Abstract: A continuum model is presented to study vdW
interaction on buckling analysis of multi-walled walled carbon
nanotube. In previous studies, only the vdW interaction between
adjacent two layers was considered and the vdW interaction between
the other two layers was neglected. The results show that the vdW
interaction cofficients are dependent on the change of interlayer
spacing and the radii of tubes. With increase of radii the vdW
coefficients approach a constant value. The numerical results show
that the effect of vdW interaction on the critical strain for a doublewalled
CNT is negligible when the radius is large enough for the
both the cases of before and after buckling.
Abstract: It is important to remove manganese from water
because of its effects on human and the environment. Human
activities are one of the biggest contributors for excessive manganese
concentration in the environment. The proposed method to remove
manganese in aqueous solution by using adsorption as in carbon
nanotubes (CNT) at different parameters: The parameters are CNT
dosage, pH, agitation speed and contact time. Different pHs are pH
6.0, pH 6.5, pH 7.0, pH 7.5 and pH 8.0, CNT dosages are 5mg,
6.25mg, 7.5mg, 8.75mg or 10mg, contact time are 10 min, 32.5 min,
55 min, 87.5 min and 120 min while the agitation speeds are 100rpm,
150rpm, 200rpm, 250rpm and 300rpm. The parameters chosen for
experiments are based on experimental design done by using Central
Composite Design, Design Expert 6.0 with 4 parameters, 5 levels and
2 replications. Based on the results, condition set at pH 7.0, agitation
speed of 300 rpm, 7.5mg and contact time 55 minutes gives the
highest removal with 75.5%. From ANOVA analysis in Design
Expert 6.0, the residual concentration will be very much affected by
pH and CNT dosage. Initial manganese concentration is 1.2mg/L
while the lowest residual concentration achieved is 0.294mg/L,
which almost satisfy DOE Malaysia Standard B requirement.
Therefore, further experiments must be done to remove manganese
from model water to the required standard (0.2 mg/L) with the initial
concentration set to 0.294 mg/L.
Abstract: This project aims to investigate the potential of
torrefaction to improve the properties of Malaysian palm kernel shell
(PKS) as a solid fuel. A study towards torrefaction of PKS was
performed under various temperature and residence time of 240, 260,
and 280oC and 30, 60, and 90 minutes respectively. The torrefied
PKS was characterized in terms of the mass yield, energy yield,
elemental composition analysis, calorific value analysis, moisture and
volatile matter contents, and ash and fixed carbon contents. The mass
and energy yield changes in the torrefied PKS were observed to
prove that the temperature has more effect compare to residence time
in the torrefaction process. The C content of PKS increases while H
and O contents decrease after torrefaction, which resulted in higher
heating value between 5 to 16%. Meanwhile, torrefaction caused the
ash and fixed carbon content of PKS to increase, and the moisture
and volatile matter to decrease.
Abstract: The presence of chemical bonding between functionalized carbon nanotubes and matrix in carbon nanotube reinforced composites is modeled by elastic beam elements representing covalent bonding characteristics. Neglecting other reinforcing mechanisms in the composite such as relatively weak interatomic Van der Waals forces, this model shows close results to the Rule of Mixtures model-s prediction for effective Young-s modulus of a Representative Volume Element of composite for small volume fractions (~1%) and high aspect ratios (L/D>200) of CNTs.
Abstract: In accordance with environmental impacts contended in Kyoto Protocol, the study aims to explore the different administrative and non-administrative measurements that industrial countries, such as America, German, Japan, Korea, Holland and British take to face with the increasing Global Warming phenomena. By large, these measurements consist of versatile dimensions, including of education and advocating, economical instruments, research developments and instances, restricted instruments, voluntary contacts, exchangeable permit for carbon-release and public investments. The results of discussion for the study are as follows: both economical impacts as well as reformations for nations that are affected via Kyoto Protocol, and human testifying for variables of global surroundings in the age of Kyoto Protocol.
Abstract: Constant amplitude fatigue crack growth (FCG) tests
were performed on dissimilar metal welded plates of Type 316L
Stainless Steel (SS) and IS 2062 Grade A Carbon steel (CS). The
plates were welded by TIG welding using SS E309 as electrode. FCG
tests were carried on the Side Edge Notch Tension (SENT)
specimens of 5 mm thickness, with crack initiator (notch) at base
metal region (BM), weld metal region (WM) and heat affected zones
(HAZ). The tests were performed at a test frequency of 10 Hz and at
load ratios (R) of 0.1 & 0.6. FCG rate was found to increase with
stress ratio for weld metals and base metals, where as in case of
HAZ, FCG rates were almost equal at high ΔK. FCG rate of HAZ of
stainless steel was found to be lowest at low and high ΔK. At
intermediate ΔK, WM showed the lowest FCG rate. CS showed
higher crack growth rate at all ΔK. However, the scatter band of data
was found to be narrow. Fracture toughness (Kc) was found to vary
in different locations of weldments. Kc was found lowest for the
weldment and highest for HAZ of stainless steel. A novel method of
characterizing the FCG behavior using an Infrared thermography
(IRT) camera was attempted. By monitoring the temperature rise at
the fast moving crack tip region, the amount of plastic deformation
was estimated.
