Abstract: Biogas can be currently considered as an alternative option for electricity production, mainly due to its high energy content (hydrocarbon-rich source), its renewable status and its relatively low utilization cost. Solid Oxide Fuel Cell (SOFC) stacks convert fuel’s chemical energy to electricity with high efficiencies and reveal significant advantages on fuel flexibility combined with lower emissions rate, especially when utilize biogas. Electricity production by biogas constitutes a composite problem which incorporates an extensive parametric analysis on numerous dynamic variables. The main scope of the presented study is to propose a detailed thermodynamic model on the optimization of SOFC-based power plants’ operation based on fundamental thermodynamics, energy and exergy balances. This model named THERMAS (THERmodynamic MAthematical Simulation model) incorporates each individual process, during electricity production, mathematically simulated for different case studies that represent real life operational conditions. Also, THERMAS offers the opportunity to choose a great variety of different values for each operational parameter individually, thus allowing for studies within unexplored and experimentally impossible operational ranges. Finally, THERMAS innovatively incorporates a specific criterion concluded by the extensive energy analysis to identify the most optimal scenario per simulated system in exergy terms. Therefore, several dynamical parameters as well as several biogas mixture compositions have been taken into account, to cover all the possible incidents. Towards the optimization process in terms of an innovative OPF (OPtimization Factor), presented here, this research study reveals that systems supplied by low methane fuels can be comparable to these supplied by pure methane. To conclude, such an innovative simulation model indicates a perspective on the optimal design of a SOFC stack based system, in the direction of the commercialization of systems utilizing biogas.
Abstract: In present paper, the performance of various alternative refrigerants is compared to find the substitute of R22, the widely used hydrochlorofluorocarbon refrigerant in developing countries. These include the environmentally friendly hydrofluorocarbon (HFC) refrigerants such as R134A, R410A, R407C and M20. In the present study, a steady state thermodynamic model (includes both first and second law analysis) which simulates the working of an actual vapor-compression system is developed. The model predicts the performance of system with alternative refrigerants. Considering the recent trends of replacement of ozone depleting refrigerants and improvement in system efficiency, R407C is found to be potential candidate to replace R22 refrigerant in the present study.
Abstract: In present study, an approach is adopted where photovoltaic thermal flat plate collector is integrated with compound parabolic concentrator. Analytical expression of temperature dependent electrical efficiency of N number of partially covered Photovoltaic Thermal (PVT) - Compound Parabolic Concentrator (CPC) water collector connected in series has been derived with the help of basic thermal energy balance equations. Analysis has been carried for winter weather condition at Delhi location, India. Energy and exergy performance of N - partially covered Photovoltaic Thermal (PVT) - Compound Parabolic Concentrator (CPC) Water collector system has been compared for two cases: (i) 25% area of water collector covered by PV module, (ii) 75% area of water collector covered by PV module. It is observed that case (i) has been best suited for thermal performance and case (ii) for electrical energy as well as overall exergy.
Abstract: This study reports a comparison from an exergetic point of view between three configurations of vapor compression industrial refrigeration systems operating with R134a as working fluid. The performances of the different cycles are analyzed as function of several operating parameters such as condensing temperature and inter stage pressure. In addition, the contributions of component exergy destruction to the total exergy destruction are obtained for each system. The results are estimated to be used in the selection of the most advantageous configuration from an exergetic view point.
Abstract: An Energetic and exergetic analysis is conducted on a
Steam Turbine Power Plant of an existing Phosphoric Acid Factory.
The heat recovery systems used in different parts of the plant are also
considered in the analysis. Mass, thermal and exergy balances are
established on the main compounds of the factory. A numerical code
is established using EES software to perform the calculations
required for the thermal and exergy plant analysis. The effects of the
key operating parameters such as steam pressure and temperature,
mass flow rate as well as seawater temperature, on the cycle
performances are investigated. A maximum Exergy Loss Rate of about 72% is obtained for the
melters, followed by the condensers, heat exchangers and the pumps.
The heat exchangers used in the phosphoric acid unit present
exergetic efficiencies around 33% while 60% to 72% are obtained for
steam turbines and blower. For the explored ranges of HP steam
temperature and pressure, the exergy efficiencies of steam turbine
generators STGI and STGII increase of about 2.5% and 5.4%
respectively. In the same way optimum HP steam flow rate values,
leading to the maximum exergy efficiencies are defined.
