Abstract: In this study, a nickel film with nano-crystalline grains,
high hardness and smooth surface was electrodeposited using a post
supercritical carbon dioxide (CO2) mixed Watts electrolyte. Although
the hardness was not as high as its Sc-CO2 counterpart, the thin coating
contained significantly less number of nano-sized pinholes. By
measuring the escape concentration of the dissolved CO2 in post
Sc-CO2 mixed electrolyte with the elapsed time, it was believed that
the residue of dissolved CO2 bubbles should closely relate to the
improvement in hardness and surface roughness over its conventional
plating counterpart. Therefore, shortening the duration of
electroplating with the raise of current density up to 0.5 A/cm2 could
effectively retain more post Sc-CO2 mixing effect. This study not only
confirms the roles of dissolved CO2 bubbles in electrolyte but also
provides a potential process to overcome most issues associated with
the cost in building high-pressure chamber for large size products and
continuous plating using supercritical method.
Abstract: Commercial infrastructures intended for use as leisure
retreats such as golf and ski resorts have been extensively developed in many rural areas of Japan. However, following the burst of the economic bubble in the 1990s, several existing resorts faced tough
management decisions and some were forced to close their business.
In this study, six alternative management options for restructuring the
existing golf courses (park, cemetery, biofuel production, reforestation,
pasturing and abandonment) are examined and their environmental
and economic impacts are quantitatively assessed. In addition,
restructuring scenarios of these options and an ex-ante assessment
model are developed. The scenario analysis by Monte Carlo simulation shows a clear trade-off between GHG savings and benefit/cost (B/C) ratios, of which “Restoring Nature" scenario
absorbs the most CO2 among the four scenarios considered, but its B/C
ratio is the lowest. This study can be used to select or examine options
and scenarios of golf course management and rural environmental
management policies.
Abstract: Using a force balanced translational-radial dynamics,
phase space of the moving single bubble sonoluminescence (m-
SBSL) in 85% wt sulfuric acid has been numerically calculated. This
phase space is compared with that of single bubble sonoluminescence
(SBSL) in pure water which has been calculated by using the mere
radial dynamics. It is shown that in 85% wt sulfuric acid, in a general
agreement with experiment, the bubble-s positional instability
threshold lays under the shape instability threshold. At the onset of
spatial instability of moving sonoluminescing (SL) bubble in 85%
wt sulfuric acid, temporal effects of the hydrodynamic force on the
bubble translational-radial dynamics have been investigated. The
appearance of non-zero history force on the moving SL bubble is
because of proper condition which was produced by high viscosity of
acid. Around the moving bubble collapse due to the rapid contraction
of the bubble wall, the inertial based added mass force overcomes the
viscous based history force and induces acceleration on the bubble
translational motion.
Abstract: Different numerical methods are employed and developed for simulating interfacial flows. A large range of applications belong to this group, e.g. two-phase flows of air bubbles in water or water drops in air. In such problems surface tension effects often play a dominant role. In this paper, various models of surface tension force for interfacial flows, the CSF, CSS, PCIL and SGIP models have been applied to simulate the motion of small air bubbles in water and the results were compared and reviewed. It has been pointed out that by using SGIP or PCIL models, we are able to simulate bubble rise and obtain results in close agreement with the experimental data.
Abstract: Based on a global kinetics of direct dimethyl ether (DME) synthesis process from syngas, a steady-state one-dimensional mathematical model for the bubble column slurry reactor (BCSR) has been established. It was built on the assumption of plug flow of gas phase, sedimentation-dispersion model of catalyst grains and isothermal chamber regardless of reaction heats and rates for the design of an industrial scale bubble column slurry reactor. The simulation results indicate that higher pressure and lower temperature were favorable to the increase of CO conversion, DME selectivity, products yield and the height of slurry bed, which has a coincidence with the characteristic of DME synthesis reaction system, and that the height of slurry bed is lessen with the increasing of operation temperature in the range of 220-260℃. CO conversion, the optimal operation conditions in BCSR were proposed.
