Abstract: Continuous upflow filters can combine the nutrient
(nitrogen and phosphate) and suspended solid removal in one unit
process. The contaminant removal could be achieved chemically or
biologically; in both processes the filter removal efficiency depends
on the interaction between the packed filter media and the influent. In
this paper a residence time distribution (RTD) study was carried out
to understand and compare the transfer behaviour of contaminants
through a selected filter media packed in a laboratory-scale
continuous up flow filter; the selected filter media are limestone and
white dolomite. The experimental work was conducted by injecting a
tracer (red drain dye tracer –RDD) into the filtration system and then
measuring the tracer concentration at the outflow as a function of
time; the tracer injection was applied at hydraulic loading rates
(HLRs) (3.8 to 15.2 m h-1). The results were analysed according to
the cumulative distribution function F(t) to estimate the residence
time of the tracer molecules inside the filter media. The mean
residence time (MRT) and variance σ2 are two moments of RTD that
were calculated to compare the RTD characteristics of limestone with
white dolomite. The results showed that the exit-age distribution of
the tracer looks better at HLRs (3.8 to 7.6 m h-1) and (3.8 m h-1) for
limestone and white dolomite respectively. At these HLRs the
cumulative distribution function F(t) revealed that the residence time
of the tracer inside the limestone was longer than in the white
dolomite; whereas all the tracer took 8 minutes to leave the white
dolomite at 3.8 m h-1. On the other hand, the same amount of the
tracer took 10 minutes to leave the limestone at the same HLR. In
conclusion, the determination of the optimal level of hydraulic
loading rate, which achieved the better influent distribution over the
filtration system, helps to identify the applicability of the material as
filter media. Further work will be applied to examine the efficiency
of the limestone and white dolomite for phosphate removal by
pumping a phosphate solution into the filter at HLRs (3.8 to 7.6 m h-1).
Abstract: In this work, we have synthesized BaTiO3 via sol gel method by sintering at different temperatures (600, 700, 800, 900, 10000C) and studied their structural, optical and ferroelectric properties through X-ray diffraction (XRD), UV-Vis spectrophotometer and PE Loop Tracer. X-ray diffraction patterns of barium titanate samples show that the peaks of the diffractogram are successfully indexed with the tetragonal and cubic structure of BaTiO3. The Optical band gap calculated through UV Visible spectrophotometer varies from 4.37 to 3.80 eV for the samples sintered at 600 to 10000C, respectively. The particle size calculated through transmission electron microscopy varies from 20 to 40 nm for the samples sintered at 600 to 10000C, respectively. Moreover, it has been observed that the ferroelectricity increases as we increase the sintering temperature.
Abstract: Fecal coliform bacteria are widely used as indicators of
sewage contamination in surface water. However, there are some
disadvantages in these microbial techniques including time consuming
(18-48h) and inability in discriminating between human and animal
fecal material sources. Therefore, it is necessary to seek a more
specific indicator of human sanitary waste. In this study, the feasibility
was investigated to apply caffeine and human pharmaceutical
compounds to identify the human-source contamination. The
correlation between caffeine and fecal coliform was also explored.
Surface water samples were collected from upstream, middle-stream
and downstream points respectively, along Rochor Canal, as well as 8
locations of Marina Bay. Results indicate that caffeine is a suitable
chemical tracer in Singapore because of its easy detection (in the range
of 0.30-2.0 ng/mL), compared with other chemicals monitored.
Relative low concentrations of human pharmaceutical compounds (<
0.07 ng/mL) in Rochor Canal and Marina Bay water samples make
them hard to be detected and difficult to be chemical tracer. However,
their existence can help to validate sewage contamination. In addition,
it was discovered the high correlation exists between caffeine
concentration and fecal coliform density in the Rochor Canal water
samples, demonstrating that caffeine is highly related to the
human-source contamination.