Abstract: The properties of hollow sandcrete blocks produced in
Minna, Nigeria are presented. Sandcrete block is made of cement,
water and sand binded together in certain mix proportions. For the
purpose of this work, fifty (50) commercial sandcrete block industries
were visited in Minna, Nigeria to obtain block samples and
aggregates used for the manufacture, and to take inventory of the mix
composition and the production process. Sieve analysis tests were
conduction on the soil sample from various block industries to
ascertain their quality to be used for block making. The mix ratios
were also investigated. Five (5) nine inches (9’’ or 225mm) blocks
were obtained from each block industry and tested for dimensional
compliance and compressive strength. The results of the soil test
shows that the grading fall within the limit for natural aggregate and
can easily are used to obtain workable mix. Physical examinations of
the block sizes show slight deviation from the standard requirement
in NIS 87:2000. Compressive strength of hollow sandcrete blocks in
range of 0.12 N/mm2 to 0.54 N/mm2 was obtained which is below the
recommendable value of 3.45 N/mm2 for load bearing hollow
sandcrete blocks. This indicates that these blocks are below the
standard for load-bearing sandcrete blocks and cannot be used as load
bearing walling units. The mix composition also indicated low
cement content resulting in low compressive strength. Most of the
commercial block industries visited does not take curing very serious.
Water were only sprinkled ones or twice before the blocks were
stacked and made readily available for sale. It is recommended that a
mix ratio of 1:4 to 1:6 should be used for the production of sandcrete
blocks and proper curing practice should be adhered. Blocks should
also be cured for 14 days before making them available for
consumers.
Abstract: In this paper, the problem of stability and stabilization
for neutral delay-differential systems with infinite delay is
investigated. Using Lyapunov method, new delay-independent
sufficient condition for the stability of neutral systems with infinite
delay is obtained in terms of linear matrix inequality (LMI).
Memory-less state feedback controllers are then designed for the
stabilization of the system using the feasible solution of the resulting
LMI, which are easily solved using any optimization algorithms.
Numerical examples are given to illustrate the results of the proposed
methods.
Abstract: Efficient use of energy, the increase in demand of
energy and also with the reduction of natural energy sources, has
improved its importance in recent years. Most of the losses in the
system from electricity produced until the point of consumption is
mostly composed by the energy distribution system. In this study,
analysis of the resulting loss in power distribution transformer and
distribution power cable is realized which are most of the losses in
the distribution system. Transformer losses in the real distribution
system are analyzed by CYME Power Engineering Software
program. These losses are disclosed for different voltage levels and
different loading conditions.
Abstract: This paper represents an experimental study of LPG
diffusion flame at elevated preheated air temperatures. The flame is
stabilized in a vertical water-cooled combustor by using air swirler. An
experimental test rig was designed to investigate the different
operating conditions. The burner head is designed so that the LPG fuel
issued centrally and surrounded by the swirling air issues from an air
swirler. There are three air swirlers having the same dimensions but
having different blade angles to give different swirl numbers of 0.5,
0.87 and 1.5. The combustion air was heated electrically before
entering the combustor up to a temperature about 500 K. Five air to
fuel mass ratios of 15, 20, 30, 40 and 50 were also studied. The effect
of preheated air temperature, swirl number and air to fuel mass ratios
on the temperature maps, visible flame length, high temperature region
(size) and exhaust species concentrations are studied. Some results
show that as the preheated air temperature increases, the volume of
high temperature region also increased but the flame length decreased.
Increasing the preheated air temperature, EINOx, EICO2 and EIO2
increased, while EICO decreased. Increasing the preheated air
temperature from 300 to 500 K, for all air swirl numbers used, the
highest increase in EINOx, EICO2 and EIO2 are 141, 4 and 65%,
respectively.
