Abstract: In the present work, Electrochemical Impedance
Spectrocopy (EIS) is applied to study the transport of different metal
cations through a cation-exchange membrane. This technique enables
the identification of the ionic-transport characteristics and to
distinguish between different transport mechanisms occurring at
different current density ranges. The impedance spectra are
dependent on the applied dc current density, on the type of cation and
on the concentration.
When the applied dc current density increases, the diameter of the
impedance spectra loops increases because all the components of
membrane system resistance increase. The diameter of the impedance
plots decreases in the order of Na(I), Ni(II) and Cr(III) due to the
increased interactions between the negatively charged sulfonic
groups of the membrane and the cations with greater charge. Nyquist
plots are shifted towards lower values of the real impedance, and its
diameter decreases with the increase of concentration due to the
decrease of the solution resistance.
Abstract: High pressure turbine (HPT) blades of DV – 2 jet
engines are made from Ni – based superalloy. This alloy was
originally manufactured in the Soviet Union and referred as ŽS6K.
For improving alloy’s high temperature resistance are blades coated
with Al – Si diffusion layer. A regular operation temperature of HPT
blades vary from 705°C to 750°C depending on jet engine regime.
An overcrossing working temperature range causes degradation of
the protective coating as well as base material which microstructure
is formed by the gamma matrix and strengthening phase gamma
prime (forming small particles in the microstructure). Diffusion
processes inside the material during exposition of the material to high
temperatures causes mainly coarsening of the gamma prime particles,
thus decreasing its strengthening effect. Degradation of the Al – Si
coating caused its thickness growth. All the microstructure changes
and coating layer thickness growth results in decreasing of the turbine
blade operation lifetime.
Abstract: This paper is part of a study to develop robots for
farming. As such power requirement to operate equipment attach to
such robots become an important factor. Soil-tool interaction plays
major role in power consumption, thus predicting accurately the
forces which act on the blade during the farming is very important for
optimal designing of farm equipment. In this paper, a finite element
investigation for tillage tools and soil interaction is described by
using an inelastic constitutive material law for agriculture
application. A 3-dimensional (3D) nonlinear finite element analysis
(FEA) is developed to examine behavior of a blade with different
rake angles moving in a block of soil, and to estimate the blade force.
The soil model considered is an elastic-plastic with non-associated
Drucker-Prager material model. Special use of contact elements are
employed to consider connection between soil-blade and soil-soil
surfaces. The FEA results are compared with experimental ones,
which show good agreement in accurately predicting draft forces
developed on the blade when it moves through the soil. Also a very
good correlation was obtained between FEA results and analytical
results from classical soil mechanics theories for straight blades.
These comparisons verified the FEA model developed. For analyzing
complicated soil-tool interactions and for optimum design of blades,
this method will be useful.
Abstract: Indonesian higher education has experienced
significant changes over the last decade. In 1999, the government
published an overall strategy for decentralisation and enhancement of
local autonomy in many sectors, including (higher) education.
Indonesian higher education reforms have forced universities to
restructure their internal university governance to become more
entrepreneurial. These new types of internal university governance
are likely to affect the institutions’ leadership and management. This
paper discusses the approach and findings of a study on the
managerial leadership styles of deans in Indonesian universities. The
study aims to get a better understanding of styles exhibited by deans
manifested in their behaviours. Using the theories of reasoned action
and planned behaviour, in combination with the competing values
framework, a large-scale survey was conducted to gather information
on the deans’ behaviours, attitudes, subjective norms, and perceived
behavioural control. Based on the responses of a sample of 218
deans, the study identifies a number of leadership styles: the Master,
the Competitive Consultant, the Consensual Goal-Setter, the Focused
Team Captain, and the Informed Trust-Builder style. The study
demonstrates that attitudes are the primary determinant of the styles
that were found. Perceived behavioural control is a factor that
explains some managerial leadership styles. By understanding the
attitudes of deans in Indonesian universities, and their leadership
styles, universities can strengthen their management and governance,
and thus improve their effectiveness.
