Abstract: In this study, the anaerobic treatability of chicken manure diluted with tap water (with an influent feed ratio of 1 kg of fresh chicken manure to 6 liter of tap water) was investigated in a lab-scale anaerobic sludge bed (ASB) reactor inoculated with the granular sludge already adapted to chicken manure. The raw waste digested in this study was the manure from laying-hens having average total solids (TS) of about 30% with ca. 60% volatile content. The ASB reactor was fed semi-continuously at ambient operating temperature range (17-23◦C) at a HRT of 13 and 26 days for about 6 months, respectively. The respective average total and soluble chemical oxygen demand (COD) removals were ca. 90% and 75%, whereas average biomethane production rate was calculated ca. 180 lt per kg of CODremoved from the ASB reactor at an average HRT of 13 days. Moreover, total suspended solids (TSS) and volatile suspended solids (VSS) in the influent were reduced more than 97%. Hence, high removals of the organic compounds with respective biogas production made anaerobic stabilization of the diluted chicken manure by ASB reactor at ambient operating temperatures viable. By this way, external heating up to 35◦C (i.e. anaerobic processes have been traditionally operated at mesophilic conditions) could be avoided in the scope of this study.
Abstract: Nanocomposites of isotactic polypropylene (iPP) and
date wood fiber were prepared after modification of the host matrix
by reactive extrusion grafting of maleic anhydride. Chemical and
mechanical treatment of date wood flour (WF) was conducted to
obtain nanocrystalline cellulose. Layered silicates (clay) were
partially intercalated with date wood fiber, and the modified layered
silicate was used as filler in the PP matrix via a melt-blending
process. The tensile strength of composites prepared from wood fiber
modified clay was greater than that of the iPP-clay and iPP-WF
composites at a 6% filler concentration, whereas deterioration of
mechanical properties was observed when clay and WF were used
alone for reinforcement. The dispersion of the filler in the matrix
significantly decreased after clay modification with cellulose at
higher concentrations, as shown by X-ray diffraction (XRD) data.
Abstract: Yogurt capsule was made by mixing 14% w/v of
reconstitution of skim milk with 2% FOS. The mixture was
fermented by commercial yogurt starter comprising Lactobacillus
bulgaricus and Streptococcus thermophilus. These yogurts were
made as yogurt powder by freeze-dried. Yogurt powder was put into
capsule then stored for 28 days at 4oc. 8ml of commercial yogurt was
found to be the most suitable inoculum size in yogurt production.
After freeze-dried, the viability of L. bulgaricus and S. thermophilus
reduced from 109 to 107 cfu/g. The precence of sucrose cannot help to
protect cell from ice crystal formation in freeze-dried process, high
(20%) sucrose reduced L. bulgaricus and S. thermophilus growth
during fermentation of yogurt. The addition of FOS had reduced
slowly the viability of both L. bulgaricus and S. thermophilus similar
to control (without FOS) during 28 days of capsule storage. The
viable cell exhibited satisfactory viability level in capsule storage
(6.7x106cfu/g) during 21 days at 4oC.
Abstract: This study attempts to understand the effect of different UV irradiation methods on the intercalation of LDPE/MMT nanocomposites, and its molecular behavior at certain isothermal crystallization temperature. Three different methods of UV exposure were employed using single composition of LDPE/MMT nanocomposites. All samples were annealed for 5 hours at a crystallization temperature of 100oC. The crystallization temperature was chosen to be at large supercooling temperature to ensure quick and complete crystallization. The raw material of LDPE consisted of two stable monoclinic and orthorhombic phases according to XRD results. The thermal behavior of both phases acted differently when UV exposure method was changed. The monoclinic phase was more dependent on the method used compared to the orthorhombic phase. The intercalation of clay, as well as, the non-isothermal crystallization temperature, has also shown a clear dependency on the type of UV exposure. A third phase that is thermally less stable was also observed. Its respond to UV irradiation was greater since it contains low molecular weight entities which make it more vulnerable to any UV exposure.
