Abstract: Experimental data are presented to show the influence of different types of chemical demulsifier on the stability and demulsification of emulsions. Three groups of demulsifier with different functional groups were used in this work namely amines, alcohol and polyhydric alcohol. The results obtained in this study have exposed the capability of chemical breaking agents in destabilization of water in crude oil emulsions. From the present study, found that molecular weight of the demulsifier were influent the capability of the emulsion to separate.
Abstract: Fecal sterol has been proposed as a chemical indicator
of human fecal pollution even when fecal coliform populations have
diminished due to water chlorination or toxic effects of industrial
effluents. This paper describes an improved derivatization procedure
for simultaneous determination of four fecal sterols including
coprostanol, epicholestanol, cholesterol and cholestanol using gas
chromatography-mass spectrometry (GC-MS), via optimization study
on silylation procedures using N-O-bis
(trimethylsilyl)-trifluoroacetamide (BSTFA), and
N-(tert-butyldimethylsilyl)-N-methyltrifluoroacetamide
(MTBSTFA), which lead to the formation of trimethylsilyl (TMS) and
tert-butyldimethylsilyl (TBS) derivatives, respectively. Two
derivatization processes of injection-port derivatization and water bath
derivatization (60 oC, 1h) were inspected and compared. Furthermore,
the methylation procedure at 25 oC for 2h with
trimethylsilydiazomethane (TMSD) for fecal sterols analysis was also
studied. It was found that most of TMS derivatives demonstrated the
highest sensitivities, followed by methylated derivatives. For BSTFA
or MTBSTFA derivatization processes, the simple injection-port
derivatization process could achieve the same efficiency as that in the
tedious water bath derivatization procedure.
Abstract: Droughts are complex, natural hazards that, to a
varying degree, affect some parts of the world every year. The range
of drought impacts is related to drought occurring in different stages
of the hydrological cycle and usually different types of droughts,
such as meteorological, agricultural, hydrological, and socioeconomical
are distinguished. Streamflow drought was analyzed by
the method of truncation level (at 70% level) on daily discharges
measured in 54 hydrometric stations in southwestern Iran. Frequency
analysis was carried out for annual maximum series (AMS) of
drought deficit volume and duration series. Some factors including
physiographic, climatic, geologic, and vegetation cover were studied
as influential factors in the regional analysis. According to the results
of factor analysis, six most effective factors were identified as area,
rainfall from December to February, the percent of area with
Normalized Difference Vegetation Index (NDVI)
Abstract: In the present work flow past circular cylinder and
cylinder with rectangular and triangular wake splitter is studied to
improve aerodynamic parameters. The Comparison of drag
coefficient is tabulated for bare cylinder, cylinder with rectangular
and triangular wake splitters. Flow past circular cylinder and cylinder
with triangular and rectangular wake splitter is performed at
Reynoldsnumber 5, 20, 40, 50,80, 100.An incompressible PISO finite
volume code employing a non-staggered grid arrangement is used, a
second order upwind scheme is used for convective terms. The time
discretization is implicit and a Second order Crank-Nicholson scheme
is employed. Length of wake splitter in both configurations is taken
to be equal to diameter of cylinder. Wake length is found to be less
with rectangular wake splitter when compared to bare cylinder and
cylinder with triangular wake splitter. Coefficient of drag is found to
be less for triangular wake splitter when compared to bare cylinder &
cylinder with rectangular wake splitter.
Abstract: This study presents the performance of membrane
bioreactor in treating high phosphate wastewater. The laboratory
scale MBR was operated at permeate flux of 25 L/m2.h with a hollow
fiber membrane (polypropylene, approx. pore size 0.01 - 0.2 μm) at
hydraulic retention time (HRT) of 12 hrs. Scanning electron
microscopy (SEM) and energy diffusive X-ray (EDX) analyzer were
used to characterize the membrane foulants. Results showed that the
removal efficiencies of COD, TSS, NH3-N and PO4
3- were 93, 98, 80
and 30% respectively. On average 91% of influent soluble microbial
products (SMP) were eliminated, with the eliminations of
polysaccharides mostly above 80%. The main fouling resistance was
cake resistance. It should be noted that SMP were found in major
portions of mixed liquor that played a relatively significant role in
membrane fouling. SEM and EDX analyses indicated that the
foulants covering the membrane surfaces comprises not only organic
substances but also inorganic elements including Mg, Ca, Al, K and
P.
Abstract: The emergence of mobile application services and App
Store has led to the explosive growth of user innovation, which users
voluntarily contribute to. User innovation communities where end
users freely reveal innovative ideas and needs with other community
members are becoming increasingly influential in this area. However,
user-s ideas in user innovation community are not enough to be new
service opportunity, because some of them can already developed as
existing services in App Store. Moreover, the existing services similar
to new service opportunity can be significant references to apply
analogy to develop service concept. In response, this research
proposes Case-Based Reasoning approach to matching the user needs
and existing services, identifying unmet opportunistic user needs, and
retrieving similar services with opportunity. Due to its intuitive and
transparent algorithm, users related to App Store innovation
communities can easily employ Case-Based Reasoning based
approach to their innovation.
Abstract: Stuck-pipe in drilling operations is one of the most
pressing and expensive problems in the oil industry. This paper
describes a computational simulation and an experimental study of
the hydrodynamic vibrator, which may be used for liquidation of
stuck-pipe problems during well drilling. The work principle of the
vibrator is based upon the known phenomena of Vortex Street of
Karman and the resulting generation of vibrations. We will discuss
the computational simulation and experimental investigations of
vibrations in this device. The frequency of the vibration parameters
has been measured as a function of the wide range Reynolds Number.
The validity of the computational simulation and of the assumptions
on which it is based has been proved experimentally. The
computational simulation of the vibrator work and its effectiveness
was carried out using FLUENT software. The research showed high
degree of congruence with the results of the laboratory tests and
allowed to determine the effect of the granular material features upon
the pipe vibration in the well. This study demonstrates the potential
of using the hydrodynamic vibrator in a well drilling system.