Abstract: Experimental investigations of the DC electric field effect on thermal decomposition of biomass, formation of the axial flow of volatiles (CO, H2, CxHy), mixing of volatiles with swirling airflow at low swirl intensity (S ≈ 0.2-0.35), their ignition and on formation of combustion dynamics are carried out with the aim to understand the mechanism of electric field influence on biomass gasification, combustion of volatiles and heat energy production. The DC electric field effect on combustion dynamics was studied by varying the positive bias voltage of the central electrode from 0.6 kV to 3 kV, whereas the ion current was limited to 2 mA. The results of experimental investigations confirm the field-enhanced biomass gasification with enhanced release of volatiles and the development of endothermic processes at the primary stage of thermochemical conversion of biomass determining the field-enhanced heat energy consumption with the correlating decrease of the flame temperature and heat energy production at this stage of flame formation. Further, the field-enhanced radial expansion of the flame reaction zone correlates with a more complete combustion of volatiles increasing the combustion efficiency by 3% and decreasing the mass fraction of CO, H2 and CxHy in the products, whereas by 10% increases the average volume fraction of CO2 and the heat energy production downstream the combustor increases by 5-10%
Abstract: WO3/SiO2 catalysts were modified by an ion exchange
method with sodium hydroxide or potassium hydroxide solution. The
performance of the modified catalysts was tested in the metathesis of
ethylene and trans-2-butene to propylene. During ion exchange,
sodium and potassium ions played different roles. Sodium modified
catalysts revealed constant trans-2-butene conversion and propylene
selectivity when the concentrations of sodium in the solution were
varied. In contrast, potassium modified catalysts showed reduction of
the conversion and increase of the selectivity. From these results,
potassium hydroxide may affect the transformation of tungsten oxide
active species, resulting in the decrease in conversion whereas
sodium hydroxide did not. Moreover, the modification of catalysts by
this method improved the catalyst stability by lowering the amount of
coke deposited on the catalyst surface.
Abstract: This work studied the isomerization of 1-butene over
hydrotalcite catalyst. The experiments were conducted at various gas
hourly space velocity (GHSV), reaction temperature and feed
concentration. No catalyst deactivation was observed over the
reaction time of 16 hours. Two major reaction products were trans-2-
butene and cis-2-butene. The reaction temperature played an
important role on the reaction selectivity. At high operating
temperatures, the selectivity of trans-2-butene was higher than the
selectivity of cis-2-butene while it was opposite at lower reaction
temperature. In the range of operating condition, the maximum
conversion of 1-butene was found at 74% when T = 673 K and GHSV
= 4 m3/h/kg-cat with trans- and cis-2-butene selectivities of 54% and
46%, respectively. Finally, the kinetic parameters of the reaction
were determined.
Abstract: This paper presents the development of a robot car
that can track the motion of an object by detecting its color through
an Android device. The employed computer vision algorithm uses the
OpenCV library, which is embedded into an Android application of a
smartphone, for manipulating the captured image of the object. The
captured image of the object is subjected to color conversion and is
transformed to a binary image for further processing after color
filtering. The desired object is clearly determined after removing
pixel noise by applying image morphology operations and contour
definition. Finally, the area and the center of the object are
determined so that object’s motion to be tracked. The smartphone
application has been placed on a robot car and transmits by Bluetooth
to an Arduino assembly the motion directives so that to follow
objects of a specified color. The experimental evaluation of the
proposed algorithm shows reliable color detection and smooth
tracking characteristics.