Abstract: E-glass-epoxy laminated composites having different fiber volume fractions (40, 50, 60 and 70) were fabricated with and without the addition of nanoclay. Flexural strength and tensile strength of the composite laminates were determined. It was observed that, with increasing the fiber volume fraction (Vf) of fiber from 40 to 60, the ability of nanoclay to enhance the tensile and flexural strength of E-glass-epoxy composites decreases significantly. At 70Vf, the tensile and flexural strength of the nanoclay reinforced E-glass-epoxy were found to be lowest when compared to the E-glass-epoxy composite made without the addition of nanoclay. Based on the obtained data and microstructure of the tested samples, plausible mechanism for the observed trends has been proposed. The enhanced mechanical properties for nanoclay reinforced E-glass-epoxy composites for 40-60 Vf, due to higher interface toughness coupled with strong interfilament bonding may have ensured the homogeneous load distribution across all the glass fibers. Results in the decrease in mechanical properties at 70Vf, may be due to the inability of the matrix to bind the nanoclay and glass-fibers.
Abstract: Introduction: Prostate cancer is one of the most common causes of morbidity and mortality in men in developed countries. Cancer Stem Cells (CSCs) could be responsible for the progression and relapse of cancer. Therefore, CSCs markers could provide a prognostic strategy for human malignancies. Aldehyde dehydrogenase 1A1 (ALDH1A1) activity has been shown to be associated with tumorigenesis and proposed to represent a functional marker for tumor initiating cells in various tumor types including prostate cancer. Material & Methods: We analyzed the immunohistochemical expression of ALDH1A1 in benign prostatic hyperplasia (BPH), prostatic intraepithelial neoplasia (PIN) and prostatic adenocarcinoma and assessed their significant correlations in 50 TURP sections. They were microscopically interpreted and the results were correlated with histopathological types and tumor grade. Results: In different prostatic histopathological lesions we found that ALDH1A1 expression was low in BPH (13.3%) and PIN (6.7%) and then its expression increased with prostatic adenocarcinoma (40%), and this was statistically highly significant (P value = 0.02). However, in different grades of prostatic adenocarcinoma we found that the higher the Gleason grade the higher the expression for ALDH1A1 and this was statistically significant (P value = 0.02). We compared the expression of ALDH1A1 in PIN and prostatic adenocarcinoma. ALDH1A1 expression was decreased in PIN and highly expressed in prostatic adenocarcinoma and this was statistically significant (P value = 0.04). Conclusion: Increasing ALDH1A1 expression is correlated with aggressive behavior of the tumor. Immunohistochemical expression of ALDH1A1 might provide a potential approach to study tumorigenesis and progression of primary prostate carcinoma.
Abstract: The solid solutions of lanthanum niobates substituted by yttrium, bismuth and tungsten were synthesized. The structure of the solid solutions is either LaNbO4-based monoclinic or BiNbO4-based triclinic. The series where niobium is substituted by tungsten on B site reveals phase-modulated structure. The values of cell parameters decrease with increasing the dopant concentration for all samples except the tungsten series although the latter show higher total conductivity.
Abstract: The combination of multi–walled carbon nanotubes
(MWCNTs) with polymers offers an attractive route to reinforce the
macromolecular compounds as well as the introduction of new
properties based on morphological modifications or electronic
interactions between the two constituents. As they are only a few
nanometers in dimension, it offers ultra-large interfacial area per
volume between the nano-element and polymer matrix. Nevertheless,
the use of MWCNTs as a rough material in different applications has
been largely limited by their poor processability, insolubility, and
infusibility. Studies concerning the nanofiller reinforced polymer
composites are justified in an attempt to overcome these limitations.
This work presents one preliminary study of MWCNTs dispersion
into the PVDF homopolymer. For preparation, the composite
components were diluted in n,n-dimethylacetamide (DMAc) with
mechanical agitation assistance. After complete dilution, followed by
slow evaporation of the solvent at 60°C, the samples were dried.
Films of about 80 μm were obtained. FTIR and UV-Vis
spectroscopic techniques were used to characterize the
nanocomposites. The appearance of absorption bands in the FTIR
spectra of nanofilled samples, when compared to the spectrum of
pristine PVDF samples, are discussed and compared with the UV-Vis
measurements.
