Abstract: Interaction of Schiff base complexes of Iron and
Manganese: Iron [N, N’ Bis (5- (triphenyl phosphonium methyl)
salicylidene) -1, 2 ethanediamine) chloride, [Fe Salen]Cl; Manganese
[N, N’ Bis (5- (triphenyl phosphonium methyl) salicylidene) -1, 2
ethanediamine) acetate, were investigated by spectroscopic and
isothermal titration calorimetry techniques (ITC).
The absorbance spectra of complexes have shown hyper and
hypochromism in the presence of DNA that is indication of
interaction of complexes with DNA. The linear dichroism (LD)
measurements confirmed the bending of DNA in the presence of
complexes.
Furthermore, Isothermal titration calorimetry experiments
approved that complexes bound to DNA on the base of both
electrostatic and hydrophobic interactions. More, ITC profile exhibits
the existence of two binding phases for the complexes. Antibacterial
activity of ligand and complexes were tested in vitro to evaluate their
activity against the gram positive and negative bacteria.
Abstract: The Algeria by its location offers a rich and diverse
vegetation. A large number of aromatic and medicinal plants grow
spontaneously. The interest in these plants has continued to grow in
recent years. Their particular properties due to the essential oil
fraction can be utilized to treat microbial infections. To this end, and
in the context of the valuation of the Algerian flora, we became
interested in the species of the family Lamiaceae which is one of the
most used as a global source of spices. The plant on which we have
based our choice is a species of sage "Salvia officinalis" from the
Isser localized region within the province of Boumerdes. This work
focuses on the study of the antimicrobial activity of essential oil
extracted from the leaves of Salvia officinalis. The extraction is
carried out by essential oil hydrodistillation and reveals a yield of
1.06℅. The study of the antimicrobial activity of the essential oil by
the method of at aromatogramme shown that Gram positive bacteria
are most susceptible (Staphylococcus aureus and Bacillus subtilis)
with a strong inhibition of growth. The yeast Candida albicans
fungus Aspergillus niger and have shown moderately sensitive.
Abstract: Innovation plays an important role in economic
growth and development. Evolutionary economics has entrepreneurs
at the centre of the innovation system, but includes all other
participants as contributors to the performance of the innovation
system. Education and training institutions, one of the participants in
the innovation system, contributes in different ways to human capital.
The gap in literature on the competence building as part of human
capital in the analysis of innovation systems is addressed in this
paper. The Mpumalanga Province of South Africa is used as a case
study. It was found that the absence of a university, the level of
education, the quality and performance in the education sector and
the condition of the education infrastructure have not been conducive
to learning.
Abstract: The FOSDT (the First Order Shear Deformation
Theory) is taking into consideration to study the static behavior of a
bimorph beam, with a delamination zone between the upper and the
lower layer. The effect of limit conditions and lengths of the
delamination zone are presented in this paper, with a PVDF
piezoelectric material application. A FEM “Finite Element Method”
is used to discretize the beam. In the axial displacement, a
displacement field appears in the debonded zone with inverse effect
between the upper and the lower layer was observed.
Abstract: Electronic Word-Of-Mouth (eWOM) communities
represent today an important source of information in which more
and more customers base their purchasing decisions. They include
thousands of reviews concerning very different products and services
posted by many individuals geographically distributed all over the
world. Due to their massive audience, eWOM communities can help
users to find the product they are looking for even if they are less
popular or rare. This is known as the long tail effect, which leads to a
larger number of lower-selling niche products. This paper analyzes
the long tail effect in a well-known eWOM community and defines a
tool for finding niche products unavailable through conventional
channels.
Abstract: The heavy metal pollution degree in the soils around
the Zangezur copper and molybdenum combine in Syunik Marz,
Armenia was assessed. The results of the study showed that heavy
metal pollution degree in the soils mainly decreased with increasing
distance from the open mine and the ore enrichment combine which
indicated that the open mine and the ore enrichment combine were
the main sources of heavy metal pollution. The only exception was
observed in the northern part of the open mine where pollution
degree in the sites (along the open mine) situated 600 meters far from
the mine was higher than that in the sites located 300 meters far from
the mine. This can be explained by the characteristics of relief and air
currents as well as the weak vegetation cover of these sites and the
characteristics of soil structure. According to geo-accumulation index
(I-geo), contamination factor (Cf), contamination degree (Cd) and
pollution load index (PLI) values, the pollution degree in the soils
around the open mine and the ore enrichment combine was higher
than that in the soils around the tailing dumps which was due to the
proper and accurate operation of the Artsvanik tailing damp and the
recultivation of the Voghji tailing dump.
