Abstract: Natural hydrocarbon seepage has helped petroleum
exploration as a direct indicator of gas and/or oil subsurface
accumulations. Surface macro-seeps are generally an indication of a
fault in an active Petroleum Seepage System belonging to a Total
Petroleum System. This paper describes a case study in which
multiple analytical techniques were used to identify and characterize
trace petroleum-related hydrocarbons and other volatile organic
compounds in groundwater samples collected from Sousse aquifer
(Central Tunisia). The analytical techniques used for analyses of
water samples included gas chromatography-mass spectrometry (GCMS),
capillary GC with flame-ionization detection, Compound
Specific Isotope Analysis, Rock Eval Pyrolysis. The objective of the
study was to confirm the presence of gasoline and other petroleum
products or other volatile organic pollutants in those samples in order
to assess the respective implication of each of the potentially
responsible parties to the contamination of the aquifer. In addition,
the degree of contamination at different depths in the aquifer was also
of interest. The oil and gas seeps have been investigated using
biomarker and stable carbon isotope analyses to perform oil-oil and
oil-source rock correlations. The seepage gases are characterized by
high CH4 content, very low δ13CCH4 values (-71,9 ‰) and high
C1/C1–5 ratios (0.95–1.0), light deuterium–hydrogen isotope ratios (-
198 ‰) and light δ13CC2 and δ13CCO2 values (-23,8‰ and-23,8‰
respectively) indicating a thermogenic origin with the contribution of
the biogenic gas. An organic geochemistry study was carried out on
the more ten oil seep samples. This study includes light hydrocarbon
and biomarkers analyses (hopanes, steranes, n-alkanes, acyclic
isoprenoids, and aromatic steroids) using GC and GC-MS. The
studied samples show at least two distinct families, suggesting two
different types of crude oil origins: the first oil seeps appears to be
highly mature, showing evidence of chemical and/or biological
degradation and was derived from a clay-rich source rock deposited
in suboxic conditions. It has been sourced mainly by the lower
Fahdene (Albian) source rocks. The second oil seeps was derived
from a carbonate-rich source rock deposited in anoxic conditions,
well correlated with the Bahloul (Cenomanian-Turonian) source rock.
Abstract: Polymer-modified bitumen is used to combat different pavement distresses and to increase the life span of pavement. Unmodified bitumen cannot perform better with the range extreme minimum and maximum pavement temperatures. The polymers commonly used to modify the bitumen are ethylene vinyl acetate (EVA) styrene butadiene styrene (SBS). The aim this study to compare the performance of EVA modified bitumen with the bitumen modified by waste low density polyethylene (LDPE), polypropylene (PP) obtained from waste carry bags and waste tyre rubber (CR) to encourage the use of waste polymer whose disposal is big problem today, in place of costly virgin polymer. From the experimental study, it was found that waste polymers are also effective in improving the properties bitumen as that of virgin polymer.
Abstract: According to Rostler method (ASTM D 2006), saturates content of bitumen is determined based on its reactivity to sulphuric acid. While Corbett method (ASTM D 4124) based on its polarity level. This paper presents results from the study on the effect of saturates content determined by two different fractionation methods on the rheological and aging characteristics of bitumen. The result indicated that the increment of saturates content tended to reduce all the rheological characteristics concerned. Bitumen became less elastic, less viscous, and less resistant to plastic deformation, but became more resistant to fatigue cracking. After short and long term aging process, the treatment effect coefficients of saturates decreased, saturates became thicker due to aging process. This study concludes that saturates is not really stable or reactive in aging process. Therefore, the reactivity of saturates should be considered in bitumen aging index
Abstract: Oilsands bitumen is an extremely important source of
energy for North America. However, due to the presence of large
molecules such as asphaltenes, the density and viscosity of the
bitumen recovered from these sands are much higher than those of
conventional crude oil. As a result the extracted bitumen has to be
diluted with expensive solvents, or thermochemically upgraded in
large, capital-intensive conventional upgrading facilities prior to
pipeline transport. This study demonstrates that globally abundant
natural zeolites such as clinoptilolite from Saint Clouds, New Mexico
and Ca-chabazite from Bowie, Arizona can be used as very effective
reagents for cracking and visbreaking of oilsands bitumen. Natural
zeolite cracked oilsands bitumen products are highly recoverable (up
to ~ 83%) using light hydrocarbons such as pentane, which indicates
substantial conversion of heavier fractions to lighter components.
