Abstract: The effect of additional magnesium oxide (MgO) was
investigated by using the tungsten oxide supported on silica catalyst
(WOx/SiO2) physically mixed with MgO in a weight ratio 1:1. The
both fresh and spent catalysts were characterized by FT-Raman
spectrometer, UV-Vis spectrometer, X-Ray diffraction (XRD) and
temperature programmed oxidation (TPO). The results indicated that
the additional MgO could enhance the conversion of trans-2-butene
due to isomerization reaction. However, adding MgO would increase
the amount of coke deposit on the WOx/SiO2 catalyst. The TPO
profile presented two peaks when the WOx/SiO2 catalyst was
physically mixed with MgO. The further peak was suggested that
came from coke precursor could be produced by isomerization
reaction of undesired product. Then, the occurred coke precursor
could deposit and form coke on the acid catalyst.
Abstract: Failure of typical seismic frames has been found by
plastic hinge occurring on beams section near column faces. On the
other hand, the seismic capacity of the frames can be enhanced if the
plastic hinges of the beams are shifted away from the column faces.
This paper presents detailing of reinforcements in the interior beam–
column connections aiming to relocate the plastic hinge of reinforced
concrete and precast concrete frames. Four specimens were tested
under quasi-static cyclic load including two monolithic specimens
and two precast specimens. For one monolithic specimen, typical
seismic reinforcement was provided and considered as a reference
specimen named M1. The other reinforced concrete frame M2
contained additional intermediate steel in the connection area
compared with the specimen M1. For the precast specimens,
embedded T-section steels in joint were provided, with and without
diagonal bars in the connection area for specimen P1 and P2,
respectively. The test results indicated the ductile failure with beam
flexural failure in monolithic specimen M1 and the intermediate steel
increased strength and improved joint performance of specimen M2.
For the precast specimens, cracks generated at the end of the steel
inserts. However, slipping of reinforcing steel lapped in top of the
beams was seen before yielding of the main bars leading to the brittle
failure. The diagonal bars in precast specimens P2 improved the
connection stiffness and the energy dissipation capacity.
Abstract: With the growing of computer and network, digital
data can be spread to anywhere in the world quickly. In addition,
digital data can also be copied or tampered easily so that the security
issue becomes an important topic in the protection of digital data.
Digital watermark is a method to protect the ownership of digital data.
Embedding the watermark will influence the quality certainly. In this
paper, Vector Quantization (VQ) is used to embed the watermark into
the image to fulfill the goal of data hiding. This kind of watermarking
is invisible which means that the users will not conscious the existing
of embedded watermark even though the embedded image has tiny
difference compared to the original image. Meanwhile, VQ needs a lot
of computation burden so that we adopt a fast VQ encoding scheme by
partial distortion searching (PDS) and mean approximation scheme to
speed up the data hiding process.
The watermarks we hide to the image could be gray, bi-level and
color images. Texts are also can be regarded as watermark to embed.
In order to test the robustness of the system, we adopt Photoshop to
fulfill sharpen, cropping and altering to check if the extracted
watermark is still recognizable. Experimental results demonstrate that
the proposed system can resist the above three kinds of tampering in
general cases.
Abstract: Ibeno, Nigeria hosts the operational base of Mobil
Producing Nigeria Unlimited (MPNU), a subsidiary of ExxonMobil
and the current highest oil & condensate producer in Nigeria. Besides
MPNU, other oil companies operate onshore, on the continental shelf
and deep offshore of the Atlantic Ocean in Ibeno, Nigeria. This study
was designed to delineate oil polluted sites in Ibeno, Nigeria using
geophysical methods of electrical resistivity (ER) and ground
penetrating radar (GPR). Results obtained revealed that there have
been hydrocarbon contaminations of this environment by past crude
oil spills as observed from high resistivity values and GPR profiles
which clearly show the distribution, thickness and lateral extent of
hydrocarbon contamination as represented on the radargram reflector
tones. Contaminations were of varying degrees, ranging from slight
to high, indicating levels of substantial attenuation of crude oil
contamination over time. Moreover, the display of relatively lower
resistivities of locations outside the impacted areas compared to
resistivity values within the impacted areas and the 3-D Cartesian
images of oil contaminant plume depicted by red, light brown and
magenta for high, low and very low oil impacted areas, respectively
confirmed significant recent pollution of the study area with crude
oil.