The high Cu and Mo pollution of the soils was conditioned by the
character of industrial activities, the moving direction of air currents
as well as the physicochemical peculiarities of the soils.
Abstract: An experimental study was performed to investigate
the behavior and strength of proposed technique to connect
reinforced concrete (RC) beam to steel or composite columns. This
approach can practically be used in several types of building
construction. In this technique, the main beam of the frame consists
of a transfer part (part of beam; Tr.P) and a common reinforcement
concrete beam. The transfer part of the beam is connected to the
column, whereas the rest of the beam is connected to the transfer part
from each side. Four full-scale beam-column connections were tested
under static loading. The test parameters were the length of the
transfer part and the column properties. The test results show that
using of the transfer part technique leads to modify the deformation
capabilities for the RC beam and hence it increases its resistance
against failure. Increase in length of the transfer part did not
necessarily indicate an enhanced behavior. The test results contribute
to the characterization of the connection behavior between RC beam -
steel column and can be used to calibrate numerical models for the
simulation of this type of connection.
Abstract: The explosion of the World Wide Web and the
electronic trend of university teaching have transformed the learning
style to become more learner-centered, which has popularized the
digital delivery of mediated lectures as an alternative or an adjunct to
traditional lectures. Despite its potential and popularity, virtual
lectures have not been adopted yet in Jordanian universities. This
research aimed to fill this gap by studying the factors that influence
students’ willingness to accept virtual lectures in one Jordanian
University. A quantitative approach was followed, by obtaining 216
survey responses and statistically applying the UTAUT model with
some modifications. Results revealed that performance expectancy,
effort expectancy, social influences, and self-efficacy could
significantly influence students’ attitudes towards virtual lectures.
Additionally, Facilitating conditions and attitudes towards virtual
lectures were found with significant influence on students’ intention
to take virtual lectures. Research implications and future work were
specified afterwards.
Abstract: This paper introduces a proposal scheme for an
Intelligent System applied to Pedagogical Advising using Case-Based
Reasoning, to find consolidated solutions before used for the new
problems, making easier the task of advising students to the
pedagogical staff. We do intend, through this work, introduce the
motivation behind the choices for this system structure, justifying the
development of an incremental and smart web system who learns
bests solutions for new cases when it’s used, showing technics and
technology.
Abstract: The thermal control in many systems is widely
accomplished applying mixed convection process due to its low cost,
reliability and easy maintenance. Typical applications include the
aircraft electronic equipment, rotating-disc heat exchangers, turbo
machinery, and nuclear reactors, etc. Natural convection in an inclined
square enclosure heated via wall heater has been studied numerically.
Finite volume method is used for solving momentum and energy
equations in the form of stream function–vorticity. The right and left
walls are kept at a constant temperature, while the other parts are
adiabatic. The range of the inclination angle covers a whole revolution.
The method is validated for a vertical cavity. A general power law
dependence of the Nusselt number with respect to the Rayleigh
number with the coefficient and exponent as functions of the
inclination angle is presented. For a fixed Rayleigh number, the
inclination angle increases or decreases is found.
Abstract: Ionic liquids consisting of a phosphonium cationic
moiety and a saccharinate anion are synthesized and compared with
their precursors, phosphonium chlorides, in reference to their
extraction efficiency towards L-lactic acid. On the base of
measurements of the acid and the water partitioning in the
equilibrium biphasic systems, the molar ratios between acid, water
and ionic liquid are estimated which allows to deduce the lactic acid
extractive pathway. The effect of a salting-out addition that
strengthens hydrophobicity in both phases is studied in view to reveal
the best biphasic system with respect to IL low toxicity and high
extraction efficiency.
Abstract: Catalytic combustion of methane is imperative due to
stability of methane at low temperature. Methane (CH4), therefore,
remains unconverted in vehicle exhausts thereby causing greenhouse
gas GHG emission problem. In this study, heterogeneous catalysts of
palladium with bio-char (2 wt% Pd/Bc) and Al2O3 (2wt% Pd/ Al2O3)
supports were prepared by incipient wetness impregnation and then
subsequently tested for catalytic combustion of CH4. Support-porous
heterogeneous catalytic combustion (HCC) material were selected
based on factors such as surface area, porosity, thermal stability,
thermal conductivity, reactivity with reactants or products, chemical
stability, catalytic activity, and catalyst life. Sustainable and
renewable support-material of bio-mass char derived from palm shell
waste material was compared with those from the conventional
support-porous materials. Kinetic rate of reaction was determined for
combustion of methane on Palladium (Pd) based catalyst with Al2O3
support and bio-char (Bc). Material characterization was done using
TGA, SEM, and BET surface area. The performance test was
accomplished using tubular quartz reactor with gas mixture ratio of
3% methane and 97% air. The methane porous-HCC conversion was
carried out using online gas analyzer connected to the reactor that
performed porous-HCC. BET surface area for prepared 2 wt% Pd/Bc
is smaller than prepared 2wt% Pd/ Al2O3 due to its low porosity
between particles. The order of catalyst activity based on kinetic rate
on reaction of catalysts in low temperature was 2wt%
Pd/Bc>calcined 2wt% Pd/ Al2O3> 2wt% Pd/ Al2O3>calcined 2wt%
Pd/Bc. Hence agro waste material can successfully be utilized as an
inexpensive catalyst support material for enhanced CH4 catalytic
combustion.
