Abstract: The biosynthesis of nanoparticles by microorganisms,
on the contrary to chemical synthesis, is an environmentally-friendly
process which has low energy requirements. In this investigation, we
used the microorganism Geobacillus wiegelii, strain GWE1, an
aerobic thermophile belonging to genus Geobacillus, isolated from a
drying oven. This microorganism has the ability to reduce selenite
evidenced by the change of color from colorless to red in the culture.
Elemental analysis and composition of the particles were verified
using transmission electron microscopy and energy-dispersive X-ray
analysis. The nanoparticles have a defined spherical shape and a
selenium elemental state. Previous experiments showed that the
presence of the whole microorganism for the reduction of selenite
was not necessary. The results strongly suggested that an intracellular
NADPH/NADH-dependent reductase mediates selenium
nanoparticles synthesis under aerobic conditions. The enzyme was
purified and identified by mass spectroscopy MALDI-TOF TOF
technique. The enzyme is a 1-pyrroline-5-carboxylate dehydrogenase.
Histograms of nanoparticles sizes were obtained. Size distribution
ranged from 40-160 nm, where 70% of nanoparticles have less than
100 nm in size. Spectroscopic analysis showed that the nanoparticles
are composed of elemental selenium. To analyse the effect of pH in
size and morphology of nanoparticles, the synthesis of them was
carried out at different pHs (4.0, 5.0, 6.0, 7.0, 8.0). For
thermostability studies samples were incubated at different
temperatures (60, 80 and 100 ºC) for 1 h and 3 h. The size of all
nanoparticles was less than 100 nm at pH 4.0; over 50% of
nanoparticles have less than 100 nm at pH 5.0; at pH 6.0 and 8.0 over
90% of nanoparticles have less than 100 nm in size. At neutral pH
(7.0) nanoparticles reach a size around 120 nm and only 20% of them
were less than 100 nm. When looking at temperature effect,
nanoparticles did not show a significant difference in size when they
were incubated between 0 and 3 h at 60 ºC. Meanwhile at 80 °C the
nanoparticles suspension lost its homogeneity. A change in size was
observed from 0 h of incubation at 80ºC, observing a size range
between 40-160 nm, with 20% of them over 100 nm. Meanwhile
after 3 h of incubation at size range changed to 60-180 nm with 50%
of them over 100 nm. At 100 °C the nanoparticles aggregate forming
nanorod structures. In conclusion, these results indicate that is
possible to modulate size and shape of biologically synthesized
nanoparticles by modulating pH and temperature.
Abstract: In this paper it was examined the influence of margin
regulation on stock market volatility in EU 1993 – 2014. Regulating
margin requirements or haircuts for securities financing transactions
has for a long time been considered as a potential tool to limit the
build-up of leverage and dampen volatility in financial markets. The
margin requirement dictates how much investors can borrow against
these securities. Margin can be an important part of investment.
Using daily and monthly stock returns and there is no convincing
evidence that EU Regulation margin requirements have served to
dampen stock market volatility. In this paper was detected the
expected negative relation between margin requirements and the
amount of margin credit outstanding. Also, it confirmed that changes
in margin requirements by the EU regulation have tended to follow
than lead changes in market volatility. For the analysis have been
used the modified Levene statistics to test whether the standard
deviation of stock returns in the 25, 50 and 100 days preceding
margin changes is the same as that in the succeeding 25, 50 and 100
days. The analysis started in May 1993 when it was first empowered
to set the initial margin requirement and the last sample was in May
2014. To test whether margin requirements influence stock market
volatility over the long term, the sample of stock returns was divided
into 14 periods, according to the 14 changes in margin requirements.
Abstract: Objective of this study is to explore the recent trends,
patterns and the structural changes in the labour migration from Sri
Lanka to Middle East countries and to discuss the possible impacts of
those changes on the remittance flow. Study uses secondary data
published by Sri Lanka Bureau of Foreign Employment and Central
Bank. Thematic analysis of the secondary data revealed that the
migration for labour has increased rapidly during past decades.