Abstract: Acute toxicity of nano SiO2, ZnO, MCM-41 (Meso
pore silica), Cu, Multi Wall Carbon Nano Tube (MWCNT), Single
Wall Carbon Nano Tube (SWCNT) , Fe (Coated) to bacteria Vibrio
fischeri using a homemade luminometer , was evaluated. The values
of the nominal effective concentrations (EC), causing 20% and 50%
inhibition of biouminescence, using two mathematical models at two
times of 5 and 30 minutes were calculated. Luminometer was
designed with Photomultiplier (PMT) detector. Luminol
chemiluminescence reaction was carried out for the calibration graph.
In the linear calibration range, the correlation coefficients and
coefficient of Variation (CV) were 0.988 and 3.21% respectively
which demonstrate the accuracy and reproducibility of the instrument
that are suitable. The important part of this research depends on how
to optimize the best condition for maximum bioluminescence. The
culture of Vibrio fischeri with optimal conditions in liquid media,
were stirring at 120 rpm at a temperature of 150C to 180C and were
incubated for 24 to 72 hours while solid medium was held at 180C
and for 48 hours. Suspension of nanoparticles ZnO, after 30 min
contact time to bacteria Vibrio fischeri, showed the highest toxicity
while SiO2 nanoparticles showed the lowest toxicity. After 5 min
exposure time, the toxicity of ZnO was the strongest and MCM-41
was the weakest toxicant component.
Abstract: This study focuses on emission of black carbon (BC)
from field open burning of corn residues. Real-time BC
concentration was measured by Micro Aethalometer from field
burning and simulated open burning in a chamber (SOC)
experiments. The average concentration of BC was 1.18±0.47 mg/m3
in the field and 0.89±0.63 mg/m3 in the SOC. The deduced emission
factor from field experiments was 0.50±0.20 gBC/kgdm, and 0.56±0.33
gBC/kgdm from SOC experiment, which are in good agreement with
other studies. In 2007, the total burned area of corn crop was 8,000
ha, resulting in an emission load of BC 20 ton corresponding to 44.5
million kg CO2 equivalent. Therefore, the control of open burning in
corn field represents a significant global warming reduction option.
Abstract: In this paper, free vibration analysis of carbon nanotube (CNT) reinforced laminated composite panels is presented. Three types of panels such as flat, concave and convex are considered for study. Numerical simulation is carried out using commercially available finite element analysis software ANSYS. Numerical homogenization is employed to calculate the effective elastic properties of randomly distributed carbon nanotube reinforced composites. To verify the accuracy of the finite element method, comparisons are made with existing results available in the literature for conventional laminated composite panels and good agreements are obtained. The results of the CNT reinforced composite materials are compared with conventional composite materials under different boundary conditions.
Abstract: The development of wearable sensing technologies is a great challenge which is being addressed by the Proetex FP6 project (www.proetex.org). Its main aim is the development of wearable sensors to improve the safety and efficiency of emergency personnel. This will be achieved by continuous, real-time monitoring of vital signs, posture, activity, and external hazards surrounding emergency workers. We report here the development of carbon dioxide (CO2) sensing boot by incorporating commercially available CO2 sensor with a wireless platform into the boot assembly. Carefully selected commercially available sensors have been tested. Some of the key characteristics of the selected sensors are high selectivity and sensitivity, robustness and the power demand. This paper discusses some of the results of CO2 sensor tests and sensor integration with wireless data transmission
Abstract: In industrial scale of Gas to Liquid (GTL) process in
Fischer-Tropsch (FT) synthesis, a part of reactor outlet gases such as
CO2 and CH4 as side reaction products, is usually recycled. In this
study, the influence of CO2 and CH4 on the performance and
selectivity of Co-Ru/Al2O3 catalyst is investigated by injection of
these gases (0-20 vol. % of feed) to the feed stream. The effect of
temperature and feed flow rate, are also inspected. The results show
that low amounts of CO2 in the feed stream, doesn`t change the
catalyst activity significantly but increasing the amount of CO2 (more
than 10 vol. %) cause the CO conversion to decrease and the
selectivity of heavy components to increase. Methane acts as an inert
gas and doesn`t affect the catalyst performance. Increasing feed flow
rate has negative effect on both CO conversion and heavy component
selectivity. By raising the temperature, CO conversion will increase
but there are more volatile components in the product. The effect of
CO2 on the catalyst deactivation is also investigated carefully and a
mechanism is suggested to explain the negative influence of CO2 on
catalyst deactivation.