Abstract: In the present study, a heterogeneous and
homogeneous gas flow dispersion model for simulation and
optimisation of a large-scale catalytic slurry reactor for the direct
synthesis of dimethyl ether (DME) from syngas and CO2, using a
churn-turbulent regime was developed. In the heterogeneous gas flow
model the gas phase was distributed into two bubble phases: small
and large, however in the homogeneous one, the gas phase was
distributed into only one large bubble phase. The results indicated
that the heterogeneous gas flow model was in more agreement with
experimental pilot plant data than the homogeneous one.
Abstract: Many algorithms are available for sorting the unordered elements. Most important of them are Bubble sort, Heap sort, Insertion sort and Shell sort. These algorithms have their own pros and cons. Shell Sort which is an enhanced version of insertion sort, reduces the number of swaps of the elements being sorted to minimize the complexity and time as compared to insertion sort. Shell sort improves the efficiency of insertion sort by quickly shifting values to their destination. Average sort time is O(n1.25), while worst-case time is O(n1.5). It performs certain iterations. In each iteration it swaps some elements of the array in such a way that in last iteration when the value of h is one, the number of swaps will be reduced. Donald L. Shell invented a formula to calculate the value of ?h?. this work focuses to identify some improvement in the conventional Shell sort algorithm. ''Enhanced Shell Sort algorithm'' is an improvement in the algorithm to calculate the value of 'h'. It has been observed that by applying this algorithm, number of swaps can be reduced up to 60 percent as compared to the existing algorithm. In some other cases this enhancement was found faster than the existing algorithms available.
Abstract: The elimination of ranitidine (a pharmaceutical
compound) has been carried out in the presence of UV-C radiation.
After some preliminary experiments, it has been experienced the no
influence of the gas nature (air or oxygen) bubbled in photolytic
experiments. From simple photolysis experiments the quantum yield
of this compound has been determined. Two photolytic
approximation has been used, the linear source emission in parallel
planes and the point source emission in spherical planes. The
quantum yield obtained was in the proximity of 0.05 mol Einstein-1
regardless of the method used. Addition of free radical promoters
(hydrogen peroxide) increases the ranitidine removal rate while the
use of photocatalysts (TiO2) negatively affects the process.
Abstract: In this paper, the two-dimensional stagger grid
interface pressure (SGIP) model has been generalized and presented
into three-dimensional form. For this purpose, various models of
surface tension force for interfacial flows have been investigated and
compared with each other. The VOF method has been used for
tracking the interface. To show the ability of the SGIP model for
three-dimensional flows in comparison with other models, pressure
contours, maximum spurious velocities, norm spurious flow
velocities and pressure jump error for motionless drop of liquid and
bubble of gas are calculated using different models. It has been
pointed out that SGIP model in comparison with the CSF, CSS and
PCIL models produces the least maximum and norm spurious
velocities. Additionally, the new model produces more accurate
results in calculating the pressure jumps across the interface for
motionless drop of liquid and bubble of gas which is generated in
surface tension force.
Abstract: Many accidents were happened because of fast driving, habitual working overtime or tired spirit. This paper presents a solution of remote warning for vehicles collision avoidance using vehicular communication. The development system integrates dedicated short range communication (DSRC) and global position system (GPS) with embedded system into a powerful remote warning system. To transmit the vehicular information and broadcast vehicle position; DSRC communication technology is adopt as the bridge. The proposed system is divided into two parts of the positioning andvehicular units in a vehicle. The positioning unit is used to provide the position and heading information from GPS module, and furthermore the vehicular unit is used to receive the break, throttle, and othersignals via controller area network (CAN) interface connected to each mechanism. The mobile hardware are built with an embedded system using X86 processor in Linux system. A vehicle is communicated with other vehicles via DSRC in non-addressed protocol with wireless access in vehicular environments (WAVE) short message protocol. From the position data and vehicular information, this paper provided a conflict detection algorithm to do time separation and remote warning with error bubble consideration. And the warning information is on-line displayed in the screen. This system is able to enhance driver assistance service and realize critical safety by using vehicular information from the neighbor vehicles.KeywordsDedicated short range communication, GPS, Control area network, Collision avoidance warning system.
