Abstract: Five lignin samples were fractionated with
Acetone/Water mixtures and the obtained fractions were subjected to
extensive structural characterization, including Fourier Transform
Infrared (FT-IR), Gel permeation Chromatography (GPC) and
Phosphorus-31 NMR spectroscopy (31P-NMR). The results showed
that for all studied lignins the solubility increases with the increment
of the acetone concentration. Wheat straw lignin has the highest
solubility in 90/10 (v/v) Acetone/Water mixture, 400 mg lignin being
dissolved in 1 mL mixture. The weight average molecular weight of
the obtained fractions increased with the increment of acetone
concentration and thus with solubility. 31P-NMR analysis based on
lignin modification by reactive phospholane into phosphitylated
compounds was used to differentiate and quantify the different types
of OH groups (aromatic, aliphatic, and carboxylic) found in the
fractions obtained with 70/30 (v/v) Acetone/Water mixture.
Abstract: The main objectives of this study are to inspect and
identify any damage of jaimusi highway prestressed concrete bridge
after repair and strengthening of damaged structural members and to
evaluate the performance of the bridge structural members by
adopting static load test. Inspection program after repair and
strengthening includes identifying and evaluating the structural
members of bridge such as T-shape cantilever structure, hanging
beams, corbels, external tendons, anchor beams, sticking steel plate,
and piers. The results of inspection show that the overall state of the
bridge structural member after repair and strengthening is good. The
results of rebound test of concrete strength show that the average
strength of concrete is 46.31Mpa. Whereas, the average value of
concrete strength of anchor beam is 49.82Mpa. According to the
results of static load test, the experimental values are less than
theoretical values of internal forces, deflection, and strain, indicating
that the stiffness of the experimental structure, overall deformation
and integrity satisfy the designed standard and the working
performance is good, and the undertaking capacity has a certain
surplus. There is not visible change in the length and width of cracks
and there are not new cracks under experimental load.
Abstract: Energetic and structural results for ethanol-water mixtures as a function of the mole fraction were calculated using Monte Carlo methodology. Energy partitioning results obtained for equimolar water-ethanol mixture and ether organic liquids are compared. It has been shown that at xet=0.22 the RDFs for waterethanol and ethanol-ethanol interactions indicated strong hydrophobic interactions between ethanol molecules and the local structure of solution is less structured at this concentration as at ether ones. Results obtained for ethanol-water mixture as a function of concentration are in good agreement with the experimental data.
Abstract: To unveil the mechanism of fast autooxidation of fish
myoglobins, the effect of temperature on the structural change of tuna
myoglobin was investigated. Purified myoglobin was subjected to
preincubation at 5, 20, 50 and 40oC. Overall helical structural decay
through thermal treatment up to 95oC was monitored by circular
dichroism spectrometry, while the structural changes around the heme
pocket was measured by ultraviolet/visible absorption spectrophotometry.
As a result, no essential structural change of myoglobin
was observed under 30oC, roughly equivalent to their body
temperature, but the structure was clearly damaged at 40oC. The Soret
band absorption hardly differed irrespective of preincubation
temperature, suggesting that the structure around the heme pocket was
not perturbed even after thermal treatment.
Abstract: The most severe damage of the turbine rotor is its
distortion. The rotor straightening process must lead, at the first
stage, to removal of the stresses from the material by annealing and
next, to straightening of the plastic distortion without leaving any
stress by hot spotting. The straightening method does not produce
stress accumulations and the heating technique, developed
specifically for solid forged rotors and disks, enables to avoid local
overheating and structural changes in the material. This process also
does not leave stresses in the shaft material. An experimental study
of hot spotting is carried out on a large turbine rotor and some of the
most important effective parameters that must be considered on
annealing and hot spotting processes are investigated in this paper.