Abstract: The performance of box-type solar cookers has been
reported by several researchers but little attention was paid to the
effect of the type of insulation material on the energy and exergy
efficiency of these cookers. This research aimed at evaluating the
energy and exergy efficiencies of the box-type cookers containing
different insulation materials. Energy and exergy efficiencies of five
box-type solar cookers insulated with maize cob, air (control), maize
husk, coconut coir and polyurethane foam respectively were obtained
over a period of three years. The cookers were evaluated using water
heating test procedures in determining the energy and exergy
analysis. The results were subjected to statistical analysis using
ANOVA. The result shows that the average energy input for the five
solar cookers were: 245.5, 252.2, 248.7, 241.5 and 245.5J
respectively while their respective average energy losses were: 201.2,
212.7, 208.4, 189.1 and 199.8J. The average exergy input for five
cookers were: 228.2, 234.4, 231.1, 224.4 and 228.2J respectively
while their respective average exergy losses were: 223.4, 230.6,
226.9, 218.9 and 223.0J. The energy and exergy efficiency was
highest in the cooker with coconut coir (37.35 and 3.90%
respectively) in the first year but was lowest for air (11 and 1.07%
respectively) in the third year. Statistical analysis showed significant
difference between the energy and exergy efficiencies over the years.
These results reiterate the importance of a good insulating material
for a box-type solar cooker.
Abstract: In this paper, the exergy analysis of vapor absorption
refrigeration system using LiBr-H2O as working fluid is carried out
with the modified Gouy-Stodola approach rather than the classical
Gouy-Stodola equation and effect of varying input parameters is also
studied on the performance of the system. As the modified approach
uses the concept of effective temperature, the mathematical
expressions for effective temperature have been formulated and
calculated for each component of the system. Various constraints and
equations are used to develop program in EES to solve these
equations. The main aim of this analysis is to determine the
performance of the system and the components having major
irreversible loss. Results show that exergy destruction rate is
considerable in absorber and generator followed by evaporator and
condenser. There is an increase in exergy destruction in generator,
absorber and condenser and decrease in the evaporator by the
modified approach as compared to the conventional approach. The
value of exergy determined by the modified Gouy-Stodola equation
deviates maximum i.e. 26% in the generator as compared to the
exergy calculated by the classical Gouy-Stodola method.
Abstract: Heating, cooling and lighting appliances in buildings
account for more than one third of the world’s primary energy
demand. Therefore, main components of the building heating systems
play an essential role in terms of energy consumption. In this context,
efficient energy and exergy utilization in HVAC-R systems has been
very essential, especially in developing energy policies towards
increasing efficiencies. The main objective of the present study is to
assess the performance of a family house with a volume of 326.7 m3
and a net floor area of 121 m2, located in the city of Izmir, Turkey in
terms of energetic, exergetic and sustainability aspects. The indoor
and exterior air temperatures are taken as 20°C and 1°C, respectively.
In the analysis and assessment, various metrics (indices or indicators)
such as exergetic efficiency, exergy flexibility ratio and sustainability
index are utilized. Two heating options (Case 1: condensing boiler
and Case 2: air heat pump) are considered for comparison purposes.
The total heat loss rate of the family house is determined to be
3770.72 W. The overall energy efficiencies of the studied cases are
calculated to be 49.4% for Case 1 and 54.7% for Case 2. The overall
exergy efficiencies, the flexibility factor and the sustainability index
of Cases 1 and 2 are computed to be around 3.3%, 0.17 and 1.034,
respectively.
Abstract: This paper carries out a performance analysis based on
the first and second laws of thermodynamics for heat recovery vapor
generator (HRVG) of ammonia-water mixture when the heat source is
low-temperature energy in the form of sensible heat. In the analysis,
effects of the ammonia mass concentration and mass flow ratio of the
binary mixture are investigated on the system performance including
the effectiveness of heat transfer, entropy generation, and exergy
efficiency. The results show that the ammonia concentration and the
mass flow ratio of the mixture have significant effects on the system
performance of HRVG.
Abstract: Organic Rankine Cycle (ORC) has potential in reducing fossil fuels and relaxing environmental problems. In this work performance analysis of ORC is conducted based on the second law of thermodynamics for recovery of low temperature heat source from 100oC to 140oC using R134a as the working fluid. Effects of system parameters such as turbine inlet pressure or source temperature are theoretically investigated on the exergy destructions (anergies) at various components of the system as well as net work production or exergy efficiency. Results show that the net work or exergy efficiency has a peak with respect to the turbine inlet pressure when the source temperature is low, however, increases monotonically with increasing turbine inlet pressure when the source temperature is high.