Abstract: The seismic risk mitigation from the perspective of
the old buildings stock is truly essential in Algerian urban areas,
particularly those located in seismic prone regions, such as Annaba
city, and which the old buildings present high levels of degradation
associated with no seismic strengthening and/or rehabilitation
concerns. In this sense, the present paper approaches the issue of the
seismic vulnerability assessment of old masonry building stocks
through the adaptation of a simplified methodology developed for a
European context area similar to that of Annaba city, Algeria.
Therefore, this method is used for the first level of seismic
vulnerability assessment of the masonry buildings stock of the old
city center of Annaba. This methodology is based on a vulnerability
index that is suitable for the evaluation of damage and for the
creation of large-scale loss scenarios. Over 380 buildings were
evaluated in accordance with the referred methodology and the
results obtained were then integrated into a Geographical Information
System (GIS) tool. Such results can be used by the Annaba city
council for supporting management decisions, based on a global view
of the site under analysis, which led to more accurate and faster
decisions for the risk mitigation strategies and rehabilitation plans.
Abstract: Testamentary succession rules in the Russian
Federation have been developing intensively since the collapse of the
Soviet Union. The article analyzes specific aspects of the closed will
in Russian civil law. It discusses advantages and drawbacks of the
closed will. In addition to that, the paper focuses on the will drafting
and attestation procedures. The research provides ways to improve
and enhance Russian legislation governing the closed will.
Abstract: The present paper presents the discussion of scholars
concerning speech impact, peculiarities of its realization, speech
strategies and techniques in particular. Departing from the viewpoints
of many prominent linguists, the paper suggests that manipulative
argumentation be viewed as a most pervasive speech strategy with a
certain set of techniques which are to be found in modern American
political discourse. The precedence of their occurrence allows us to
regard them as pragmatic patterns of speech impact realization in
effective public speaking.
Abstract: Roadway planning and design is a very complex
process involving five key phases before a project is completed;
planning, project development, final design, right-of-way, and
construction. The planning phase for a new roadway transportation
project is a very critical phase as it greatly affects all latter phases of
the project. A location study is usually performed during the
preliminary planning phase in a new roadway project. The objective
of the location study is to develop alignment alternatives that are cost
efficient considering land acquisition and construction costs. This
paper describes a methodology to develop optimal preliminary
roadway alignments utilizing spatial-data. Four optimization criteria
are taken into consideration; roadway length, land cost, land slope,
and environmental impacts. The basic concept of the methodology is
to convert the proposed project area into a grid, which represents the
search space for an optimal alignment. The aforementioned
optimization criteria are represented in each of the grid’s cells. A
spatial-data optimization technique is utilized to find the optimal
alignment in the search space based on the four optimization criteria.
Two case studies for new roadway projects in Duval County in the
State of Florida are presented to illustrate the methodology. The
optimization output alignments are compared to the proposed Florida
Department of Transportation (FDOT) alignments. The comparison is
based on right-of-way costs for the alignments. For both case studies,
the right-of-way costs for the developed optimal alignments were
found to be significantly lower than the FDOT alignments.
Abstract: The structures obtained with the use of sandwich
technologies combine low weight with high energy absorbing
capacity and load carrying capacity. Hence, there is a growing and
markedly interest in the use of sandwiches with aluminum foam core
because of very good properties such as flexural rigidity and energy
absorption capability. In the current investigation, the static threepoint
bending tests were carried out on the sandwiches with
aluminum foam core and glass fiber reinforced polymer (GFRP)
skins at different values of support span distances aiming the analyses
of their flexural performance. The influence of the core thickness and
the GFRP skin type was reported in terms of peak load and energy
absorption capacity. For this purpose, the skins with two different
types of fabrics which have same thickness value and the aluminum
foam core with two different thicknesses were bonded with a
commercial polyurethane based flexible adhesive in order to combine
the composite sandwich panels. The main results of the bending tests
are: force-displacement curves, peak force values, absorbed energy,
collapse mechanisms and the effect of the support span length and
core thickness. The results of the experimental study showed that the
sandwich with the skins made of S-Glass Woven fabrics and with the
thicker foam core presented higher mechanical values such as load
carrying and energy absorption capacities. The increment of the
support span distance generated the decrease of the mechanical
values for each type of panels, as expected, because of the inverse
proportion between the force and span length. The most common
failure types of the sandwiches are debonding of the lower skin and
the core shear. The obtained results have particular importance for
applications that require lightweight structures with a high capacity
of energy dissipation, such as the transport industry (automotive,
aerospace, shipbuilding and marine industry), where the problems of
collision and crash have increased in the last years.
