Abstract: Strong anion exchange resins with QN+OH-, have the
potential to be developed and employed as heterogeneous catalyst for
transesterification, as they are chemically stable to leaching of the
functional group. Nine different SIERs (SIER1-9) with QN+OH-were
prepared by suspension polymerization of vinylbenzyl chloridedivinylbenzene
(VBC-DVB) copolymers in the presence of n-heptane
(pore-forming agent). The amine group was successfully grafted into
the polymeric resin beads through functionalization with
trimethylamine. These SIERs are then used as a catalyst for the
transesterification of triacetin with methanol. A set of differential
equations that represents the Langmuir-Hinshelwood-Hougen-
Watson (LHHW) and Eley-Rideal (ER) models for the
transesterification reaction were developed. These kinetic models of
LHHW and ER were fitted to the experimental data. Overall, the
synthesized ion exchange resin-catalyzed reaction were welldescribed
by the Eley-Rideal model compared to LHHW models,
with sum of square error (SSE) of 0.742 and 0.996, respectively.
Abstract: Developing young people’s employability is a key
policy issue for ensuring their successful transition to the labour
market and their access to career oriented employment. The youths of
today irrespective of their gender need to acquire the knowledge,
skills and attitudes that will enable them to create or find jobs as well
as cope with unpredictable labour market changes throughout their
working lives. In a study carried out to determine the influence of
gender on job-competencies requirements of chemical-based
industries and undergraduate-competencies acquisition by chemists
working in the industries, all chemistry graduates working in twenty
(20) chemical-based industries that were randomly selected from six
sectors of chemical-based industries in Lagos and Ogun States of
Nigeria were administered with Job-competencies required and
undergraduate-competencies acquired assessment questionnaire. The
data were analysed using means and independent sample t-test. The
findings revealed that the population of female chemists working in
chemical-based industries is low compared with the number of male
chemists; furthermore, job-competencies requirements are found not
to be gender biased while there is no significant difference in
undergraduate-competencies acquisition of male and female
chemists. This suggests that females should be given the same
opportunity of employment in chemical-based industries as their male
counterparts. The study also revealed the level of acquisition of
undergraduate competencies as related to the needs of chemicalbased
industries.
Abstract: e-Service has moved from the usual manual and
traditional way of rendering services to electronic service provision
for the public and there are several reasons for implementing these
services, Airline ticketing have gone from its manual traditional way
to an intelligent web-driven service of purchasing. Many companies
have seen their profits doubled through the use of online services in
their operation and a typical example is Hewlett Packard (HP) which
is rapidly transforming their after sales business into a profit
generating e-service business unit.
This paper will examine the various challenges confronting e-
Service adoption and implementation in Nigeria and also analyse
lessons learnt from e-Service adoption and implementation in Asia to
see how it could be useful in Nigeria which is a lower middle income
country. From the analysis of the online survey data, it has been
identified that the public in Nigeria are much aware of e-Services but
successful adoption and implementation have been the problems
faced.
Abstract: The recommended limit for cadmium concentration in
potable water is less than 0.005 mg/L. A continuous biosorption
process using indigenous red seaweed, Gracilaria corticata, was
performed to remove cadmium from the potable water. The process
was conducted under fixed conditions and the breakthrough curves
were achieved for three consecutive sorption-desorption cycles. A
modeling based on Artificial Neural Network (ANN) was employed
to fit the experimental breakthrough data. In addition, a simplified
semi empirical model, Thomas, was employed for this purpose. It
was found that ANN well described the experimental data (R2>0.99)
while the Thomas prediction were a bit less successful with R2>0.97.
The adjusted design parameters using the nonlinear form of Thomas
model was in a good agreement with the experimentally obtained
ones. The results approve the capability of ANN to predict the
cadmium concentration in potable water.
Abstract: The final step to complete the “Analytical Systems
Engineering Process” is the “Allocated Architecture” in which all
Functional Requirements (FRs) of an engineering system must be
allocated into their corresponding Physical Components (PCs). At
this step, any design for developing the system’s allocated
architecture in which no clear pattern of assigning the exclusive
“responsibility” of each PC for fulfilling the allocated FR(s) can be
found is considered a poor design that may cause difficulties in
determining the specific PC(s) which has (have) failed to satisfy a
given FR successfully. The present study utilizes the Axiomatic
Design method principles to mathematically address this problem and
establishes an “Axiomatic Model” as a solution for reaching good
alternatives for developing the allocated architecture. This study
proposes a “loss Function”, as a quantitative criterion to monetarily
compare non-ideal designs for developing the allocated architecture
and choose the one which imposes relatively lower cost to the
system’s stakeholders. For the case-study, we use the existing design
of U. S. electricity marketing subsystem, based on data provided by
the U.S. Energy Information Administration (EIA). The result for
2012 shows the symptoms of a poor design and ineffectiveness due to
coupling among the FRs of this subsystem.