Abstract: In the present time, energy crises is considered a severe problem across the world. For the protection of global environment and maintain ecological balance, energy saving is considered one of the most vital issues from the view point of fuel consumption. As the industrial sectors everywhere continue efforts to improve their energy efficiency, recovering waste heat losses provides an attractive opportunity for an emission free and less costly energy resource. In the other hand the using of solar energy has become more insistent particularly after the high gross of prices and running off the conventional energy sources. Therefore, it is essential that we should endeavor for waste heat recovery as well as solar energy by making significant and concrete efforts. For these reasons this investigation is carried out to study and analyze the performance of a power plant working by a combined cycle in which heat recovery system generator (HRSG) gets its energy from the waste heat of a gas turbine unit. Evaluation of the performance of the plant is based on different thermal efficiencies of the main components in addition to the second law analysis considering the exergy destructions for the whole components. The contribution factors including the solar as well as the wasted energy are considered in the calculations. The final results have shown that there is significant exergy destruction in solar concentrator and the combustion chamber of the gas turbine unit. Other components such as compressor, gas turbine, steam turbine and heat exchangers having insignificant exergy destruction. Also, solar energy can contribute by about 27% of the input energy to the plant while the energy lost with exhaust gases can contribute by about 64% at maximum cases.
Abstract: Seawater desalination has been accepted as one of the most effective solutions to the growing problem of a diminishing clean drinking water supply. Currently two desalination technologies dominate the market – the thermally driven multi-stage flash distillation (MSF) and the membrane based reverse osmosis (RO). However, in recent years membrane distillation (MD) has emerged as a potential alternative to the established means of desalination. This research project intended to determine the viability of MD as an alternative process to MSF and RO for seawater desalination. Specifically the project involves conducting thermodynamic analysis of the process based on the second law of thermodynamics to determine the efficiency of the MD. Data was obtained from experiments carried out on a laboratory rig. To determine exergy values required for the exergy analysis, two separate models were built in Engineering Equation Solver – the ’Minimum Separation Work Model’ and the ‘Stream Exergy Model’. The efficiency of MD process was found to be 17.3 % and the energy consumption was determined to be 4.5 kWh to produce one cubic meter of fresh water. The results indicate MD has potential as a technique for seawater desalination compared to RO and MSF. However it was shown that this was only the case if an alternate energy source such as green or waste energy was available to provide the thermal energy input to the process. If the process was required to power itself, it was shown to be highly inefficient and in no way thermodynamically viable as a commercial desalination process.
Abstract: Recently ORC(Organic Rankine Cycle) has attracted
much attention due to its potential in reducing consumption of fossil
fuels and its favorable characteristics to exploit low-grade heat sources.
In this work thermodynamic performance of ORC with superheating of
vapor is comparatively assessed for various working fluids. Special
attention is paid to the effects of system parameters such as the evaporating
temperature and the turbine inlet temperature on the characteristics
of the system such as maximum possible work extraction from
the given source, volumetric flow rate per 1 kW of net work and
quality of the working fluid at turbine exit as well as thermal and
exergy efficiencies. Results show that for a given source the thermal
efficiency increases with decrease of the superheating but exergy
efficiency may have a maximum value with respect to the superheating
of the working fluid. Results also show that in selection of working
fluid it is required to consider various criteria of performance characteristics
as well as thermal efficiency.
Abstract: Cogeneration may be defined as a system which
contains electricity production and regain of the thermo value of
exhaust gases simultaneously. The examination is based on the data-s
of an active cogeneration plant. This study, it is aimed to determine
which component of the system should be revised first to raise the
efficiency and decrease the loss of exergy. For this purpose, second
law analysis of thermodynamics is applied to each component due to
consider the effects of environmental conditions and take the quality
of energy into consideration as well as the quantity of it. The exergy
balance equations are produced and exergy loss is calculated for each
component. 44,44 % loss of exergy in heat exchanger, 29,59 % in
combustion chamber, 18,68 % in steam boiler, 5,25 % in gas turbine
and 2,03 % in compressor is calculated.
Abstract: Thermal-driven refrigeration systems have attracted increasing research and development interest in recent years. These systems do not cause ozone depletion and can reduce demand on electricity. The main objective of this work is to perform theoretical analyses of a thermal-driven refrigeration system using a new sorbent-sorptive pair as the working pair. The active component of sorbent is sodium thiocyanate (NaSCN). Ammonia (NH3) is chosen as sorptive. Based on the thermodynamic properties of the working solution, a mathematical model is introduced to analyze the system characteristics and performance. The results are used to compare with other thermal-driven refrigeration systems. It is shown that the advantages provided by this system over other absorption units include lower generator and evaporator temperatures, a higher coefficient of performance (COP). The COP is about 10 percent higher than the ones for the NH3-H2O system working at the same conditions.