The resultant liquid products are much less viscous, and have lighter
product distribution compared to those produced from pure thermal
treatment. These natural minerals impart similar effect on industrially
extracted Athabasca bitumen.
Abstract: Use of a sliding joint is an effective method to
decrease the stress in foundation structure where there is a horizontal
deformation of subsoil (areas afflicted with underground mining) or
horizontal deformation of a foundation structure (pre-stressed
foundations, creep, shrinkage, temperature deformation). A
convenient material for a sliding joint is a bitumen asphalt belt.
Experiments for different types of bitumen belts were undertaken at
the Faculty of Civil Engineering - VSB Technical University of
Ostrava in 2008. This year an extension of the 2008 experiments is in
progress and the shear resistance of a slide joint is being tested as a
function of temperature in a temperature controlled room. In this
paper experimental results of temperature dependant shear resistance
are presented. The result of the experiments should be the sliding
joint shear resistance as a function of deformation velocity and
temperature. This relationship is used for numerical analysis of
stress/strain relation between foundation structure and subsoil. Using
a rheological slide joint could lead to a decrease of the reinforcement
amount, and contribute to higher reliability of foundation structure
and thus enable design of more durable and sustainable building
structures.
Abstract: Asphalt surfaces are exposed to various weather
conditions and dynamic loading caused by passing trucks and
vehicles. In such situations, asphalt cement shows so different
rheological-mechanical behavior. If asphalt cement isn-t compatible
enough, asphalt layer will be damaged immediately and expensive
repairing procedures should be performed then. To overcome this
problem, researchers study on mechanical improved asphalt cement.
In this study, bentonite was used in order to modify bitumen
characteristics and the modified bitumen's characteristics were
investigated by asphalt cement tests. Then, the optimal bitumen
content in various compounds was determined and asphalt samples
with different contents of additives were prepared and tested. Results
show using this kind of additive not only has caused improvement in
bitumen mechanical properties, but also improvement in Marshall
Parameters was achieved.
Abstract: This paper presents a part of research on the
rheological properties of bitumen modified by thermoplastic namely
linear low density polyethylene (LLDPE), high density polyethylene
(HDPE) and polypropylene (PP) and its interaction with 80 pen base
bitumen. As it is known that the modification of bitumen by the use
of polymers enhances its performance characteristics but at the same
time significantly alters its rheological properties. The rheological
study of polymer modified bitumen (PMB) was made through
penetration, ring & ball softening point and viscosity test. The results
were then related to the changes in the rheological properties of
polymer modified bitumen. It was observed that thermoplastic
copolymer shows profound effect on penetration rather than
softening point. The viscoelastic behavior of polymer modified
bitumen depend on the concentration of polymer, mixing
temperature, mixing technique, solvating power of base bitumen and
molecular structure of polymer used. PP offer better blend in
comparison to HDPE and LLDPE. The viscosity of base bitumen was
also enhanced with the addition of polymer. The pseudoplastic
behavior was more prominent for HDPE and LLDPE than PP. Best
results were obtained when polymer concentration was kept below
3%
Abstract: Concrete pavement has superior durability and longer
structural life than asphalt pavement. Concrete pavement requires
less maintenance compared to asphalt pavement which requires maintenance and major rehabilitation. Use of the concrete pavement
has been grown over the past decade in developing countries. Fibre reinforced concrete (FRC) has been successfully used in design of concrete pavement in past decade. In this research, the effect of fibre
volume fraction in modulus of rupture, load-deflection, equivalent flexural strength (fe,3) and the equivalent flexural strength ratio (Re,3)
has been used in different fibre volume fraction. Crimped-type flat
steel fibre of size 50 x 2.0 x 0.6 mm was used with 1.0%, 1.5% and 2.0% volume fraction. Beam specimens of size 500 x 100 x 100 mm were used for flexural as well as with JCI method for analysis flexural toughness, equivalent flexural strength. It was obtained as the 2% fibre volume fractions; reduce 45% of the concrete pavement
thickness.