Abstract: One of the difficulties of the vibration-based damage identification methods is the nonuniqueness of the results of damage identification. The different damage locations and severity may cause the identical response signal, which is even more severe for detection of the multiple damage. This paper proposes a new strategy for damage detection to avoid this nonuniqueness. This strategy firstly determines the approximates damage area based on the statistical pattern recognition method using the dynamic strain signal measured by the distributed fiber Bragg grating, and then accurately evaluates the damage information based on the Bayesian model updating method using the experimental modal data. The stochastic simulation method is then used to compute the high-dimensional integral in the Bayesian problem. Finally, an experiment of the plate structure, simulating one part of mechanical structure, is used to verify the effectiveness of this approach.
Abstract: In order to improve the effect of isolation structure, the
principles and behaviours of the base-isolation system are studied, and
the types and characteristics of the base-isolation are also discussed.
Compared to the traditional aseismatic structures, the base isolation
structures decrease the seismic response obviously: the total structural
aseismatic value decreases to 1/4-1/32 and the seismic shear stress in
the upper structure decreases to 1/14-1/23. In the huge seism, the
structure can have an obvious aseismatic effect.
Abstract: The paper presents the brief information on particular results of experimental study focused to the problems of behavior of structural plated components made of fiber-cement-based materials and used in building constructions, exposed to atmospheric physical effects given by the weather changes in the summer period. Weather changes represented namely by temperature and rain cause also the changes of the temperature and moisture of the investigated structural components. This can affect their static behavior that means stresses and deformations, which have been monitored as the main outputs of tests performed. Experimental verification is based on the simulation of the influence of temperature and rain using the defined procedure of warming and water sprinkling with respect to the corresponding weather conditions during summer period in the South Moravian region at the Czech Republic, for which the application of these structural components is mainly planned. Two types of components have been tested: (i) glass-fiber-concrete panels used for building façades and (ii) fiber-cement slabs used mainly for claddings, but also as a part of floor structures or lost shuttering, and so on.
Abstract: In this paper we investigate how wide-ranging
organizational support and the more specific form of support,
namely management support, may influence on tourism workers
satisfaction with a cash transaction system. The IS continuance
theory, proposed by Bhattacherjee in 2001, is utilized as a
theoretical framework. This implies that both perceived usefulness
and ease of use is included in the research model, in addition to
organizational and management support. The sample consists of
500 workers from 10 cruise and tourist ferries in Scandinavia that
use a cash transaction system to perform their work tasks. Using
structural equation modelling, results indicate that organizational
support and ease of use perceptions is critical for the users- level of
satisfaction with the cash transaction system.The findings have
implications for business managers and IS practitioners that want
to increase the quality of IT-based business processes within the
tourism industry.
Abstract: Data of wave height and wind speed were collected
from three existing oil fields in South China Sea – offshore
Peninsular Malaysia, Sarawak and Sabah regions. Extreme values
and other significant data were employed for analysis. The data were
recorded from 1999 until 2008. The results show that offshore
structures are susceptible to unacceptable motions initiated by wind
and waves with worst structural impacts caused by extreme wave
heights. To protect offshore structures from damage, there is a need
to quantify descriptive statistics and determine spectra envelope of
wind speed and wave height, and to ascertain the frequency content
of each spectrum for offshore structures in the South China Sea
shallow waters using measured time series. The results indicate that
the process is nonstationary; it is converted to stationary process by
first differencing the time series. For descriptive statistical analysis,
both wind speed and wave height have significant influence on the
offshore structure during the northeast monsoon with high mean wind
speed of 13.5195 knots ( = 6.3566 knots) and the high mean wave
height of 2.3597 m ( = 0.8690 m). Through observation of the
spectra, there is no clear dominant peak and the peaks fluctuate
randomly. Each wind speed spectrum and wave height spectrum has
its individual identifiable pattern. The wind speed spectrum tends to
grow gradually at the lower frequency range and increasing till it
doubles at the higher frequency range with the mean peak frequency
range of 0.4104 Hz to 0.4721 Hz, while the wave height tends to
grow drastically at the low frequency range, which then fluctuates
and decreases slightly at the high frequency range with the mean
peak frequency range of 0.2911 Hz to 0.3425 Hz.
