Abstract: Mixtures of sand and clay are frequently used to serve for specific purposes in several engineering practices. In environmental engineering, liner layers and cover layers are common for controlling waste disposal facilities. These layers are exposed to moisture and temperature fluctuation specially when existing in unsaturated condition. The relationship between soil suction and water content for these materials is essential for understanding their unsaturated behavior and properties such as retention capacity and unsaturated follow (hydraulic conductivity). This study is aimed at investigating retention capacity for two sand-natural expansive clay mixtures (15% (C15) and 30% (C30) expansive clay) at two ambient temperatures within the range of 5 -50 °C. Soil water retention curves (SWRC) for these materials were determined at these two ambient temperatures using different salt solutions for a wide range of suction (up to 200MPa). The results indicate that retention capacity of C15 mixture underwent significant changes due to temperature variations. This effect tends to be less visible when the clay fraction is doubled (C30). In addition, the overall volume change is marginally affected by high temperature within the range considered in this study.
Abstract: The objective of this research is to study the physical and mechanical properties and durability of self-compacting mortars prepared by substituting a part of cement up to a percentage of 30% pozzolan according to different Blaine specific surface area (SSB1=7000 cm2/g and SSB=9000 cm2/g)). Order to evaluate durability, mortars were subjected to chemical attacks in various aggressive environments, a solution of a mixture of nitric acid and ammonium nitrate (HNO3 + NH4NO3) and a magnesium sulfate salt solution (MgSO4)) with a concentration of 10%, for a period of one month. This study is complemented by a comparative study of the durability of mortars elaborated with sulphate resistant cement (SRC). The results show that these mortars develop long-term, mechanical and chemical resistance better than mortars based Portland cement with 5% gypsum (CEM 1) and SRC. We found that the mass losses are lowest in mortars elaborated with pozzolanic cement (30% substitution with SSB2) in both of chemical attack solutions (3.28% in the solution acid and 1.16% in the salt solution) and the compressive strength gains of 14.68% and 8.5% respectively in the two media. This is due to the action of pozzolan which fixes portlandite to form hydrated calcium silicate (CSH) from the hydration of tricalcic silicate (C3S).
Abstract: Hydrogel films were prepared from kappa carrageenan by crosslinking with glutaraldehyde. Carrageenan films extracted from Kappaphycus alvarezii seaweed were immersed in glutaraldehyde solution for 2 min and then cured at 110 °C for 25 min. The obtained crosslinked films were washed with ethanol to remove the unreacted glutaraldehyde and then air dried to constant weights. The aim of this research was to study the swelling degree behaviour of the hydrogel film to neutral salts solution, namely NaCl, KCl, and CaCl2. The results showed that swelling degree of crosslinked films varied non-monotonically with salinity of NaCl. Swelling degree decreased with the increasing of KCl concentration. Swelling degree of crosslinked film in CaCl2 solution was lower than that in NaCl and in KCl solutions.
Abstract: Human amniotic membrane (HAM) is a useful
biological material for the reconstruction of damaged ocular surface.
The processing and preservation of HAM is critical to prevent the
patients undergoing amniotic membrane transplant (AMT) from cross
infections. For HAM preparation human placenta is obtained after an
elective cesarean delivery. Before collection, the donor is screened
for seronegativity of HCV, Hbs Ag, HIV and Syphilis. After
collection, placenta is washed in balanced salt solution (BSS) in
sterile environment. Amniotic membrane is then separated from the
placenta as well as chorion while keeping the preparation in BSS.
Scrapping of HAM is then carried out manually until all the debris is
removed and clear transparent membrane is acquired. Nitrocellulose
membrane filters are then placed on the stromal side of HAM, cut
around the edges with little membrane folded towards other side
making it easy to separate during surgery. HAM is finally stored in
solution of glycerine and Dulbecco-s Modified Eagle Medium
(DMEM) in 1:1 ratio containing antibiotics. The capped borosil vials
containing HAM are kept at -80°C until use. This vial is thawed to
room temperature and opened under sterile operation theatre
conditions at the time of surgery.
