Abstract: These Monolayer and multilayer coatings of CrN and
AlCrN deposited on 100Cr6 (AISI 52100) substrate by PVD
magnetron sputtering system. The microstructures of the coatings
were characterized using atomic force microscopy (AFM). The AFM
analysis revealed the presence of domes and craters that are
uniformly distributed over all surfaces of the various layers.
Nanoindentation measurement of CrN coating showed maximum
hardness (H) and modulus (E) of 14 GPa and 190 GPa, respectively.
The measured H and E values of AlCrN coatings were found to be 30
GPa and 382 GPa, respectively. The improved hardness in both the
coatings was attributed mainly to a reduction in crystallite size and
decrease in surface roughness. The incorporation of Al into the CrN
coatings has improved both hardness and Young’s modulus.
Abstract: Distillery spentwash contains high chemical oxygen
demand (COD), biological oxygen demand (BOD), color, total
dissolved solids (TDS) and other contaminants even after biological
treatment. The effluent can’t be discharged as such in the surface
water bodies or land without further treatment. Reverse osmosis (RO)
treatment plants have been installed in many of the distilleries at
tertiary level in many of the distilleries in India, but are not properly
working due to fouling problem which is caused by the presence of
high concentration of organic matter and other contaminants in
biologically treated spentwash. In order to make the membrane
treatment a proven and reliable technology, proper pre-treatment is
mandatory. In the present study, ultra-filtration (UF) for pretreatment
of RO at tertiary stage has been performed. Operating
parameters namely initial pH (pHo: 2–10), trans-membrane pressure
(TMP: 4-20 bars) and temperature (T: 15-43°C) were used for
conducting experiments with UF system. Experiments were
optimized at different operating parameters in terms of COD, color,
TDS and TOC removal by using response surface methodology
(RSM) with central composite design. The results showed that
removal of COD, color and TDS was 62%, 93.5% and 75.5%
respectively, with UF, at optimized conditions with increased
permeate flux from 17.5 l/m2/h (RO) to 38 l/m2/h (UF-RO). The
performance of the RO system was greatly improved both in term of
pollutant removal as well as water recovery.
Abstract: Biodiesel production from vegetable oil will produce
glycerol as by-product about 10% of the biodiesel production. The
amount of glycerol that was produced needed alternative way to
handling immediately so as to not become the waste that polluted
environment. One of the solutions was to process glycerol to
polyglycidyl nitrate (PGN). PGN is synthesized from glycerol by
three-step reactions i.e. nitration of glycerol, cyclization of 13-
dinitroglycerine and polymerization of glycosyl nitrate. Optimum
condition of nitration of glycerol with nitric acid has not been known.
Thermodynamic feasibility should be done before run experiments in
the laboratory. The aim of this study was to determine the parameters
those affect nitration of glycerol and nitric acid and chose the
operation condition. Many parameters were simulated to verify its
possibility to experiment under conditions which would get the
highest conversion of 1, 3-dinitroglycerine and which was the ideal
condition to get it. The parameters that need to be studied to obtain
the highest conversion of 1, 3-dinitroglycerine were mol ratio of
nitric acid/glycerol, reaction temperature, mol ratio of
glycerol/dichloromethane and pressure. The highest conversion was
obtained in the range of mol ratio of nitric acid /glycerol between 2/1
– 5/1, reaction temperature of 5-25oC and pressure of 1 atm. The
parameters that need to be studied further to obtain the highest
conversion of 1.3 DNG are mol ratio of nitric acid/glycerol and
reaction temperature.
Abstract: The economic use and ease of construction of profiled
deck composite slab is marred with the complex and un-economic
strength verification required for the serviceability and general safety
considerations. Beside these, albeit factors such as shear span length,
deck geometries and mechanical frictions greatly influence the
longitudinal shear strength, that determines the ultimate strength of
profiled deck composite slab, and number of methods available for its
determination; partial shear and slope-intercept are the two methods
according to Euro-code 4 provision. However, the complexity
associated with shear behavior of profiled deck composite slab, the
use of these methods in determining the load carrying capacities of
such slab yields different and conflicting values. This couple with the
time and cost constraint associated with the strength verification is a
source of concern that draws more attentions nowadays, the issue is
critical. Treating some of these known shear strength influencing
factors as random variables, the load carrying capacity violation of
profiled deck composite slab from the use of the two-methods
defined according to Euro-code 4 are determined using reliability
approach, and comparatively studied. The study reveals safety values
from the use of m-k method shows good standing compared with that
from the partial shear method.