Parallel with that the gender and the skill composition of the
migration flow has been changing. Similarly, the destinations for
male migration have changed over the period. These show positive
implications on the international remittance receipts to the country.
Abstract: Magnetic powder of Sr-ferrite was prepared by
conventional and sol-gel auto-combustion methods. In conventional
method, strontium carbonate and ferric oxide powders were mixed
together and then mixture was calcined. In sol-gel auto-combustion
method, a solution containing strontium nitrate, ferric nitrate and
citric acid was heated until the combustion took place automatically;
then, as-burnt powder was calcined. Thermal behavior, phase
identification, morphology and magnetic properties of powders
obtained by these two methods were compared by DTA, XRD, SEM
and VSM techniques. According to the results of DTA analysis,
formation temperature of Sr-ferrite obtained by conventional and solgel
auto-combustion methods were 1300°C and 1000°C, respectively.
XRD results confirmed the formation of pure Sr-ferrite at the
mentioned temperatures. Plate and hexagonal-shape particles of Srferrite
were observed using SEM. The Sr-ferrite powder obtained by
sol-gel auto-combustion method had saturation magnetization of
66.03 emu/g and coercivity of 5731 Oe in comparison with values of
58.20 emu/g and 4378 Oe obtained by conventional method.
Abstract: A series of polystyrene (PS) nanoparticles were
prepared by grafting polystyrene from both aggregated silica and
colloidally dispersed silica nanoparticles using atom-transfer radical
polymerisation (ATRP). Cross-linking and macroscopic gelation
were minimised by using a miniemulsion system. The thermal and
mechanical behaviour of the nanocomposites have been examined by
differential scanning calorimetry (DSC) and dynamic mechanical
thermal analysis (DMTA).
Abstract: Heightened concerns over the amount of carbon
emitted from coal-related processes are generating shifts to the
application of biomass. In co-gasification, where coal is gasified
along with biomass, the biomass may be fed together with coal (cofeeding)
or an independent biomass gasifier needs to be integrated
with the coal gasifier. The main aim of this work is to evaluate the
biomass introduction methods in coal co-gasification. This includes
the evaluation of biomass concentration input (B0 to B100) and its
gasification performance. A process model is developed and
simulated in Aspen HYSYS, where both coal and biomass are
modelled according to its ultimate analysis. It was found that the
syngas produced increased with increasing biomass content for both
co-feeding and independent schemes. However, the heating values
and heat duties decreases with biomass concentration as more CO2
are produced from complete combustion.
Abstract: South Africa has some regions which are susceptible
to moderate seismic activity. A peak ground acceleration of between
0.1g and 0.15g can be expected in the southern parts of the Western
Cape. Unreinforced Masonry (URM) is commonly used as a
construction material for 2 to 5 storey buildings in underprivileged
areas in and around Cape Town. URM is typically regarded as the
material most vulnerable to damage when subjected to earthquake
excitation. In this study, a three-storey URM building was analysed
by applying seven earthquake time-histories, which can be expected
to occur in South Africa using a finite element approach.
Experimental data was used to calibrate the in- and out-of-plane
stiffness of the URM. The results indicated that tensile cracking of
the in-plane piers was the dominant failure mode. It is concluded that
URM buildings of this type are at risk of failure especially if
sufficient ductility is not provided. The results also showed that
connection failure must be investigated further.
Abstract: Electricity is recognized as fundamental to
industrialization and improving the quality of life of the people.
Harnessing the immense untapped hydropower potential in Tripura
region opens avenues for growth and provides an opportunity to
improve the well-being of the people of the region, while making
substantial contribution to the national economy. Gumti hydro power
plant generates power to mitigate the crisis of power in Tripura,
India. The first unit of hydro power plant (5MW) was commissioned
in June 1976 & another two units of 5 MW was commissioned
simultaneously. But out of 15MW capacity at present only 8MW-
9MW power is produced from Gumti hydro power plant during rainy
season. But during lean season the production reduces to 0.5MW due
to shortage of water. Now, it is essential to implement some
mitigation measures so that the further atrocities can be prevented
and originality will be possible to restore. The decision making
ability of the Analytic Hierarchy Process (AHP) and Concordance
Analysis Techniques (CAT) are utilized to identify the better decision
or solution to the present problem. Some related attributes are
identified by the method of surveying within the experts and the
available reports and literatures. Similar criteria are removed and
ultimately seven relevant ones are identified. All the attributes are
compared with each other and rated accordingly to their importance
over the other with the help of Pair wise Comparison Matrix. In the
present investigation different mitigation measures are identified and
compared to find the best suitable alternative which can solve the
present uncertainties involving the existence of the Gumti Hydro
Power Plant.