Abstract: Rhodamine B (RB) is a toxic dye used extensively in
textile industry, which must be remediated before its drainage to
environment. In the present study, supported gold nanoparticles on
commercially available titania and zincite were successfully prepared
and then their activity on the photodegradation of RB under UV A
light irradiation were evaluated. The synthesized photocatalysts were
characterized by ICP, BET, XRD, and TEM. Kinetic results showed
that Au/TiO2 was an inferior photocatalyst to Au/ZnO. This
observation could be attributed to the strong reflection of UV
irradiation by gold nanoparticles over TiO2 support.
Abstract: Brown seaweeds are abundant in Portuguese coastline
and represent an almost unexploited marine economic resource. One
of the most common species, easily available for harvesting in the
northwest coast, is Saccorhiza polyschides grows in the lowest shore
and costal rocky reefs. It is almost exclusively used by local farmers
as natural fertilizer, but contains a substantial amount of valuable
compounds, particularly alginates, natural biopolymers of high
interest for many industrial applications.
Alginates are natural polysaccharides present in cell walls of
brown seaweed, highly biocompatible, with particular properties that
make them of high interest for the food, biotechnology, cosmetics
and pharmaceutical industries. Conventional extraction processes are
based on thermal treatment. They are lengthy and consume high
amounts of energy and solvents. In recent years, microwave-assisted
extraction (MAE) has shown enormous potential to overcome major
drawbacks that outcome from conventional plant material extraction
(thermal and/or solvent based) techniques, being also successfully
applied to the extraction of agar, fucoidans and alginates. In the
present study, acid pretreatment of brown seaweed Saccorhiza
polyschides for subsequent microwave-assisted extraction (MAE) of
alginate was optimized. Seaweeds were collected in Northwest
Portuguese coastal waters of the Atlantic Ocean between May and
August, 2014. Experimental design was used to assess the effect of
temperature and acid pretreatment time in alginate extraction.
Response surface methodology allowed the determination of the
optimum MAE conditions: 40 mL of HCl 0.1 M per g of dried
seaweed with constant stirring at 20ºC during 14h. Optimal acid
pretreatment conditions have enhanced significantly MAE of
alginates from Saccorhiza polyschides, thus contributing for the
development of a viable, more environmental friendly alternative to
conventional processes.
Abstract: Monocopter is a single-wing rotary flying vehicle
which has the capability of hovering. This flying vehicle includes two
dynamic parts in which more efficiency can be expected rather than
other Micro UAVs due to the extended area of wing compared to its
fuselage. Low cost and simple mechanism in comparison to other
vehicles such as helicopter are the most important specifications of
this flying vehicle.
In the previous paper we discussed the introduction of the final
system but in this paper, the experimental design process of
Monocopter and its control algorithm has been investigated in
general. Also the editorial bugs in the previous article have been
corrected and some translational ambiguities have been resolved.
Initially by constructing several prototypes and carrying out many
flight tests the main design parameters of this air vehicle were
obtained by experimental measurements. Eventually the required
main monocopter for this project was constructed. After construction
of the monocopter in order to design, implementation and testing of
control algorithms first a simple optic system used for determining
the heading angle. After doing numerous tests on Test Stand, the
control algorithm designed and timing of applying control inputs
adjusted. Then other control parameters of system were tuned in
flight tests. Eventually the final control system designed and
implemented using the AHRS sensor and the final operational tests
performed successfully.
Abstract: Skin detection is an important task for computer
vision systems. A good method of skin detection means a good and
successful result of the system.
The colour is a good descriptor for image segmentation and
classification; it allows detecting skin colour in the images. The
lighting changes and the objects that have a colour similar than skin
colour make the operation of skin detection difficult.
In this paper, we proposed a method using the YCbCr colour space
for skin detection and lighting effects elimination, then we use the
information of texture to eliminate the false regions detected by the
YCbCr skin model.
Abstract: Yttrium oxide (Y2O3) films have been successfully
deposited with yttrium-ethylenediamine tetraacetic acid (EDTA·Y·H)
complexes prepared by various milling techniques. The effects of the
properties of the EDTA·Y·H complex on the properties of the
deposited Y2O3 films have been analyzed. Seven different types of the
raw EDTA·Y·H complexes were prepared by various commercial
milling techniques such as ball milling, hammer milling, commercial
milling, and mortar milling. The milled EDTA·Y·H complexes
exhibited various particle sizes and distributions, depending on the
milling method. Furthermore, we analyzed the crystal structure,
morphology and elemental distribution profile of the metal oxide films
deposited on stainless steel substrate with the milled EDTA·Y·H
complexes. Depending on the milling technique, the flow properties of
the raw powders differed. The X-ray diffraction pattern of all the
samples revealed the formation of Y2O3 crystalline phase, irrespective
of the milling technique. Of all the different milling techniques, the
hammer milling technique is considered suitable for fabricating dense
Y2O3 films.