Abstract: This paper presented a novel combined cycle of air separation and natural gas liquefaction. The idea is that natural gas can be liquefied, meanwhile gaseous or liquid nitrogen and oxygen are produced in one combined cryogenic system. Cycle simulation and exergy analysis were performed to evaluate the process and thereby reveal the influence of the crucial parameter, i.e., flow rate ratio through two stages expanders β on heat transfer temperature difference, its distribution and consequent exergy loss. Composite curves for the combined hot streams (feeding natural gas and recycled nitrogen) and the cold stream showed the degree of optimization available in this process if appropriate β was designed. The results indicated that increasing β reduces temperature difference and exergy loss in heat exchange process. However, the maximum limit value of β should be confined in terms of minimum temperature difference proposed in heat exchanger design standard and heat exchanger size. The optimal βopt under different operation conditions corresponding to the required minimum temperature differences was investigated.
Abstract: Energy and exergy study of air-water combined solar collector which is called dual purpose solar collector (DPSC) is investigated. The method of ε - NTU is used. Analysis is performed for triangle channels. Parameters like the air flow rate and water inlet temperature are studied. Results are shown that DPSC has better energy and exergy efficiency than single collector. In addition, the triangle passage with water inlet temperature of 60O C has shown better exergy and energy efficiency.
Abstract: Solid oxide fuel cells have been considered in the last years as one of the most promising technologies for very highefficiency electric energy generation from hydrogen or other hydrocarbons, both with simple fuel cell plants and with integrated gas turbine-fuel cell systems. In the present study, a detailed thermodynamic analysis has been carried out. Mass and exergy balances are performed not only for the whole plant but also for each component in order to evaluate the thermal efficiency of combined cycle. Moreover, different sources of irreversibilities within the SOFC stack have been discussed and a parametric study conducted to evaluate the effect of temperature as well as pressure on SOFC irreversibilities and its performance. In this investigation methane and hydrogen have been used for fueling the SOFC stack and combustion chamber.
Abstract: This paper provides an exergy analysis of the multistage refrigeration cycle used for C2+ recovery plant. The behavior of an industrial refrigeration cycle with refrigerant propane has been investigated by the exergy method. A computational model based on the exergy analysis is presented for the investigation of the effects of the valves on the exergy losses, the second law of efficiency, and the coefficient of performance (COP) of a vapor compression refrigeration cycle. The equations of exergy destruction and exergetic efficiency for the main cycle components such as evaporators, condensers, compressors, and expansion valves are developed. The relations for the total exergy destruction in the cycle and the cycle exergetic efficiency are obtained. An ethane recovery unit with its refrigeration cycle has been simulated to prepare the exergy analysis. Using a typical actual work input value; the exergetic efficiency of the refrigeration cycle is determined to be 39.90% indicating a great potential for improvements. The simulation results reveal that the exergetic efficiencies of the heat exchanger and expansion sections get the lowest rank among the other compartments of refrigeration cycle. Refrigeration calculations have been carried out through the analysis of T–S and P–H diagrams where coefficient of performance (COP) was obtained as 1.85. The novelty of this article includes the effect and sensitivity analysis of molar flow, pressure drops and temperature on the exergy efficiency and coefficient of performance of the cycle.
Abstract: In this paper a polymer electrolyte membrane (PEM)
fuel cell power system including burner, steam reformer, heat
exchanger and water heater has been considered to meet the
electrical, heating, cooling and domestic hot water loads of
residential building which in Tehran. The system uses natural gas as
fuel and works in CHP mode. Design and operating conditions of a
PEM fuel cell system is considered in this study. The energy
requirements of residential building and the number of fuel cell
stacks to meet them have been estimated. The method involved
exergy analysis and entropy generation thorough the months of the
year. Results show that all the energy needs of the building can be
met with 12 fuel cell stacks at a nominal capacity of 8.5 kW. Exergy
analysis of the CHP system shows that the increase in the ambient air
temperature from 1oC to 40oC, will have an increase of entropy
generation by 5.73%.Maximum entropy generates for 15 hour in 15th
of June and 15th of July is estimated to amount at 12624 (kW/K).
Entropy generation of this system through a year is estimated to
amount to 1004.54 GJ/k.year.