Abstract: The effect of additional magnesium oxide (MgO) was
investigated by using the tungsten oxide supported on silica catalyst
(WOx/SiO2) physically mixed with MgO in a weight ratio 1:1. The
both fresh and spent catalysts were characterized by FT-Raman
spectrometer, UV-Vis spectrometer, X-Ray diffraction (XRD) and
temperature programmed oxidation (TPO). The results indicated that
the additional MgO could enhance the conversion of trans-2-butene
due to isomerization reaction. However, adding MgO would increase
the amount of coke deposit on the WOx/SiO2 catalyst. The TPO
profile presented two peaks when the WOx/SiO2 catalyst was
physically mixed with MgO. The further peak was suggested that
came from coke precursor could be produced by isomerization
reaction of undesired product. Then, the occurred coke precursor
could deposit and form coke on the acid catalyst.
Abstract: Pt/γ-Al2O3 membrane catalysts were prepared via an
evaporative-crystallization deposition method. The obtained Pt/γ-
Al2O3 catalyst activity was tested after characterization (SEM-EDAX
observation, BET measurement, permeability assessment) in the
catalytic oxidation of selected volatile organic compound (VOC) i.e.
propane, fed in mixture of oxygen. The VOC conversion (nearly
90%) obtained by varying the operating temperature showed that
flow-through membrane reactor might do better in the abatement of
VOCs.
Abstract: Design concepts of real-time embedded system can be
realized initially by introducing novel design approaches. In this
literature, model based design approach and in-the-loop testing were
employed early in the conceptual and preliminary phase to formulate
design requirements and perform quick real-time verification. The
design and analysis methodology includes simulation analysis, model
based testing, and in-the-loop testing. The design of conceptual driveby-
wire, or DBW, algorithm for electronic control unit, or ECU, was
presented to demonstrate the conceptual design process, analysis, and
functionality evaluation. The concepts of DBW ECU function can be
implemented in the vehicle system to improve electric vehicle, or EV,
conversion drivability. However, within a new development process,
conceptual ECU functions and parameters are needed to be evaluated.
As a result, the testing system was employed to support conceptual
DBW ECU functions evaluation. For the current setup, the system
components were consisted of actual DBW ECU hardware, electric
vehicle models, and control area network or CAN protocol. The
vehicle models and CAN bus interface were both implemented as
real-time applications where ECU and CAN protocol functionality
were verified according to the design requirements. The proposed
system could potentially benefit in performing rapid real-time
analysis of design parameters for conceptual system or software
algorithm development.
Abstract: This study investigates the use of a time-series of
MODIS NDVI data to identify agricultural land cover change on an
annual time step (2007 - 2012) and characterize the trend. Following
an ISODATA classification of the MODIS imagery to selectively
mask areas not agriculture or semi-natural, NDVI signatures were
created to identify areas cereals and vineyards with the aid of
ancillary, pictometry and field sample data for 2010. The NDVI
signature curve and training samples were used to create a decision
tree model in WEKA 3.6.9 using decision tree classifier (J48)
algorithm; Model 1 including ISODATA classification and Model 2
not. These two models were then used to classify all data for the
study area for 2010, producing land cover maps with classification
accuracies of 77% and 80% for Model 1 and 2 respectively. Model 2
was subsequently used to create land cover classification and change
detection maps for all other years. Subtle changes and areas of
consistency (unchanged) were observed in the agricultural classes
and crop practices. Over the years as predicted by the land cover
classification. Forty one percent of the catchment comprised of
cereals with 35% possibly following a crop rotation system.
Vineyards largely remained constant with only one percent
conversion to vineyard from other land cover classes.
Abstract: We have designed wavelength conversion based on
four wave mixing in an optical fiber at 10 Gb/s. The power of
converted signal increases with increase in signal power. The
converted signal power is investigated as a function of input signal
power and pump power. On comparison of converted signal power at
different value of input signal power, we observe that best converted
signal power is obtained at -2 dBm input signal power for both up
conversion as well as for down conversion. Further, FWM efficiency,
quality factor is observed for increase in input signal power and
optical fiber length.