Abstract: The thermo-mechanical behaviour of concrete energy
pile foundations with different single and double U-tube shapes
incorporated was analysed using the Comsol Multi-physics package.
For the analysis, a 3D numerical model in real scale of the concrete
pile and surrounding soil was simulated regarding actual operation of
ground heat exchangers (GHE) and the surrounding ambient
temperature. Based on initial ground temperature profile measured in
situ, tube inlet temperature was considered to range from 6oC to 0oC
(during the contraction process) over a 30-day period. Extra thermal
stresses and deformations were calculated during the simulations and
differences arising from the use of two different systems (single-tube
and double-tube) were analysed. The results revealed no significant
difference for extra thermal stresses at the centre of the pile in either
system. However, displacements over the pile length were found to
be up to 1.5-fold higher in the double-tube system than the singletube
system.
Abstract: This paper discusses about the findings of preliminary
survey on MATLAB software learning among power electronics
students. One of the main focuses of power electronics course is on
DC to DC boost convertors, because boost convertors are generally
used in different industrial and non industrial applications. Population
samples of this study were randomly selected final year bachelor of
electronics and electrical engineering students from University Tun
Hussein Onn Malaysia (UTHM).As per the results from the survey
questioner analysis, almost eighty percent students are facing
problem and difficulties in Dc to Dc boost convertors experimental
understanding without using MATLAB simulink package. As per
finding of this study it is clear that MATLAB play an effective and
efficient function for better understanding of boost convertors
experimental work among power electronics learners.
Abstract: This paper explains about the voltage output for DC to
DC boost converter between open loop, PID controller and fuzzy
logic controller through Matlab Simulink. Simulink input voltage was
set at 12V and the voltage reference was set at 24V. The analysis on
the deviation of voltage resulted that the difference between reference
voltage setting and the output voltage is always lower. Comparison
between open loop, PID and FLC shows that, the open loop circuit
having a bit higher on the deviation of voltage. The PID circuit
boosts for FLC has a lesser deviation of voltage and proved that it is
such a better performance on control the deviation of voltage during
the boost mode.
Abstract: There are pending discussions over the mapping of
country export potential in order to refocus export strategy of firms
and its evidence-based promotion by the Export Credit Agencies
(ECAs) and other permitted vehicles of governments.
In this paper we develop our version of an applied model that
offers “stepwise” elimination of unattractive markets. We modify and
calibrate the model for the particular features of the Czech Republic
and specific pilot cases where we apply an individual approach to
each sector.
Abstract: This study offers a comprehensive review of the
research papers published in the field of cooling towers and gives an
insight into the latest developments of the natural draught cooling
towers. Different modeling, analysis and design techniques are
summarized and the challenges are discussed. The 118 references
included in this paper are mostly concentrated on the review of the
published papers after 2005. The present paper represents a complete
collection of the studies done for cooling towers and would give an
updated material for the researchers and design engineers in the field
of hyperbolic cooling towers.
Abstract: The use of information and communication
technologies such as computers, mobile phones and the Internet is
becoming prevalent in today’s world; and it is facilitating access to a
vast amount of data, services and applications for the improvement of
people’s lives. However, this prevalence of ICTs is hampered by the
problem of low income levels in developing countries to the point
where people cannot timeously replace or repair their ICT devices
when damaged or lost; and this problem serves as a motivation for
this study whose aim is to examine the perceptions of teachers on the
reliability of cellphones when used for teaching and learning
purposes. The research objectives unfolding this aim are of two
types: Objectives on the selection and design of theories and models,
and objectives on the empirical testing of these theories and models.