Abstract: This article discusses ways to implement a
differentiated approach to developing academic motivation for
mathematical studies which relies on defining the primary structural
characteristics of motivation. The following characteristics are
considered: features of realization of cognitive activity, meaningmaking
characteristics, level of generalization and consistency of
knowledge acquired by personal experience. The assessment of the
present level of individual student understanding of each component
of academic motivation is the basis for defining the relevant
educational strategy for its further development.
Abstract: Adolescents with Autism Spectrum Disorders (ASD)
often experience social-communication difficulties that negatively
impact their social interactions with typical peers. However, unlike
other age and disability groups, there is little intervention research to
inform best practice for these students. One evidence-based strategy
for younger students with ASD is peer-mediated intervention (PMI).
PMI may be particularly promising for use with adolescents, as peers
are readily available and are natural experts for encouraging authentic
high school conversations. This paper provides a review of previous
research that evaluated the use of PMI to improve the socialcommunication
skills of students with ASD. Specific intervention
features associated with positive student outcomes are identified and
recommendations for future research are provided. Adolescents with
ASD are targeted due the critical importance of social conversation at
the high school level.
Abstract: In this work, we attempt to analyze the contribution of
innovative activities to firm performance and growth. We examine
economic data from some of the economies that were heavily
affected by current economic crisis: the countries of southern Europe
(Portugal, Italy, Greece and Spain) and Ireland. Following literature,
an appropriate econometric model is developed and several indicators
are tested in order to disclose possible relation with innovative
activity. Findings confirm the crucial effect of innovative process in
economic activity, in firm and country level.
Abstract: This study aimed to examine the management and
development of forest tourism Kamchanoad. Ban Dung, Udon Thani
sustainability. Data were collected by means of qualitative research
including in-depth interviews, semi- structured, and then the data
were summarized and discussed in accordance with the objectives.
And make a presentation in the form of lectures. The target
population for the study consisted of 16 people, including
representatives from government agencies, community leaders and
the community. The results showed that Guidelines for the
Management and Development of Forest Tourism Kamchanoad
include management of buildings and infrastructure such as roads,
water, electricity, toilets. Other developments are the establishment
of a service center that provides information and resources to
facilitate tourists.; nature trails and informative signage to educate
visitors on the path to the jungle Kamchanoad; forest activities for
tourists who are interested only in occasional educational activities
such as vegetation, etc.; disseminating information on various aspects
of tourism through various channels in both Thailand and English, as
well as a web site to encourage community involvement in the
planning and management of tourism together with the care and
preservation of natural resources and preserving the local cultural
tourist area of Kamchanoad.
Abstract: To determine the potential of a low cost Irish
engineered timber product to replace high cost solid timber for use in
bending active structures such as gridshells a single Irish engineered
timber product in the form of orientated strand board (OSB) was
selected. A comparative study of OSB and solid timber was carried
out to determine the optimum properties that make a material suitable
for use in gridshells. Three parameters were identified to be relevant
in the selection of a material for gridshells. These three parameters
are the strength to stiffness ratio, the flexural stiffness of
commercially available sections, and the variability of material and
section properties. It is shown that when comparing OSB against
solid timber, OSB is a more suitable material for use in gridshells that
are at the smaller end of the scale and that have tight radii of
curvature. Typically, for solid timber materials, stiffness is used as an
indicator for strength and engineered timber is no different. Thus, low
flexural stiffness would mean low flexural strength. However, when
it comes to bending active gridshells, OSB offers a significant
advantage. By the addition of multiple layers, an increased section
size is created, thus endowing the structure with higher stiffness and
higher strength from initial low stiffness and low strength materials
while still maintaining tight radii of curvature. This allows OSB to
compete with solid timber on large scale gridshells. Additionally, a
preliminary sustainability study using a set of sustainability indicators
was carried out to determine the relative sustainability of building a
large-scale gridshell in Ireland with a primary focus on economic
viability but a mention is also given to social and environmental
aspects. For this, the Savill garden gridshell in the UK was used as
the functional unit with the sustainability of the structural roof
skeleton constructed from UK larch solid timber being compared
with the same structure using Irish OSB. Albeit that the advantages of
using commercially available OSB in a bending active gridshell are
marginal and limited to specific gridshell applications, further study
into an optimised engineered timber product is merited.