Abstract: The effect of N2 pretreatment on the catalytic activity
of tungsten-based catalysts was investigated in the metathesis of
ethylene and trans-2-butene at 450oC and atmospheric pressure. The
presence of tungsten active species was confirmed by UV-Vis and
Raman spectroscopy. Compared to the WO3-based catalysts treated
in air, higher amount of WO4 2-tetrahedral species and lower amount
of WO3 crystalline species were observed on the N2-treated ones.
These contribute to the higher conversion of 2-butene and propylene
selectivity during 10 h time-on-stream. Moreover, N2 treatment led to
lower amount of coke formation as revealed by TPO of the spent
catalysts.
Abstract: Cesium iodide (CsI) melt was injected into anodic aluminum oxide (AAO) template and was solidified to CsI column. The controllable AAO channel size (10~500 nm) can makes CsI column size from 10 to 500 nm in diameter. In order to have a shorter light irradiate from each singe CsI column top to bottom the AAO template was coated a TiO2 nano-film. The TiO2 film acts a refraction film and makes X-ray has a shorter irradiation path in the CsI crystal making a stronger the photo-electron signal. When the incidence light irradiate from air (R=1.0) to CsI’s first surface (R=1.84) the first refraction happen, the first refraction continue into TiO2 film (R=2.88) and produces the low angle of the second refraction. Then the second refraction continue into AAO wall (R=1.78) and produces the third refraction after refractions between CsI and AAO wall (R=1.78) produce the fourth refraction. The incidence light through TiO2 filmand the first surface of CsI then arrive to the second surface of CsI. Therefore, the TiO2 film can has shorter refraction path of incidence light and increase the photo-electron conversion efficiency.
Abstract: Propylene self-metathesis to ethylene and butene was
studied over WOx/SiO2 catalysts at 450oC and atmospheric pressure.
The WOx/SiO2 catalysts were prepared by incipient wetness
impregnation of ammonium metatungstate aqueous solution. It was
found that, adding nano-sized extra supports (SiO2 and TiO2) by
physical mixing with the WOx/SiO2 enhanced propylene conversion.
The UV-Vis and FT-Raman results revealed that WOx could migrate
from the original silica support to the extra support, leading to a
better dispersion of WOx. The ICP-OES results also indicate that
WOx existed on the extra support. Coke formation was investigated
on the catalysts after 10 h time-on-stream by TPO. However, adding
nano-sized extra supports led to higher coke formation which may be
related to acidity as characterized by NH3-TPD.
Abstract: Catalytic combustion of methane is imperative due to
stability of methane at low temperature. Methane (CH4), therefore,
remains unconverted in vehicle exhausts thereby causing greenhouse
gas GHG emission problem. In this study, heterogeneous catalysts of
palladium with bio-char (2 wt% Pd/Bc) and Al2O3 (2wt% Pd/ Al2O3)
supports were prepared by incipient wetness impregnation and then
subsequently tested for catalytic combustion of CH4. Support-porous
heterogeneous catalytic combustion (HCC) material were selected
based on factors such as surface area, porosity, thermal stability,
thermal conductivity, reactivity with reactants or products, chemical
stability, catalytic activity, and catalyst life. Sustainable and
renewable support-material of bio-mass char derived from palm shell
waste material was compared with those from the conventional
support-porous materials. Kinetic rate of reaction was determined for
combustion of methane on Palladium (Pd) based catalyst with Al2O3
support and bio-char (Bc). Material characterization was done using
TGA, SEM, and BET surface area. The performance test was
accomplished using tubular quartz reactor with gas mixture ratio of
3% methane and 97% air. The methane porous-HCC conversion was
carried out using online gas analyzer connected to the reactor that
performed porous-HCC. BET surface area for prepared 2 wt% Pd/Bc
is smaller than prepared 2wt% Pd/ Al2O3 due to its low porosity
between particles. The order of catalyst activity based on kinetic rate
on reaction of catalysts in low temperature was 2wt%
Pd/Bc>calcined 2wt% Pd/ Al2O3> 2wt% Pd/ Al2O3>calcined 2wt%
Pd/Bc. Hence agro waste material can successfully be utilized as an
inexpensive catalyst support material for enhanced CH4 catalytic
combustion.
