Abstract: In this study, the designed dual stage membrane
bioreactor (MBR) system was conceptualized for the treatment of
cyanide and heavy metals in electroplating wastewater. The design
consisted of a primary treatment stage to reduce the impact of
fluctuations and the secondary treatment stage to remove the residual
cyanide and heavy metal contaminants in the wastewater under
alkaline pH conditions. The primary treatment stage contained
hydrolyzed Citrus sinensis (C. sinensis) pomace and the secondary
treatment stage contained active Aspergillus awamori (A. awamori)
biomass, supplemented solely with C. sinensis pomace extract from
the hydrolysis process. An average of 76.37%, 95.37%, 93.26 and
94.76% and 99.55%, 99.91%, 99.92% and 99.92% degradation
efficiency for total cyanide (T-CN), including the sorption of nickel
(Ni), zinc (Zn) and copper (Cu) were observed after the first and
second treatment stages, respectively. Furthermore, cyanide
conversion by-products degradation was 99.81% and 99.75 for both
formate (CHOO-) and ammonium (NH4
+) after the second treatment
stage. After the first, second and third regeneration cycles of the C.
sinensis pomace in the first treatment stage, Ni, Zn and Cu removal
achieved was 99.13%, 99.12% and 99.04% (first regeneration cycle),
98.94%, 98.92% and 98.41% (second regeneration cycle) and 98.46
%, 98.44% and 97.91% (third regeneration cycle), respectively.
There was relatively insignificant standard deviation detected in all
the measured parameters in the system which indicated
reproducibility of the remediation efficiency in this continuous
system.
Abstract: Contamination of aromatic compounds in water can
cause severe long-lasting effects not only for biotic organism but also
on human health. Several alternative technologies for remediation of
polluted water have been attempted. One of these is adsorption
process of aromatic compounds by using organic modified clay
mineral. Porous structure of clay is potential properties for molecular
adsorptivity and it can be increased by immobilizing hydrophobic
structure to attract organic compounds. In this work natural
montmorillonite were modified with cetyltrimethylammonium
(CTMA+) and was evaluated for use as adsorbents of aromatic
compounds: benzene, toluene, and 2-chloro phenol in its single and
multicomponent solution by ethanol:water solvent. Preparation of
CTMA-montmorillonite was conducted by simple ion exchange
procedure and characterization was conducted by using x-day
diffraction (XRD), Fourier-transform infra red (FTIR) and gas
sorption analysis. The influence of structural modification of
montmorillonite on its adsorption capacity and adsorption affinity of
organic compound were studied. It was shown that adsorptivity of
montmorillonite was increased by modification associated with
arrangements of CTMA+ in the structure even the specific surface
area of modified montmorillonite was lower than raw
montmorillonite. Adsorption rate indicated that material has affinity
to adsorb compound by following order: benzene> toluene > 2-chloro
phenol. The adsorption isotherms of benzene and toluene showed 1st
order adsorption kinetic indicating a partition phenomenon of
compounds between the aqueous and organophilic CTMAmontmorillonite.
Abstract: In the present work we report a gram negative
bacterial isolate, from soil of a dye industry, with promising
biorefining and bioremediation potential. This isolate (GBS.5) could
utilize carbazole (nitrogen containing polycyclic aromatic
hydrocarbon) as the sole source of nitrogen and carbon and utilize
almost 98% of 3mM carbazole in 100 hours. The specific activity of
our GBS.5 isolate for carbazole degradation at 30°C and pH 7.0 was
found to be 11.36 μmol/min/g dry cell weight as compared to 10.4
μmol/min/g dry cell weight, the highest reported specific activity till
date. The presence of car genes (the genes involved in
denitrogenation of carbazole) was confirmed through PCR
amplification.
Abstract: In order to provide existing SOAP (Simple Object
Access Protocol)-based Web services with users who are familiar with
REST (REpresentational State Transfer)-style Web services, this
paper proposes Web service providing method using Web service
transformation. This enables SOAP-based service providers to define
rules for mapping from RESTful Web services to SOAP-based ones.
Using these mapping rules, HTTP request messages for RESTful
services are converted automatically into SOAP-based service
invocations. Web service providers need not develop duplicate
RESTful services and they can avoid programming mediation
modules per service. Furthermore, they need not equip mediation
middleware like ESB (Enterprise Service Bus) only for the purpose of
transformation of two different Web service styles.
Abstract: The assessment of surface waters in Enugu metropolis
for fecal coliform bacteria was undertaken. Enugu urban was divided
into three areas (A1, A2 and A3), and fecal coliform bacteria
analysed in the surface waters found in these areas for four years
(2005-2008). The plate count method was used for the analyses. Data
generated were subjected to statistical tests involving; Normality test,
Homogeneity of variance test, correlation test, and tolerance limit
test. The influence of seasonality and pollution trends were
investigated using time series plots. Results from the tolerance limit
test at 95% coverage with 95% confidence, and with respect to EU
maximum permissible concentration show that the three areas suffer
from fecal coliform pollution. To this end, remediation procedure
involving the use of saw-dust extracts from three woods namely;
Chlorophora-Excelsa (C-Excelsa),Khayan-Senegalensis,(CSenegalensis)
and Erythrophylum-Ivorensis (E-Ivorensis) in
controlling the coliforms was studied. Results show that mixture of
the acetone extracts of the woods show the most effective
antibacterial inhibitory activities (26.00mm zone of inhibition)
against E-coli. Methanol extract mixture of the three woods gave best
inhibitory activity (26.00mm zone of inhibition) against S-areus, and
25.00mm zones of inhibition against E-Aerogenes. The aqueous
extracts mixture gave acceptable zones of inhibitions against the
three bacteria organisms.
Abstract: The aim of this work was to investigate the potential of soil microorganisms and the burhead plant, as well as the combination of soil microorganisms and plants to remediate monoethylene glycol (MEG), diethylene glycol (DEG), and triethylene glycol (TEG) in synthetic wastewater. The result showed that a system containing both burhead plant and soil microorganisms had the highest efficiency in EGs removal. Around 100% of MEG and DEG and 85% of TEG were removed within 15 days of the experiments. However, the burhead plant had higher removal efficiency than soil microorganisms for MEG and DEG but the same for TEG in the study systems. The removal rate of EGs in the study system related to the molecular weight of the compounds and MEG, the smallest glycol, was removed faster than DEG and TEG by both the burhead plant and soil microorganisms in the study system.