Abstract: The article presents two mathematical models of the
interaction between a rotating shaft and an incompressible fluid. The
mathematical model includes both the journal bearings and the
axially traversed hydrodynamic sealing gaps of hydraulic machines.
A method is shown for the identification of additional effects of the
fluid acting on the rotor of the machine, both for a linear and a nonlinear
model. The interaction is expressed by matrices of mass,
stiffness and damping.
Abstract: One of the main challenges in using the Discrete
Element Method (DEM) is to specify the correct input parameter
values. In general, the models are sensitive to the input parameter
values and accurate results can only be achieved if the correct values
are specified. For the linear contact model, micro-parameters such as
the particle density, stiffness, coefficient of friction, as well as the
particle size and shape distributions are required. There is a need for
a procedure to accurately calibrate these parameters before any
attempt can be made to accurately model a complete bulk materials
handling system. Since DEM is often used to model applications in
the mining and quarrying industries, a calibration procedure was
developed for materials that consist of relatively large (up to 40 mm
in size) particles. A coarse crushed aggregate was used as the test
material. Using a specially designed large shear box with a diameter
of 590 mm, the confined Young’s modulus (bulk stiffness) and
internal friction angle of the material were measured by means of the
confined compression test and the direct shear test respectively. DEM
models of the experimental setup were developed and the input
parameter values were varied iteratively until a close correlation
between the experimental and numerical results was achieved. The
calibration process was validated by modelling the pull-out of an
anchor from a bed of material. The model results compared well with
experimental measurement.
Abstract: In this paper, an analytical simplified method for
calculating elasto-plastic stresses strains of notched bodies subject to
non-proportional loading paths is discussed. The method was based
on the Neuber notch correction, which relates the incremental elastic
and elastic-plastic strain energy densities at the notch root and the
material constitutive relationship. The validity of the method was
presented by comparing computed results of the proposed model
against finite element numerical data of notched shaft. The
comparison showed that the model estimated notch-root elasto-plastic
stresses strains with good accuracy using linear-elastic stresses. The
prosed model provides more efficient and simple analysis method
preferable to expensive experimental component tests and more
complex and time consuming incremental non-linear FE analysis.
The model is particularly suitable to perform fatigue life and fatigue
damage estimates of notched components subjected to nonproportional
loading paths.
Abstract: This paper investigates the benefits of deliberately
unbalancing both operation time means (MTs) and unreliability
(failure and repair rates) for non-automated production lines. The
lines were simulated with various line lengths, buffer capacities,
degrees of imbalance and patterns of MT and unreliability imbalance.
Data on two performance measures, namely throughput (TR) and
average buffer level (ABL) were gathered, analyzed and compared to
a balanced line counterpart. A number of conclusions were made
with respect to the ranking of configurations, as well as to the
relationships among the independent design parameters and the
dependent variables. It was found that the best configurations are a
balanced line arrangement and a monotone decreasing MT order,
coupled with either a decreasing or a bowl unreliability configuration,
with the first generally resulting in a reduced TR and the second
leading to a lower ABL than those of a balanced line.
Abstract: In today’s rapidly changing and increasingly complex
environment, organizations have relied on their members’ positive
attitude toward their employers. In particular, employees’
organizational commitment (primarily, the affective component) has
been recognized as an essential component of organizational
functioning and success. Hence, identifying the determinants of
affective commitment is one of the most important research issues.
