Abstract: Liners are made to protect the groundwater table from
the infiltration of leachate which normally carries different kinds of
toxic materials from landfills. Although these liners are engineered to
last for long period of time; unfortunately these liners fail; therefore,
toxic materials pass to groundwater. This paper focuses on the
changes of the hydraulic conductivity of a sand-bentonite liner due to
the infiltration of biofuel and ethanol fuel. Series of laboratory tests
were conducted in 20-cm-high PVC columns. Several compositions
of sand-bentonite liners were tested: 95% sand: 5% bentonite; 90%
sand: 10% bentonite; and 100% sand (passed mesh #40). The
columns were subjected to extreme pressures of 40 kPa, and 100 kPa
to evaluate the transport of alternative fuels (biofuel and ethanol
fuel). For comparative studies, similar tests were carried out using
water. Results showed that hydraulic conductivity increased due to
the infiltration of alternative fuels through the liners. Accordingly,
the increase in the hydraulic conductivity showed significant
dependency on the type of liner mixture and the characteristics of the
liquid. The hydraulic conductivity of a liner (subjected to biofuel
infiltration) consisting of 5% bentonite: 95% sand under pressure of
40 kPa and 100 kPa had increased by one fold. In addition, the
hydraulic conductivity of a liner consisting of 10% bentonite: 90%
sand under pressure of 40 kPa and 100 kPa and infiltrated by biofuel
had increased by three folds. On the other hand, the results obtained
by water infiltration under 40 kPa showed lower hydraulic
conductivities of 1.50×10-5 and 1.37×10-9 cm/s for 5% bentonite:
95% sand, and 10% bentonite: 90% sand, respectively. Similarly,
under 100 kPa, the hydraulic conductivities were 2.30×10-5 and
1.90×10-9 cm/s for 5% bentonite: 95% sand, and 10% bentonite: 90%
sand, respectively.
Abstract: Fixed-bed slow pyrolysis experiments of rice husk
have been conducted to determine the effect of pyrolysis
temperature, heating rate, particle size and reactor length on the
pyrolysis product yields. Pyrolysis experiments were performed at
pyrolysis temperature between 400 and 600°C with a constant
heating rate of 60°C/min and particle sizes of 0.60-1.18 mm. The
optimum process conditions for maximum liquid yield from the rice
husk pyrolysis in a fixed bed reactor were also identified. The highest
liquid yield was obtained at a pyrolysis temperature of 500°C,
particle size of
1.18-1.80 mm, with a heating rate of 60°C/min in a 300 mm length
reactor. The obtained yield of, liquid, gas and solid were found be in
the range of 22.57-31.78 %, 27.75-42.26 % and 34.17-42.52 % (all
weight basics) respectively at different pyrolysis conditions. The
results indicate that the effects of pyrolysis temperature and particle
size on the pyrolysis yield are more significant than that of heating
rate and reactor length. The functional groups and chemical
compositions present in the liquid obtained at optimum conditions
were identified by Fourier Transform-Infrared (FT-IR) spectroscopy
and Gas Chromatography/ Mass Spectroscopy (GC/MS) analysis
respectively.