Abstract: In this study, a mathematical model was proposed and
the accuracy of this model was assessed to predict the growth of
Pseudomonas aeruginosa and rhamnolipid production under nitrogen
limiting (sodium nitrate) fed-batch fermentation. All of the
parameters used in this model were achieved individually without
using any data from the literature.
The overall growth kinetic of the strain was evaluated using a
dual-parallel substrate Monod equation which was described by
several batch experimental data. Fed-batch data under different
glycerol (as the sole carbon source, C/N=10) concentrations and feed
flow rates were used to describe the proposed fed-batch model and
other parameters. In order to verify the accuracy of the proposed
model several verification experiments were performed in a vast
range of initial glycerol concentrations. While the results showed an
acceptable prediction for rhamnolipid production (less than 10%
error), in case of biomass prediction the errors were less than 23%. It
was also found that the rhamnolipid production by P. aeruginosa was
more sensitive at low glycerol concentrations.
Based on the findings of this work, it was concluded that the
proposed model could effectively be employed for rhamnolipid
production by this strain under fed-batch fermentation on up to 80 g l-
1 glycerol.
Abstract: A shaft-type activated sludge reactor has been
developed in order to study the feasibility of high-rate wastewater
treatment. The reactor having volume of about 14.5 L was operated
with the acclimated mixed activated sludge under batch and
continuous mode using a synthetic wastewater as feed. The batch
study was performed with varying chemical oxygen demand (COD)
concentrations of 1000–3500 mg·L-1 for a batch period up to 9 h. The
kinetic coefficients: Ks, k, Y and kd were obtained as 2040.2 mg·L-1
and 0.105 h-1, 0.878 and 0.0025 h-1 respectively from Monod-s
approach. The continuous study showed a stable and steady state
operation for a hydraulic retention time (HRT) of 8 h and influent
COD of about 1000 mg·L-1. A maximum COD removal efficiency of
about 80% was attained at a COD loading rate and food-tomicroorganism
(F/M) ratio (COD basis) of 3.42 kg·m-3d-1 and 1.0
kg·kg-1d-1 respectively under a HRT of 8 h. The reactor was also
found to handle COD loading rate and F/M ratio of 10.8 kg·m-3d-1
and 2.20 kg·kg-1d-1 respectively showing a COD removal efficiency
of about 46%.
Abstract: In this project cadmium ions were adsorbed from
aqueous solutions onto either date pits; a cheap agricultural and nontoxic
material, or chemically activated carbon prepared from date pits
using phosphoric acid. A series of experiments were conducted in a
batch adsorption technique to assess the feasibility of using the
prepared adsorbents. The effects of the process variables such as
initial cadmium ions concentration, contact time, solution pH and
adsorbent dose on the adsorption capacity of both adsorbents were
studied. The experimental data were tested using different isotherm
models such as Langmuir, Freundlich, Tempkin and Dubinin-
Radushkevich. The results showed that although the equilibrium data
could be described by all models used, Langmuir model gave slightly
better results when using activated carbon while Freundlich model,
gave better results with date pits.
Abstract: Nowadays there is a growing interest in biofuel production in most countries because of the increasing concerns about hydrocarbon fuel shortage and global climate changes, also for enhancing agricultural economy and producing local needs for transportation fuel. Ethanol can be produced from biomass by the hydrolysis and sugar fermentation processes. In this study ethanol was produced without using expensive commercial enzymes from sugarcane bagasse. Alkali pretreatment was used to prepare biomass before enzymatic hydrolysis. The comparison between NaOH, KOH and Ca(OH)2 shows NaOH is more effective on bagasse. The required enzymes for biomass hydrolysis were produced from sugarcane solid state fermentation via two fungi: Trichoderma longibrachiatum and Aspergillus niger. The results show that the produced enzyme solution via A. niger has functioned better than T. longibrachiatum. Ethanol was produced by simultaneous saccharification and fermentation (SSF) with crude enzyme solution from T. longibrachiatum and Saccharomyces cerevisiae yeast. To evaluate this procedure, SSF of pretreated bagasse was also done using Celluclast 1.5L by Novozymes. The yield of ethanol production by commercial enzyme and produced enzyme solution via T. longibrachiatum was 81% and 50% respectively.