Abstract: The maintenance of work rolls in hot strip processing
has been lengthy and difficult tasks for hot strip manufacturer
because heavy work rolls have to be taken out of the production line,
which could take hours. One way to increase the time between
maintenance is to improve the effectiveness of the work roll cooling
system such that the wear and tear more slowly occurs, while the
operation cost is kept low. Therefore, this study aims to improve the
work roll cooling system by providing the manufacturer the
relationship between the work-roll temperature reduced by cooling
and the water flow that can help manufacturer determining the more
effective water flow of the cooling system. The relationship is found
using simulation with a systematic process adjustment so that the
satisfying quality of product is achieved. Results suggest that the
manufacturer could reduce the water flow by 9% with roughly the
same performance. With the same process adjustment, the feasibility
of finishing-mill-stand reduction is also investigated. Results suggest
its possibility.
Abstract: Motion response of floating structures is of great
concern in marine engineering. Nonlinearity is an inherent property
of any floating bodies subjected to irregular waves. These floating
structures are continuously subjected to environmental loadings from
wave, current, wind etc. This can result in undesirable motions of the
vessel which may challenge the operability. For a floating body to
remain in its position, it should be able to induce a restoring force
when displaced. Mooring is provided to enable this restoring force.
This paper discusses the hydrodynamic performance and motion
characteristics of an 8 point spread mooring system applied to a pipe
laying barge operating in the West African sea. The modelling of the
barge is done using a computer aided-design (CAD) software
RHINOCEROS. Irregular waves are generated using a suitable wave
spectrum. Both frequency domain and time domain analysis is done.
Numerical simulations based on potential theory are carried out to
find the responses and hydrodynamic performance of the barge in
both free floating as well as moored conditions. Initially, potential
flow frequency domain analysis is done to obtain the Response
Amplitude Operator (RAO) which gives an idea about the structural
motion in free floating state. RAOs for different wave headings are
analyzed. In the following step, a time domain analysis is carried out
to obtain the responses of the structure in the moored condition. In
this study, wave induced motions are only taken into consideration.
Wind and current loads are ruled out and shall be included in further
studies. For the current study, 2000 seconds simulation is taken. The
results represent wave induced motion responses, mooring line
tensions and identify critical mooring lines.
Abstract: Nanofibers are defined as fibers with diameters less
than 100 nanometers. In this study, behaviours of activated carbon
nanofiber (ACNF), carbon nanofiber (CNF), polyacrylonitrile/ carbon
nanotube (PAN/CNT), polyvinyl alcohol/nanosilver (PVA/Ag) in
proton exchange membrane (PEM) fuel cells are investigated
experimentally. This material was used as gas diffusion layer (GDL)
in PEM fuel cells. In this study, the electrical conductivities of
nanofiber and nanofiber/nanoparticles have been studied to
understand their effects on PEM fuel cell performance. According to
the experimental results, the maximum electrical conductivity
performance of the fuel cell with nanofiber was found to be at
PVA/Ag (at UConn condition). The electrical conductivities of CNF,
ACNF, PAN/CNT are lower for PEM. The resistance of cell with
PVA/Ag is lower than the resistance of cell with PAN/CNT, ACNF,
CNF.
Abstract: This work aims to investigate the structure–property
relationship in ternary nanocomposites consisting of polypropylene
as the matrix, polyamide 66 as the minor phase and treated nanoclay
DELLITE 67G as the reinforcement. All PP/PA66/Nanoclay systems
with polypropylene grafted maleic anhydride PP-g-MAH as a
compatibilizer were prepared via melt compounding and
characterized in terms of nanoclay content. Morphological structure
was investigated by scanning electron microscopy. The rheological
behavior of the nanocomposites was determined by various methods,
viz melt flow index (MFI) and parallel plate rheological
measurements. The PP/PP-g-MAH/PA66 nanocomposites showed a homogeneous
morphology supporting the compatibility improvement between PP,
PA66, and nanoclay. SEM results revealed the formation of
nanocomposites as the nanoclay was intercalated and exfoliated. In
the ternary nanocomposites, the rheological behavior showed that, the
complex viscosity is increased with increasing the nanoclay. The results showed that the use of nanoclay affects the variations
of storage modulus (G′), loss modulus (G″) and the melt elasticity.