Abstract: In this article, we synthesize a novel chitosan -based
superabsorbent hydrogel via graft copolymerization of mixtures
acrylic acid (AA) and N-vinyl pyrollidon onto chitosan backbones.
The polymerization reaction was carried out in an aqueous medium
and in the presence of ammonium persulfate (APS) as an initiator and
N,N'-methylene bisacrylamide (MBA) as a crosslinker.The hydrogel
structures were confirmed by FTIR spectroscopy. The swelling
behavior of these absorbent polymers was also investigated in
various salt solutions. Results indicated that the swelling capacity
decreased with an increase in the ionic strength of the swelling
medium. Furthermore, the swelling of superabsorbing hydrogels was
examined in solutions with pH values ranging between 1.0 and 13.0.
It showed a reversible pH-responsive behavior at pHs 2.0 and 8.0.
This on-off switching behavior makes the synthesized hydrogels as
an excellent candidate for controlled delivery of bioactive agents.
Abstract: Response surface methodology was used for
quantitative investigation of water and solids transfer during osmotic
dehydration of beetroot in aqueous solution of salt. Effects of
temperature (25 – 45oC), processing time (30–150 min), salt
concentration (5–25%, w/w) and solution to sample ratio (5:1 – 25:1)
on osmotic dehydration of beetroot were estimated. Quadratic
regression equations describing the effects of these factors on the
water loss and solids gain were developed. It was found that effects
of temperature and salt concentrations were more significant on the
water loss than the effects of processing time and solution to sample
ratio. As for solids gain processing time and salt concentration were
the most significant factors. The osmotic dehydration process was
optimized for water loss, solute gain, and weight reduction. The
optimum conditions were found to be: temperature – 35oC,
processing time – 90 min, salt concentration – 14.31% and solution
to sample ratio 8.5:1. At these optimum values, water loss, solid gain
and weight reduction were found to be 30.86 (g/100 g initial sample),
9.43 (g/100 g initial sample) and 21.43 (g/100 g initial sample)
respectively.
Abstract: Membrane distillation (MD) is a rising technology for
seawater or brine desalination process. In this work, an air gap
membrane distillation (AGMD) performance was investigated for
aqueous NaCl solution along with natural ground water and seawater.
In order to enhance the performance of the AGMD process in
desalination, that is, to get more flux, it is necessary to study the
effect of operating parameters on the yield of distillate water. The
influence of operational parameters such as feed flow rate, feed
temperature, feed salt concentration, coolant temperature and air gap
thickness on the membrane distillation (MD) permeation flux have
been investigated for low and high salt solution. the natural
application of ground water and seawater over 90 h continuous
operation, scale deposits observed on the membrane surface and
reduction in flux represents 23% for ground water and 60% for
seawater, in 90 h. This reduction was eliminated (less than 14 %) by
acidification of feed water. Hence, promote the research attention in
apply of AGMD for the ground water as well as seawater
desalination over today-s conventional RO operation.
Abstract: In this paper, we have focused on study of swelling kinetics and salt-sensitivity behavior of a superabsorbing hydrogel based on carboxymethylcellulose (CMC) and acrylic acid and 2- Buthyl methacrylate. The swelling kinetics of the hydrogels with various particle sizes was preliminary investigated as well. The swelling of the hydrogel showed a second order kinetics of swelling in water. In addition, swelling measurements of the synthesized hydrogels in various chloride salt solutions was measured. Results indicated that a swelling-loss with an increase in the ionic strength of the salt solutions.
Abstract: Compacted clay liners (CCLs) are the main materials
used in waste disposal landfills due to their low permeability. In this
study, the effect on the shear resistant of clays with inorganic salt
solutions as permeate fluid was experimentally investigated. For this
purpose, NaCl inorganic salt solution at concentrations of 2, 5, 10%
and deionized water were used. Laboratory direct shear and Vane
shear tests were conducted on three compacted clays with low,
medium and high plasticity. Results indicated that the solutions type
and its concentration affect the shear properties of the mixture. In the
light of this study, the influence magnitude of these inorganic salts in
varies concentrations in different clays were determined and more
suitable compacted clay with the compare of plasticity were found.