Abstract: Landfill gas, particularly methane is one of the
greenhouse gases which contributes to global warming. This paper presents the findings of a study on methane gas production from
simulated landfill reactor under saturated conditions. A reactor was constructed to represent a landfill cell of 2.5 m thickness on sandy
soil. The reactor was 0.2 m in diameter and 4 m in height. One meter of sand and pebble layer was packed at the bottom of the reactor
followed by 2.5 m of solid waste layer and 0.4 m of sand layer as the cover soil. Degradation of waste in the solid waste layer was at
acidification stage as indicated by the leachate quality with COD as
high as 55,511 mg/L and pH as low as 5.1. However, methanogenic
environment was established at the bottom sand layer after one year of operation indicated by pH of 7.2 and methane gas generation.
Leachate degradation took place as the leachate moved through the
sand layer at an infiltration of rate 0.7 cm/day. This resulted in landfill gas production of 77 mL/day/kg containing 55 to 65% methane. The application of sand layer contributed to the gas
production from landfill by an in-situ degradation of leachate in the
sand at the bottom of the landfill.
Abstract: The agriculture lignocellulosic by-products are receiving increased attention, namely in the search for filter materials that retain contaminants from water. These by-products, specifically almond and hazelnut shells are abundant in Portugal once almond and hazelnuts production is a local important activity. Hazelnut and almond shells have as main constituents lignin, cellulose and hemicelluloses, water soluble extractives and tannins. Along the adsorption of heavy metals from contaminated waters, water soluble compounds can leach from shells and have a negative impact in the environment. Usually, the chemical characterization of treated water by itself may not show environmental impact caused by the discharges when parameters obey to legal quality standards for water. Only biological systems can detect the toxic effects of the water constituents. Therefore, the evaluation of toxicity by biological tests is very important when deciding the suitability for safe water discharge or for irrigation applications.
The main purpose of the present work was to assess the potential impacts of waters after been treated for heavy metal removal by hazelnut and almond shells adsorption systems, with short term acute toxicity tests.
To conduct the study, water at pH 6 with 25 mg.L-1 of lead, was treated with 10 g of shell per litre of wastewater, for 24 hours. This procedure was followed for each bark. Afterwards the water was collected for toxicological assays; namely bacterial resistance, seed germination, Lemna minor L. test and plant grow. The effect in isolated bacteria strains was determined by disc diffusion method and the germination index of seed was evaluated using lettuce, with temperature and humidity germination control for 7 days. For aquatic higher organism, Lemnas were used with 4 days contact time with shell solutions, in controlled light and temperature. For terrestrial higher plants, biomass production was evaluated after 14 days of tomato germination had occurred in soil, with controlled humidity, light and temperature.
Toxicity tests of water treated with shells revealed in some extent effects in the tested organisms, with the test assays showing a close behaviour as the control, leading to the conclusion that its further utilization may not be considered to create a serious risk to the environment.
Abstract: This work presents the experimental results obtained
at a pilot plant which works with a slow, wet and catalytic pyrolysis
process of dry fowl manure. This kind of process mainly consists in
the cracking of the organic matrix and in the following reaction of
carbon with water, which is either already contained in the organic
feed or added, to produce carbon monoxide and hydrogen. Reactions
are conducted in a rotating reactor maintained at a temperature of
500°C; the required amount of water is about 30% of the dry organic
feed. This operation yields a gas containing about 59% (on a volume
basis) of hydrogen, 17% of carbon monoxide and other products such
as light hydrocarbons (methane, ethane, propane) and carbon
monoxide in lesser amounts. The gas coming from the reactor can be
used to produce not only electricity, through internal combustion
engines, but also heat, through direct combustion in industrial
boilers. Furthermore, as the produced gas is devoid of both solid
particles and pollutant species (such as dioxins and furans), the
process (in this case applied to fowl manure) can be considered as an
optimal way for the disposal and the contemporary energetic
valorization of organic materials, in such a way that is not damaging
to the environment.