Abstract: Carbon steel is used in boilers, pressure vessels, heat
exchangers, piping, structural elements and other moderatetemperature
service systems in which good strength and ductility are
desired. ASME Boiler and Pressure Vessel Code, Section II Part A
(2004) provides specifications of ferrous materials for construction of
pressure equipment, covering wide range of mechanical properties
including high strength materials for power plants application.
However, increased level of springback is one of the major problems
in fabricating components of high strength steel using bending.
Presented work discuss the springback simulations for five different
steels (i.e. SA-36, SA-299, SA-515 grade 70, SA-612 and SA-724
grade B) using finite element analysis of air V-bending. Analytical
springback simulations of hypothetical layered materials are
presented. Result shows that; (i) combination of the material property
parameters controls the springback, (ii) layer of the high ductility
steel on the high strength steel greatly suppresses the springback.
Abstract: The carbon based coils with the nanometer scale have
the 3 dimension helix geometry. We synthesized the carbon nano-coils
by the use of chemical vapor deposition technique with iron and tin as
the catalysts. The fabricated coils have the external diameter of
ranging few hundred nm to few thousand nm. The Scanning
Electro-Microscope (SEM) and Tunneling Electro-Microscope has
shown detail images of the coil-s structure. The fabrication of the
carbon nano-coils can be grown on the metal and non-metal substrates,
such as the stainless steel and silicon substrates. Besides growth on the
flat substrate; they also can be grown on the stainless steel wires. After
the synthesis of the coils, the mechanical and electro-mechanical
property is measured. The experimental results were reported.
Abstract: Response Surface Methodology (RSM) is a powerful
and efficient mathematical approach widely applied in the
optimization of cultivation process. Cellulase enzyme production by
Trichoderma reesei RutC30 using agricultural waste rice straw and
banana fiber as carbon source were investigated. In this work,
sequential optimization strategy based statistical design was
employed to enhance the production of cellulase enzyme through
submerged cultivation. A fractional factorial design (26-2) was applied
to elucidate the process parameters that significantly affect cellulase
production. Temperature, Substrate concentration, Inducer
concentration, pH, inoculum age and agitation speed were identified
as important process parameters effecting cellulase enzyme synthesis.
The concentration of lignocelluloses and lactose (inducer) in the
cultivation medium were found to be most significant factors. The
steepest ascent method was used to locate the optimal domain and a
Central Composite Design (CCD) was used to estimate the quadratic
response surface from which the factor levels for maximum
production of cellulase were determined.
Abstract: Environmental decision making, particularly about
hazardous waste management, is inherently exposed to a high
potential conflict, principally because of the trade-off between sociopolitical,
environmental, health and economic factors. The need to
plan complex contexts has led to an increasing request for decision
analytic techniques as support for the decision process. In this work,
alternative systems of asbestos-containing waste management
(ACW) in Puglia (Southern Italy) were explored by a multi-criteria
decision analysis. In particular, through Analytic Hierarchy Process
five alternatives management have been compared and ranked
according to their performance and efficiency, taking into account
environmental, health and socio-economic aspects. A separated
valuation has been performed for different temporal scale. For short
period results showed a narrow deviation between the disposal
alternatives “mono-material landfill in public quarry" and “dedicate
cells in existing landfill", with the best performance of the first one.
While for long period “treatment plant to eliminate hazard from
asbestos-containing waste" was prevalent, although high energy
demand required to achieve the change of crystalline structure. A
comparison with results from a participative approach in valuation
process might be considered as future development of method
application to ACW management.
Abstract: In recent years, there have been attempts to store
natural gas in adsorptive form. This is called adsorptive natural gas,
or ANG. The problem with this technology is the low sorption
capacity. The purpose is to achieve compressed natural gas (CNG)
capacity of 230 V/V. Further research is required to achieve such
target. Several research studies have been performed with this target;
through either the modification or development of new sorbents or
the optimization of the operation sorption process itself. In this work,
storage of methane on molecular sieves 5A and 13X was studied on
dry basis, and on wet basis to certain extent. The temperature and the
pressure dynamics were investigated. The results indicated that
regardless of the charge pressure, the time for the peak temperature
during the methane charge process is always the same. This can be
used as a characteristic of the adsorbent. The total achieved
deliveries using molecular sieves were much lower than that of
activated carbons; 53.0 V/V for the case of 13X molecular sieves and
43 V/V for the case of 5A molecular sieves, both at 2oC and 4 MPa
(580 psi). Investigation of charge pressure dynamic using wet
molecular sieves at 2oC and a mass ratio of 0.5, revealed slowness of
the process and unexpected behavior.