This study tested the influence of leader-member exchange (LMX)
and exchange ideology on employee’s affective commitment. In
addition, the interactive effect of LMX and exchange ideology was
examined. Data from 198 members of the Korean military supports
each of the hypotheses. Lastly, implications for research and directions
for future research are discussed.
Abstract: The strawberry tree (Arbutus unedo L.) is a small tree
or shrub from botanical Ericaceae family that grows spontaneously
nearby the Mediterranean basin and produce edible red fruits. A
traditional processed fruit application, in Mediterranean countries, is
the production of a spirit (known as aguardente de medronho, in
Portugal) obtained from the fermented fruit. The main objective of
our study was to contribute to the knowledge about the influence of
the degree of maturation of fruits in the volatile composition and
quality of arbutus spirit. The major volatiles in the three distillates
fractions (head, heart and tail) obtained from fermentation of two
different fruit maturation levels were quantified by GC-FID analysis
and ANOVA one-way was performed. Additionally, the total
antioxidant capacity and total phenolic compounds of both arbutus
fruit spirits were determined, by ABTS and Folin-Ciocalteau method,
respectively. The methanol concentration is higher (1022.39 g/hL
a.a.) in the spirit made from fruits with highest total soluble solids,
which is a value above the legal limit (1000 g/hL a.a.). Overall, our
study emphasizes, for the first time, the influence of maturation
degree of arbutus fruits in the spirit volatile composition and quality.
Abstract: The coaxial transformer-coupled push-pull circuitry
has been used widely in HF and VHF amplifiers for many decades
without significant changes in the topology of the transformers. Basic
changes over the years concerned the construction and turns ratio of
the transformers as has been imposed upon the newer technologies
active devices demands. The balun transmission line transformers
applied in push-pull amplifiers enable input/output impedance
transformation, but are mainly used to convert the balanced output
into unbalanced and the input unbalanced into balanced. A simple
and affordable alternative solution over the traditional coaxial
transformer is the coreless planar balun. A key advantage over the
traditional approach lies in the high specifications repeatability;
simplifying the amplifier construction requirements as the planar
balun constitutes an integrated part of the PCB copper layout. This
paper presents the performance analysis of a planar LDMOS
MRFE6VP5600 Push-Pull amplifier that enables robust operation in
Band III, DVB-T, DVB-T2 standards but functions equally well in
Band II, for DRM+ new generation transmitters.
Abstract: During the post-Civil War era, the city of Nashville,
Tennessee, had the highest mortality rate in the United States. The
elevated death and disease rates among former slaves were
attributable to lack of quality healthcare. To address the paucity of
healthcare services, Meharry Medical College, an institution with the
mission of educating minority professionals and serving the
underserved population, was established in 1876.
Purpose: The social ecological framework and partial least squares
(PLS) path modeling were used to quantify the impact of
socioeconomic status and adverse health outcome on primary care
professionals serving the disadvantaged community. Thus, the study
results could demonstrate the accomplishment of the College’s
mission of training primary care professionals to serve in underserved
areas.
Methods: Various statistical methods were used to analyze alumni
data from 1975 – 2013. K-means cluster analysis was utilized to
identify individual medical and dental graduates in the cluster groups
of the practice communities (Disadvantaged or Non-disadvantaged
Communities). Discriminant analysis was implemented to verify the
classification accuracy of cluster analysis. The independent t-test was
performed to detect the significant mean differences of respective
clustering and criterion variables. Chi-square test was used to test if
the proportions of primary care and non-primary care specialists are
consistent with those of medical and dental graduates practicing in
the designated community clusters. Finally, the PLS path model was
constructed to explore the construct validity of analytic model by
providing the magnitude effects of socioeconomic status and adverse
health outcome on primary care professionals serving the
disadvantaged community.
Results: Approximately 83% (3,192/3,864) of Meharry Medical
College’s medical and dental graduates from 1975 to 2013 were
practicing in disadvantaged communities. Independent t-test confirmed the content validity of the cluster analysis model. Also, the
PLS path modeling demonstrated that alumni served as primary care
professionals in communities with significantly lower socioeconomic
status and higher adverse health outcome (p < .001). The PLS path
modeling exhibited the meaningful interrelation between primary
care professionals practicing communities and surrounding
environments (socioeconomic statues and adverse health outcome),
which yielded model reliability, validity, and applicability.