Abstract: Soft clays are defined as cohesive soil whose water
content is higher than its liquid limits. Thus, soil-cement mixing is
adopted to improve the ground conditions by enhancing the strength
and deformation characteristics of the soft clays. For the above
mentioned reasons, a series of laboratory tests were carried out to
study some fundamental mechanical properties of cement stabilized
soft clay. The test specimens were prepared by varying the portion of
ordinary Portland cement to the soft clay sample retrieved from the
test site of RECESS (Research Centre for Soft Soil). Comparisons
were made for both homogeneous and columnar system specimens
by relating the effects of cement stabilized clay of for 0, 5 and 10 %
cement and curing for 3, 28 and 56 days. The mechanical properties
examined included one-dimensional compressibility and undrained
shear strength. For the mechanical properties, both homogeneous and
columnar system specimens were prepared to examine the effect of
different cement contents and curing periods on the stabilized soil.
The one-dimensional compressibility test was conducted using an
oedometer, while a direct shear box was used for measuring the
undrained shear strength. The higher the value of cement content, the
greater is the enhancement of the yield stress and the decrease of
compression index. The value of cement content in a specimen is a
more active parameter than the curing period.
Abstract: The objective of this research was to identify the
vegetation-soil relationships in Nodushan arid rangelands of Yazd. 5
sites were selected for measuring the cover of plant species and soil
attributes. Soil samples were taken in 0-10 and 10-80 cm layers. The
species studied were Salsola tomentosa, Salsola arbuscula, Peganum
harmala, Zygophylum eurypterum and Eurotia ceratoides. Canonical
correspondence analysis (CCA) was used to analyze the data. Based
on the CCA results, 74.9 % of vegetation-soil variation was explained
by axis 1-3. Axis 1, 2 and 3 accounted for 27.2%, 24.9 % and 22.8%
of variance respectively. Correlation between axis 1, 2, 3 and speciesedaphic
variables were 0.995, 0.989, 0.981 respectively. Soil texture,
lime, salinity and organic matter significantly influenced the
distribution of these plant species. Determination of soil-vegetation
relationships will be useful for managing and improving rangelands
in arid and semi arid environments.
Abstract: There are many sources trough which the soil get
enriched and contaminated with REEs. The determination of REEs in
environmental samples has been limited because of the lack of
sensitive analytical techniques. Soil samples were collected from
four sites including open cast coal mine, natural coal burning, coal
washery and control in the coal field located in Dhanbad, India.
Total concentrations of rare earth elements (REEs) were determined
using the inductively coupled plasma atomic absorption spectrometry
in order to assess enrichment status in the coal field. Results showed
that the mean concentrations of La, Pr, Eu, Tb, Ho, and Tm in open
cast mine and natural coal burning sites were elevated compared to
the reference concentrations, while Ce, Nd, Sm, and Gd were
elevated in coal washery site. When compared to reference soil,
heavy REEs (HREEs) were enriched in open cast mines and natural
coal burning affected soils, however, the HREEs were depleted in the
coal washery sites. But, the Chondrite-normalization diagram showed
significant enrichment for light REEs (LREEs) in all the soils. High
concentration of Pr, Eu, Tb, Ho, Tm, and Lu in coal mining and coal
burning sites may pose human health risks. Factor analysis showed
that distribution and relative abundance of REEs of the coal washery
site is comparable with the control. Eventually washing or cleaning
of coal could significantly decrease the emission of REEs from coal
into the environment.
Abstract: In this experimental investigation shake table tests
were conducted on two reduced models that represent normal single
room building constructed by Compressed Stabilized Earth Block
(CSEB) from locally available soil. One model was constructed with
earthquake resisting features (EQRF) having sill band, lintel band and
vertical bands to control the building vibration and another one was
without Earthquake Resisting Features. To examine the seismic
capacity of the models particularly when it is subjected to long-period
ground motion by large amplitude by many cycles of repeated
loading, the test specimen was shaken repeatedly until the failure.
The test results from Hi-end Data Acquisition system show that
model with EQRF behave better than without EQRF. This modified
masonry model with new material combined with new bands is used
to improve the behavior of masonry building.
