Abstract: The goal of this experiment is to evaluate the
effectiveness of different leachate pre-treatment options in terms of
COD and ammonia removal. This research focused on the evaluation
of physical-chemical methods for pre-treatment of leachate that
would be effective and rapid in order to satisfy the requirements of
the sewer discharge by-laws. The four pre-treatment options
evaluated were: air stripping, chemical coagulation, electrocoagulation
and advanced oxidation with sodium ferrate. Chemical
coagulation reported the best COD removal rate at 43%, compared to
18% for both air stripping and electro-coagulation, and 20% for
oxidation with sodium ferrate. On the other hand, air stripping was
far superior to the other treatment options in terms of ammonia
removal with 86%. Oxidation with sodium ferrate reached only 16%,
while chemical coagulation and electro-coagulation removed less
than 10%. When combined, air stripping and chemical coagulation
removed up to 50% COD and 85% ammonia.
Abstract: Acoustic properties of polymeric liquids are high
sensitive to free gas traces in the form of fine bubbles. Their presence
is typical for such liquids because of chemical reactions, small
wettability of solid boundaries, trapping of air in technological
operations, etc. Liquid temperature influences essentially its
rheological properties, which may have an impact on the bubble
pulsations and sound propagation in the system. The target of the
paper is modeling of the liquid temperature effect on single bubble
dynamics and sound dispersion and attenuation in polymeric solution
with spherical gas bubbles. The basic sources of attenuation (heat
exchange between gas in microbubbles and surrounding liquid,
rheological and acoustic losses) are taken into account. It is supposed
that in the studied temperature range the interface mass transfer has a
minor effect on bubble dynamics. The results of the study indicate
that temperature raise yields enhancement of bubble pulsations and
increase in sound attenuation in the near-resonance range and may
have a strong impact on sound dispersion in the liquid-bubble
mixture at frequencies close to the resonance frequency of bubbles.
Abstract: In this paper air quality conditions in Makkah and
Leeds are compared. These two cities have totally different climatic
conditions. Makkah climate is characterised as hot and dry (arid)
whereas that of Leeds is characterised as cold and wet (temperate).
This study uses air quality data from 2012 collected in Makkah,
Saudi Arabia and Leeds, UK. The concentrations of all pollutants,
except NO are higher in Makkah. Most notable, the concentrations of
PM10 are much higher in Makkah than in Leeds. This is probably due
to the arid nature of climatic conditions in Makkah and not solely due
to anthropogenic emission sources, otherwise like PM10 some of the
other pollutants, such as CO, NO, and SO2 would have shown much
greater difference between Leeds and Makkah. Correlation analysis is
performed between different pollutants at the same site and the same
pollutants at different sites. In Leeds the correlation between PM10
and other pollutants is significantly stronger than in Makkah. Weaker
correlation in Makkah is probably due to the fact that in Makkah
most of the gaseous pollutants are emitted by combustion processes,
whereas most of the PM10 is generated by other sources, such as
windblown dust, re-suspension, and construction activities. This is in
contrast to Leeds where all pollutants including PM10 are
predominantly emitted by combustions, such as road traffic.
Furthermore, in Leeds frequent rains wash out most of the
atmospheric particulate matter and suppress re-suspension of dust.
Temporal trends of various pollutants are compared and discussed.
This study emphasises the role of climatic conditions in managing air
quality, and hence the need for region-specific controlling strategies
according to the local climatic and meteorological conditions.
Abstract: Zn alloy and composite coatings are widely used in
buildings and structures, automobile and fasteners industries to
protect steel component from corrosion. In this paper, Zn-Ni-Al2O3
nanocomposite coatings were electrodeposited on mild steel using a
novel sol enhanced electroplating method. In this method, transparent
Al2O3 sol was added into the acidic Zn-Ni bath to produced Zn-Ni-
Al2O3 nanocomposite coatings. The effect of alumina sol on the
electrodeposition process, and coating properties was investigated
using cyclic voltammetry, XRD, ESEM and Tafel test. Results from
XRD tests showed that the structure of all coatings was single γ-
Ni5Zn21 phase. Cyclic voltammetry results showed that the
electrodeposition overpotential was lower in the presence of alumina
sol in the bath, and caused the reduction potential of Zn-Ni to shift to
more positive values. Zn-Ni-Al2O3 nanocomposite coatings produced
more uniform and compact deposits, with fine grained microstructure
when compared to Zn-Ni coatings. The corrosion resistance of Zn-Ni
coatings was improved significantly by incorporation of alumina
nanoparticles into the coatings.