Abstract: In the past few years, the amount of malicious software
increased exponentially and, therefore, machine learning algorithms
became instrumental in identifying clean and malware files through
(semi)-automated classification. When working with very large
datasets, the major challenge is to reach both a very high malware
detection rate and a very low false positive rate. Another challenge
is to minimize the time needed for the machine learning algorithm to
do so. This paper presents a comparative study between different
machine learning techniques such as linear classifiers, ensembles,
decision trees or various hybrids thereof. The training dataset consists
of approximately 2 million clean files and 200.000 infected files,
which is a realistic quantitative mixture. The paper investigates the
above mentioned methods with respect to both their performance
(detection rate and false positive rate) and their practicability.
Abstract: The objective of present research paper is to highlight
the importance of measuring advertisement effectiveness in print
media and to develop a conceptual model for advertisement
effectiveness. The developed model is based on dimensions on which
advertisement effectiveness depends and on the dimensions which are
used to measure the effectiveness. An in-depth and extensive
literature review is carried out to understand the concept of
advertisement effectiveness and its various determinants in context of
print media. Based on the insights gained, a conceptual framework
for advertisement effectiveness is presented. The model is an attempt
to uncover the relatively less explored area of advertisement
effectiveness in Indian advertising scenario. It is believed that present
work will encourage scholars and academicians to further explore the
area and will offer conceptual assistance and a fresh direction in the
domain of advertisement effectiveness.
Abstract: Proposed paper dealt with the modelling and analysis of induction motor based on the mathematical expression using the graphical programming environment of Laboratory Virtual Instrument Engineering Workbench (LabVIEW). Induction motor modelling with the mathematical expression enables the motor to be simulated with the various required parameters. Owing to the invention of variable speed drives study about the induction motor characteristics became complex. In this simulation motor internal parameter such as stator resistance and reactance, rotor resistance and reactance, phase voltage, frequency and losses will be given as input. By varying the speed of motor corresponding parameters can be obtained they are input power, output power, efficiency, torque induced, slip and current.
Abstract: Non contact evaluation of the thickness of paint
coatings can be attempted by different destructive and nondestructive
methods such as cross-section microscopy, gravimetric mass
measurement, magnetic gauges, Eddy current, ultrasound or
terahertz. Infrared thermography is a nondestructive and non-invasive
method that can be envisaged as a useful tool to measure the surface
thickness variations by analyzing the temperature response. In this
paper, the thermal quadrupole method for two layered samples heated
up with a pulsed excitation is firstly used. By analyzing the thermal
responses as a function of thermal properties and thicknesses of both
layers, optimal parameters for the excitation source can be identified.
Simulations show that a pulsed excitation with duration of ten
milliseconds allows obtaining a substrate-independent thermal
response. Based on this result, an experimental setup consisting of a
near-infrared laser diode and an Infrared camera was next used to
evaluate the variation of paint coating thickness between 60 μm and
130 μm on two samples. Results show that the parameters extracted
for thermal images are correlated with the estimated thicknesses by
the Eddy current methods. The laser pulsed thermography is thus an
interesting alternative nondestructive method that can be moreover
used for nonconductive substrates.
Abstract: Turkish migrants constitute the largest group among
people with migration background living in Germany. Turkish
women’s labor market participation is of significant importance for
their social and economic integration to the German society. This
paper thus aims to investigate their labor market positions. Turkish
migrant women participate less in the labor market compared to men,
and are responsible for most of the housework, child care, and elderly
care. This is due to their traditional roles in the family, educational
level, insufficient knowledge of German language, and insufficient
professional experience. We strongly recommend that wide-reaching
integration policies for women are formulated, so as to encourage
participation of not only migrant women but also their husbands,
fathers and/or brothers, and natives.