Abstract: Nanoemulsions are a class of emulsions with a droplet
size in the range of 50–500 nm and have attracted a great deal of
attention in recent years because it is unique characteristics. The
physicochemical properties of nanoemulsion suggests that it can be
successfully used to recover the residual oil which is trapped in the
fine pore of reservoir rock by capillary forces after primary and
secondary recovery. Oil-in-water nanoemulsion which can be formed
by high-energy emulsification techniques using specific surfactants
can reduce oil-water interfacial tension (IFT) by 3-4 orders of
magnitude. The present work is aimed on characterization of oil-inwater
nanoemulsion in terms of its phase behavior, morphological
studies; interfacial energy; ability to reduce the interfacial tension and
understanding the mechanisms of mobilization and displacement of
entrapped oil blobs by lowering interfacial tension both at the
macroscopic and microscopic level. In order to investigate the
efficiency of oil-water nanoemulsion in enhanced oil recovery
(EOR), experiments were performed to characterize the emulsion in
terms of their physicochemical properties and size distribution of the
dispersed oil droplet in water phase. Synthetic mineral oil and a series
of surfactants were used to prepare oil-in-water emulsions.
Characterization of emulsion shows that it follows pseudo-plastic
behaviour and drop size of dispersed oil phase follows lognormal
distribution. Flooding experiments were also carried out in a
sandpack system to evaluate the effectiveness of the nanoemulsion as
displacing fluid for enhanced oil recovery. Substantial additional
recoveries (more than 25% of original oil in place) over conventional
water flooding were obtained in the present investigation.
Abstract: We measured the major and trace element contents
and Rb-Sr isotopic compositions of 12 tektites from the Maoming
area, Guandong province (south China). All the samples studied are
splash-form tektites which show pitted or grooved surfaces with
schlieren structures on some surfaces. The trace element ratios Ba/Rb
(avg. 4.33), Th/Sm (avg. 2.31), Sm/Sc (avg. 0.44), Th/Sc (avg. 1.01) ,
La/Sc (avg. 2.86), Th/U (avg. 7.47), Zr/Hf (avg. 46.01) and the rare
earth elements (REE) contents of tektites of this study are similar to the
average upper continental crust. From the chemical composition, it is
suggested that tektites in this study are derived from similar parental
terrestrial sedimentary deposit which may be related to post-Archean
upper crustal rocks. The tektites from the Maoming area have high
positive εSr(0) values-ranging from 176.9~190.5 which indicate that
the parental material for these tektites have similar Sr isotopic
compositions to old terrestrial sedimentary rocks and they were not
dominantly derived from recent young sediments (such as soil or
loess). The Sr isotopic data obtained by the present study support the
conclusion proposed by Blum et al. (1992)[1] that the depositional age
of sedimentary target materials is close to 170Ma (Jurassic). Mixing
calculations based on the model proposed by Ho and Chen (1996)[2]
for various amounts and combinations of target rocks indicate that the
best fit for tektites from the Maoming area is a mixture of 40% shale,
30% greywacke, 30% quartzite.
Abstract: National Biodiversity Database System (NBIDS) has
been developed for collecting Thai biodiversity data. The goal of this
project is to provide advanced tools for querying, analyzing,
modeling, and visualizing patterns of species distribution for
researchers and scientists. NBIDS data record two types of datasets:
biodiversity data and environmental data. Biodiversity data are
specie presence data and species status. The attributes of biodiversity
data can be further classified into two groups: universal and projectspecific
attributes. Universal attributes are attributes that are common
to all of the records, e.g. X/Y coordinates, year, and collector name.
Project-specific attributes are attributes that are unique to one or a
few projects, e.g., flowering stage. Environmental data include
atmospheric data, hydrology data, soil data, and land cover data
collecting by using GLOBE protocols. We have developed webbased
tools for data entry. Google Earth KML and ArcGIS were used
as tools for map visualization. webMathematica was used for simple
data visualization and also for advanced data analysis and
visualization, e.g., spatial interpolation, and statistical analysis.
NBIDS will be used by park rangers at Khao Nan National Park, and
researchers.