Abstract: This paper presents a research conducted to investigate the effect of mixing process on polypropylene (PP) modified bitumen mixed with well graded aggregate to form modified bituminous concrete mix. Two mode of mixing, namely dry and wet with different concentration of polymer polypropylene was used with 80/100 pen bitumen, to evaluate the bituminous concrete mix properties. Three percentages of polymer varying from 1-3% by the weight of bitumen was used in this study. Three mixes namely control mix, wet mix and dry mix were prepared. Optimum binder content was calculated considering Marshall Stability, flow, air voids and Marshall Quotient at different bitumen content varying from 4% - 6.5% for control, dry and wet mix. Engineering properties thus obtained at the calculated optimum bitumen content revealed that wet mixing process is advantageous in comparison to dry mixing as it increases the stiffness of the mixture with the increase in polymer content in bitumen. Stiffness value for wet mix increases with the increase in polymer content which is beneficial in terms of rutting. 1% PP dry mix also shows enhanced stiffness, with the air void content limited to 4%.The flow behaviour of dry mix doesn't indicate any major difference with the increase in polymer content revealing that polymer acting as an aggregate only without affecting the viscosity of the binder in the mix. Polypropylene (PP) when interacted with 80 pen base bitumen enhances its performance characteristics which were brought about by altered rheological properties of the modified bitumen. The decrease in flow with the increase in binder content reflects the increase in viscosity of binder which induces the plastic flow in the mix. Workability index indicates that wet mix were easy to compact up to desired void ratio in comparison to dry mix samples.
Abstract: The present study explains the effect of aggregate
gradation on moisture damage in bituminous mixes. Three types of
aggregate gradation and two types of binder; VG-30 and Polymer
modified bitumen (PMB-40) are used. Moisture susceptibility tests
like retained stability and tensile strength ratio (TSR) and static creep
test are conducted on Marshall specimens. The creep test was also
conducted for conditioned and unconditioned specimens to observe
the effect of moisture on creep behaviour. The results indicate that
Marshall stability value is higher in PMB-40 mix than VG-30 mixes.
Moisture susceptibility of PMB-40 mixes is low when compared with
mix using VG-30. The reduction in retained stability, and indirect
tensile strength and increase in creep are evaluated for finer, coarser
and normal gradation of aggregate to observe the effect of gradation
on moisture susceptibility of mixes. The retained stability is least
affected when compared with other moisture susceptibility
parameters
Abstract: This study has applied the L16 orthogonal array of the
Taguchi method to determine the optimized polymeric
Nanocomposite asphalt binder. Three control factors are defined as
polypropylene plastomer (PP), styrene-butadiene-styrene elastomer
(SBS) and Nanoclay. Four level of concentration contents are
introduced for prepared asphalt binder samples. all samples were
prepared with 4.5% of bitumen 60/70 content. Compressive strength
tests were carried out for defining the optimized sample via
QUALITEK-4 software. SBS with 3%, PP with 5 % and Nanoclay
with 1.5% of concentrations are defined as the optimized
Nanocomposite asphalt binders. The confirmation compressive
strength and also softening point tests showed that modification of
asphalt binders with this method, improved the compressive strength
and softening points of asphalt binders up to 55%.
Abstract: One of the important factors of cracks on the asphalt
pavements is bitumen aging that associated with the loss of volatile
components and oxidation of asphalt binder. This paper is about
effect of Styrene-Butadiene-Styrene (SBS) polymer on asphalt aging
In order to decrease asphalt aging effects. For this purpose samples of
base bitumen and SBS modified bitumen aged according to the
rolling thin film oven test (RTFOT) and pressure aging vessel (PAV),
respectively. Properties of each sample were evaluated using Fourier
Transform Infrared (FTIR) spectroscopy, n-heptane precipitation,
viscosity test, softening point test and penetration test. FT-IR
Analysis, showed lower oxidation of SBS modified bitumen than
base bitumen, after aging.
Abstract: Fatigue cracking continues to be the main challenges in
improving the performance of bituminous mixture pavements. The
purpose of this paper is to look at some aspects of the effects of fine
aggregate properties on the fatigue behaviour of hot mixture asphalt.
Two types of sand (quarry and mining sand) with two conventional
bitumen (PEN 50/60 & PEN 80/100) and four polymers modified
bitumen PMB (PM1_82, PM1_76, PM2_82 and PM2_76) were used.
Physical, chemical and mechanical tests were performed on the sands
to determine their effect when incorporated with a bituminous
mixture. According to the beam fatigue results, quarry sand that has
more angularity, rougher, higher shear strength and a higher
percentage of Aluminium oxide presented higher resistance to
fatigue. Also a PMB mixture gives better fatigue results than
conventional mixtures, this is due to the PMB having better viscosity
property than that of the conventional bitumen.