is too high. While in the wet bed risk
radius has a less wide. Therefore in the first state constructions and
storage facilities are encountered with destruction risk. Further
velocity due to dam break in the second state is more comparing to
the first state. Hence erosion and scour the river bed in the dry bed is
too more compare to the wet bed.
Abstract: In recent years, there have been attempts to store
natural gas in adsorptive form. This is called adsorptive natural gas,
or ANG. The problem with this technology is the low sorption
capacity. The purpose is to achieve compressed natural gas (CNG)
capacity of 230 V/V. Further research is required to achieve such
target. Several research studies have been performed with this target;
through either the modification or development of new sorbents or
the optimization of the operation sorption process itself. In this work,
storage of methane on molecular sieves 5A and 13X was studied on
dry basis, and on wet basis to certain extent. The temperature and the
pressure dynamics were investigated. The results indicated that
regardless of the charge pressure, the time for the peak temperature
during the methane charge process is always the same. This can be
used as a characteristic of the adsorbent. The total achieved
deliveries using molecular sieves were much lower than that of
activated carbons; 53.0 V/V for the case of 13X molecular sieves and
43 V/V for the case of 5A molecular sieves, both at 2oC and 4 MPa
(580 psi). Investigation of charge pressure dynamic using wet
molecular sieves at 2oC and a mass ratio of 0.5, revealed slowness of
the process and unexpected behavior.
Abstract: Carbon Capture & Storage (CCS) is one of the various
methods that can be used to reduce the carbon footprint of the
energy sector. This paper focuses on the absorption of CO2 from
flue gas using packed columns, whose efficiency is highly dependent
on the structure of the liquid films within the column. To study the
characteristics of liquid films a CFD solver, OpenFOAM is utilised
to solve two-phase, isothermal film flow using the volume-of-fluid
(VOF) method. The model was validated using existing experimental
data and the Nusselt theory. It was found that smaller plate inclination
angles, with respect to the horizontal plane, resulted in larger wetted
areas on smooth plates. However, only a slight improvement in
the wetted area was observed. Simulations were also performed
using a ridged plate and it was observed that these surface textures
significantly increase the wetted area of the plate. This was mainly
attributed to the channelling effect of the ridges, which helped to
oppose the surface tension forces trying to minimise the surface area.
Rivulet formations on the ridged plate were also flattened out and
spread across a larger proportion of the plate width.
Abstract: Our objectives were to evaluate the effects of sire
breed, type of protein supplement, level of supplementation and sex
on wool spinning fineness (SF), its correlations with other wool
characteristics and prediction accuracy in F1 Merino crossbred lambs.
Texel, Coopworth, White Suffolk, East Friesian and Dorset rams
were mated with 500 purebred Merino dams at a ratio of 1:100 in
separate paddocks within a single management system. The F1
progeny were raised on ryegrass pasture until weaning, before forty
lambs were randomly allocated to treatments in a 5 x 2 x 2 x 2
factorial experimental design representing 5 sire breeds, 2
supplementary feeds (canola or lupins), 2 levels of supplementation
(1% or 2% of liveweight) and sex (wethers or ewes). Lambs were
supplemented for six weeks after an initial three weeks of adjustment,
wool sampled at the commencement and conclusion of the feeding
trial and analyzed for SF, mean fibre diameter (FD), coefficient of
variation (CV), standard deviation, comfort factor (CF), fibre
curvature (CURV), and clean fleece yield. Data were analyzed using
mixed linear model procedures with sire fitted as a random effect,
and sire breed, sex, supplementary feed type, level of
supplementation and their second-order interactions as fixed effects.
Sire breed (P
Abstract: Natural gas usually includes H2S component which is
very toxic, hazardous and corrosive to environment, human being and
process equipments, respectively. Therefore, sweetening of the gas
(separation of H2S) is inevitable. To achieve this purpose, using
packed-bed columns with liquid absorbents such as MEA or DEA is
very common. Due to some problems of usual packed columns
especially high pressure drop of gas phase, a novel kind of them
called wetted-wire column (WWC) has been invented. The column
decreases the pressure drop significantly and improves the absorption
efficiency. The packings are very thin rods (like wire) and as long as
column. The column has 100 wires with a triangular arrangement and
counter current flows of gas and liquid phases. The observation
showed that at the same conditions, the absorption performance was
quite comparable to conventional packed-bed towers and a very low
pressure drop.
