Abstract: Cementitious materials are an excellent example of a composite material with complex hierarchical features and random features that range from nanometer (nm) to millimeter (mm) scale. Multi-scale modeling of complex material systems requires starting from fundamental building blocks to capture the scale relevant features through associated computational models. In this paper, molecular dynamics (MD) modeling is employed to predict the effect of plasticizer additive on the mechanical properties of key hydrated cement constituent calcium-silicate-hydrate (CSH) at the molecular, nanometer scale level. Due to complexity, still unknown molecular configuration of CSH, a representative configuration widely accepted in the field of mineral Jennite is employed. The effectiveness of the Molecular Dynamics modeling to understand the predictive influence of material chemistry changes based on molecular / nanoscale models is demonstrated.
Abstract: Superfine pigments that consist of natural and artificial pigments and are made of mineral soil with special characteristics are used in cementitious materials for various purposes. These pigments can decrease the amount of cement needed without loss of performance and strength and also change the monotonous and turbid colours of concrete into various attractive and light colours. In this study, the mechanical strength and resistance against chloride and halogen attacks of cement mortars containing ceramic nano-pigments in an affected environment are studied. This research suggests utilisation of ceramic nano-pigments between 50 and 1000 nm, obtaining full-depth coloured concrete, preventing chlorine penetration in the concrete up to a certain depth, and controlling corrosion in steel rebar with the Potentiostat (EG&G) apparatus.
Abstract: Reinforced Concrete (RC) structures strengthened
with fiber reinforced polymer (FRP) lack in thermal resistance under
elevated temperatures in the event of fire. This phenomenon led to
the lining of strengthened concrete with thin high performance
cementitious composites (THPCC) to protect the substrate against
elevated temperature. Elevated temperature effects on THPCC, based
on different cementitious materials have been studied in the past but
high-alumina cement (HAC)-based THPCC have not been well
characterized. This research study will focus on the THPCC based on
HAC replaced by 60%, 70%, 80% and 85% of ground granulated
blast furnace slag (GGBS). Samples were evaluated by the
measurement of their mechanical strength (28 & 56 days of curing)
after exposed to 400°C, 600°C and 28°C of room temperature for
comparison and corroborated by their microstructure study. Results
showed that among all mixtures, the mix containing only HAC
showed the highest compressive strength after exposed to 600°C as
compared to other mixtures. However, the tensile strength of THPCC
made of HAC and 60% GGBS content was comparable to the
THPCC with HAC only after exposed to 600°C. Field emission
scanning electron microscopy (FESEM) images of THPCC
accompanying Energy Dispersive X-ray (EDX) microanalysis
revealed that the microstructure deteriorated considerably after
exposure to elevated temperatures which led to the decrease in
mechanical strength.
Abstract: Natural pozzolan (NP) is one of the potential
prehistoric alternative binders in the construction industry. It has
been investigated as cement replacement in ordinary concrete by
several researchers for many purposes. Various supplementary
cementitious materials (SCMs) such as fly ash, limestone dust and
silica fume are widely used in the production of SCC; however,
limited studies to address the effect of NP on the properties of SCC
are documented. The current research is composed of different SCC
paste and concrete mixtures containing different replacement levels
of local NP as an alternative SCM. The effect of volume of paste
containing different amounts of local NP related to W/B ratio and
cement content on SCC fresh properties was assessed. The variations
in the fresh properties of SCC paste and concrete represented by
slump flow (flowability) and the flow rate were determined and
discussed. The results indicated that the flow properties of SCC paste
and concrete mixtures, at their optimized superplasticizer dosages,
were affected by the binder content of local NP and the total volume
fraction of SCC paste.
Abstract: The main objective of this paper is to determine the
isolated effect of silica fume on tensile, compressive and flexure strengths on high strength lightweight concrete. Many experiments
were carried out by replacing cement with different percentages of silica fume at different constant water-binder ratio keeping other mix
design variables constant. The silica fume was replaced by 0%, 5%,
10%, 15%, 20% and 25% for a water-binder ratios ranging from 0.26
to 0.42. For all mixes, split tensile, compressive and flexure strengths
were determined at 28 days. The results showed that the tensile, compressive and flexure strengths increased with silica fume incorporation but the optimum replacement percentage is not
constant because it depends on the water–cementitious material (w/cm) ratio of the mix. Based on the results, a relationship between
split tensile, compressive and flexure strengths of silica fume concrete was developed using statistical methods.
Abstract: Steel corrosion in concrete is considered as a main
engineering problems for many countries and lots of expenses has been paid for their repair and maintenance annually. This problem
may occur in all engineering structures whether in coastal and offshore or other areas. Hence, concrete structures should be able to
withstand corrosion factors existing in water or soil. Reinforcing
steel corrosion enhancement can be measured by use of concrete
electrical resistance; and maintaining high electric resistivity in concrete is necessary for steel corrosion prevention. Lots of studies
devoted to different aspects of the subjects worldwide. In this paper, an evaluation of the effects of W/C ratio, cementitious materials, and
percent increase in silica fume were investigated on electric resistivity of high strength concrete. To do that, sixteen mix design
with one aggregate grading was planned. Five of them had varying amount of W/C ratio and other eleven mixes was prepared with
constant W/C ratio but different amount of cementitious materials.
Silica fume and super plasticizer were used with different proportions
in all specimens. Specimens were tested after moist curing for 28 days. A total of 80 cube specimens (50 mm) were tested for concrete
electrical resistance. Results show that concrete electric resistivity can be increased with increasing amount of cementitious materials
and silica fume.