Abstract: The modified Claus process is commonly used in oil
refining and gas processing to recover sulfur and destroy
contaminants formed in upstream processing. A Claus furnace feed
containing a relatively low concentration of H2S may be incapable of
producing a stable flame. Also, incomplete combustion of
hydrocarbons in the feed can lead to deterioration of the catalyst in
the reactors due to soot or carbon deposition. Therefore, special
consideration is necessary to achieve the appropriate overall sulfur
recovery. In this paper, some configurations available to treat lean
acid gas streams are described and the most appropriate ones are
studied to overcome low H2S concentration problems. As a result,
overall sulfur recovery is investigated for feed preheating and hot gas
configurations.
Abstract: The modified Claus process is the major technology
for the recovery of elemental sulfur from hydrogen sulfide. The
chemical reactions that can occur in the reaction furnace are
numerous and many byproducts such as carbon disulfide and carbon
carbonyl sulfide are produced. These compounds can often contribute
from 20 to 50% of the pollutants and therefore, should be hydrolyzed
in the catalytic converter. The inlet temperature of the first catalytic
reactor should be maintained over than 250 °C, to hydrolyze COS
and CS2. In this paper, the various configurations for the first
converter reheating of sulfur recovery unit are investigated. As a
result, the performance of each method is presented for a typical
clause unit. The results show that the hot gas method seems to be
better than the other methods.