Abstract: This paper presents the effects of mixing procedures
on mechanical properties of flyash-based geopolymer matrices
containing nanosilica (NS) at 0.5%, 1.0%, 2.0%, and 3.0% by weight.
Comparison is made with conventional mechanical dry-mixing of NS
with flyash and wet-mixing of NS in alkaline solutions. Physical and
mechanical properties are investigated using X-Ray Diffraction
(XRD) and Scanning Electron Microscope (SEM). Results show that
generally the addition of NS particles enhanced the microstructure
and improved flexural and compressive strengths of geopolymer
nanocomposites. However, samples, prepared using dry-mixing
approach, demonstrate better physical and mechanical properties
comparing to wet-mixing samples.
Abstract: Low density polyethylene (LDPE) nanocomposites
with 3, 5 and 7 wt. % cobalt ferrite (CoFe2O4) nanopowder fabricated
with extrusion mixing and followed up by hot press to reach compact
samples. The transmission/reflection measurements were carried out
with a network analyzer in the frequency range of 8-12 GHz. By
increasing the percent of CoFe2O4 nanopowder, reflection loss (S11)
increases, while transferring loss (S21) decreases. Reflectivity (R)
calculations made using S11 and S21. Increase in percent of CoFe2O4
nanopowder up to 7 wt. % in composite leaded to higher reflectivity
amount, and revealed that increasing the percent of CoFe2O4
nanopowder up to 7 wt. % leads to further microwave absorption in
8-12 GHz range.
Abstract: Inspired by the Formula-1 competition, IMechE
(Institute of Mechanical Engineers) and Formula SAE (Society of
Mechanical Engineers) organize annual competitions for University
and College students worldwide to compete with a single-seat racecar
they have designed and built. Design of the chassis or the frame is a
key component of the competition because the weight and stiffness
properties are directly related with the performance of the car and the
safety of the driver. In addition, a reduced weight of the chassis has
direct influence on the design of other components in the car. Among
others, it improves the power to weight ratio and the aerodynamic
performance. As the power output of the engine or the battery
installed in the car is limited to 80 kW, increasing the power to
weight ratio demands reduction of the weight of the chassis, which
represents the major part of the weight of the car. In order to reduce
the weight of the car, ION Racing team from University of
Stavanger, Norway, opted for a monocoque design. To ensure
fulfilment of the competition requirements of the chassis, the
monocoque design should provide sufficient torsional stiffness and
absorb the impact energy in case of possible collision. The study reported in this article is based on the requirements for
Formula Student competition. As part of this study, diverse
mechanical tests were conducted to determine the mechanical
properties and performances of the monocoque design. Upon a
comprehensive theoretical study of the mechanical properties of
sandwich composite materials and the requirements of monocoque
design in the competition rules, diverse tests were conducted
including 3-point bending test, perimeter shear test and test for
absorbed energy. The test panels were homemade and prepared with
equivalent size of the side impact zone of the monocoque, i.e. 275
mm x 500 mm, so that the obtained results from the tests can be
representative. Different layups of the test panels with identical core
material and the same number of layers of carbon fibre were tested
and compared. Influence of the core material thickness was also
studied. Furthermore, analytical calculations and numerical analysis
were conducted to check compliance to the stated rules for Structural
Equivalency with steel grade SAE/AISI 1010. The test results were
also compared with calculated results with respect to bending and
torsional stiffness, energy absorption, buckling, etc. The obtained results demonstrate that the material composition
and strength of the composite material selected for the monocoque
design has equivalent structural properties as a welded frame and thus
comply with the competition requirements. The developed analytical
calculation algorithms and relations will be useful for future
monocoque designs with different lay-ups and compositions.