Abstract: The main parameters affecting the workability are the
water content, particle size, and the total surface of the grains, as long
as the mixing water begins by wetting the surface of the grains and
then fills the voids between the grains to form entrapped water, the
quantity of water remaining is called free water. The aim of this study is to undertake a fractal approach through
the relationship between the concrete formulation parameters and
workability. To develop this approach a series of concrete taken from
the literature was investigated by varying formulation parameters
such as G/S, the quantity of cement C and the quantity of water W. We also call another model as the model of water layer thickness
and model of paste layer thickness to judge their relevance, hence the
following results: the relevance of the water layer thickness model is
considered as a relevant when there is a variation in the water
quantity. The model of the paste layer thickness is only applicable if
we considered that the paste is made with the grain value Dmax =
2.85: value from which we see a stability of the model.
Abstract: We apply the non-parametric, unconditional,
hyperbolic order-α quantile estimator to appraise the relative
efficiency of Microfinance Institutions in Africa in terms of outreach.
Our purpose is to verify if these institutions, which must constantly
try to strike a compromise between their social role and financial
sustainability are operationally efficient.
Using data on African MFIs extracted from the Microfinance
Information eXchange (MIX) database and covering the 2004 to
2006 periods, we find that more efficient MFIs are also the most
profitable. This result is in line with the view that social performance
is not in contradiction with the pursuit of excellent financial
performance. Our results also show that large MFIs in terms of asset
and those charging the highest fees are not necessarily the most
efficient.
Abstract: Superabsorbent polymers received much attention and
are used in many fields because of their superior characters to
traditional absorbents, e.g., sponge and cotton. So, it is very
important but challenging to prepare highly and fast-swelling
superabsorbents. A reliable, efficient and low-cost technique for
removing heavy metal ions from wastewater is the adsorption using
bio-adsorbents obtained from biological materials, such as
polysaccharides-based hydrogels superabsorbents. In this study, novel multi-functional superabsorbent composites
type semi-interpenetrating polymer networks (Semi-IPNs) were
prepared via graft polymerization of acrylamide onto chitosan
backbone in presence of gelatin, CTS-g-PAAm/Ge, using potassium
persulfate and N,N’-methylene bisacrylamide as initiator and
crosslinker, respectively. These hydrogels were also partially
hydrolyzed to achieve superabsorbents with ampholytic properties
and uppermost swelling capacity. The formation of the grafted
network was evidenced by Fourier Transform Infrared Spectroscopy
(ATR-FTIR) and Thermogravimetric Analysis (TGA). The porous
structures were observed by Scanning Electron Microscope (SEM).
From TGA analysis, it was concluded that the incorporation of the Ge
in the CTS-g-PAAm network has marginally affected its thermal
stability. The effect of gelatin content on the swelling capacities of
these superabsorbent composites was examined in various media
(distilled water, saline and pH-solutions). The water absorbency was
enhanced by adding Ge in the network, where the optimum value was
reached at 2 wt. % of Ge. Their hydrolysis has not only greatly
optimized their absorption capacity but also improved the swelling
kinetic.These materials have also showed reswelling ability. We
believe that these super-absorbing materials would be very effective
for the adsorption of harmful metal ions from wastewater.
Abstract: Processing of Al-19.4Si alloy by high intensive
electron beam has been carried out and multiple increases in fatigue
life of the material have been revealed. Investigations of structure and
surface modified layer destruction of Al-19.4Si alloy subjected to
multicycle fatigue tests to fracture have been carried out by methods
of scanning electron microscopy. The factors responsible for the
increase of fatigue life of Al-19.4Si alloy have been revealed and
analyzed.
Abstract: EEG correlates of mathematical and trait anxiety level
were studied in 52 healthy Russian-speakers during execution of
error-recognition tasks with lexical, arithmetic and algebraic
conditions. Event-related spectral perturbations were used as a
measure of brain activity. The ERSP plots revealed alpha/beta
desynchronizations within a 500-3000 ms interval after task onset
and slow-wave synchronization within an interval of 150-350 ms.
Amplitudes of these intervals reflected the accuracy of error
recognition, and were differently associated with the three conditions.