Abstract: Most people today are aware that global climate
change is not just a scientific theory but also a fact with worldwide
consequences. Global climate change is due to rapid urbanization,
industrialization, high population growth and current vulnerability of
the climatic condition. Water is becoming scarce as a result of global
climate change. To mitigate the problem arising due to global climate
change and its drought effect, harvesting rainwater from green roofs,
an environmentally-friendly and versatile technology, is becoming
one of the best assessment criteria and gaining attention in Malaysia.
This paper addresses the sustainability of green roofs and examines
the quality of water harvested from green roofs in comparison to
rainwater. The factors that affect the quality of such water, taking
into account, for example, roofing materials, climatic conditions, the
frequency of rainfall frequency and the first flush. A green roof was
installed on the Humid Tropic Centre (HTC) is a place of the study
on monitoring program for urban Stormwater Management Manual
for Malaysia (MSMA), Eco-Hydrological Project in Kuala Lumpur,
and the rainwater was harvested and evaluated on the basis of four
parameters i.e., conductivity, dissolved oxygen (DO), pH and
temperature. These parameters were found to fall between Class I and
Class III of the Interim National Water Quality Standards (INWQS)
and the Water Quality Index (WQI). Some preliminary treatment
such as disinfection and filtration could likely to improve the value of
these parameters to class I. This review paper clearly indicates that
there is a need for more research to address other microbiological and
chemical quality parameters to ensure that the harvested water is
suitable for use potable water for domestic purposes. The change in
all physical, chemical and microbiological parameters with respect to
storage time will be a major focus of future studies in this field.
Abstract: Array-based gene expression analysis is a powerful
tool to profile expression of genes and to generate information on
therapeutic effects of new anti-cancer compounds. Anti-apoptotic
effect of thymoquinone was studied in MCF7 breast cancer cell line
using gene expression profiling with cDNA microarray. The purity
and yield of RNA samples were determined using RNeasyPlus Mini
kit. The Agilent RNA 6000 NanoLabChip kit evaluated the quantity
of the RNA samples. AffinityScript RT oligo-dT promoter primer
was used to generate cDNA strands. T7 RNA polymerase was used to
convert cDNA to cRNA. The cRNA samples and human universal
reference RNA were labelled with Cy-3-CTP and Cy-5-CTP,
respectively. Feature Extraction and GeneSpring softwares analysed
the data. The single experiment analysis revealed involvement of 64
pathways with up-regulated genes and 78 pathways with downregulated
genes. The MAPK and p38-MAPK pathways were
inhibited due to the up-regulation of PTPRR gene. The inhibition of
p38-MAPK suggested up-regulation of TGF-ß pathway. Inhibition of
p38-MAPK caused up-regulation of TP53 and down-regulation of
Bcl2 genes indicating involvement of intrinsic apoptotic pathway.
Down-regulation of CARD16 gene as an adaptor molecule regulated
CASP1 and suggested necrosis-like programmed cell death and
involvement of caspase in apoptosis. Furthermore, down-regulation
of GPCR, EGF-EGFR signalling pathways suggested reduction of
ER. Involvement of AhR pathway which control cytochrome P450
and glucuronidation pathways showed metabolism of Thymoquinone.
The findings showed differential expression of several genes in
apoptosis pathways with thymoquinone treatment in estrogen
receptor-positive breast cancer cells.
Abstract: In the past few decades, the field of chemistry
education has grown tremendously and researches indicated that after
traditional chemistry instruction students often lacked deep
conceptual understanding and failed to integrate their ideas into
coherent conceptual framework. For several concepts in chemistry,
students at all levels have demonstrated difficulty in changing their
initial perceptions. Their perceptions are most often wrong and don't
agree with correct scientific concepts. This study explored the
effectiveness of intervention discussion sections for a college general
chemistry course designed to apply research on students
preconceptions, knowledge integration and student explanation.
Three interventions discussions lasting three hours on bond energy
and spontaneity were done tested and intervention (treatment)
students’ performances were compared with that of control group
which did not use the experimental pedagogy. Results indicated that
this instruction which was capable of identifying students'
misconceptions, initial conceptions and integrating those ideas into
class discussion led to enhanced conceptual understanding and better
achievement for the experimental group.