The first type of objectives is achieved using content analysis in an
extensive literature survey: and the second type of objectives is
achieved through a survey of high school teachers from the ILembe
and UMgungundlovu districts in the KwaZulu-Natal province of
South Africa. Data collected from this questionnaire based survey is
analysed in SPSS using descriptive statistics and Pearson correlations
after checking the reliability and validity of the questionnaires. The
main hypothesis driving this study is that there is a relationship
between the demographics and the attribution identity of teachers on
one hand, and their perceptions on the reliability of cellphones on the
other hand, as suggested by existing literature; except that attribution
identities are considered in this study under three angles: intention,
knowledge and ability, and action. The results of this study confirm
that the perceptions of teachers on the reliability of cellphones for
teaching and learning are affected by the school location of these
teachers, and by their perceptions on learners’ cellphones usage
intentions and actual use.
Abstract: At-site flood frequency analysis is used to estimate
flood quantiles when at-site record length is reasonably long. In
Australia, FLIKE software has been introduced for at-site flood
frequency analysis. The advantage of FLIKE is that, for a given
application, the user can compare a number of most commonly
adopted probability distributions and parameter estimation methods
relatively quickly using a windows interface. The new version of
FLIKE has been incorporated with the multiple Grubbs and Beck test
which can identify multiple numbers of potentially influential low
flows. This paper presents a case study considering six catchments in
eastern Australia which compares two outlier identification tests
(original Grubbs and Beck test and multiple Grubbs and Beck test)
and two commonly applied probability distributions (Generalized
Extreme Value (GEV) and Log Pearson type 3 (LP3)) using FLIKE
software. It has been found that the multiple Grubbs and Beck test
when used with LP3 distribution provides more accurate flood
quantile estimates than when LP3 distribution is used with the
original Grubbs and Beck test. Between these two methods, the
differences in flood quantile estimates have been found to be up to
61% for the six study catchments. It has also been found that GEV
distribution (with L moments) and LP3 distribution with the multiple
Grubbs and Beck test provide quite similar results in most of the
cases; however, a difference up to 38% has been noted for flood
quantiles for annual exceedance probability (AEP) of 1 in 100 for one
catchment. This finding needs to be confirmed with a greater number
of stations across other Australian states.
Abstract: An investigation into the effect of countersunk depth,
plate thickness, countersunk angle and plate width on the stress
concentration around countersunk hole is carried out with the help of
finite element analysis. The variation of stress concentration with
respect to these parameters is studied for three types of loading viz.
uniformly distributed load, uniformly varying load and functionally
distributed load. The results of the finite element analysis are
interpreted and some conclusions are drawn. The distribution of
stress concentration around countersunk hole in isotropic plates
simply supported at all the edges is found similar and is independent
of loading. The maximum stress concentration also occurs at a
particular point irrespective of the loading conditions.
Abstract: Self-service technologies (SSTs) make an important
contribution to the daily life of people nowadays. However, the
introduction of SST does not lead to its usage. Thereby, this paper
was an attempt on discovery of the most preferred SST in the
customers’ point of view. To fulfill this aim, the Analytical Hierarchy
Process (AHP) was applied based on Saaty’s questionnaire which
was administered to the customers of e-banking services located in
Golestan providence, northern Iran. This study used qualitative
factors in association with the intention of consumers’ usage of SSTs
to rank three SSTs: ATM, mobile banking and internet banking. The
results showed that mobile banking get the highest weight in
consumers’ point of view. This research can be useful both for
managers and service providers and also for customers who intend to
use e-banking.
Abstract: This paper is drawn from a wider study of the
management of gender, age and disability diversity in the banking
sector in the Kingdom of Saudi Arabia (KSA), which aims to develop
a framework for diversity management (DM) in this sector. The
paper focuses on the management of disability diversity. The purpose
of the paper is to assist in understanding disability DM in the banking
sector in KSA and to make suggestions for its enhancement. Hence, it
contributes to filling a research gap, as there is a dearth of literature
on disability DM, in KSA in general, and in the banking sector
specifically.