Abstract: Contemporary theories of sustainability, concerning
the natural and built environment, have recently introduced an
environmental attitude towards the architectural design that, in turn,
affects the practice of conservation and reuse of the existing building
stock. This paper presents an environmentally friendly approach
towards the conservation of vernacular architecture and it is based on
the results of a research program which involved the investigation of
sustainable design elements of traditional buildings in Cyprus. The
research in question showed that Cypriot vernacular architecture gave
more emphasis on cooling rather than heating strategies. Another
notable finding of the investigation was the great importance given to
courtyards as they enhance considerably, and in various ways, the
microclimatic conditions of the immediate environment with
favorable results throughout the year. Moreover, it was shown that
the reduction in temperature fluctuation observed in the closed and
semi-open spaces, compared to the respective temperature fluctuation
of the external environment -due to the thermal inertia of the building
envelope- helps towards the achievement of more comfortable living
conditions within traditional dwellings. This paper concludes with a
proposal of a sustainable approach towards the conservation of the
existing environment and the introduction of new environmental
criteria for the conservation of traditional buildings, beyond the
aesthetic, morphological and structural ones that are generally
applied.
Abstract: Sodium formate is the chemical substance used for
food additive. Catalase is the important antioxidative enzyme in
protecting the cell from oxidative damage by reactive oxygen species
(ROS). The resultant level of oxidative stress in sodium formatetreated
lymphocytes was investigated. The sodium formate
concentrations of 0.05, 0.1, 0.2, 0.4 and 0.6 mg/mL were treated in
human lymphocytes for 12 hours. After 12 treated hours, catalase
activity change was measured in sodium formate-treated
lymphocytes. The results showed that the sodium formate
concentrations of 0.4 and 0.6 mg/mL significantly decreased catalase
activities in lymphocytes (P < 0.05). The change of catalase activity
in sodium formate-treated lymphocytes may be the oxidative damage
marker for detect sodium formate exposure in human.
Abstract: This paper presents the design, development and
evaluation of an application prototype developed to support
tuberculosis (TB) patients’ treatment adherence. The system makes
use of graphics and voice reminders as opposed to text messaging to
encourage patients to follow their medication routine. To evaluate the
effect of the prototype applications, participants were given mobile
phones on which the reminder system was installed. Thirty-eight
people, including TB health workers and patients from Zanzibar,
Tanzania, participated in the evaluation exercises. The results
indicate that the participants found the mobile image-based
application is useful to support TB treatment. All participants
understood and interpreted the intended meaning of every image
correctly. The study findings revealed that the use of a mobile visualbased
application may have potential benefit to support TB patients
(both literate and illiterate) in their treatment processes.
Abstract: In light of the technological development and its
introduction into the field of education, an online course was
designed in parallel to the 'conventional' course for teaching the
''Qualitative Research Methods''. This course aimed to characterize
learning-teaching processes in a 'Qualitative Research Methods'
course studied in two different frameworks. Moreover, its objective
was to explore the difference between the culture of a physical
learning environment and that of online learning. The research
monitored four learner groups, a total of 72 students, for two years,
two groups from the two course frameworks each year. The courses
were obligatory for M.Ed. students at an academic college of
education and were given by one female-lecturer. The research was
conducted in the qualitative method as a case study in order to attain
insights about occurrences in the actual contexts and sites in which
they transpire. The research tools were open-ended questionnaire and
reflections in the form of vignettes (meaningful short pictures) to all
students as well as an interview with the lecturer. The tools facilitated
not only triangulation but also collecting data consisting of voices
and pictures of teaching and learning. The most prominent findings
are: differences between the two courses in the change features of the
learning environment culture for the acquisition of contents and
qualitative research tools. They were manifested by teaching
methods, illustration aids, lecturer's profile and students' profile.
