Abstract: Superplastic deformation and high temperature load
relaxation behavior of coarse-grained iron aluminides with the
composition of Fe-28 at.% Al have been investigated. A series of load
relaxation and tensile tests were conducted at temperatures ranging
from 600 to 850oC. The flow curves obtained from load relaxation
tests were found to have a sigmoidal shape and to exhibit stress vs.
strain rate data in a very wide strain rate range from 10-7/s to 10-2/s.
Tensile tests have been conducted at various initial strain rates ranging
from 3×10-5/s to 1×10-2/s. Maximum elongation of ~500 % was
obtained at the initial strain rate of 3×10-5/s and the maximum strain
rate sensitivity was found to be 0.68 at 850oC in binary Fe-28Al alloy.
Microstructure observation through the optical microscopy (OM) and
the electron back-scattered diffraction (EBSD) technique has been
carried out on the deformed specimens and it has revealed the
evidences for grain boundary migration and grain refinement to occur
during superplastic deformation, suggesting the dynamic
recrystallization mechanism. The addition of Cr by the amount of 5
at.% appeared to deteriorate the superplasticity of the binary iron
aluminide. By applying the internal variable theory of structural
superplasticity, the addition of Cr has been revealed to lower the
contribution of the frictional resistance to dislocation glide during high
temperature deformation of the Fe3Al alloy.
Abstract: MinC plays an important role in bacterial cell division
system by inhibiting FtsZ assembly. However, the molecular
mechanism of the action is poorly understood. E. coli MinC Nterminus
domain was purified and crystallized using 1.4 M sodium
citrate pH 6.5 as a precipitant. X-ray diffraction data was collected
and processed to 2.3 Å from a native crystal. The crystal belonged to
space group P212121, with the unit cell parameters a = 52.7, b = 54.0,
c = 64.7 Å. Assuming the presence of two molecules in the
asymmetric unit, the Matthews coefficient value is 1.94 Å3 Da-1,
which corresponds to a solvent content of 36.5%. The overall
structure of MinCN is observed as a dimer form through anti-parallel
ß-strand interaction.
Abstract: The main objective of this study was to remove and recover Ni, Cu and Fe from a mixed metal system using sodium hypophosphite as a reducing agent and nickel powder as seeding material. The metal systems studied consisted of Ni-Cu, Ni-Fe and Ni-Cu-Fe solutions. A 5 L batch reactor was used to conduct experiments where 100 mg/l of each respective metal was used. It was found that the metals were reduced to their elemental form with removal efficiencies of over 80%. The removal efficiency decreased in the order Fe>Ni>Cu. The metal powder obtained contained between 97-99% Ni and was almost spherical and porous. Size enlargement by aggregation was the dominant particulate process.
Abstract: Crystallization has been used for the separation of
chloronitrobenzene or CNBs, which are isomeric substances (o-, mand
p-CNB) and important intermediates in chemical productions. Effects of feed composition on the crystallization of m- and p-CNB was first studied. The results conform to the binary phase diagram of
m- and p-CNB. After that, effects of FAU zeolites (NaX, CaX, BaX, NaY and CaY) above the eutectic composition (63.5 and 65.0 wt% m-CNB in the feed) was also investigated. The results showed that
the FAU zeolites significantly affected the precipitates, the
composition of which was shifted from being rich in m-CNB to rich
in p-CNB. Effects of the number of FAU zeolites on the precipitate composition was then studied. The results revealed that the
precipitates from the lower number of the zeolites had higher p-CNB purity than those from the higher number of zeolite.
Abstract: The crystallization kinetics and phase transformation
of SiO2.Al2O3.0,56P2O5.1,8CaO.0,56CaF2 glass have been
investigated using differential thermal analysis (DTA), x-ray
diffraction (XRD), and scanning electron microscopy (SEM). Glass
samples were obtained by melting the glass mixture at 14500С/120
min. in platinum crucibles. The mixture were prepared from
chemically pure reagents: SiO2, Al(OH)3, H3PO4, CaCO3 and CaF2.
The non-isothermal kinetics of crystallization was studied by
applying the DTA measurements carried out at various heating rates.