Abstract: Solid waste management in steel industry is broadly
classified in “4 Rs” i.e. reduce, reuse, recycle and restore the
materials. Reuse and recycling the entire solid waste generated in the
process of steel making is a viable solution in targeting a clean, green
and zero waste technology leading to sustainable development of the
steel industry. Solid waste management has gained importance in
steel industry in view of its uncertainty, volatility and speculation due
to world competitive standards, rising input costs, scarcity of raw
materials and solid waste generated like in other sectors. The
challenges that the steel Industry faces today are the requirement of a
sustainable development by meeting the needs of our present
generation without compromising the ability of future generations.
Technologies are developed not only for gainful utilization of solid
wastes in manufacture of conventional products but also for
conversion of same in to completely new products.
Abstract: Africa enjoys some of the best solar radiation levels in
the world averaging between 4-6 kWh/m2/day for most of the year
and the global economic and political conditions that tend to make
African countries more dependent on their own energy resources
have caused growing interest in renewable energy based
technologies. However to-date, implementation of modern Energy
Technologies in Africa is still very low especially the use of solar
conversion technologies. This paper presents literature review and
analysis relating to the techno-economic feasibility of solar
photovoltaic power generation in Africa. The literature is basically
classified into the following four main categories. Techno-economic
feasibility of solar photovoltaic power generation, design methods,
performance evaluations of various systems and policy of potential
future of technological development of photovoltaic (PV) in Africa
by exploring the impact of alternative policy instruments and
technology cost reductions on the financial viability of investing solar
photovoltaic in Africa.
Abstract: Presently, it is necessary to ensure the sustainable
development of passenger and freight transport. Increasing
performance of road freight has had a negative impact to environment
and society. It is therefore necessary to increase the competitiveness
of intermodal transport, which is more environmentally friendly. The
study describes the effectiveness of logistical centers realization for
companies and society and research how the partial internalization of
external costs reflected in the efficient use of these centers and
increase the competitiveness of intermodal transport to road freight.
In our research, we use the method of comparative analysis and
market research to describe the advantages of logistic centers for their
users as well as for society as a whole. Method normal costing is used
for calculation infrastructure and total costs, method of conversion
costing for determine the external costs. We modelled total society
costs for road freight transport and inter modal transport chain (we
assumed that most of the traffic is carried by rail) with different
loading schemes for condition in the Slovak Republic. Our research
has shown that higher utilization of inter modal transport chain do
good not only for society, but for companies providing freight
services too. Increase in use of inter modal transport chain can bring
many benefits to society that do not bring direct immediate financial
return. They often bring the multiplier effects, such as greater use of
environmentally friendly transport mode and reduce the total society
costs.
Abstract: Flow blockages referring to the increase in flow are
being considered as a vital equipment for marine current energy
conversion. However, the shape of these devices will result in
extracted energy under the operation. The present work investigates
the effect of two configurations of a grating, convergent and
divergent that located upstream, to the water flow velocity. The flow
characteristics are studied by Computational Fluid Dynamic
simulation by using the ANSYS Fluent solver for these specified
arrangements of the grating. The results indicate that distinguished
characteristics of flow velocity between “convergent” and
“divergent” grating placements is up to 10% in confined conditions.
Furthermore, the velocity in case of convergent grating is higher
than that of divergent grating.
Abstract: Evaluated nuclear decay data for the 217Po nuclide is
presented in the present work. These data include recommended
values for the half-life T1/2, α-, β-- and γ-ray emission energies and
probabilities. Decay data from 221Rn α and 217Bi β—decays are
presented. Q(α) has been updated based on the recent published work
of the Atomic Mass Evaluation AME2012. In addition, the logft
values were calculated using the Logft program from the ENSDF
evaluation package. Moreover, the total internal conversion electrons
and the K-shell to L-shell and L-shell to M-shell and to N-shell
conversion electrons ratios K/L, L/M and L/N have been calculated
using Bricc program. Meanwhile, recommendation values or the
multi-polarities have been assigned based on recently measurement
yield a better intensity balance at the 254 keV and 264 keV gamma
transitions.