Abstract: This paper explores the plant maintenance management system that has been used by giant oil and gas company in Malaysia. The system also called as PMMS used to manage the upstream operations for more than 100 plants of the case study company. Moreover, from the observations, focus group discussion with PMMS personnel and application through simulation (SAP R/3), the paper reviews the step-by-step approach and the elements that required for the PMMS. The findings show that the PMMS integrates the overall business strategy in upstream operations that consist of asset management, work management and performance management. In addition, PMMS roles are to help operations personnel organize and plan their daily activities, to improve productivity and reduce equipment downtime and to help operations management analyze the facilities and create performance, and to provide and maintain the operational effectiveness of the facilities.
Abstract: This work involved the use of phytoremediation to
remediate an aged soil contaminated with polychlorinated biphenyls
(PCBs). At microcosm scale, tests were prepared using soil samples
that have been collected in an industrial area with a total PCBs
concentration of about 250 μg kg-1. Medicago sativa and Lolium
italicum were the species selected in this study that is used as
“feasibility test" for full scale remediation. The experiment was
carried out with the addition of a mixture of randomly methylatedbeta-
cyclodextrins (RAMEB). At the end of the experiment analysis
of soil samples showed that in general the presence of plants has led
to a higher degradation of most congeners with respect to not
vegetated soil. The two plant species efficiencies were comparable
and improved by RAMEB addition with a final reduction of total
PCBs near to 50%. With increasing the chlorination of the congeners
the removal percentage of PCBs progressively decreased.
Abstract: Due to increased number of terrorist attacks in recent years, loads induced by explosions need to be incorporated in building designs. For safer performance of a structure, its foundation should have sufficient strength and stability. Therefore, prior to any reconstruction or rehabilitation of a building subjected to blast, it is important to examine adverse effects on the foundation caused by blast induced ground shocks. This paper evaluates the effects of a buried explosion on a pile foundation. It treats the dynamic response of the pile in saturated sand, using explicit dynamic nonlinear finite element software LS-DYNA. The blast induced wave propagation in the soil and the horizontal deformation of pile are presented and the results are discussed. Further, a parametric study is carried out to evaluate the effect of varying the explosive shape on the pile response. This information can be used to evaluate the vulnerability of piled foundations to credible blast events as well as develop guidance for their design.
Abstract: Molecular dynamics simulation of annular flow
boiling in a nanochannel with 70000 particles is numerically
investigated. In this research, an annular flow model is developed to
predict the superheated flow boiling heat transfer characteristics in a
nanochannel. To characterize the forced annular boiling flow in a
nanochannel, an external driving force F ext ranging from 1to12PN
(PN= Pico Newton) is applied along the flow direction to inlet fluid
particles during the simulation. Based on an annular flow model
analysis, it is found that saturation condition and superheat degree
have great influences on the liquid-vapor interface. Also, the results
show that due to the relatively strong influence of surface tension in
small channel, the interface between the liquid film and vapor core is
fairly smooth, and the mean velocity along the stream-wise direction
does not change anymore.
Abstract: Structured phospholipids from commercial soybean
lecithin with oil enriched omega-3 fatty acid form by product of tuna
canning is alternative procedure to provides the stability of omega-3
fatty acid structure and increase these bioactive function in
metabolism. Best treatment condition was obtain in 18 hours
acidolysis reaction with 30% enzyme concentration, which EPADHA
incorporation level was 127,47 mg/g and incorporation
percentage of EPA-DHA was 51,04% at phospholipids structure.
This structured phospolipids could reduce atherosclerosis risk in
male Sprague dawley rat. Provision of structured phospholipids has
significant effect (α = 0.05) on changes in lipid profile, intima-media
thickness of aorta rats (male Sprague dawley) fed atherogenic diet.
Structured phospholipids intake can lower total cholesterol 78.36
mg/dL, total triglycerides 94,57 mg/dL, LDL levels 87.08 mg/dL and
increased HDL level as much as 12,64 mg/dL in 10 weeks cares.
Structured phospholipids intake also can prevent the thickening of
the intima-media layer of the aorta.
Abstract: Waste lubricating oil re-refining adsorption process by
different adsorbent materials was investigated. Adsorbent materials
such as oil adsorbent, egg shale powder, date palm kernel powder,
and acid activated date palm kernel powder were used. The
adsorption process over fixed amount of adsorbent at ambient
conditions was investigated. The adsorption/extraction process was
able to deposit the asphaltenic and metallic contaminants from the
waste oil to lower values. It was found that the date palm kernel
powder with contact time of 4 h was able to give the best conditions
for treating the waste oil. The recovered solvent could be also reused.