Abstract: In recent research copper and manganese systems
were found to be the most active in CO and organic compounds
oxidation among the base catalysts. The mixed copper manganese
oxide has been widely studied in oxidation reactions because of their
higher activity at low temperatures in comparison with single oxide
catalysts. The results showed that the formation of spinel
CuxMn3−xO4 in the oxidized catalyst is responsible for the activity
even at room temperature. That is why the most of the investigations
are focused on the hopcalite catalyst (CuMn2O4) as the best coppermanganese
catalyst. Now it’s known that this is true only for CO
oxidation, but not for mixture of CO and VOCs. The purpose of this
study is to investigate the alumina supported copper-manganese
catalysts with different Cu/Mn molar ratio in terms of oxidation of
CO, methanol and dimethyl ether. The catalysts were prepared by impregnation of γ-Al2O3 with
copper and manganese nitrates and the catalytic activity
measurements were carried out in two stage continuous flow
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions closest possible to the industrial. Gas
mixtures on the input and output of the reactor were analyzed with a
gas chromatograph, equipped with FID and TCD detectors. The
texture characteristics were determined by low-temperature (- 196oС)
nitrogen adsorption in a Quantachrome Instruments NOVA 1200e
(USA) specific surface area & pore analyzer. Thermal, XRD and
TPR analyses were performed. It was established that the active component of the mixed Cu-
Mn/γ–alumina catalysts strongly depends on the Cu/Mn molar ratio.
Highly active alumina supported Cu-Mn catalysts for CO, methanol
and DME oxidation were synthesized. While the hopcalite is the best
catalyst for CO oxidation, the best compromise for simultaneous
oxidation of all components is the catalyst with Cu/Mn molar ratio
1:5.
Abstract: A new fast growing trend in tourism is ecotourism, in
which tourists visit natural ecosystems under low impact, nonconsumptive
and locally oriented activities. Through these activities
species and habitats are maintained and typically, underdeveloped
regions are emphasized. Ecotourism provides a great alternative,
especially for rural and undeveloped area. At the same time, despite
its many benefits, it also poses many risks for the naturally protected
areas. If ecotourism is practiced improperly degradation and
irreversible damages could be the unwanted result. In addition, the
lack of MSc programs in the field of Ecotourism in Europe makes it a
necessity to be developed. Such an MSc program is being
implemented with the lead partner the Technical University of
Madrid. The entire partnership has six Universities, seven SMEs and
one National Park from seven different countries all over Europe.
The MSc will have 10 educational modules that will be available
online and will prepare professionals that will be able to implement
ecotourism in a sustainable way. Only through awareness and
education a sustainable ecotourism will be achieved in the protected
areas of Europe.
Abstract: It is a major challenge to build a bridge superstructure
that has long-term durability and low maintenance requirements. A
solution to this challenge may be to use new materials or to
implement new structural systems. Fiber Reinforced Polymer (FRP)
composites have continued to play an important role in solving some
of persistent problems in infrastructure applications because of its
high specific strength, light weight, and durability. In this study, the
concept of the hybrid FRP-concrete structural systems is applied to a
bridge superstructure. The hybrid FRP-concrete bridge superstructure
is intended to have durable, structurally sound, and cost effective
hybrid system that will take full advantage of the inherent properties
of both FRP materials and concrete. In this study, two hybrid FRP-concrete
bridge systems were investigated. The first system consists
of trapezoidal cell units forming a bridge superstructure. The second
one is formed by arch cells. The two systems rely on using cellular
components to form the core of the bridge superstructure, and an
outer shell to warp around those cells to form the integral unit of the
bridge. Both systems were investigated analytically by using finite
element (FE) analysis. From the rigorous FE studies, it was
concluded that first system is more efficient than the second.
Abstract: Based on Business and Consumer Survey (BCS) data,
the European Commission (EC) regularly publishes the monthly
Economic Sentiment Indicator (ESI) for each EU member state. ESI
is conceptualized as a leading indicator, aimed ad tracking the overall
economic activity. In calculating ESI, the EC employs arbitrarily
chosen weights on 15 BCS response balances. This paper raises the
predictive quality of ESI by applying nonlinear programming to find
such weights that maximize the correlation coefficient of ESI and
year-on-year GDP growth. The obtained results show that the highest
weights are assigned to the response balances of industrial sector
questions, followed by questions from the retail trade sector. This
comes as no surprise since the existing literature shows that the
industrial production is a plausible proxy for the overall Croatian
economic activity and since Croatian GDP is largely influenced by
the aggregate personal consumption.
Abstract: This work studies the effect of chemical composition
on the activity and selectivity of γ–alumina supported CuO/
MnO2/Cr2O3 catalysts toward deep oxidation of CO, dimethyl ether
(DME) and methanol. The catalysts were prepared by impregnation
of the support with an aqueous solution of copper nitrate, manganese
nitrate and CrO3 under different conditions. Thermal, XRD and TPR
analysis were performed. The catalytic measurements of single
compounds oxidation were carried out on continuous flow equipment
with a four-channel isothermal stainless steel reactor. Flow-line
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions that mimic closely the industrial
ones was used. The reactant and product gases were analyzed by
means of on-line gas chromatographs.