Abstract: Greenhouses offer us suitable conditions which can
be controlled easily for the growth of the plant and they are made by
using a covering material that allows the sun light entering into the
system. Covering material can be glass, fiber glass, plastic or another
transparent element. This study investigates the solar energy usability
rates and solar energy benefitting rates of a semi-spherical (modified
arch) type greenhouse system according to different orientations and
positions which exists under climatic conditions of Bayburt. In the
concept of this study it is tried to determine the best direction and
best sizes of a semi-spherical greenhouse to get best solar benefit
from the sun. To achieve this aim a modeling study is made by using
MATLAB. However, this modeling study is run for some determined
shapes and greenhouses it can be used for different shaped
greenhouses or buildings. The basic parameters are determined as
greenhouse azimuth angle, the rate of size of long edge to short and
seasonal solar energy gaining of greenhouse. The optimum azimuth
angles of 400, 300, 250, 200, 150, 100, 50 m2 modified arch
greenhouse are 90o, 90o, 35o, 35o, 34o, 33o and 22o while their
optimum k values (ratio of length to width) are 10, 10, 10, 10, 6, 4
and 4 respectively. Positioning the buildings in order to get more
solar heat energy in winter and less in summer brings out energy and
money savings and increases the comfort.
Abstract: Residential buildings consume significant amounts of
energy and produce large amount of emissions and waste. However,
there is a substantial potential for energy savings in this sector which
needs to be evaluated over the life cycle of residential buildings. Life
Cycle Assessment (LCA) methodology has been employed to study
the primary energy uses and associated environmental impacts of
different phases (i.e., product, construction, use, end of life, and
beyond building life) for residential buildings. Four different
alternatives of residential buildings in Vancouver (BC, Canada) with
a 50-year lifespan have been evaluated, including High Rise
Apartment (HRA), Low Rise Apartment (LRA), Single family
Attached House (SAH), and Single family Detached House (SDH).
Life cycle performance of the buildings is evaluated for embodied
energy, embodied environmental impacts, operational energy,
operational environmental impacts, total life-cycle energy, and total
life cycle environmental impacts. Estimation of operational energy
and LCA are performed using DesignBuilder software and Athena
Impact estimator software respectively.
The study results revealed that over the life span of the buildings,
the relationship between the energy use and the environmental
impacts are identical. LRA is found to be the best alternative in terms
of embodied energy use and embodied environmental impacts; while,
HRA showed the best life-cycle performance in terms of minimum
energy use and environmental impacts. Sensitivity analysis has also
been carried out to study the influence of building service lifespan
over 50, 75, and 100 years on the relative significance of embodied
energy and total life cycle energy. The life-cycle energy requirements
for SDH are found to be a significant component among the four
types of residential buildings. The overall disclose that the primary
operations of these buildings accounts for 90% of the total life cycle
energy which far outweighs minor differences in embodied effects
between the buildings.
Abstract: This paper presents results of compressive strength,
capillary water absorption, and density tests conducted on concrete
containing recycled aggregate (RCA) which is obtained from
structural waste generated by the construction industry in Turkey. In
the experiments, 0%, 15%, 30%, 45% and 60% of the normal
(natural) coarse aggregate was replaced by the recycled aggregate.
Maximum aggregate particle sizes were selected as 16 mm, 22,4 mm
and 31,5 mm; and 0,06%, 0,13% and 0,20% of air-entraining agent
(AEA) were used in mixtures. Fly ash and superplasticizer were used
as a mineral and chemical admixture, respectively. The same type
(CEM I 42.5) and constant dosage of cement were used in the study.
Water/cement ratio was kept constant as 0.53 for all mixture. It was
concluded that capillary water absorption, compressive strength, and
density of concrete decreased with increasing RCA ratio. Increasing
in maximum aggregate particle size and amount of AEA also affect
the properties of concrete significantly.
Abstract: Due to the resultant leachate from waste
decomposition in landfills has polluter potential hundred times
greater than domestic sewage, this is considered a problem related to
the depreciation of environment requiring pre-disposal treatment.In
seeking to improve this situation, this project proposes the treatment
of landfill leachate using natural fibers intercropped with advanced
oxidation processes. The selected natural fibers were palm, coconut
and banana fiber.These materials give sustainability to the project
because, besides having adsorbent capacity, are often part of waste
discarded. The study was conducted in laboratory scale.In trials, the
effluents were characterized as Chemical Oxygen Demand (COD),
Turbidity and Color. The results indicate that is technically
promising since that there were extremely oxidative conditions, the
use of certain natural fibers in the reduction of pollutants in leachate
have been obtained results of COD removals between 67.9% and
90.9%, Turbidity between 88.0% and 99.7% and Color between
67.4% and 90.4%.The expectation generated is to continue evaluating
the association of efficiency of other natural fibers with other landfill
leachate treatment processes.