It was also found that the activated bentonite gave the best
physical properties followed by the date palm kernel powder.
Abstract: These Nowadays the explosion of bombs or explosive
materials such as gas and oil near or inside the buildings cause some
losses in installations and building components. This has made the
engineers to make the buildings and their components resistance
against the effects of explosion. These activities lead to provide
regulations and different methods. The above regulations are mostly
focused on the explosion effects resulting from the vehicles around
the buildings. Therefore, the explosion resulting from the vehicles
outside the buildings will be studied in this research.
In the present study, the main goals are to investigate the
explosion load effects on the structures located on the piles with the
specific quantity of plasticity and observing the permissible response
of these structures. The concentrated mass system and the spring with
two degree of freedom will be used to study the structural system.
Abstract: This study was designed to formulate,
pharmaceutically evaluate a topical skin-care cream (w/o emulsion)
of Aloe Vera versus its vehicle (Base) as control and determine their
effects on Stratum Corneum (SC) water content and Transepidermal
water loss (TEWL). Base containing no extract and a Formulation
containing 3% concentrated extract of Aloe Vera was developed by
entrapping in the inner aqueous phase of w/o emulsion (cream).
Lemon oil was incorporated to improve the odor. Both the Base and
Formulation were stored at 8°C ±0.1°C (in refrigerator), 25°C±0.1°C,
40°C±0.1°C and 40°C± 0.1°C with 75% RH (in incubator) for a
period of 4 weeks to predict their stability. The evaluation parameters
consisted of color, smell, type of emulsion, phase separation,
electrical conductivity, centrifugation, liquefaction and pH. Both the
Base and Formulation were applied to the cheeks of 21 healthy
human volunteers for a period of 8 weeks Stratum corneum (SC)
water content and Transepidermal water loss (TEWL) were
monitored every week to measure any effect produced by these
topical creams. The expected organoleptic stability of creams was
achieved from 4 weeks in-vitro study period. Odor was disappeared
with the passage of time due to volatilization of lemon oil. Both the
Base and Formulation produced significant (p≤0.05) changes in
TEWL with respect to time. SC water content was significantly
(p≤0.05) increased by the Formulation while the Base has
insignificant (p 0.05) effects on SC water content. The newly
formulated cream of Aloe Vera, applied is suitable for improvement
and quantitative monitoring of skin hydration level (SC water
content/ moisturizing effects) and reducing TEWL in people with dry
skin.
Abstract: In this paper, the feasibility study of using a hybrid
system of ground heat exchangers (GHE) and direct evaporative
cooling system in arid weather condition has been performed. The
model is applied for Yazd and Kerman, two cities with arid weather
condition in Iran. The system composed of three sections: Ground-
Coupled-Circuit (GCC), Direct Evaporative Cooler (DEC) and
Cooling Coil Unite (CCU). The GCC provides the necessary precooling
for DEC. The GCC includes four vertical GHE which are
designed in series configuration. Simulation results show that
hybridization of GCC and DEC could provide comfort condition
whereas DEC alone did not. Based on the results the cooling
effectiveness of a hybrid system is more than unity. Thus, this novel
hybrid system could decrease the air temperature below the ambient
wet-bulb temperature. This environmentally clean and energy
efficient system can be considered as an alternative to the mechanical
vapor compression systems.
Abstract: The sand production problem has led researchers into making various attempts to understand the phenomenon. The generally accepted concept is that the occurrence of sanding is due to the in-situ stress conditions and the induced changes in stress that results in the failure of the reservoir sandstone during hydrocarbon production from wellbores. By using a hypothetical cased (perforated) well, an approach to the problem is presented here by using Finite Element numerical modelling techniques. In addition to the examination of the erosion problem, the influence of certain key parameters is studied in order to ascertain their effect on the failure and subsequent erosion process. The major variables investigated include: drawdown, perforation depth, and the erosion criterion. Also included is the determination of the optimal mud pressure for given operational and reservoir conditions. The improved understanding between parameters enables the choice of optimal values to minimize sanding during oil production.