Abstract: Dissimilar joining of Titanium and Aluminum thin
sheets has potential applications in aerospace and automobile
industry which can reduce weight and cost and improve strength,
corrosion resistance and high temperature properties. However
successful welding of Titanium/Aluminium sheets is of challenge due
to differences in physical, chemical and metallurgical properties
between the two. This paper describes research results of Laser Beam
Welding (LBW) of Ti/Al thin sheets in which many researchers have
recently performed and critically reviewed from different
perspectives. Also some of notable works in the field of laser welding
with changes in mechanical properties, crack propagation, diffusion
behavior, chemical potential, interfacial reaction and the
microstructure are reported.
Abstract: The primary purpose of this paper is to explain the
impact of successful classroom management on the academic
achievements of students, the importance of positive relationship
between teacher and students, among students, between teacher and
parents. Effective communication plays an important role to
encourage students study hard and learn materials which are covered
by the teacher in the class. Friendly relationships among students
other than their preferred friends help them to have team working and
be socialized. In addition, a well-organized classroom arrangement
enhances students learning. As the consequence of successful
classroom management students should feel responsibility and need
to feel it. The one who is responsible to provide a comfortable
environment and help students learn is the manager of the classroom
who is named Teacher.
Abstract: We have experimentally demonstrated bright-dark
pulses in a nonlinear polarization rotation (NPR) based mode-locked
Erbium-doped fiber laser (EDFL) with a long cavity configuration.
Bright–dark pulses could be achieved when the laser works in the
passively mode-locking regime and the net group velocity dispersion
is quite anomalous. The EDFL starts to generate a bright pulse train
with degenerated dark pulse at the mode-locking threshold pump
power of 35.09 mW by manipulating the polarization states of the
laser oscillation modes using a polarization controller (PC). A split
bright–dark pulse is generated when further increasing the pump
power up to 37.95 mW. Stable bright pulses with no obvious
evidence of a dark pulse can also be generated when further adjusting
PC and increasing the pump power up to 52.19 mW. At higher pump
power of 54.96 mW, a new form of bright-dark pulse emission was
successfully identified with the repetition rate of 29 kHz. The bright
and dark pulses have a duration of 795.5 ns and 640 ns, respectively.
Abstract: Due to growing concern about environmental and
social consequences throughout the world, a need has been felt to
incorporate sustainability concepts in conventional manufacturing.
This paper is an attempt to identify and evaluate drivers in
implementing sustainable manufacturing in Indian context. Nine
possible drivers for successful implementation of sustainable
manufacturing have been identified from extensive review. Further,
Decision Making Trial and Evaluation Laboratory (DEMATEL)
approach has been utilized to evaluate and categorize these identified
drivers for implementing sustainable manufacturing in to the cause
and effect groups. Five drivers (Societal Pressure and Public
Concerns; Regulations and Government Policies; Top Management
Involvement, Commitment and Support; Effective Strategies and
Activities towards Socially Responsible Manufacturing and Market
Trends) have been categorized into the cause group and four drivers
(Holistic View in Manufacturing Systems; Supplier Participation;
Building Sustainable culture in Organization; and Corporate Image
and Benefits) have been categorized into the effect group. “Societal
Pressure and Public Concerns” has been found the most critical driver
and “Corporate Image and Benefits” as least critical or the most
easily influenced driver to implementing sustainable manufacturing
in Indian context. This paper may surely help practitioners in better
understanding of these drivers and their priorities towards effective
implementation of sustainable manufacturing.
Abstract: Nanostructured catalysts were successfully prepared
by acidification of diatomite and regeneration of FCC spent catalysts.
The obtained samples were characterized by IR, XRD, SEM, EDX,
MAS-NMR (27Al and 29Si), NH3-TPD and tested in catalytic
pyrolysis of biomass (rice straw). The results showed that the similar
bio-oil yield of 41.4% can be obtained by pyrolysis with catalysts at
450oC as compared to that of the pyrolysis without catalyst at 550oC.
The bio-oil yield reached a maximum of 42.55% at the pyrolysis
temperature of 500oC with catalytic content of 20%. Moreover, by
catalytic pyrolysis, bio-oil quality was better as reflected in higher
ratio of H/C, lower ratio of O/C. This clearly indicated high
application potential of these new nanostructured catalysts in the
production of bio-oil with low oxygenated compounds.
