Abstract: In this paper the combination of thermal oxidation and
electrochemical anodizing processes is used to produce titanium
oxide layers. The response of titanium alloy Ti6Al4V to oxidation
processes at various temperatures and electrochemical anodizing in
various voltages are investigated. Scanning electron microscopy
(SEM); X-Ray Diffraction (XRD) and porosity determination have
been used to characterize the oxide layer thickness, surface
morphology, oxide layer-substrate adhesion and porosity. In the first
experiment, samples modified by thermal oxidation process then
followed by electrochemical anodizing. Second experiment consists
of surfaces modified by electrochemical anodizing process and then
followed by thermal oxidation. The first method shows better
properties than other one. In second experiment, Surfaces modified
were achieved by thicker and more adherent thick oxide layers on
titanium surface. The existence of an electrochemical anodized oxide
layer did not improve the adhesion of thermal oxide layer. The high
temperature, thermal formation of an oxide layer leads to a coarse
oxide grain morphology and a complete oxidative particle. In
addition, in high temperature oxidation porosity content is increased.
The oxide layer of thermal oxidation and electrochemical anodizing
processes; on Ti–6Al–4V substrate was covered with different
colored oxide layers.
Abstract: In this investigation, anatase TiO2 thin films were
grown by radio frequency magnetron sputtering on glass substrates at
a high sputtering pressure and room temperature. The anatase films
were then annealed at 300-600 °C in air for a period of 1 hour. To
examine the structure and morphology of the films, X-ray diffraction
(XRD) and atomic force microscopy (AFM) methods were used
respectively. From X-ray diffraction patterns of the TiO2 films, it was
found that the as-deposited film showed some differences compared
with the annealed films and the intensities of the peaks of the
crystalline phase increased with the increase of annealing
temperature. From AFM images, the distinct variations in the
morphology of the thin films were also observed. The optical
constants were characterized using the transmission spectra of the
films obtained by UV-VIS-IR spectrophotometer. Besides, optical
thickness of the film deposited at room temperature was calculated
and cross-checked by taking a cross-sectional image through SEM.
The optical band gaps were evaluated through Tauc model. It was
observed that TiO2 films produced at room temperatures exhibited
high visible transmittance and transmittance decreased slightly with
the increase of annealing temperatures. The films were found to be
crystalline having anatase phase. The refractive index of the films
was found from 2.31-2.35 in the visible range. The extinction
coefficient was nearly zero in the visible range and was found to
increase with annealing temperature. The allowed indirect optical
band gap of the films was estimated to be in the range from 3.39 to
3.42 eV which showed a small variation. The allowed direct band
gap was found to increase from 3.67 to 3.72 eV. The porosity was
also found to decrease at a higher annealing temperature making the
film compact and dense.
Abstract: In this paper, a methodology of a model based on
predicting the tool forces oblique machining are introduced by
adopting the orthogonal technique. The applied analytical calculation
is mostly based on Devries model and some parts of the methodology
are employed from Amareggo-Brown model. Model validation is
performed by comparing experimental data with the prediction results
on machining titanium alloy (Ti-6Al-4V) based on micro-cutting tool
perspective. Good agreements with the experiments are observed. A
detailed friction form that affected the tool forces also been examined
with reasonable results obtained.
Abstract: Highly ordered TiO2 nanotube (TNT) arrays were
fabricated onto a pre-treated titanium foil by anodic oxidation with a
voltage of 20V in phosphoric acid/sodium fluoride electrolyte. A pretreatment
of titanium foil involved washing with acetone,
isopropanol, ethanol and deionized water. Carbon doped TiO2
nanotubes (C-TNT) was fabricated 'in-situ' with the same method in
the presence of polyvinyl alcohol and urea as carbon sources. The
affects of polyvinyl alcohol concentration and oxidation time on the
composition, morphology and structure of the C-TN were studied by
FE-SEM, EDX and XRD techniques. FESEM images of the
nanotubes showed uniform arrays of C-TNTs. The density and
microstructures of the nanotubes were greatly affected by the content
of PVA. The introduction of the polyvinyl alcohol into the electrolyte
increases the amount of C content inside TiO2 nanotube arrays
uniformly. The influence of carbon content on the photo-current of
C-TNT was investigated and the I-V profiles of the nanotubes were
established. The preliminary results indicated that the 'in-situ'
doping technique produced a superior quality nanotubes compared to
post doping techniques.
Abstract: Commercial nanocomposite food packaging type nano-silver containers were characterised using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). The presence of nanoparticles consistent with the incorporation of 1% nano-silver (Ag) and 0.1% titanium dioxide (TiO2) nanoparticle into polymeric materials formed into food containers was confirmed. Both nanomaterials used in this type of packaging appear to be embedded in a layered configuration within the bulk polymer. The dimensions of the incorporated nanoparticles were investigated using X-ray diffraction (XRD) and determined by calculation using the Scherrer Formula; these were consistent with Ag and TiO2 nanoparticles in the size range 20-70nm both were spherical shape nanoparticles. Antimicrobial assessment of the nanocomposite container has also been performed and the results confirm the antimicrobial activity of Ag and TiO2 nanoparticles in food packaging containers. Migration assessments were performed in a wide range of food matrices to determine the migration of nanoparticles from the packages. The analysis was based upon the relevant European safety Directives and involved the application of inductively coupled plasma mass spectrometry (ICP-MS) to identify the range of migration risk. The data pertain to insignificance levels of migration of Ag and TiO2 nanoparticles into the selected food matrices.