Abstract: Rainfall runoff models play important role in
hydrological predictions. However, the model is only one part of the
process for creation of flood prediction. The aim of this paper is to
show the process of successful prediction for flood event (May 15 –
May 18 2014). Prediction was performed by rainfall runoff model
HEC–HMS, one of the models computed within Floreon+ system.
The paper briefly evaluates the results of automatic hydrologic
prediction on the river Olše catchment and its gages Český Těšín and
Věřňovice.
Abstract: The aims of this study were to determine the factor
structure and psychometric properties (i.e., reliability and convergent
validity) of the Malaysian Multi-Ethnic Discrimination Scale
(MMEDS). It consists of 71-items measure experience, strategies
used and consequences of ethnic discrimination. A sample of 649
university students from one of the higher education institution in
Malaysia was asked to complete MMEDS, as well as Perceived
Ethnic and Racial Discrimination. The exploratory factor analysis on
ethnic discrimination experience extracted two factors labeled ‘unfair
treatment’ (15 items) and ‘Denial of the ethnic right’ (12 items)
which accounted for 60.92% of the total variance. The two sub scales
demonstrated clear reliability with internal consistency above .70.
The convergent validity of the Scale was supported by an expected
pattern of correlations (positive and significant correlation) between
the score of unfair treatment and denial of the ethnic right and the
score of Perceived Ethnic and Racial Discrimination by Peers Scale.
The results suggest that the MMEDS is a reliable and valid measure.
However, further studies need to be carried out in other groups of
sample as to validate the Scale.
Abstract: PhilSHORE is a multi-site, multi-device and multicriteria
decision support tool designed to support the development of
tidal current energy in the Philippines. Its platform is based on
Geographic Information Systems (GIS) which allows for the
collection, storage, processing, analyses and display of geospatial
data. Combining GIS tools with open source web development
applications, PhilSHORE becomes a webGIS-based marine spatial
planning tool. To date, PhilSHORE displays output maps and graphs
of power and energy density, site suitability and site-device analysis.
It enables stakeholders and the public easy access to the results of
tidal current energy resource assessments and site suitability
analyses. Results of the initial development show that PhilSHORE is
a promising decision support tool for ORE project developments.
Abstract: Coal is an important non-renewable energy source of
and can be associated with radioactive elements. In Figueira city,
Paraná state, Brazil, it was recorded high uranium activity near the
coal mine that supplies a local thermoelectric power plant. In this
context, the radon activity (Rn-222, produced by the Ra-226 decay in
the U-238 natural series) was evaluated in groundwater, river water
and effluents produced from the acid mine drainage in the coal reject
dumps. The samples were collected in August 2013 and in February
2014 and analyzed at LABIDRO (Laboratory of Isotope and
Hydrochemistry), UNESP, Rio Claro city, Brazil, using an alpha
spectrometer (AlphaGuard) adjusted to evaluate the mean radon
activity concentration in five cycles of 10 minutes. No radon activity
concentration above 100 Bq.L-1, which was a previous critic value
established by the World Health Organization. The average radon
activity concentration in groundwater was higher than in surface
water and in effluent samples, possibly due to the accumulation of
uranium and radium in the aquifer layers that favors the radon
trapping. The lower value in the river waters can indicate dilution and
the intermediate value in the effluents may indicate radon absorption
in the coal particles of the reject dumps. The results also indicate that
the radon activities in the effluents increase with the sample
acidification, possibly due to the higher radium leaching and the
subsequent radon transport to the drainage flow. The water samples
of Laranjinha River and Ribeirão das Pedras stream, which,
respectively, supply Figueira city and receive the mining effluent,
exhibited higher pH values upstream the mine, reflecting the acid
mine drainage discharge. The radionuclides transport indicates the
importance of monitoring their activity concentration in natural
waters due to the risks that the radioactivity can represent to human
health.