Discrimination against people with disabilities is a social issue that
has not been entirely overcome in any society. However, in KSA,
Islam informs almost every aspect of daily life including work, and
Islam is against discrimination. Hence, in KSA, there are regulations
to accommodate people with disabilities; however, employers are still
free not to hire job applicants with disabilities specifically because of
their condition. Indeed, disabled people are almost entirely absent
from the labour market.
There are 12 Saudi-owned or part-Saudi-owned banks in KSA and
two managers from each of these were interviewed, making a total of
24. The interviews aimed to investigate empirically the understanding
of managers in the banking sector in KSA of diversity management,
including disability DM, in the banking sector. The interview data
were analysed using thematic analysis. Two interviewees stated that
banks used the employment of people with disabilities to enhance
their corporate image, while five expressed the opinion that disabled
employees could contribute to the bank provided they did not have to
deal with customers face-to-face. Nine of the interviewees perceived
that disabled employees could be of value to the bank for their own
sake, not only in ‘behind the scenes’ roles. Another two interviewees
mentioned that employing disabled people could be part of the bank’s
community service programme and one thought it would be part of
the bank’s Saudisation efforts. The remaining five interviewees did
not know how disabled people could contribute to the bank.
The findings show that disability DM in the banking sector in
KSA is a relatively new concept, and is not yet well understood. In
the light of the findings, in order to achieve the purpose of the paper,
the following suggestions were made for the enhancement of
disability DM in the banking sector in KSA. A change in attitudes
towards disabled people is necessary. Such a change in the workplace
can only be achieved if a top-down approach is taken to the
integration of disabled people. Hence, it is suggested that
management and employees follow a course in disability awareness.
Further, a diversity officer in the HR department could enhance the
integration of disabled people into the banking workforce. It is also
suggested that greater government support is required through closely
monitored and enforced anti-discrimination legislation. Moreover,
flexible working arrangements such as part-time work would
facilitate the employment of disabled people and benefit other groups
of employees.
Abstract: The substantial similarity of fatigue mechanism in a
new test rig for rolling contact fatigue (RCF) has been investigated. A
new reduced-scale test rig is designed to perform controlled RCF
tests in wheel-rail materials. The fatigue mechanism of the rig is
evaluated in this study using a combined finite element-fatigue
prediction approach. The influences of loading conditions on fatigue
crack initiation have been studied. Furthermore, the effects of some
artificial defects (squat-shape) on fatigue lives are examined. To
simulate the vehicle-track interaction by means of the test rig, a threedimensional
finite element (FE) model is built up. The nonlinear
material behaviour of the rail steel is modelled in the contact
interface. The results of FE simulations are combined with the critical
plane concept to determine the material points with the greatest
possibility of fatigue failure. Based on the stress-strain responses, by
employing of previously postulated criteria for fatigue crack initiation
(plastic shakedown and ratchetting), fatigue life analysis is carried
out. The results are reported for various loading conditions and
different defect sizes. Afterward, the cyclic mechanism of the test rig
is evaluated from the operational viewpoint. The results of fatigue
life predictions are compared with the expected number of cycles of
the test rig by its cyclic nature. Finally, the estimative duration of the
experiments until fatigue crack initiation is roughly determined.
Abstract: A new small–scale test rig developed for rolling
contact fatigue (RCF) investigations in wheel–rail material. This
paper presents the scaling strategy of the rig based on dimensional
analysis and mechanical modelling. The new experimental rig is
indeed a spinning frame structure with multiple wheel components
over a fixed rail-track ring, capable of simulating continuous wheelrail
contact in a laboratory scale. This paper describes the
dimensional design of the rig, to derive its overall scaling strategy
and to determine the key elements’ specifications. Finite element
(FE) modelling is used to simulate the mechanical behavior of the rig
with two sample scale factors of 1/5 and 1/7. The results of FE
models are compared with the actual railway system to observe the
effectiveness of the chosen scales. The mechanical properties of the
components and variables of the system are finally determined
through the design process.