Abstract: Titanium oxide hollow microspheres were synthesized from organic precursor titanium tetraisopropoxide (TTIP) using continuous spray pyrolysis reactor. Effects of precursor concentration, applied voltage and annealing have been investigated. It was observed that the annealing of the as-synthesized TiO2 hollow microspheres at 2500C, which had an average external diameter of 200 nm, leads to an increase in the size and also more spherical shape. The precursor concentration was found to have a direct impact on the size of the microspheres, which is also evident in the absorption spectrum. The as-prepared TiO2 hollow microspheres exhibited good photocatalytic activity for the degradation of MO.
Abstract: The aim of the work was to attenuate the vibration amplitude in CESNA 172 airplane wing by using Functionally Graded Material instead of uniform or composite material. Wing strength was achieved by means of stress analysis study, while wing vibration amplitudes and shapes were achieved by means of Modal and Harmonic analysis. Results were verified by applying the methodology in a simple cantilever plate to the simple model and the results were promising and the same methodology can be applied to the airplane wing model. Aluminum models, Titanium models, and functionally graded materials of Aluminum and titanium results were compared to show a great vibration attenuation after using the FGM. Optimization in FGM gradation satisfied our objective of reducing and attenuating the vibration amplitudes to show the effect of using FGM in vibration behavior. Testing the Aluminum rich models, and comparing it with the titanium rich model was an optimization in this paper. Results have shown a significant attenuation in vibration magnitudes when using FGM instead of Titanium Plate, and Aluminium wing with FGM Spurs instead of Aluminium wings. It was also recommended that in future, changing the graphical scale to 1:10 or even 1:1 when the computers- capabilities allow.
Abstract: Composites based on a biodegradable polycaprolactone (PCL) containing 0.5, 1.0 and 2.0 wt % of titanium dioxide (TiO2) micro and nanoparticles were prepared by melt mixing and the effect of filler type and contents on the thermal properties, dynamic-mechanical behaviour and morphology were investigated. Measurements of storage modulus and loss modulus by dynamic mechanical analysis (DMA) showed better results for microfilled PCL/TiO2 composites than nanofilled composites, with the same filler content. DSC analysis showed that the Tg and Tc of micro and nanocomposites were slightly lower than those of neat PCL. The crystallinity of the PCL increased with the addition of TiO2 micro and nanoparticles; however, the cc for the PCL was unchanged with micro TiO2 content. The thermal stability of PCL/TiO2 composites were characterized using thermogravimetric analysis (TGA). The initial weight loss (5 wt %) occurs at slightly higher temperature with micro and nano TiO2 addition and with increasing TiO2 content.
Abstract: Sol-gel method has been used to fabricate
nanocomposite films on glass substrates composed halloysite clay
mineral and nanocrystalline TiO2. The methodology for the synthesis
involves a simple chemistry method utilized nonionic surfactant
molecule as pore directing agent along with the acetic acid-based solgel
route with the absence of water molecules. The thermal treatment
of composite films at 450oC ensures elimination of organic material
and lead to the formation of TiO2 nanoparticles onto the surface of
the halloysite nanotubes. Microscopy techniques and porosimetry
methods used in order to delineate the structural characteristics of the
materials. The nanocomposite films produced have no cracks and
active anatase crystal phase with small crystallite size were deposited
on halloysite nanotubes. The photocatalytic properties for the new
materials were examined for the decomposition of the Basic Blue 41
azo dye in solution. These, nanotechnology based composite films
show high efficiency for dye’s discoloration in spite of different
halloysite quantities and small amount of halloysite/TiO2 catalyst
immobilized onto glass substrates. Moreover, we examined the
modification of the halloysite/TiO2 films with silver particles in order
to improve the photocatalytic properties of the films. Indeed, the
presence of silver nanoparticles enhances the discoloration rate of the
Basic Blue 41 compared to the efficiencies obtained for unmodified
films.
Abstract: The blood ducts must be occluded to avoid loss of
blood from vessels in laparoscopic surgeries. This paper presents a
locking mechanism to be used in a ligation laparoscopic procedure
(LigLAP I), as an alternative solution for a stapling procedure.
Currently, stapling devices are being used to occlude vessels. Using
these devices may result in some problems, including injury of bile
duct, taking up a great deal of space behind the vessel, and bile leak.
In this new procedure, a two-layer suture occludes a vessel. A
locking mechanism is also required to hold the suture. Since there is
a limited space at the device tip, a Shape Memory Alloy (SMA)
actuator is used in this mechanism. Suitability for cleanroom
applications, small size, and silent performance are among the
advantages of SMA actuators in biomedical applications. An
experimental study is conducted to examine the function of the
locking mechanism. To set up the experiment, a prototype of a
locking mechanism is built using nitinol, which is a nickel-titanium
shape memory alloy. The locking mechanism successfully locks a
polymer suture for all runs of the experiment. In addition, the effects
of various surface materials on the applied pulling forces are studied.