Abstract: Fly ash (FA) thanks to the significant presence of SiO2
and Al2O3 as the main components is a potential raw material for
geopolymers production. Mechanical activation is a method for
improving FA reactivity and also the porosity of final mixture; those
parameters can be analysed through sorption properties. They have
direct impact on the durability of fly ash based geopolymer mortars.
In the paper, effect of FA fineness on sorption properties of
geopolymers based on sodium silicate, as well as relationship
between fly ash fineness and apparent density, compressive and
flexural strength of geopolymers are presented. The best results in the
evaluated area reached the sample H1, which contents the highest
portion of particle under 20μm (100% of GFA). The interdependence
of individual tested properties was confirmed for geopolymer
mixtures corresponding to those in the cement based mixtures: higher
is portion of fine particles < 20μm, higher is strength, density and
lower are sorption properties. The compressive strength as well as
sorption parameters of the geopolymer can be reasonably controlled
by grinding process and also ensured by the higher share of fine
particle (to 20μm) in total mass of the material.
Abstract: Coal fly ash is formed as a solid waste product from
the combustion of coal in coal fired power stations. Huge amounts of
fly ash are produced globally every year and are predicted to
increase. Nowadays, less than half of the fly ash is used as a raw
material for cement manufacturing, construction and the rest of it is
disposed as a waste causing yet another environmental concern. For
this reason, the recycling of this kind of slurries into useful materials
is quite important in terms of economical and environmental aspects.
The purpose of this study is to evaluate the Orhaneli and
Tuncbilek coal fly ashes for utilization in some industrial
applications. Therefore the mineralogical and chemical compositions
of these fly ashes were analyzed by X-ray fluorescence spectroscopy,
ourier-transform infrared spectrometer, and X-ray diffraction. The
silicon (Si) and aluminum (Al) in the fly ashes were activated by
alkali fusion technique with sodium hydroxide. The obtained extracts
were analyzed for Si and Al content by inductively coupled plasma
optical emission spectrometry.
Abstract: In this study, out-of-plane free vibrations of a circular
rods is investigated theoretically. The governing equations for
naturally twisted and curved spatial rods are obtained using
Timoshenko beam theory and rewritten for circular rods. Effects of
the axial and shear deformations are considered in the formulations.
Ordinary differential equations in scalar form are solved analytically
by using transfer matrix method. The circular rods of the mass matrix
are obtained by using straight rod of consistent mass matrix. Free
vibrations frequencies obtained by solving eigenvalue problem. A
computer program coded in MATHEMATICA language is prepared.
Circular beams are analyzed through various examples for free
vibrations analysis. Results are compared with ANSYS results based
on finite element method and available in the literature.
Abstract: This study was carried out to investigate the adverse
effect of industrial wastewater on surface water quality in Gebeng
industrial estate, Pahang, Malaysia. Surface water was collected from
six sampling stations. Physicochemical parameters were
characterized based on in-situ and ex-situ analysis according to
standard methods by American Public Health Association (APHA).
Selected heavy metals were determined by using Inductively Coupled
Plasma Mass Spectrometry (ICP MS). The results revealed that the
concentration of heavy metals such as Pb, Cu, Cd, Cr and Hg were
high in samples. The results also showed that the value of Pb and Hg
were higher in the wet season in comparison to dry season.
According to Malaysia National Water Quality Standard (NWQS)
and Water Quality Index (WQI) all the sampling station were
categorized as class IV (highly polluted). The present study revealed
that the adverse effects of careless disposal of wastes and directly
discharge of effluents affected on surface water quality. Therefore,
the authorities should implement the laws to ensure the proper
practices of wastewater management for environmental sustainability
around the study area.
Abstract: The Aptima® HIV-1 Quant Dx Assay is a fully
automated assay on the Panther system. It is based on Transcription-
Mediated Amplification and real time detection technologies. This
assay is intended for monitoring HIV-1 viral load in plasma
specimens and for the detection of HIV-1 in plasma and serum
specimens.