Abstract: A comparison of activity and stability of the as-formed
Pt/C, Pt-Co and Pt-Pd/C electrocatalysts, prepared by a combined
approach of impregnation and seeding, was performed. According to
the activity test in a single Proton Exchange Membrane (PEM) fuel
cell, the Oxygen Reduction Reaction (ORR) activity of the Pt-M/C
electrocatalyst was slightly lower than that of Pt/C. The j0.9 V and
E10 mA/cm2 of the as-prepared electrocatalysts increased in the order of
Pt/C > Pt-Co/C > Pt-Pd/C. However, in the medium-to-high current
density region, Pt-Pd/C exhibited the best performance. With regard to
their stability in a 0.5 M H2SO4 electrolyte solution, the
electrochemical surface area decreased as the number of rounds of
repetitive potential cycling increased due to the dissolution of the
metals within the catalyst structure. For long-term measurement, Pt-
Pd/C was the most stable than the other three electrocatalysts.
Abstract: This work studies the effect of chemical composition
on the activity and selectivity of γ–alumina supported CuO/
MnO2/Cr2O3 catalysts toward deep oxidation of CO, dimethyl ether
(DME) and methanol. The catalysts were prepared by impregnation
of the support with an aqueous solution of copper nitrate, manganese
nitrate and CrO3 under different conditions. Thermal, XRD and TPR
analysis were performed. The catalytic measurements of single
compounds oxidation were carried out on continuous flow equipment
with a four-channel isothermal stainless steel reactor. Flow-line
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions that mimic closely the industrial
ones was used. The reactant and product gases were analyzed by
means of on-line gas chromatographs.
On the basis of XRD analysis it can be concluded that the active
component of the mixed Cu-Mn-Cr/γ–alumina catalysts consists of at
least six compounds – CuO, Cr2O3, MnO2, Cu1.5Mn1.5O4,
Cu1.5Cr1.5O4 and CuCr2O4, depending on the Cu/Mn/Cr molar ratio.
Chemical composition strongly influences catalytic properties, this
influence being quite variable with regards to the different processes.
The rate of CO oxidation rapidly decrease with increasing of
chromium content in the active component while for the DME was
observed the reverse trend. It was concluded that the best
compromise are the catalysts with Cu/(Mn + Cr) molar ratio 1:5 and
Mn/Cr molar ratio from 1:3 to 1:4.
Abstract: In this work new macroporous Ni electrodes modified
with Au nanoparticles for hydrogen production have been developed.
The supporting macroporous Ni electrodes have been obtained by
means of the electrodeposition at high current densities. Then, the Au
nanoparticles were synthesized and added to the electrode surface.
The electrocatalytic behaviour of the developed electrocatalysts was
studied by means of pseudo-steady-state polarization curves,
electrochemical impedance spectroscopy (EIS) and hydrogen
discharge curves. The size of the Au synthetized nanoparticles shows
a monomodal distribution, with a very sharp band between 10 and 50
nm. The characteristic parameters d10, d50 and d90 were 14, 20 and
31 nm respectively. From Tafel polarization data has been concluded
that the Au nanoparticles improve the catalytic activity of the
developed electrodes towards the HER respect to the macroporous Ni
electrodes. EIS permits to obtain the electrochemically active area by
means of the roughness factor value. All the developed electrodes
show roughness factor values in the same order of magnitude. From
the activation energy results it can be concluded that the Au
nanoparticles improve the intrinsic catalytic activity of the
macroporous Ni electrodes.
Abstract: Mustard leaves are rich in folates, vitamin A, K and
B-complex. Mustard greens are low in calories and fats and rich in
dietary fiber. They are rich in potassium, manganese, iron, copper,
calcium, magnesium and low in sodium. It is very rich in antioxidants
and Phytonutrients. For the optimization of process variables
(moisture content and mustard leave powder), the experiments were
conducted according to central composite Face Centered Composite
design of RSM. The mustard leaves powder was replaced with
composite flour (a combination of rice, chickpea and corn in the ratio
of 70:15:15). The extrudate was extruded in a twin screw extruder at
a barrel temperature of 120°C. The independent variables were
mustard leaves powder (2-10 %) and moisture content (12-20 %).
Responses analyzed were bulk density, water solubility index, water
absorption index, lateral expansion, antioxidant activity, total
phenolic content, and overall acceptability. The optimum conditions
obtained were 7.19 g mustard leaves powder in 100g premix having
16.8% moisture content (w.b).