The activation energies of crystallization and viscous flow were
measured as 348,4 kJ.mol–1 and 479,7 kJ.mol–1 respectively. Value of
Avrami parameter n ≈ 3 correspond to a three dimensional of crystal
growth mechanism. The major crystalline phase determined by XRD
analysis was fluorapatite (Ca(PO4)3F) and as the minor phases –
fluormargarite (CaAl2(Al2SiO2)10F2) and vitlokite (Ca9P6O24). The
resulting glass-ceramic has a homogeneous microstructure, composed
of prismatic crystals, evenly distributed in glass phase.
Abstract: Kepsut-Dursunbey volcanic field (KDVF) is located
in NW Turkey and contains various products of the post-collisional
Neogene magmatic activity. Two distinct volcanic suites have been
recognized; the Kepsut volcanic suite (KVS) and the Dursunbey
volcanic suite (DVS). The KVS includes basaltic trachyandesitebasaltic
andesite-andesite lavas and associated pyroclastic rocks. The
DVS consists of dacite-rhyodacite lavas and extensive pumice-ash
fall and flow deposits. Petrographical features (i.e. existence of
xenocrysts, glomerocrysts, and mixing-compatible textures) and
mineral chemistry of phenocryst assemblages of both suites provide
evidence for magma mixing/AFC. Calculated crystallization
pressures and temperatures give values of 5.7–7.0 kbar and 927–982
°C for the KVS and 3.7–5.3 kbar and 783-787°C for the DVS,
indicating separate magma reservoirs and crystallization in magma
chambers at deep and mid crustal levels, respectively. These
observations support the establishment and evolution of KDVF
magma system promoted by episodic basaltic inputs which may
generate and mix with crustal melts.
Abstract: The excessive consumption of fossil energies (electrical energy) during summer caused by the technological development involves more and more climate warming.
In order to reduce the worst impact of gas emissions produced from classical air conditioning, heat driven solar absorption chiller is pretty promising; it consists on using solar as motive energy which is clean and environmentally friendly to provide cold.
Solar absorption machine is composed by four components using Lithium Bromide /water as a refrigerating couple. LiBr- water is the most promising in chiller applications due to high safety, high volatility ratio, high affinity, high stability and its high latent heat. The lithium bromide solution is constitute by the salt lithium bromide which absorbs water under certain conditions of pressure and temperature however if the concentration of the solution is high in the absorption chillers; which exceed 70%, the solution will crystallize.
The main aim of this article is to study the phenomena of the crystallization and to evaluate how the dependence between the electric conductivity and the concentration which should be controlled.
Abstract: A piston cylinder based high pressure differential
thermal analyzer system is developed to investigate phase
transformations, melting, glass transitions, crystallization behavior of
inorganic materials, glassy systems etc., at ambient to 4 GPa and at
room temperature to 1073 K. The pressure is calibrated by the phase
transition of bismuth and ytterbium and temperature is calibrated
by using thermocouple data chart. The system developed is
calibrated using benzoic acid, ammonium nitrate and it has a
pressure and temperature control of ± 8.9 x 10 -4 GPa , ± 2 K
respectively. The phase transition of Asx Te100-x chalcogenides,
ferrous oxide and strontium boride are studied using the
indigenously developed system.
Abstract: Petrology and geochemical characteristics of granitic
rocks from South Sulawesi, especially from Polewaliand Masamba
area are presented in order to elucidate their origin of magma and
geodynamic setting. The granitic rocks in these areas are dominated by
granodiorite and granite in composition. Quartz, K-feldspar and
plagioclase occur as major phases with hornblende and biotite as
major ferromagnesian minerals. All of the samples were plotted in
calc-alkaline field, show metaluminous affinity and typical of I-type
granitic rock. Harker diagram indicates that granitic rocks experienced
fractional crystallization during magmatic evolution. Both groups
displayed an extreme enrichment of LILE, LREE and a slight negative
Eu anomaly which resemble upper continental crust affinity. They
were produced from partial melting of upper continental crust and
have close relationship of sources composition within a suite. The
geochemical characteristics explained the arc related subduction
environment which later give an evidence of continent-continent
collision between Australia-derived microcontinent and Sundalandto
form continental arc environment.