On the basis of XRD analysis it can be concluded that the active
component of the mixed Cu-Mn-Cr/γ–alumina catalysts consists of at
least six compounds – CuO, Cr2O3, MnO2, Cu1.5Mn1.5O4,
Cu1.5Cr1.5O4 and CuCr2O4, depending on the Cu/Mn/Cr molar ratio.
Chemical composition strongly influences catalytic properties, this
influence being quite variable with regards to the different processes.
The rate of CO oxidation rapidly decrease with increasing of
chromium content in the active component while for the DME was
observed the reverse trend. It was concluded that the best
compromise are the catalysts with Cu/(Mn + Cr) molar ratio 1:5 and
Mn/Cr molar ratio from 1:3 to 1:4.
Abstract: This paper presents a rheological model for producing
shape-memory thermoplastic polymers. Shape-memory occurs as a
result of internal rearrangement of the structural elements of a
polymer. A non-linear viscoelastic model was developed that allows
qualitative and quantitative prediction of the stress-strain behavior of
shape-memory polymers during heating. This research was done to
develop a technique to determine the maximum possible change in
size of shape-memory products during heating. The rheological
model used in this work was particularly suitable for defining process
parameters and constructive parameters of the processing equipment.
Abstract: Mobil Producing Nigeria Unlimited (MPNU), a
subsidiary of ExxonMobil and the highest crude oil & condensate
producer in Nigeria has its operational base and an oil terminal, the
Qua Iboe terminal (QIT) located at Ibeno, Nigeria. Other oil
companies like Network Exploration and Production Nigeria Ltd,
Frontier Oil Ltd; Shell Petroleum Development Company Ltd; Elf
Petroleum Nigeria Ltd and Nigerian Agip Energy, a subsidiary of the
Italian ENI E&P operate onshore, on the continental shelf and in deep
offshore of the Atlantic Ocean, respectively with the coastal waters of
Ibeno, Nigeria as the nearest shoreline. This study was designed to
delineate the oil-polluted sites in Ibeno, Nigeria using
microbiological and physico-chemical characterization of soils,
sediments and ground and surface water samples from the study area.
Results obtained revealed that there have been significant recent
hydrocarbon inputs into this environment as observed from the high
counts of hydrocarbonoclastic microorganisms in excess of 1% at all
the stations sampled. Moreover, high concentrations of THC, BTEX
and heavy metals contents in all the samples analyzed corroborate the
high recent crude oil input into the study area. The results also
showed that the pollution of the different environmental media
sampled were of varying degrees, following the trend: ground water
> surface water > sediments > soils.
Abstract: It is an established fact that polymers have several
physical limitations such as low stiffness and low resistance to
impact on loading. Hence, polymers do not usually have requisite
mechanical strength for application in various fields. The
reinforcement by high strength fibers provides the polymer
substantially enhanced mechanical properties and makes them more
suitable for a large number of diverse applications. This research
evaluates the effects of particulate Cow bone and Groundnut shell
additions on the mechanical properties and microstructure of cow
bone and groundnut shell reinforced epoxy composite in order to
assess the possibility of using it as a material for engineering
applications. Cow bone and groundnut shell particles reinforced with
epoxy (CBRPC and GSRPC) was prepared by varying the cow bone
and groundnut shell particles from 0-25 wt% with 5 wt% intervals. A
Hybrid of the Cow bone and Groundnut shell (HGSCB) reinforce
with epoxy was also prepared. The mechanical properties of the
developed composites were investigated. Optical microscopy was
used to examine the microstructure of the composites. The results
revealed that mechanical properties did not increase uniformly with
additions in filler but exhibited maximum properties at specific
percentages of filler additions. From the Microscopic evaluation, it
was discovered that homogeneity decreases with increase in % filler,
this could be due to poor interfacial bonding.