Abstract: This initial study is concerned with the behavior of
engineering students in Kuwait University which became a concern
due to the global issues of education in all levels. A survey has been
conducted to identify academic and societal issues affecting the
engineering student performance. The study is drawing major
conclusions with regard to private tutoring and the online availability
of textbooks’ solution manuals.
Abstract: Mobil Producing Nigeria Unlimited (MPNU), a
subsidiary of ExxonMobil and the highest crude oil & condensate
producer in Nigeria has its operational base and an oil terminal, the
Qua Iboe terminal (QIT) located at Ibeno, Nigeria. Other oil
companies like Network Exploration and Production Nigeria Ltd,
Frontier Oil Ltd; Shell Petroleum Development Company Ltd; Elf
Petroleum Nigeria Ltd and Nigerian Agip Energy, a subsidiary of the
Italian ENI E&P operate onshore, on the continental shelf and in deep
offshore of the Atlantic Ocean, respectively with the coastal waters of
Ibeno, Nigeria as the nearest shoreline. This study was designed to
delineate the oil-polluted sites in Ibeno, Nigeria using
microbiological and physico-chemical characterization of soils,
sediments and ground and surface water samples from the study area.
Results obtained revealed that there have been significant recent
hydrocarbon inputs into this environment as observed from the high
counts of hydrocarbonoclastic microorganisms in excess of 1% at all
the stations sampled. Moreover, high concentrations of THC, BTEX
and heavy metals contents in all the samples analyzed corroborate the
high recent crude oil input into the study area. The results also
showed that the pollution of the different environmental media
sampled were of varying degrees, following the trend: ground water
> surface water > sediments > soils.
Abstract: In recent years, multi-antenna techniques are being considered as a potential solution to increase the flow of future wireless communication systems. The objective of this article is to study the emission and reception system MIMO (Multiple Input Multiple Output), and present the different reception decoding techniques. First we will present the least complex technical, linear receivers such as the zero forcing equalizer (ZF) and minimum mean squared error (MMSE). Then a nonlinear technique called ordered successive cancellation of interferences (OSIC) and the optimal detector based on the maximum likelihood criterion (ML), finally, we simulate the associated decoding algorithms for MIMO system such as ZF, MMSE, OSIC and ML, thus a comparison of performance of these algorithms in MIMO context.
Abstract: Rice bran is normally used as a raw material for rice
bran oil production or sold as feed with a low price. Conventionally,
the protein in defatted rice bran was extracted using alkaline
extraction and acid precipitation, which involves in chemical usage
and lowering some nutritious component. This study was conducted
in order to extract of rice bran protein concentrate (RBPC) from
defatted rice bran using enzymes and employing polysaccharides in a
precipitating step. The properties of RBPC obtained will be compared
to those of a control sample extracted using a conventional method.
The results showed that extraction of protein from rice bran using
enzymes exhibited the higher protein recovery compared to that
extraction with alkaline. The extraction conditions using alcalase 2%
(v/w) at 50 C, pH 9.5 gave the highest protein (2.44%) and yield
(32.09%) in extracted solution compared to other enzymes. Rice bran
protein concentrate powder prepared by a precipitation step using
alginate (protein in solution: alginate 1:0.016) exhibited the highest
protein (27.55%) and yield (6.84%). Precipitation using alginate was
better than that of acid. RBPC extracted with alkaline (ALK) or
enzyme alcalase (ALC), then precipitated with alginate (AL)
(samples RBP-ALK-AL and RBP-ALC-AL) yielded the precipitation
rate of 75% and 91.30%, respectively. Therefore, protein
precipitation using alginate was then selected. Amino acid profile of
control sample, and sample precipitated with alginate, as compared to
casein and soy protein isolated, showed that control sample showed
the highest content among all sample. Functional property study of
RBP showed that the highest nitrogen solubility occurred in pH 8-10.
There was no statically significant between emulsion capacity and
emulsion stability of control and sample precipitated by alginate.
However, control sample showed a higher of foaming capacity and
foaming stability compared to those of sample precipitated with
alginate. The finding was successful in terms of minimizing
chemicals used in extraction and precipitation steps in preparation of
rice bran protein concentrate. This research involves in a production
of value-added product in which the double amount of protein (28%)
compared to original amount (14%) contained in rice bran could be
beneficial in terms of adding to food products e.g. healthy drink with
high protein and fiber. In addition, the basic knowledge of functional
property of rice bran protein concentrate was obtained, which can be
used to appropriately select the application of this value-added
product from rice bran.