The correlates of anxiety were found in theta (4-8 Hz) and beta2 (16-
20 Hz) frequency bands. In theta band the effects of mathematical
anxiety were stronger expressed in lexical, than in arithmetic and
algebraic condition. The mathematical anxiety effects in theta band
were associated with differences between anterior and posterior
cortical areas, whereas the effects of trait anxiety were associated
with inter-hemispherical differences. In beta1 and beta2 bands effects
of trait and mathematical anxiety were directed oppositely. The trait
anxiety was associated with increase of amplitude of
desynchronization, whereas the mathematical anxiety was associated
with decrease of this amplitude. The effect of mathematical anxiety
in beta2 band was insignificant for lexical condition but was the
strongest in algebraic condition. EEG correlates of anxiety in theta
band could be interpreted as indexes of task emotionality, whereas
the reaction in beta2 band is related to tension of intellectual
resources.
Abstract: This paper presents a state-of-the-art survey of the
operations research models developed for internal audit planning.
Two alternative approaches have been followed in the literature for
audit planning: (1) identifying the optimal audit frequency; and (2)
determining the optimal audit resource allocation. The first approach
identifies the elapsed time between two successive audits, which can
be presented as the optimal number of audits in a given planning
horizon, or the optimal number of transactions after which an audit
should be performed. It also includes the optimal audit schedule. The
second approach determines the optimal allocation of audit frequency
among all auditable units in the firm. In our review, we discuss both
the deterministic and probabilistic models developed for audit
planning. In addition, game theory models are reviewed to find the
optimal auditing strategy based on the interactions between the
auditors and the clients.
Abstract: Accurate forecasting of fresh produce demand is one
the challenges faced by Small Medium Enterprise (SME)
wholesalers. This paper is an attempt to understand the cause for the
high level of variability such as weather, holidays etc., in demand of
SME wholesalers. Therefore, understanding the significance of
unidentified factors may improve the forecasting accuracy. This
paper presents the current literature on the factors used to predict
demand and the existing forecasting techniques of short shelf life
products. It then investigates a variety of internal and external
possible factors, some of which is not used by other researchers in the
demand prediction process. The results presented in this paper are
further analysed using a number of techniques to minimize noise in
the data. For the analysis past sales data (January 2009 to May 2014)
from a UK based SME wholesaler is used and the results presented
are limited to product ‘Milk’ focused on café’s in derby. The
correlation analysis is done to check the dependencies of variability
factor on the actual demand. Further PCA analysis is done to
understand the significance of factors identified using correlation.
The PCA results suggest that the cloud cover, weather summary and
temperature are the most significant factors that can be used in
forecasting the demand. The correlation of the above three factors
increased relative to monthly and becomes more stable compared to
the weekly and daily demand.
Abstract: Background: The change in foot posture can possibly
generate changes in the pelvic alignment. There is still a lack of
evidence about the effects of bilateral and unilateral flatfoot on
possible changes in pelvic alignment. The purpose of this study was
to investigate the effect of flatfoot on the sagittal and frontal planes of
pelvic postures. Materials and Methods: 56 subjects, aged 18–40
years, were assigned into three groups: 20 healthy subjects, 19
subjects with bilateral flexible second-degree flat foot, and 17
subjects with unilateral flexible second-degree flat foot. 3D
assessment of the pelvis using the formetric-II device was used to
evaluate pelvic alignment in the frontal and sagittal planes by
measuring pelvic inclination and pelvic tilt angles. Results: ANOVA
test with LSD test were used for statistical analysis. Both Unilateral
and bilateral second degree flatfoot produced significant (P
Abstract: Research Objectives: The roles and activities of
Human Resource Management (HRM) have changed a lot in the past
years. Driven by a changing environment and therefore new business
requirements, the scope of human resource (HR) activities has
widened. The extent to which these activities should focus on
strategic issues to support the long term success of a company has
been discussed in science for many years. As many economies of
Central and Eastern Europe (CEE) experienced a phase of transition
after the socialist era and are now recovering from the 2008 global
crisis it is needed to examine the current state of HR positioning.
