Abstract: Interaction of Schiff base complexes of Iron and
Manganese: Iron [N, N’ Bis (5- (triphenyl phosphonium methyl)
salicylidene) -1, 2 ethanediamine) chloride, [Fe Salen]Cl; Manganese
[N, N’ Bis (5- (triphenyl phosphonium methyl) salicylidene) -1, 2
ethanediamine) acetate, were investigated by spectroscopic and
isothermal titration calorimetry techniques (ITC).
The absorbance spectra of complexes have shown hyper and
hypochromism in the presence of DNA that is indication of
interaction of complexes with DNA. The linear dichroism (LD)
measurements confirmed the bending of DNA in the presence of
complexes.
Furthermore, Isothermal titration calorimetry experiments
approved that complexes bound to DNA on the base of both
electrostatic and hydrophobic interactions. More, ITC profile exhibits
the existence of two binding phases for the complexes. Antibacterial
activity of ligand and complexes were tested in vitro to evaluate their
activity against the gram positive and negative bacteria.
Abstract: In the present work the internal sulfate attack on
pastes made from pure clinker phases was studied. Two binders were
produced: (a) a binder with 2% C3A and 18% C4AF content; (b) a
binder with 10% C3A and C4AF content each. Gypsum was used as
the sulfate bearing compound, while calcium carbonate added to
differentiate the binders produced. The phases formed were identified
by XRD analysis. The results showed that ettringite was the
deterioration phase detected in the case of the low C3A content
binder. Carbonation occurred in the specimen without calcium
carbonate addition, while portlandite was observed in the one
containing calcium carbonate. In the case of the high C3A content
binder, traces of thaumasite were detected when calcium carbonate
was not incorporated in the binder. A solid solution of thaumasite and
ettringite was found when calcium carbonate was added. The amount
of C3A had not fully reacted with sulfates, since its corresponding
peaks were detected.
Abstract: Perishable goods constitute a large portion of retailer inventory and lose value with time due to deterioration and/or obsolescence. Retailers dealing with such goods required considering the factors of short shelf life and the dependency of sales on inventory displayed in determining optimal procurement policy. Many retailers follow the practice of using two bins - primary bin sales fresh items at a list price and secondary bin sales unsold items at a discount price transferred from primary bin on attaining certain age. In this paper, mathematical models are developed for primary bin and for secondary bin that maximizes profit with decision variables of order quantities, optimal review period and optimal selling price at secondary bin. The demand rates in two bins are assumed to be deterministic and dependent on displayed inventory level, price and age but independent of each other. The validity of the model is shown by solving an example and the sensitivity analysis of the model is also reported.