Abstract: Modeling and simulation of biochemical reactions is of great interest in the context of system biology. The central dogma of this re-emerging area states that it is system dynamics and organizing principles of complex biological phenomena that give rise to functioning and function of cells. Cell functions, such as growth, division, differentiation and apoptosis are temporal processes, that can be understood if they are treated as dynamic systems. System biology focuses on an understanding of functional activity from a system-wide perspective and, consequently, it is defined by two hey questions: (i) how do the components within a cell interact, so as to bring about its structure and functioning? (ii) How do cells interact, so as to develop and maintain higher levels of organization and functions? In recent years, wet-lab biologists embraced mathematical modeling and simulation as two essential means toward answering the above questions. The credo of dynamics system theory is that the behavior of a biological system is given by the temporal evolution of its state. Our understanding of the time behavior of a biological system can be measured by the extent to which a simulation mimics the real behavior of that system. Deviations of a simulation indicate either limitations or errors in our knowledge. The aim of this paper is to summarize and review the main conceptual frameworks in which models of biochemical networks can be developed. In particular, we review the stochastic molecular modelling approaches, by reporting the principal conceptualizations suggested by A. A. Markov, P. Langevin, A. Fokker, M. Planck, D. T. Gillespie, N. G. van Kampfen, and recently by D. Wilkinson, O. Wolkenhauer, P. S. Jöberg and by the author.
Abstract: The pulp and paper mill effluent is one of the high
polluting effluent amongst the effluents obtained from polluting
industries. All the available methods for treatment of pulp and paper
mill effluent have certain drawbacks. The coagulation is one of the
cheapest process for treatment of various organic effluents. Thus, the
removal of chemical oxygen demand (COD) and colour of paper mill
effluent is studied using coagulation process. The batch coagulation
process was performed using various coagulants like: aluminium
chloride, poly aluminium chloride and copper sulphate. The initial
pH of the effluent (Coagulation pH) has tremendous effect on COD
and colour removal. Poly aluminium chloride (PAC) as coagulant
reduced COD to 84 % and 92 % of colour was removed at an
optimum pH 5 and coagulant dose of 8 ml l-1. With aluminium
chloride at an optimum pH = 4 and coagulant dose of 5 g l-1, 74 %
COD and 86 % colour removal were observed. The results using
copper sulphate as coagulant (a less commercial coagulant) were
encouraging. At an optimum pH 6 and mass loading of 5 g l-1, 76 %
COD reduction and 78 % colour reduction were obtained. It was also
observed that after addition of coagulant, the pH of the effluent
decreases. The decrease in pH was highest for AlCl3, which was
followed by PAC and CuSO4. Significant amount of COD reductions
was obtained by coagulation process. Since the coagulation process
is the first stage for treatment of effluent and some of the coagulant
cations usually remain in the treated effluents. Thus, cation like
copper may be one of the good catalyst for second stage of treatment
process like wet oxidation. The copper has been found to be good
oxidation catalyst then iron and aluminum.
Abstract: Efficient luminescence is reported for the first time in Eu2+ activated double Chlorides A2BCl4 (A=Alkali metal, B=Alkaline earth element). A simple wet-chemical preparation is described. Emission intensities are comparable to that of the commercial phosphor. Excitation covers near UV region. These phosphors may be useful for applications like solid state lighting, scintillation detectors and X-ray storage using photo-stimulable phosphors.
Abstract: A cross-sectional study was carried out to determine the prevalence, species characterization and associated risk factors with Eimeria (E.) in sheep of district Toba Tek Singh from April, 2009 to March, 2010. Of the total 486 faecal samples examined for Eimeria, 209 (43%) were found infected with five species of Eimeria. Amongst the identified species of Eimeria, E. ovinoidalis was the commonest one (48.32%), followed in order by E. ahsata, E. intricata, E. parva and E. faurei with prevalence of 45.45, 28.71, 24.40 and 19.14 percent respectively. Peak prevalence was observed in August. Wet season (rainy and post-rainy) was found to be favourable for Eimeria infection. Lambs had significantly higher prevalence (P < 0.05) of Eimeria than adults. Similarly higher prevalence of Eimeria was observed in female as compared to male. Among management and husbandry practices; watering system, housing system, floor type and herd size strongly influenced the prevalence of Eimeria. Coccidiosis was more prevalent in closed housing system, non-cemented floor type, pond watered animals and larger herds (P < 0.05) as compared to open housing system, partially cemented floor type, tap watered animals and smaller herds respectively. Feeding system, breed and body condition of animals were not found as risk factors (P>0.05) influencing prevalence of Eimeria.