Abstract: This study investigates the roles of knowledge
acquisition, absorptive capacity, and innovation capability in finance
and manufacturing industries. With 362 valid questionnaires from
manufactures and financial industries in Taiwan, we examine the
relationships between absorptive capacity, knowledge acquisition and
innovation capability using a structural equation model. The results
indicate that absorptive capacity is the mediator between knowledge
acquisition and innovation capability, and that knowledge acquisition
has a positive effect on absorptive capacity.
Abstract: Stress Concentration Factors are significant in
machine design as it gives rise to localized stress when any change in
the design of surface or abrupt change in the cross section occurs.
Almost all machine components and structural members contain
some form of geometrical or microstructural discontinuities. These
discontinuities are very dangerous and lead to failure. So, it is very
much essential to analyze the stress concentration factors for critical
applications like Turbine Rotors. In this paper Finite Element
Analysis (FEA) with extremely fine mesh in the vicinity of the
blades of Steam Turbine Rotor is applied to determine stress
concentration factors. A model of Steam Turbine Rotor is shown in
Fig. 1.
Abstract: Nowadays use of a new structural bracing system
called 'Knee Bracing System' have taken the specialists attention too
much. On the other hand nonlinear static analysis procedures in
estimate structures performance in earthquake time have taken
attention too much. One of these procedure is modal pushover
analysis (MPA) procedure. The accuracy of MPA procedure for
simple steel moment resisting frame has been verified and considered
in Chintanapakdee and Chopra-s article in 2003. Since the accuracy
of MPA procedure has not verified for semi-rigid steel frames with
knee bracing, we are going to get through with this matter in this
study. For this purpose, the selected structures are four frames with
different heights, 5 to 20 stories, will be designed according to AISC
criteria. Then MPA procedure is used for the same frames with
different rigidity percentiles of connections. The results of seismic
responses are compared with dynamic nonlinear response history
analysis as exact procedure and accuracy of MPA procedure is
evaluated. It seems that MPA procedure accuracy will come down by
reduction of the rigidity percentiles of semi-rigid connections.
Abstract: Some physical properties of musk lime (Citrus
microcarpa) were determined in this study. The average moisture
content (wet basis) of the fruit was found to be 85.10 (±0.72) %. The
mean of length, width and thickness of the fruit was 26.36 (±0.97),
26.40 (±1.04) and 25.26 (±0.94) mm respectively. The average value
for geometric mean diameter, sphericity, aspect ratio, mass, surface
area, volume, true density, bulk density and porosity was 26.00
(±0.82) mm, 98.67 (±2.04) %, 100.23 (±3.28) %, 10.007 (±0.878) g,
2125.07 (±133.93) mm2, 8800.00 (±731.82) mm3, 1002.87 (±39.16)
kgm-3, 501.70 (±22.58) kgm-3 and 49.89 (±3.15) % respectively.
The coefficient of static friction on four types of structural surface
was found to be varying from 0.238 (±0.025) for glass to 0.247
(±0.024) for steel surface.
Abstract: Today, numerical simulation is a powerful tool to
solve various hydraulic engineering problems. The aim of this
research is numerical solutions of shallow water equations using
finite volume method for Simulations of dam break over wet and dry
bed. In order to solve Riemann problem, Roe-s approximate solver is
used. To evaluate numerical model, simulation was done in 1D and
2D states. In 1D state, two dam break test over dry bed (with and
without friction) were studied. The results showed that Structural
failure around the dam and damage to the downstream constructions
in bed without friction is more than friction bed. In 2D state, two
tests for wet and dry beds were done. Generally in wet bed case,
waves are propagated to canal sides but in dry bed it is not
significant. Therefore, damage to the storage facilities and
agricultural lands in wet bed case is more than in dry bed.
Abstract: Non-saturated soils that while saturation greatly
decrease their volume, have sudden settlement due to increasing
humidity, fracture and structural crack are called loess soils. Whereas
importance of civil projects including: dams, canals and
constructions bearing this type of soil and thereof problems, it is
required for carrying out more research and study in relation to loess
soils. This research studies shear strength parameters by using
grading test, Atterberg limit, compression, direct shear and
consolidation and then effect of using cement and lime additives on
stability of loess soils is studied. In related tests, lime and cement are
separately added to mixed ratios under different percentages of soil
and for different times the stabilized samples are processed and effect
of aforesaid additives on shear strength parameters of soil is studied.