Abstract: Climate change would cause mean sea level to rise +1
m by 2100. To prevent coastal floods resulting from the sea level
rising, different flood control structures have been built, with
acceptable protection levels. Gothenburg with the River Göta älv
located on the southwest coast of Sweden is a vulnerable city to the
accelerated rises in mean sea level. We evaluated using a sea barrage
in the River Göta älv to protect Gothenburg during this century. The
highest sea level was estimated to 2.95 m above the current mean sea
level by 2100. To verify flood protection against such high sea levels,
both barriers have to be closed. To prevent high water level in the
River Göta älv reservoir, the barriers would be open when the sea
level is low. The suggested flood control structures would
successfully protect the city from flooding events during this century.
Abstract: The connection between past travel experience and
tourists’ revisit behavioral intentions has not been widely explored
but the existing studies suggest a close relationship between them.
Destination image can equally be construed as having effects on the
attitudes of the tourists at the end of their actual visitation and the
satisfaction of a tourist with his or her travel experiences contributes
to a revisit intention towards a particular destination. With strong
marketing efforts, UAE is not only considered to be successful in
attracting foreign investors, but is becoming the most popular tourism
destination in the Arab region. UAE is seriously developing its
tourism image and taking serious initiatives to attract new or repeat
visitations from the international tourists. This study empirically
investigates the causal relationships between tourism destination
image, tourist satisfaction and revisit intention using UAE as a
contextual study setting. A very clear picture emerged which
provides a host country with potential implications for its tourism
industry practitioners, Department of Tourism and Commerce
Marketing and the travel agencies who act as the intermediaries
between the potential tourists and the hotel operators.
Abstract: We introduced an all-optical multicasting
characteristics with wavelength conversion based on a novel
all-optical triode using negative feedback semiconductor optical
amplifier. This study was demonstrated with a transfer speed of 10
Gb/s to a non-return zero 231-1 pseudorandom bit sequence system.
This multi-wavelength converter device can simultaneously provide
three channels of output signal with the support of non-inverted and
inverted conversion. We studied that an all-optical multicasting and
wavelength conversion accomplishing cross gain modulation is
effective in a semiconductor optical amplifier which is effective to
provide an inverted conversion thus negative feedback. The
relationship of received power of back to back signal and output
signals with wavelength 1535 nm, 1540 nm, 1545 nm, 1550 nm, and
1555 nm with bit error rate was investigated. It was reported that the
output signal wavelengths were successfully converted and modulated
with a power penalty of less than 8.7 dB, which the highest is 8.6 dB
while the lowest is 4.4 dB. It was proved that all-optical multicasting
and wavelength conversion using an optical triode with a negative
feedback by three channels at the same time at a speed of 10 Gb/s is a
promising device for the new wavelength conversion technology.
Abstract: Cement-based grouts has been used successfully to
repair cracks in many concrete structures such as bridges, tunnels,
buildings and to consolidate soils or rock foundations. In the present
study the rheological characterization of cement grout with
water/binder ratio (W/B) is fixed at 0.5. The effect of the replacement
of cement by bentonite (2 to 10% wt) in presence of superplasticizer
(0.5% wt) was investigated. Several rheological tests were carried out
by using controlled-stress rheometer equipped with vane geometry in
temperature of 20°C. To highlight the influence of bentonite and
superplasticizer on the rheological behavior of grout cement, various
flow tests in a range of shear rate from 0 to 200 s-1 were observed.
Cement grout showed a non-Newtonian viscosity behavior at all
concentrations of bentonite. Three parameter model Herschel-
Bulkley was chosen for fitting of experimental data. Based on the
values of correlation coefficients of the estimated parameters, The
Herschel-Bulkley law model well described the rheological behavior
of the grouts. Test results showed that the dosage of bentonite
increases the viscosity and yield stress of the system and introduces
more thixotropy. While the addition of both bentonite and
superplasticizer with cement grout improve significantly the fluidity
and reduced the yield stress due to the action of dispersion of SP.
Abstract: There are several methods to monitor software
projects and the objective for monitoring is to ensure that the
software projects are developed and delivered successfully. A
performance measurement is a method that is closely associated with
monitoring and it can be scrutinized by looking at two important
attributes which are efficiency and effectiveness both of which are
factors that are important for the success of a software project.
Consequently, a successful steering is achieved by monitoring and
controlling a software project via the performance measurement
criteria and metrics. Hence, this paper is aimed at identifying the
performance measurement criteria and the metrics for monitoring the
performance of a software project by using the Goal Question
Metrics (GQM) approach. The GQM approach is utilized to ensure
that the identified metrics are reliable and useful. These identified
metrics are useful guidelines for project managers to monitor the
performance of their software projects.