Abstract: While the form of crises may change, their essence
remains the same (such as a cycle of abundant liquidity, rapid credit
growth, and a low-inflation environment followed by an asset-price
bubble). The current market turbulence began in mid-2000s when the
US economy shifted to imbalanced both internal and external
macroeconomic positions. We see two key causes of these problems
– loose US monetary policy in early 2000s and US government
guarantees issued on the securities by government-sponsored
enterprises what was further fueled by financial innovations such as
structured credit products. We have discovered both negative and
positive lessons deriving from this crisis and divided the negative
lessons into three groups: financial products and valuation, processes
and business models, and strategic issues. Moreover, we address key
risk management lessons and exit strategies derived from the current
crisis and recommend policies that should help diminish the negative
impact of future potential crises.
Abstract: We have previously introduced an ultrasonic imaging
approach that combines harmonic-sensitive pulse sequences with a
post-beamforming quadratic kernel derived from a second-order
Volterra filter (SOVF). This approach is designed to produce images
with high sensitivity to nonlinear oscillations from microbubble
ultrasound contrast agents (UCA) while maintaining high levels of
noise rejection. In this paper, a two-step algorithm for computing the
coefficients of the quadratic kernel leading to reduction of tissue
component introduced by motion, maximizing the noise rejection and
increases the specificity while optimizing the sensitivity to the UCA
is presented. In the first step, quadratic kernels from individual
singular modes of the PI data matrix are compared in terms of their
ability of maximize the contrast to tissue ratio (CTR). In the second
step, quadratic kernels resulting in the highest CTR values are
convolved. The imaging results indicate that a signal processing
approach to this clinical challenge is feasible.
Abstract: A phorbol-12-myristate-13-acetate (TPA) is a synthetic analogue of phorbol ester (PE), a natural toxic compound of Euphorbiaceae plant. The oil extracted from plants of this family is useful source for primarily biofuel. However this oil might also be used as a foodstuff due to its significant nutrition content. The limitations for utilizing the oil as a foodstuff are mainly due to a toxicity of PE. Currently, a majority of PE detoxification processes are expensive as include multi steps alcohol extraction sequence.
Ozone is considered as a strong oxidative agent. It reacts with PE by attacking the carbon-carbon double bond of PE. This modification of PE molecular structure yields a non toxic ester with high lipid content.
This report presents data on development of simple and cheap PE detoxification process with water application as a buffer and ozone as reactive component. The core of this new technique is an application for a new microscale plasma unit to ozone production and the technology permits ozone injection to the water-TPA mixture in form of microbubbles.
The efficacy of a heterogeneous process depends on the diffusion coefficient which can be controlled by contact time and interfacial area. The low velocity of rising microbubbles and high surface to volume ratio allow efficient mass transfer to be achieved during the process. Direct injection of ozone is the most efficient way to process with such highly reactive and short lived chemical.
Data on the plasma unit behavior are presented and the influence of gas oscillation technology on the microbubble production mechanism has been discussed. Data on overall process efficacy for TPA degradation is shown.
Abstract: Air bubbles have been detected in human circulation
of end-stage renal disease patients who are treated by hemodialysis.
The consequence of air embolism, air bubbles, is under recognized
and usually overlooked in daily practice. This paper shows results of
a capacitor based detection method that capable of detecting the
presence of air bubbles in the blood stream in different frequencies.
The method is based on a parallel plates capacitor made of platinum
with an area of 1.5 cm2 and a distance between the two plates is 1cm.
The dielectric material used in this capacitor is Dextran70 solution
which mimics blood rheology. Simulations were carried out using
RC circuit at two frequencies 30Hz and 3 kHz and results compared
with experiments and theory. It is observed that by injecting air
bubbles of different diameters into the device, there were significant
changes in the capacitance of the capacitor. Furthermore, it is
observed that the output voltage from the circuit increased with
increasing air bubble diameter. These results demonstrate the
feasibility of this approach in improving air bubble detection in
Hemodialysis.
Abstract: In this paper, growth and collapse of a vapour bubble
generated due to a local energy input inside a rigid cylinder and in
the absence of buoyancy forces is investigated using Boundary
Integral Equation Method and Finite Difference Method .The fluid is
treated as potential flow and Boundary Integral Equation Method is
used to solve Laplace-s equation for velocity potential. Different
ratios of the diameter of the rigid cylinder to the maximum radius of
the bubble are considered. Results show that during the collapse
phase of the bubble inside a vertical rigid cylinder, two liquid micro
jets are developed on the top and bottom sides of the vapour bubble
and are directed inward. It is found that by increasing the ratio of the
cylinder diameter to the maximum radius of the bubble, the rate of
the growth and collapse phases of the bubble increases and the life
time of the bubble decreases.