Furthermore a trend in HR work developing from rather
administrative units to being strategic partners of management can be
noticed. This leads to the question of better understanding the
underlying competencies which are necessary to support
organisations. This topic was addressed by the international study
“HR Competencies in international comparison”. The quantitative
survey was conducted by the Institute for Human Resources &
Organisation of FHWien University of Applied Science of WKW (A)
in cooperation with partner universities in the countries Bosnia-
Herzegovina, Croatia, Serbia and Slovenia. Methodology: Using the
questionnaire developed by Dave Ulrich we tested whether the HR
Competency model can be used for Austria, Bosnia and Herzegovina,
Croatia, Serbia and Slovenia. After performing confirmatory and
exploratory factor analysis for the whole data set containing all five
countries we could clearly distinguish between four competencies. In
a further step our analysis focused on median and average
comparisons between the HR competency dimensions. Conclusion:
Our literature review, in alignment with other studies, shows a
relatively rapid pace of development of HR Roles and HR
Competencies in BCSS in the past decades. Comparing data from
BCSS and Austria we still can notice that regards strategic orientation
there is a lack in BCSS countries, thus competencies are not as
developed as in Austria. This leads us to the tentative conclusion that
HR has undergone a rapid change but is still in a State of Transition
from being a rather administrative unit to performing the role of a
strategic partner.
Abstract: In this paper, we explore the macroeconomic effects
of the European Single Market on Austria by simulating the
McKibbin-Sachs Global Model. Global interdependences and the
impact of long-run effects on short-run adjustments are taken into
account. We study the sensitivity of the results with respect to
different assumptions concerning monetary and fiscal policies for the
countries and regions of the world economy. The consequences of
different assumptions about budgetary policies in Austria are also
investigated. The simulation results are contrasted with ex-post
evaluations of the actual impact of Austria’s membership in the
Single Market. As a result, it can be concluded that the Austrian
participation in the European Single Market entails considerable
long-run gains for the Austrian economy with nearly no adverse sideeffects
on any macroeconomic target variable.
Abstract: This study examined whether big five personality traits
affect game addiction with control of psychological, social, and
demographic factors. Specifically, using data from a survey of 789
game users in Korea, we conducted a regression analysis to see the
associations of psychological (loneliness/depression), social (activities
with family/friends), self-efficacy (game/general), gaming (daily
gaming time/perception), demographic (age/gender), and personality
traits (extraversion, neuroticism conscientiousness, agreeableness, &
openness) with the degree of game addiction. Results showed that
neuroticism increase game addiction with no effect of extraversion on
the addiction. General self-efficacy negatively affected game
addiction, whereas game self-efficacy increased the degree of game
addiction. Loneliness enhanced game addiction while depression
showed a negative effect on the addiction. Results and implications are
discussed.
Abstract: The article describes the effect of the replacement of
the used reference coordinate system in the georeferencing of an old
map of Europe. The map was georeferenced into three types of
projection – the equal-area conic (original cartographic projection),
cylindrical Plate Carrée and cylindrical Mercator map projection. The
map was georeferenced by means of the affine and the second-order
polynomial transformation. The resulting georeferenced raster
datasets from the Plate Carrée and Mercator projection were
projected into the equal-area conic projection by means of projection
equations. The output is the comparison of drawn graphics, the
magnitude of standard deviations for individual projections and types
of transformation.
Abstract: In present global scenario, aluminum alloys are
coining the attention of many innovators as competing structural
materials for automotive and space applications. Comparing to other
challenging alloys, especially, 7xxx series aluminum alloys have
been studied seriously because of benefits such as moderate strength;
better deforming characteristics and affordable cost. It is expected
that substitution of aluminum alloys for steels will result in great
improvements in energy economy, durability and recyclability.
However, it is necessary to improve the strength and the formability
levels at low temperatures in aluminum alloys for still better
applications. Aluminum–Zinc–Magnesium with or without other
wetting agent denoted as 7XXX series alloys are medium strength
heat treatable alloys. In addition to Zn, Mg as major alloying
additions, Cu, Mn and Si are the other solute elements which
contribute for the improvement in mechanical properties by suitable
heat treatment process. Subjecting to suitable treatments like age
hardening or cold deformation assisted heat treatments; known as low
temperature thermomechanical treatments (LTMT) the challenging
properties might be incorporated. T6 is the age hardening or
precipitation hardening process with artificial aging cycle whereas T8
comprises of LTMT treatment aged artificially with X% cold
deformation. When the cold deformation is provided after solution
treatment, there is increase in hardness related properties such as
wear resistance, yield and ultimate strength, toughness with the
expense of ductility. During precipitation hardening both hardness
and strength of the samples are increasing. The hardness value may
further improve when room temperature deformation is positively
supported with age hardening known as thermomechanical treatment.
