Abstract: Post growth annealing of solution grown ZnO
nanowire array is performed under controlled oxygen ambience. The
role of annealing over surface defects and their consequence on
dark/photo-conductivity and photosensitivity of nanowire array is
investigated. Surface defect properties are explored using various
measurement tools such as contact angle, photoluminescence, Raman
spectroscopy and XPS measurements. The contact angle of the NW
films reduces due to oxygen annealing and nanowire film surface
changes from hydrophobic (96°) to hydrophilic (16°). Raman and
XPS spectroscopy reveal that oxygen annealing improves the crystal
quality of the nanowire films. The defect band emission intensity
(relative to band edge emission, ID/IUV) reduces from 1.3 to 0.2 after
annealing at 600 °C at 10 SCCM flow of oxygen. An order
enhancement in dark conductivity is observed in O2 annealed
samples, while photoconductivity is found to be slightly reduced due
to lower concentration of surface related oxygen defects.
Abstract: The objective of this work is to study the influence of the properties of the substrate on the retrofit (thin repair) of damaged concrete elements, with the SCC. Fluidity, principal characteristic of the SCC, would enable it to cover and adhere to the concrete to be repaired. Two aspects of repair are considered, the bond (Adhesion) and the tensile strength and the cracking. The investigation is experimental; It was conducted over test specimens made up of ordinary concrete prepared and hardened in advance (the material to be repaired) over which a self compacting concrete layer is cast. Three alternatives of SC concrete and one ordinary concrete (comparison) were tested. It appears that the self-compacting concrete constitutes a good material for repairing. It follows perfectly the surfaces- forms to be repaired and allows a perfect bond. Fracture tests made on specimens of self-compacting concrete show a brittle behaviour. However when a small percentage of fibres is added, the resistance to cracking is very much improve.
Abstract: This paper investigates experimentally and
analytically the torsion behavior of steel fibered high strength self
compacting concrete beams reinforced by GFRP bars. Steel fibered
high strength self compacting concrete (SFHSSCC) and GFRP bars
became in the recent decades a very important materials in the
structural engineering field. The use of GFRP bars to replace steel
bars has emerged as one of the many techniques put forward to
enhance the corrosion resistance of reinforced concrete structures.
High strength concrete and GFRP bars attract designers and
architects as it allows improving the durability as well as the esthetics
of a construction. One of the trends in SFHSSCC structures is to
provide their ductile behavior and additional goal is to limit
development and propagation of macro-cracks in the body of
SFHSSCC elements. SFHSSCC and GFRP bars are tough, improve
the workability, enhance the corrosion resistance of reinforced
concrete structures, and demonstrate high residual strengths after
appearance of the first crack. Experimental studies were carried out
to select effective fiber contents. Three types of volume fraction from
hooked shape steel fibers are used in this study, the hooked steel
fibers were evaluated in volume fractions ranging between 0.0%,
0.75% and 1.5%. The beams shape is chosen to create the required
forces (i.e. torsion and bending moments simultaneously) on the test
zone. A total of seven beams were tested, classified into three groups.
All beams, have 200cm length, cross section of 10×20cm,
longitudinal bottom reinforcement of 3
Abstract: A self-association model has been used to understand
the concentration dependence of free energy of mixing (GM), heat of
mixing (HM), entropy of mixing (SM), activity (a) and microscopic
structures, such as concentration fluctuation in long wavelength limit
(Scc(0)) and Warren-Cowley short range order parameter ( 1
α )for Cu-
Tl molten alloys at 1573K. A comparative study of surface tension of
the alloys in the liquid state at that temperature has also been carried
out theoretically as function of composition in the light of Butler-s
model, Prasad-s model and quasi-chemical approach. Most of the
computed thermodynamic properties have been found in agreement
with the experimental values. The analysis reveals that the Cu-Tl
molten alloys at 1573K represent a segregating system at all
concentrations with moderate interaction. Surface tensions computed
from different approaches have been found to be comparable to each
other showing increment with the composition of copper.
Abstract: The paper presents a comparative performance of the
models developed to predict 28 days compressive strengths using
neural network techniques for data taken from literature (ANN-I) and
data developed experimentally for SCC containing bottom ash as
partial replacement of fine aggregates (ANN-II). The data used in the
models are arranged in the format of six and eight input parameters
that cover the contents of cement, sand, coarse aggregate, fly ash as
partial replacement of cement, bottom ash as partial replacement of
sand, water and water/powder ratio, superplasticizer dosage and an
output parameter that is 28-days compressive strength and
compressive strengths at 7 days, 28 days, 90 days and 365 days,
respectively for ANN-I and ANN-II. The importance of different
input parameters is also given for predicting the strengths at various
ages using neural network. The model developed from literature data
could be easily extended to the experimental data, with bottom ash as
partial replacement of sand with some modifications.
Abstract: Environment-assisted cracking (EAC) is one of the most serious causes of structural failure over a broad range of industrial applications including offshore structures. In EAC condition there is not a definite relation such as Paris equation in Linear Elastic Fracture Mechanics (LEFM). According to studying and searching a lot what the researchers said either a material has contact with hydrogen or any other corrosive environment, phenomenon of electrical and chemical reactions of material with its environment will be happened. In the literature, there are many different works to consider fatigue crack growing and solve it but they are experimental works. Thus, in this paper, authors have an aim to evaluate mathematically the pervious works in LEFM. Obviously, if an environment is more sour and corrosive, the changes of stress intensity factor is more and the calculation of stress intensity factor is difficult. A mathematical relation to deal with the stress intensity factor during the diffusion of sour environment especially hydrogen in a marine pipeline is presented. By using this relation having and some experimental relation an analytical formulation will be presented which enables the fatigue crack growth and critical crack length under cyclic loading to be predicted. In addition, we can calculate KSCC and stress intensity factor in the pipeline caused by EAC.