Nine-hundred and seventy nine specimens selected at random
from routine testing at St Thomas’ Hospital, London were
anonymised and used to compare the performance of the Aptima
HIV-1 Quant Dx assay and Roche COBAS® AmpliPrep/COBAS®
TaqMan® HIV-1 Test, v2.0. Two-hundred and thirty four specimens
gave quantitative HIV-1 viral load results in both assays. The
quantitative results reported by the Aptima Assay were comparable to
those reported by the Roche COBAS AmpliPrep/COBAS TaqMan
HIV-1 Test, v2.0 with a linear regression slope of 1.04 and an
intercept on -0.097.
The Aptima assay detected HIV-1 in more samples than the
COBAS assay. This was not due to lack of specificity of the Aptima
assay because this assay gave 99.83% specificity on testing plasma
specimens from 600 HIV-1 negative individuals. To understand the
reason for this higher detection rate a side-by-side comparison of low
level panels made from the HIV-1 3rd international standard
(NIBSC10/152) and clinical samples of various subtypes were tested
in both assays. The Aptima assay was more sensitive than the
COBAS assay.
The good sensitivity, specificity and agreement with other
commercial assays make the HIV-1 Quant Dx Assay appropriate for
both viral load monitoring and detection of HIV-1 infections.
Abstract: 600 schools going adolescents and 100 teachers from
16 schools of Dhemaji and Lakhimpur district of Assam, India were
surveyed to assess and compare their awareness regarding AIDS and
AIDS Education. An awareness test was administered containing 38
items for adolescents and 40 items for teachers in the test.
Observations revealed that the majority of school-going adolescents
are poor in their HIV/AIDS and AIDS education awareness. It shows
that the school going adolescents of Dhemaji district are better in
HIV/AIDS and AIDS education awareness than the school going
adolescents of Lakhimpur district while comparing the gender,
settlement, steam and district wise variables.
Abstract: Introduction: Researchers globally have strived to explore diverse factors that augment the continuation and uptake of family planning methods. Clients’ satisfaction is one of the core determinants facilitating continuation of family planning methods. There is a major debate yet scanty evidence to contrast public and private sectors with respect to client satisfaction. The objective of this study is to compare quality-of-care provided by public and private sectors of Pakistan through a client satisfaction lens. Methods: We used Pakistan Demographic Heath Survey 2012-13 dataset on 3133 women. Ten different multivariate models were made. to explore the relationship between client satisfaction and dependent outcome after adjusting for all known confounding factors and results are presented as OR and AOR (95% CI). Results: Multivariate analyses showed that clients were less satisfied in contraceptive provision from private sector as compared to public sector (AOR 0.92, 95% CI 0.63-1.68) even though the result was not statistically significant. Clients were more satisfied from private sector as compared to the public sector with respect to other determinants of quality-of-care follow-up care (AOR 3.29, 95% CI 1.95-5.55), infection prevention (AOR 2.41, 95% CI 1.60-3.62), counseling services (AOR 2.01, 95% CI 1.27-3.18, timely treatment (AOR 3.37, 95% CI 2.20-5.15), attitude of staff (AOR 2.23, 95% CI 1.50-3.33), punctuality of staff (AOR 2.28, 95% CI 1.92-4.13), timely referring (AOR 2.34, 95% CI 1.63-3.35), staff cooperation (AOR 1.75, 95% CI 1.22-2.51) and complications handling (AOR 2.27, 95% CI 1.56-3.29). Discussion: Public sector has successfully attained substantial satisfaction levels with respect to provision of contraceptives, but it contrasts previous literature from a multi country studies. Our study though in is concordance with a study from Tanzania where public sector was more likely to offer family planning services to clients as compared to private facilities. Conclusion: In majority of the developing countries, public sector is more involved in FP service provision; however, in Pakistan clients’ satisfaction in private sector is more, which opens doors for public-private partnerships and collaboration in the near future.