Abstract: Diagnostic enzymes like aspartate aminotransferase
(AST), alanine aminotransferase (ALT) and alkaline phosphatase
(ALP) were determined as indices of heavy metal pollution in Tilapia
guinensis. Three different sets of fishes treated with lead (Pb), iron
(Fe) and copper (Cu) were used for the study while a fourth group
with no heavy metal served as a control. Fishes in each of the groups
were exposed to 2.65mg/l of Pb, 0.85mg/l of Fe and 0.35 mg/l of Cu
in aerated aquaria for 96 hours. Tissue fractionation of the liver
tissues was carried out and the three diagnostic enzymes (AST, ALT,
and ALP) were estimated. Serum levels of the same diagnostic
enzymes were also measured. The mean values of the serum enzyme
activity for ALP in each experimental group were 19.5±1.62,
29.67±2.17 and 1.15±0.27 IU/L for Pb, Fe and Cu groups compared
with 9.99±1.34 IU/L enzyme activity in the control. This result
showed that Pb and Fe caused increased release of the enzyme into
the blood circulation indicating increased tissue damage while Cu
caused a reduction in the serum level as compared with the level in
the control group. The mean values of enzyme activity obtained in
the liver were 102.14±6.12, 140.17±2.06 and 168.23±3.52 IU/L for
Pb, Fe and Cu groups, respectively compared to 91.20±9.42 IU/L
enzyme activity for the control group. The serum and liver AST and
ALT activities obtained in Pb, Fe, Cu and control groups are
reported. It was generally noted that the presence of the heavy metal
caused liver tissues damage and consequent increased level of the
diagnostic enzymes in the serum.
Abstract: Experimental investigations of the DC electric field effect on thermal decomposition of biomass, formation of the axial flow of volatiles (CO, H2, CxHy), mixing of volatiles with swirling airflow at low swirl intensity (S ≈ 0.2-0.35), their ignition and on formation of combustion dynamics are carried out with the aim to understand the mechanism of electric field influence on biomass gasification, combustion of volatiles and heat energy production. The DC electric field effect on combustion dynamics was studied by varying the positive bias voltage of the central electrode from 0.6 kV to 3 kV, whereas the ion current was limited to 2 mA. The results of experimental investigations confirm the field-enhanced biomass gasification with enhanced release of volatiles and the development of endothermic processes at the primary stage of thermochemical conversion of biomass determining the field-enhanced heat energy consumption with the correlating decrease of the flame temperature and heat energy production at this stage of flame formation. Further, the field-enhanced radial expansion of the flame reaction zone correlates with a more complete combustion of volatiles increasing the combustion efficiency by 3% and decreasing the mass fraction of CO, H2 and CxHy in the products, whereas by 10% increases the average volume fraction of CO2 and the heat energy production downstream the combustor increases by 5-10%
Abstract: Intermittent behavior near the boundary of phase
synchronization in the presence of noise is studied. In certain range of
the coupling parameter and noise intensity the intermittency of eyelet
and ring intermittencies is shown to take place. Main results are
illustrated using the example of two unidirectional coupled Rössler
systems. Similar behavior is shown to take place in two
hydrodynamical models of Pierce diode coupled unidirectional.
Abstract: Toxicity of copper (Cu), lead (Pb) and iron (Fe) to
Tilapia guinensis was carried out for 4 days with a view to
determining their effects on the liver and muscle tissues. Tilapia
guinensis samples of about 10 - 14cm length and 0.2 – 0.4kg weight
each were obtained from University of Calabar fish ponds and
acclimated for three (3) days before the experimental set up.
Survivors after the 96-hr LC50 test period were selected from test
solutions of the heavy metals for the histopathological studies.
Histological preparations of liver and muscle tissues were randomly
examined for histopathological lesions. Results of the histological
examinations showed gross abnormalities in the liver tissues due to
pathological and degenerative changes compared to liver and muscle
tissues from control samples (tilapia fishes from aquaria without
heavy metals). Extensive hepatocyte necrosis with chronic
inflammatory changes was observed in the liver of fishes exposed to
Cu solution. Similar but less damaging effects were observed in the
liver of fishes exposed to Pb and Fe. The extent of lesion observed
was therefore heavy metal-related. However, no pathologic changes
occurred in the muscle tissues.
Abstract: In this work, the Ictalurus punctatus species estimated
available physical habitat is compared with the estimated physical
habitat for the same but modified river reach, with the aim of creating
a linear park, along a length of 5 500 m.