It is intended to perform heat treatment and evaluate hardness, tensile
strength, wear resistance and distribution pattern of reinforcement in
the matrix. 2 to 2.5 and 3 to 3.5 times increase in hardness is reported
in age hardening and LTMT treatments respectively as compared to
as-cast composite. There was better distribution of reinforcements in
the matrix, nearly two fold increase in strength levels and up to 5
times increase in wear resistance are also observed in the present
study.
Abstract: The environmental, cultural, social, and technological
changes have led higher education institutes to question their
traditional roles. Many declarations and frameworks highlight the
importance of fulfilling social responsibility of higher education
institutes. The study aims at developing a framework of university
social responsibility and sustainability (USR&S) with focus on South
Valley University (SVU) as a case study of Egyptian Universities.
The study used meetings with 12 vice deans of community services
and environmental affairs on social responsibility and environmental
issues. The proposed framework integrates social responsibility with
strategic management through the establishment and maintenance of
the vision, mission, values, goals and management systems;
elaboration of policies; provision of actions; evaluation of services
and development of social collaboration with stakeholders to meet
current and future needs of the community and environment. The
framework links between different stakeholders internally and
externally using communication and reporting tools. The results show
that SVU integrates social responsibility and sustainability in its
strategic plans. It has policies and actions however fragmented and
lack of appropriate structure and budgeting. The proposed framework
could be valuable for researchers and decision makers of the
Egyptian Universities. The study proposed recommendations and
highlighted building on the results and conducting future research.
Abstract: Numerical studies have been carried out using a
validated two-dimensional standard k-omega turbulence model for
the design optimization of a thrust vector control system using shock
induced self-impinging supersonic secondary double jet. Parametric
analytical studies have been carried out at different secondary
injection locations to identifying the highest unsymmetrical
distribution of the main gas flow due to shock waves, which produces
a desirable side force more lucratively for vectoring. The results from
the parametric studies of the case on hand reveal that the shock
induced self-impinging supersonic secondary double jet is more
efficient in certain locations at the divergent region of a CD nozzle
than a case with supersonic single jet with same mass flow rate. We
observed that the best axial location of the self-impinging supersonic
secondary double jet nozzle with a given jet interaction angle, built-in
to a CD nozzle having area ratio 1.797, is 0.991 times the primary
nozzle throat diameter from the throat location. We also observed
that the flexible steering is possible after invoking ON/OFF facility to
the secondary nozzles for meeting the onboard mission requirements.
Through our case studies we concluded that the supersonic self-impinging
secondary double jet at predesigned jet interaction angle
and location can provide more flexible steering options facilitating
with 8.81% higher thrust vectoring efficiency than the conventional
supersonic single secondary jet without compromising the payload
capability of any supersonic aerospace vehicle.
Abstract: In this paper air quality conditions in Makkah and
Leeds are compared. These two cities have totally different climatic
conditions. Makkah climate is characterised as hot and dry (arid)
whereas that of Leeds is characterised as cold and wet (temperate).
This study uses air quality data from 2012 collected in Makkah,
Saudi Arabia and Leeds, UK. The concentrations of all pollutants,
except NO are higher in Makkah. Most notable, the concentrations of
PM10 are much higher in Makkah than in Leeds. This is probably due
to the arid nature of climatic conditions in Makkah and not solely due
to anthropogenic emission sources, otherwise like PM10 some of the
other pollutants, such as CO, NO, and SO2 would have shown much
greater difference between Leeds and Makkah. Correlation analysis is
performed between different pollutants at the same site and the same
pollutants at different sites. In Leeds the correlation between PM10
and other pollutants is significantly stronger than in Makkah. Weaker
correlation in Makkah is probably due to the fact that in Makkah
most of the gaseous pollutants are emitted by combustion processes,
whereas most of the PM10 is generated by other sources, such as
windblown dust, re-suspension, and construction activities. This is in
contrast to Leeds where all pollutants including PM10 are
predominantly emitted by combustions, such as road traffic.
Furthermore, in Leeds frequent rains wash out most of the
atmospheric particulate matter and suppress re-suspension of dust.
Temporal trends of various pollutants are compared and discussed.
This study emphasises the role of climatic conditions in managing air
quality, and hence the need for region-specific controlling strategies
according to the local climatic and meteorological conditions.