Various materials are mounted at the mechanism tip to compare the
maximum pulling forces applied to the suture for each material. The
results show that the various surface materials on the device tip
provide large differences in the applied pulling forces.
Abstract: The field of biomedical materials plays an imperative
requisite and a critical role in manufacturing a variety of biological
artificial replacements in a modern world. Recently, titanium (Ti)
materials are being used as biomaterials because of their superior
corrosion resistance and tremendous specific strength, free- allergic
problems and the greatest biocompatibility compared to other
competing biomaterials such as stainless steel, Co-Cr alloys,
ceramics, polymers, and composite materials. However, regardless of
these excellent performance properties, Implantable Ti materials have
poor shear strength and wear resistance which limited their
applications as biomaterials. Even though the wear properties of Ti
alloys has revealed some improvements, the crucial effectiveness of
biomedical Ti alloys as wear components requires a comprehensive
deep understanding of the wear reasons, mechanisms, and techniques
that can be used to improve wear behavior. This review examines
current information on the effect of thermal and thermomechanical
processing of implantable Ti materials on the long-term prosthetic
requirement which related with wear behavior. This paper focuses
mainly on the evolution, evaluation and development of effective
microstructural features that can improve wear properties of bio
grade Ti materials using thermal and thermomechanical treatments.
Abstract: In turning hardened steel, polycrystalline cubic boron
nitride (cBN) compacts are widely used, due to their higher hardness
and higher thermal conductivity. However, in milling hardened steel,
fracture of cBN cutting tools readily occurs because they have poor
fracture toughness. Therefore, coated cemented carbide tools, which
have good fracture toughness and wear resistance, are generally
widely used. In this study, hardened steel (ASTM D2, JIS SKD11,
60HRC) was milled with three physical vapor deposition
(PVD)-coated cemented carbide end mill cutters in order to determine
effective tool materials for cutting hardened steel at high cutting
speeds. The coating films used were (Ti,W)N/(Ti,W,Si)N and
(Ti,W)N/(Ti,W,Si,Al)N coating films. (Ti,W,Si,Al)N is a new type of
coating film. The inner layer of the (Ti,W)N/(Ti,W,Si)N and
(Ti,W)N/(Ti,W,Si,Al)N coating system is (Ti,W)N coating film, and
the outer layer is (Ti,W,Si)N and (Ti,W,Si,Al)N coating films,
respectively. Furthermore, commercial (Ti,Al)N-based coating film
was also used. The following results were obtained: (1) In milling
hardened steel at a cutting speed of 3.33 m/s, the tool wear width of the
(Ti,W)N/(Ti,W,Si,Al)N-coated tool was smaller than that of the
(Ti,W)N/(Ti,W,Si)N-coated tool. And, compared with the commercial
(Ti,Al)N, the tool wear width of the (Ti,W)N/(Ti,W,Si,Al)N-coated
tool was smaller than that of the (Ti,Al)N-coated tool. (2) The tool
wear of the (Ti,W)N/(Ti,W,Si,Al)N-coated tool increased with an
increase in cutting speed. (3) The (Ti,W)N/(Ti,W,Si,Al)N-coated
cemented carbide was an effective tool material for high-speed cutting
below a cutting speed of 3.33 m/s.
Abstract: Characteristics and sonocatalytic activity of zeolite
Y catalysts loaded with TiO2 using impregnation and ion exchange
methods for the degradation of amaranth dye were investigated.
The Ion-exchange method was used to encapsulate the TiO2 into
the internal pores of the zeolite while the incorporation of TiO2
mostly on the external surface of zeolite was carried out using the
impregnation method. Different characterization techniques were
used to elucidate the physicochemical properties of the produced
catalysts. The framework of zeolite Y remained virtually
unchanged after the encapsulation of TiO2 while the crystallinity of
zeolite decreased significantly after the incorporation of 15 wt% of
TiO2. The sonocatalytic activity was enhanced by TiO2
incorporation with maximum degradation efficiencies of 50% and
68% for the encapsulated titanium and titanium loaded onto the
zeolite, respectively after 120min of reaction. Catalysts
characteristics and sonocatalytic behaviors were significantly
affected by the preparation method and the location of TiO2
introduced with zeolite structure. Behaviors in the sonocatalytic
process were successfully correlated with the characteristics of the
catalysts used.
Abstract: The peculiarities of the nanoscale structure-phase
states formed after electroexplosive carburizing and subsequent
electron-beam treatment of technically pure titanium surface in different regimes are established by methods of transmission electron
diffraction microscopy and physical mechanisms are discussed. Electroexplosive carburizing leads to surface layer formation
(40 m thickness) with increased (in 3.5 times) microhardness. It consists of β-titanium, graphite (monocrystals 100-150 nm,
polycrystals 5-10 nm, amorphous particles 3-5nm), TiC (5-10 nm), β-Ti02 (2-20nm). After electron-beam treatment additionally increasing the microhardness the surface layer consists of TiC.