Abstract: The effects of basil and/or chamomile seed
supplementation on the growth of Hubbard broiler chicks were
evaluated. The antioxidant effects of these supplements were also
assessed. 120 1-day-old broiler chicks were randomly divided into
four equal groups. The control group (group 1) was fed a basal diet
(BD) without supplementation. Groups 2, 3, and 4 were fed the BD
supplemented with 10g basil, 10g chamomile, and 5g basil plus 5g
chamomile per kg of food, respectively. Basil supplementation alone
or in combination with chamomile non-significantly (P≥0.05)
increased final body weight (3.2% and 0.3%, respectively) and
weight gain (3.5% and 3.6%, respectively) over the experimental
period. Chamomile supplementation alone non-significantly (P≥0.05)
reduced final body weight and weight gain over the experimental
period by 1.7% and 1.7%, respectively. In comparison to the control
group, herbal seed supplementation reduced feed intake and
improved the feed conversion and protein efficiency ratios. In
general, basil seed supplementation stimulated chicken growth and
improved the feed efficiency more effectively than chamomile seed
supplementation. The antioxidant activities of basil and/or chamomile
supplementation were examined in the thymus, bursa, and spleen. In
chickens that received supplements, the level of malondialdehyde
was significantly decreased, whereas the activities of glutathione,
superoxide dismutase, and catalase were significantly increased
(P
Abstract: This study evaluated the use of raw or processed
Prosopis juliflora (Meskit) pods as a major ingredient in a formulated
ration to provide an alternative non-conventional concentrate for
livestock feeding in Oman. Dry Meskit pods were reduced to lengths
of 0.5- 1.0 cm to ensure thorough mixing into three diets. Meskit
pods were subjected to two types of treatments; roasting and soaking.
They were roasted at 150оC for 30 minutes using a locally-made
roasting device (40 kg barrel container rotated by electric motor and
heated by flame gas cooker). Chopped pods were soaked in tap water
for 24 hours and dried for 2 days under the sun with frequent turning.
The Meskit-pod-based diets (MPBD) were formulated and pelleted
from 500 g/kg ground Meskit pods, 240 g/kg wheat bran, 200 g/kg
barley grain, 50 g/kg local dried sardines and 10 g/kg of salt. Twenty
four 10 months-old intact Omani male lambs with average body
weight of 27.3 kg (± 0.5 kg) were used in a feeding trial for 84 days.
They were divided (on body weight basis) and allocated to four diet
combination groups. These were: Rhodes grass hay (RGH) plus a
general ruminant concentrate (GRC); RGH plus raw Meskit pods
(RMP) based concentrate; RGH plus roasted Meskit pods (ROMP)
based concentrate; RGH plus soaked Meskit pods (SMP) based
concentrate Daily feed intakes and bi-weekly body weights were
recorded. MPBD had higher contents of crude protein (CP), acid
detergent fibre (ADF) and neutral detergent fibre (NDF) than the
GRC. Animals fed various types of MPBD did not show signs of ill
health. There was a significant effect of feeding ROMP on the
performance of Omani sheep compared to RMP and SMP. The
ROMP fed animals had similar performance to those fed the GRC in
terms of feed intake, body weight gain and feed conversion ratio
(FCR).This study indicated that roasted Meskit pods based diet may
be used instead of the commercial concentrate for feeding Omani
sheep without adverse effects on performance. It offers a cheap
alternative source of protein and energy for feeding Omani sheep.
Also, it might help in solving the spread impact of Meskit trees,
maintain the ecosystem and helping in preserving the local tree
species.