To determine the effect of ecological park construction, on
physical habitat of the Lerma river stretch of study, first, the available
habitat for the Ictalurus punctatus species was estimated through the
simulation of the physical habitat, by using surveying, hydraulics,
and habitat information gotten at the river reach in its actual situation.
Second, it was estimated the available habitat for the above species,
upon the simulation of the physical habitat through the proposed
modification for the ecological park creation. Third, it is presented a
comparison between both scenarios in terms of available habitat
estimated for Ictalurus punctatus species, concluding that in cases of
adult and spawning life stages, changes in the channel to create an
ecological park would produce a considerable loss of potentially
usable habitat (PUH), while in the case of the juvenile life stage PUH
remains virtually unchanged, and in the case of life stage fry the PUH
would increase due to the presence of velocities and depths of lesser
magnitude, due to the presence of minor flow rates and lower volume
of the wet channel.
It is expected that habitat modification for linear park construction
may produce the lack of Ictalurus punktatus species conservation at
the river reach of the study.
Abstract: The venture capital becomes more and more advanced
and effective source of the innovation project financing, connected
with a high-risk level. In the developed countries, it plays a key role
in transforming innovation projects into successful businesses and
creating the prosperity of the modern economy. In Russia, there are
many necessary preconditions for creation of the effective venture
investment system: the network of the public institutes for innovation
financing operates; there is a significant number of the small and
medium-sized enterprises, capable to sell production with good
market potential. However, the current system does not confirm the
necessary level of efficiency in practice that can be substantially
explained by the absence of the accurate plan of action to form the
national venture model and by the lack of experience of successful
venture deals with profitable exits in Russian economy. This paper
studies the influence of various factors on the venture industry
development by the example of the IT-sector in Russia. The choice of
the sector is based on the fact, that this segment is the main driver of
the venture capital market growth in Russia, and the necessary set of
data exists. The size of investment of the second round is used as the
dependent variable. To analyse the influence of the previous round,
such determinant as the volume of the previous (first) round
investments is used. There is also used a dummy variable in
regression to examine that the participation of an investor with high
reputation and experience in the previous round can influence the size
of the next investment round. The regression analysis of short-term
interrelations between studied variables reveals prevailing influence
of the volume of the first round investments on the venture
investments volume of the second round. The most important
determinant of the value of the second-round investment is the value
of first–round investment, so it means that the most competitive on
the Russian market are the start-up teams that can attract more money
on the start, and the target market growth is not the factor of crucial
importance. This supports the point of view that VC in Russia is
driven by endogenous factors and not by exogenous ones that are
based on global market growth.
Abstract: Doxorubicin (DOX) is an anthracycline drug used to treat many cancer diseases. Similarly to other cytostatic drugs, DOX has serious side effects; the biggest obstacle is the cardiotoxicity. With the aim of lowering the negative side effects and to target the DOX into the tumor tissue, the different nanoparticles (NPs) are studied. The aim of this work was to synthetized different NPs and conjugated them with DOX and determine the binding capacity of the NPs. For this experiment, carbon nanotubes (CNTs), graphene oxide (GO), fullerene (FUL) and liposomes (LIP) were used. The highest binding capacity was observed in GO (85%). Subsequently the toxicity of NPs and NPs-DOX conjugates was analyzed in in vivo system (chicken embryos). Some NPs (GO) can increase the toxicity of DOX, whereas other NPs (LIP, CNTs) decrease DOX toxicity.
Abstract: Surf is an increasingly popular sport and its performance evaluation is often qualitative. This work aims at using a smartphone to collect and analyze the GPS and inertial sensors data in order to obtain quantitative metrics of the surfing performance. Two approaches are compared for detection of wave rides, computing the number of waves rode in a surfing session, the starting time of each wave and its duration. The first approach is based on computing the velocity from the Global Positioning System (GPS) signal and finding the velocity thresholds that allow identifying the start and end of each wave ride. The second approach adds information from the Inertial Measurement Unit (IMU) of the smartphone, to the velocity thresholds obtained from the GPS unit, to determine the start and end of each wave ride. The two methods were evaluated using GPS and IMU data from two surfing sessions and validated with similar metrics extracted from video data collected from the beach. The second method, combining GPS and IMU data, was found to be more accurate in determining the number of waves, start time and duration. This paper shows that it is feasible to use smartphones for quantification of performance metrics during surfing. In particular, detection of the waves rode and their duration can be accurately determined using the smartphone GPS and IMU.