Abstract: Strong anthropogenic impact has uncontrolled
consequences on the nature of the soil. Hence, up-to-date sustainable
methods of soil state improvement are essential. Investigators provide
the evidence that biochar can positively effects physical, chemical,
and biological soil properties and the abundance of mycorrhizal fungi
which are in the focus of this study. The main aim of the present
investigation is to demonstrate the effect of two types of plant growth
promoting bacteria (PGPB) inoculums along with the beech wood
biochar and mineral N additives on mycorrhizal colonization.
Experiment has been set up in laboratory conditions with containers
filled with arable soil from the protection zone of the main water
source “Brezova nad Svitavou”. Lactuca sativa (lettuce) has been
selected as a model plant. Based on the obtained data, it can be
concluded that mycorrhizal colonization increased as the result of
combined influence of biochar and PGPB inoculums amendment. In
addition, correlation analyses showed that the numbers of main
groups of cultivated bacteria were dependent on the degree of
mycorrhizal colonization.
Abstract: Geopolymer composites reinforced with flax fabrics
and nanoclay are fabricated and studied for physical and mechanical
properties using X-Ray Diffraction (XRD), Fourier Transform
Infrared Spectroscopy (FTIR), and Scanning Electron Microscope
(SEM). Nanoclay platelets at a weight of 1.0%, 2.0%, and 3.0% were
added to geopolymer pastes. Nanoclay at 2.0 wt.% was found to
improve density and decrease porosity while improving flexural
strength and post-peak toughness. A microstructural analysis
indicated that nanoclay behaves as filler and as an activator
supporting geopolymeric reaction while producing a higher content
geopolymer gel improving the microstructure of binders. The process
enhances adhesion between the geopolymer matrix and flax fibres.
Abstract: This study evaluated the acute toxicity and tissue
distribution of intravenously administered gold nanoparticles
(AuNPs) in male rabbits. Rabbits were exposed to single dose of
AuNPs (300 μg/ kg). Toxic effects were assessed via general
behavior, hematological parameters, serum biochemical parameters,
and histopathological examination of various rabbits’ organs.
Inductively coupled plasma–mass spectrometry (ICP-MS) was used
to determine gold concentrations in tissue samples collected at
predetermined time intervals. After one week, AuNPs exerted no
obvious acute toxicity in rabbits. However, inflammatory reactions
were observed in liver, lungs and kidneys accompanied with mild
absolute neutrophilia and significant monocytosis. The highest gold
levels were found in the spleen and liver followed by lungs, and
kidneys. These results indicated that AuNPs could be distributed
extensively to various tissues in the body, but primarily in the spleen
and liver.
Abstract: Mechanical behavior of 6082T6 aluminum is
investigated at different temperatures. The strain rate sensitivity is
investigated at different temperatures on the grain size variants. The
sensitivity of the measured grain size variants on 3-D grain is
discussed. It is shown that the strain rate sensitivities are negative for
the grain size variants during the deformation of nanostructured
materials. It is also observed that the strain rate sensitivities vary in
different ways with the equivalent radius, semi minor axis radius,
semi major axis radius and major axis radius. From the obtained
results, it is shown that the variation of strain rate sensitivity with
temperature suggests that the strain rate sensitivity at the low and the
high temperature ends of the 6082T6 aluminum range is different.
The obtained results revealed transition at different temperature from
negative strain rate sensitivity as temperature increased on the grain
size variants.
Abstract: Biochar can be produced from the waste matter and its
application has been associated with returning of carbon in large
amounts into the soil. The impacts of this material on physical and
chemical properties of soil have been described. The biggest part of
the research work is dedicated to the hypothesis of this material’s
toxic effects on the soil life regarding its effect on the soil biological
component. At present, it has been worked on methods which could
eliminate these undesirable properties of biochar. One of the
possibilities is to mix biochar with organic material, such as compost,
or focusing on the natural processes acceleration in the soil. In the
experiment has been used as the addition of compost as well as the
elimination of toxic substances by promoting microbial activity in
aerated water environment. Biochar was aerated for 7 days in a
container with a volume of 20 l. This way modified biochar had six
times higher biomass production and reduce mineral nitrogen
leaching. Better results have been achieved by mixing biochar with
compost.