Abstract: The theoretical investigation is carried out to describe
the effect of increase of pressure waves amplitude in clean and bubbly liquid. The goal of the work is to capture the regime of multiple magnification of acoustic and shock waves in the liquid,
which enables to get appropriate conditions to enlarge collapses of
micro-bubbles. The influence of boundary conditions and frequency
of the governing acoustic field is studied for the case of the
cylindrical acoustic resonator. It has been observed the formation of
standing waves with large amplitude at resonant frequencies. The
interaction of the compression wave with gas and vapor bubbles is
investigated for the convergent channel. It is shown theoretically that
the chemical reactions, which occur inside gas bubbles, provide additional impulse to the wave, that affect strongly on the collapses
of the vapor bubbles
Abstract: Thermal water hammer is a special type of water
hammer which rarely occurs in heat exchangers. In biphasic fluids, if
steam bubbles are surrounded by condensate, regarding lower
condensate temperature than steam, they will suddenly collapse. As a
result, the vacuum caused by an extreme change in volume lead to
movement of the condensates in all directions and their collision the
force produced by this collision leads to a severe stress in the pipe
wall. This phenomenon is a special type of water hammer. According
to fluid mechanics, this phenomenon is a particular type of transient
flows during which abrupt change of fluid leads to sudden pressure
change inside the tube. In this paper, the mechanism of abrupt failure
of 80 tubes of 481 tubes of a methanol heat exchanger is discussed.
Initially, due to excessive temperature differences between heat
transfer fluids and simultaneous failure of 80 tubes, thermal shock
was presupposed as the reason of failure. Deeper investigation on
cross-section of failed tubes showed that failure was, ductile type of
failure, so the first hypothesis was rejected. Further analysis and more
accurate experiments revealed that failure of tubes caused by thermal
water hammer. Finally, the causes of thermal water hammer and
various solutions to avoid such mechanism are discussed.
Abstract: Microbubbbles incorporating ultrasound have been used to increase the efficacy of targeted drug delivery, because microstreaming induced by cavitating bubbles affects the drug perfusion into the target cells and tissues. In order to clarify the physical effects of microstreaming on drug perfusion into tissues, a preliminary experimental study of perfusion enhancement by a stably oscillating microbubble was performed. Microstreaming was induced by an oscillating bubble at 15 kHz, and perfusion of dye into an agar phantom was optically measured by histology on agar phantom. Surface color intensity and the penetration length of dye in the agar phantom were increased more than 70% and 30%, respectively, due to the microstreaming induced by an oscillating bubble. The mass of dye perfused into a tissue phantom for 30 s was increased about 80% in the phantom with an oscillating bubble. This preliminary experiment shows the physical effects of steady streaming by an oscillating bubble can enhance the drug perfusion into the tissues while minimizing the biological effects.
Abstract: In this study, direct numerical simulation for the bubble condensation in the subcooled boiling flow was performed. The main goal was to develop the CFD modeling for the bubble condensation and to evaluate the accuracy of the VOF model with the developed CFD modeling. CFD modeling for the bubble condensation was developed by modeling the source terms in the governing equations of VOF model using UDF. In the modeling, the amount of condensation was determined using the interfacial heat transfer coefficient obtained from the bubble velocity, liquid temperature and bubble diameter every time step. To evaluate the VOF model using the CFD modeling for the bubble condensation, CFD simulation results were compared with SNU experimental results such as bubble volume and shape, interfacial area, bubble diameter and bubble velocity. Simulation results predicted well the behavior of the actual condensing bubble. Therefore, it can be concluded that the VOF model using the CFD modeling for the bubble condensation will be a useful computational fluid dynamics tool for analyzing the behavior of the condensing bubble in a wide range of the subcooled boiling flow.
Abstract: The hydrodynamic processes in bubbly liquid flowing
in tubes and nozzles are studied theoretically and numerically. The
principal regularities of non-stationary processes of boiling liquid
outflow are established under conditions of experiments when the
depressurization of a tube with high pressure inside occurs. The
steady-state solution of bubbly liquid flow in the nozzle of round
cross section with high pressure and temperature conditions inside
bubbles is studied accounting for phase transition and chemical
reactions.