Abstract: Based on the field investigation and long term remote
sensing data, the dynamics of the alpine wetland in the river basin and
their response to climate change were studied. Results showed the
alpine wetlands accounted for 3.73% of total basin in 2010. Lake and
river appeared an increasing trend in the past 30 years, with an
increase of 34.36 % and 24.57%. However, swamp exhibited a
tendency of decreasing with 233.74 km2. Annual average temperature,
maximum temperature, minimum temperature and precipitation in the
river basin all exhibited an increasing trend, whereas relative humidity
exhibited a decreasing trend. Ice and snow melting are main reasons of
lake and river area enhancement and swamp area descend. There
existed 91.78%-97.86% of reduced swamp converted into lakes on the
basis of remote sensing image interpretation. China-s government
policy of implementing development in the river basin is the major
driving force of artificial wetland growth.
Abstract: The use of contour strips of perennial vegetation with
bio-fuel potential can improve surface water quality by reducing
NO3-N and sediment outflow from cropland to surface water-bodies.
It also has economic benefits of producing ethanol. In this study,
The Soil and Water Assessment Tool (SWAT) model was applied to
a watershed in Iowa, USA to examine the effectiveness of contour
strips of switch grass in reducing the NO3-N outflows from crop
fields to rivers or lakes. Numerical experiments were conducted to
identify potential subbasins in the watershed that have high water
quality impact, and to examine the effects of strip size on NO3-N
reduction under various meteorological conditions, i.e. dry, average
and wet years. Useful information was obtained for the evaluation of
economic feasibility of growing switch grass for bio-fuel in contour
strips. The results can assist in cost-benefit analysis and decisionmaking
in best management practices for environmental protection.
Abstract: The pollutant removal efficiency of the Intermittently
Decanted Extended Aeration (IDEA) wastewater treatment system at
Curtin University Sarawak Campus, and conventional activated
sludge wastewater treatment system at a local resort, Resort A, is
monitored. The influent and effluent characteristics are tested during
wet and dry weather conditions, and peak and off peak periods. For
the wastewater treatment systems at Curtin Sarawak and Resort A,
during dry weather and peak season, it was found that the BOD5
concentration in the influent is 121.7mg/L and 80.0mg/L
respectively, and in the effluent, 18.7mg/L and and 18.0mg/L
respectively. Analysis of the performance of the IDEA treatment
system showed that the operational costs can be minimized by 3%, by
decreasing the number of operating cycles. As for the treatment
system in Resort A, by utilizing a smaller capacity air blower, a
saving of 12% could be made in the operational costs.
Abstract: In this paper, the babbitting of a bearing in boiler feed pump of an electromotor has been studied. These bearings have an important role in reducing the shut down times in the pumps, compressors and turbines. The most conventional method in babbitting is casting as a melting method. The comparison between thermal spray and casting methods in babbitting shows that the thermal spraying babbitt layer has better performance and tribological behavior. The metallurgical and tribological analysis such as SEM, EDS and wet chemical analysis has been made in the Babbitt alloys and worn surfaces. Two type of babbitt materials: tinbase and lead-base babbitt was used. The benefits of thermally sprayed babbitt layers are completely clear especially in large bearings.
Abstract: The experimental thermal performance of two heat
exchangers in closed-wet cooling tower (CWCT) was investigated in
this study. The test sections are heat exchangers which have multi path
that is used as the entrance of cooling water and are consisting of
bare-type copper tubes between 15.88mm and 19.05mm. The process
fluids are the cooling water that flows from top part of heat exchanger
to bottom side in the inner side of tube, and spray water that flows
gravitational direction in the outer side of it. Air contacts its outer side
of that as it counterflows. Heat and mass transfer coefficients and
cooling capacity were calculated with variations of process fluids,
multi path and different diameter tubes to figure out the performance
of characteristics of CWCT.
The main results were summarized as follows: The results show this
experiment is reliable with values of heat and mass transfer
coefficients comparing to values of correlations. Heat and mass
transfer coefficients and cooling capacity of two paths are higher than
these with one path using 15.88 and 19.05mm tubes. Cooling capacity
per unit volume with 15.88mm tube using one and two paths are
higher than 19.05mm tube due to increase of surface area per unit
volume.