Conclusion: This study applied social ecological theory and
analytic modeling approaches to assess the attainment of Meharry
Medical College’s mission of training primary care professionals to
serve in underserved areas, particularly in communities with low
socioeconomic status and high rates of adverse health outcomes. In
summary, the majority of medical and dental graduates from Meharry
Medical College provided primary care services to disadvantaged
communities with low socioeconomic status and high adverse health
outcome, which demonstrated that Meharry Medical College has
fulfilled its mission. The high reliability, validity, and applicability of
this model imply that it could be replicated for comparable
universities and colleges elsewhere.
Abstract: Theory of Mind (ToM) refers to the ability to infer
another’s mental state. With appropriate ToM, one can behave well in
social interactions. A growing body of evidence has demonstrated that
patients with temporal lobe epilepsy (TLE) may damage ToM by
affecting on regions of the underlying neural network of ToM.
However, the question of whether there is cerebral laterality for ToM
functions remains open. This study aimed to examine whether there is
cerebral lateralization for ToM abilities in TLE patients. Sixty-seven
adult TLE patients and 30 matched healthy controls (HC) were
recruited. Patients were classified into right (RTLE), left (LTLE), and
bilateral (BTLE) TLE groups on the basis of a consensus panel review
of their seizure semiology, EEG findings, and brain imaging results.
All participants completed an intellectual test and four tasks measuring
basic and advanced ToM. The results showed that, on all ToM tasks,
(1) each patient group performed worse than HC; (2) there were no
significant differences between LTLE and RTLE groups; and (3) the
BTLE group performed the worst. It appears that the neural network
responsible for ToM is distributed evenly between the cerebral
hemispheres.
Abstract: This work sets out to debate the tensions involved in
the processes of contamination and self-purification in the urban
space, particularly in the streams that run through the Buenos Aires
metropolitan area. For much of their course, those streams are piped;
their waters do not come into contact with the outdoors until they
have reached deeply impoverished urban areas with high levels of
environmental contamination. These are peripheral zones that, until
thirty years ago, were marshlands and fields. They are now densely
populated areas largely lacking in urban infrastructure.
The Cárcova neighborhood, where this project is underway, is in
the José León Suárez section of General San Martín county, Buenos
Aires province. A stretch of José León Suarez canal crosses the
neighborhood. Starting upstream, this canal carries pollutants due to
the sewage and industrial waste released into it. Further downstream,
in the neighborhood, domestic drainage is poured into the stream. In
this paper, we formulate a hypothesis diametrical to the one that
holds that these neighborhoods are the primary source of
contamination, suggesting instead that in the stretch of the canal that
runs through the neighborhood the stream’s waters are actually
cleaned and the sediments accumulate pollutants. Indeed, the
stretches of water that runs through these neighborhoods act as water
processing plants for the metropolis.
This project has studied the different organic-load polluting
contributions to the water in a certain stretch of the canal, the
reduction of that load over the course of the canal, and the
incorporation of pollutants into the sediments. We have found that
the surface water has considerable ability to self-purify, mostly due to
processes of sedimentation and adsorption. The polluting load is
accumulated in the sediments where that load stabilizes slowly by
means of anaerobic processes. In this study, we also investigated the
risks of sediment management and the use of the processes studied
here in controlled conditions as tools of environmental restoration.
Abstract: Quality of Service (QoS) attributes as part of the
service description is an important factor for service attribute. It is not
easy to exactly quantify the weight of each QoS conditions since
human judgments based on their preference causes vagueness. As
web services selection requires optimization, evolutionary computing
based on heuristics to select an optimal solution is adopted. In this
work, the evolutionary computing technique Particle Swarm
Optimization (PSO) is used for selecting a suitable web services
based on the user’s weightage of each QoS values by optimizing the
QoS weight vector and thereby finding the best weight vectors for
best services that is being selected. Finally the results are compared
and analyzed using static inertia weight and deterministic inertia
weight of PSO.