Results show that upon passing time the effect of additives and
collapsible potential is greatly decreased and upon increasing
percentage of cement and lime the maximum dry density is
decreased; however, optimum humidity is increased. In addition,
liquid limit and plastic index is decreased; however, plastic index
limit is increased. It is to be noted that results of direct shear test
reveal increasing shear strength of soil due to increasing cohesion
parameter and soil friction angle.
Abstract: Baltic competitiveness is quite controversial. In a
situation with the rapid structural changes, economy develops in
balance very rarely - in different fields will always be more rapid
changes in another more stagnation.
Analyzing different economic indices developed by international
organizations the situation in three Baltic countries are described
from a different competitiveness positions highlighting strengths and
weaknesses of each country.
Exploring the openness of the economy, it is possible to observe
certain risks included in the reports describing situation of
competitiveness where government policies competing in the tax
system, the rates of labour market policies, investment environment,
etc. This is a very important factor resulting in competitive
advantage.
Baltic countries are still at a weak position from a technological
perspective, and need to borrow the knowledge and technology from
more developed countries.
Abstract: Schema matching plays a key role in many different
applications, such as schema integration, data integration, data
warehousing, data transformation, E-commerce, peer-to-peer data
management, ontology matching and integration, semantic Web,
semantic query processing, etc. Manual matching is expensive and
error-prone, so it is therefore important to develop techniques to
automate the schema matching process. In this paper, we present a
solution for XML schema automated matching problem which
produces semantic mappings between corresponding schema
elements of given source and target schemas. This solution
contributed in solving more comprehensively and efficiently XML
schema automated matching problem. Our solution based on
combining linguistic similarity, data type compatibility and structural
similarity of XML schema elements. After describing our solution,
we present experimental results that demonstrate the effectiveness of
this approach.
Abstract: Un-doped GaN film of thickness 1.90 mm, grown on
sapphire substrate were uniformly implanted with 325 keV Mn+ ions
for various fluences varying from 1.75 x 1015 - 2.0 x 1016 ions cm-2 at
3500 C substrate temperature. The structural, morphological and
magnetic properties of Mn ion implanted gallium nitride samples
were studied using XRD, AFM and SQUID techniques. XRD of the
sample implanted with various ion fluences showed the presence of
different magnetic phases of Ga3Mn, Ga0.6Mn0.4 and Mn4N.
However, the compositions of these phases were found to be
depended on the ion fluence. AFM images of non-implanted sample
showed micrograph with rms surface roughness 2.17 nm. Whereas
samples implanted with the various fluences showed the presence of
nano clusters on the surface of GaN. The shape, size and density of
the clusters were found to vary with respect to ion fluence. Magnetic
moment versus applied field curves of the samples implanted with
various fluences exhibit the hysteresis loops. The Curie temperature
estimated from zero field cooled and field cooled curves for the
samples implanted with the fluence of 1.75 x 1015, 1.5 x 1016 and 2.0
x 1016 ions cm-2 was found to be 309 K, 342 K and 350 K
respectively.
Abstract: The mechanical properties of granular solids are
dependent on the flow of stresses from one particle to another
through inter-particle contact. Although some experimental methods
have been used to study the inter-particle contacts in the past,
preliminary work with these techniques indicated that they do not
have the necessary resolution to distinguish between those contacts
that transmit the load and those that do not, especially for systems
with a wide distribution of particle sizes. In this research, computer
simulations are used to study the nature and distribution of contacts
in a compact with wide particle size distribution, representative of
aggregate size distribution used in asphalt pavement construction.
The packing fraction, the mean number of contacts and the
distribution of contacts were studied for different scenarios. A
methodology to distinguish and compute the fraction of load-bearing
particles and the fraction of space-filling particles (particles that do
not transmit any force) is needed for further investigation.