Abstract: The aim of this study was to examine the dynamics of functional composition of a non flooded Amazonian forest in response to drought stress in terms of diameter growth, recruitment and mortality. The survey was carried out in the continuous forest of the Biological dynamics of forest fragments project 90 km outside the city of Manaus, state of Amazonas Brazil. All stems >10 cm dbh where identified to species level and monitored in 18 one hectare permanent sample plots from 1981 to 2004.For statistical analysis all species where aggregated in three ecological guilds. Two distinct drought events occurred in 1983 and 1997. Results showed that more early successional species performed better than later successional ones. Response was significant for both events but for the 1997 event this was more pronounced possibly because of the fact that the event was in the middle of the dry rather than the wet period as was the 1983 one.
Abstract: This research aimed to modify pineapple leaf paper
(PALP) for using as wet media in the evaporation cooling system by
improving wet mechanical property (tensile strength) without
compromising water absorption property. Polyamideamineepichorohydrin
resin (PAE) and carboxymethylcellulose (CMC)
were used to strengthen the paper, and the PAE and CMC ratio of
80:20 showed the optimum wet and dry tensile index values, which
were higher than those of the commercial cooling pad (CCP).
Compared with CCP, PALP itself and all the PAE/CMC modified
PALP possessed better water absorption. The PAE/CMC modified
PALP had potential to become a new type of wet media.
Abstract: Since the beginning of human history, human
activities have caused many changes in the environment. Today, a
particular attention should be paid to gaining knowledge about water
quality of wetlands which are pristine natural environments rich in
genetic reserves. If qualitative conditions of industrial areas (in terms
of both physicochemical and biological conditions) are not addressed
properly, they could cause disruption in natural ecosystems,
especially in rivers. With regards to the quality of water resources,
determination of pollutant sources plays a pivotal role in engineering
projects as well as designing water quality control systems. Thus,
using different methods such as flow duration curves, dischargepollution
load model and frequency analysis by HYFA software
package, risk of various industrial pollutants in international and
ecologically important Gavkhoni wetland is analyzed. In this study, a
station located at Varzaneh City is used as the last station on
Zayanderud River, from where the river water is discharged into the
wetland. Results showed that elements- concentrations often
exceeded the allowed level and river water can endanger regional
ecosystem. In addition, if the river discharge is managed on Q25
basis, this basis can lower concentrations of elements, keeping them
within the normal level.
Abstract: This paper deals with the evaluation of flow properties
of polymeric matrix with natural animal fillers. Technical university
of Liberec cooperates on the long-term development of “green
materials“ that should replace conventionally used materials
(especially in automotive industry). Natural fibres (of animal and
plant origin) from all over the world are collected and adapted
(drying, cutting etc.) for extrusion processing. Inside the extruder
these natural additives are blended with polymeric (synthetic and
biodegradable - PLA) matrix and created compound is subsequently
cut for pellets in the wet way. These green materials with unique
recipes are then studied and their mechanical, physical and
processing properties are determined. The main goal of this research
is to develop new ecological materials very similar to unfilled
polymers. In this article the rheological behaviour of chosen natural
animal fibres is introduced considering their shape and surface that
were observed with use of SEM microscopy.
Abstract: Signalized intersections on high-volume arterials are
often congested during peak hours, causing a decrease in through
movement efficiency on the arterial. Much of the vehicle delay
incurred at conventional intersections is caused by high left-turn
demand. Unconventional intersection designs attempt to reduce
intersection delay and travel time by rerouting left-turns away from
the main intersection and replacing it with right-turn followed by Uturn.
The proposed new type of U-turn intersection is geometrically
designed with a raised island which provides a protected U-turn
movement. In this study several scenarios based on different
distances between U-turn and main intersection, traffic volume of
major/minor approaches and percentage of left-turn volumes were
simulated by use of AIMSUN, a type of traffic microsimulation
software. Subsequently some models are proposed in order to
compute travel time of each movement. Eventually by correlating
these equations to some in-field collected data of some implemented
U-turn facilities, the reliability of the proposed models are approved.
With these models it would be possible to calculate travel time of
each movement under any kind of geometric and traffic condition. By
comparing travel time of a conventional signalized intersection with
U-turn intersection travel time, it would be possible to decide on
converting signalized intersections into this new kind of U-turn
facility or not. However comparison of travel time is not part of the
scope of this research. In this paper only travel time of this innovative
U-turn facility would be predicted. According to some before and
after study about the traffic performance of some executed U-turn
facilities, it is found that commonly, this new type of U-turn facility
produces lower travel time. Thus, evaluation of using this type of
unconventional intersection should be seriously considered.