Abstract: Medicinal and aromatic plants are promising and are characterized by the biosynthesis of odorous molecules that make up the so-called essential oils (EO), which have long been known for their antiseptic and therapeutic activity in folk medicine. Essential oils have many therapeutic properties. In herbal medicine, they are used for their antiseptic properties against infectious diseases of fungal origin, against dermatophytes, those of bacterial origin. The objective of this study was to evaluate the influence of drying in the shade on the water content and on the content of essential oils extracted from leaves of Eucalyptus camendulensis for better quality control of medicinal and aromatic plants. The water content of the Eucalyptus camendulensis plant material decreases during the drying process. It decreased from 100% to 0.006% for the drying in the shade after ten days. The moisture content is practically constant at the end of the drying period. The drying in the shade increases the concentration of essential oils of Eucalyptus camendulensis. When the leaves of Eucalyptus camendulensis plant are in the shade, the maximum of the essential oil content was obtained on the eighth day, the recorded value was 1.43% ± 0.01%. Beyond these periods, the content continuously drop in before stabilizing. The optimum drying time is between 6 and 9 days.
Abstract: Some of the main causes for degradation of polymeric materials are thermal aging, hydrolysis, oxidation or chemical degradation by acids, alkalis or water. The first part of this paper provides a brief summary of advances in technology, methods and specification of composite materials for relining as a rehabilitation technique for sewage systems. The second part summarizes an investigation on frequently used composite materials for relining in Sweden, the rubber filled epoxy composite and reinforced polyester composite when they were immersed in deionized water or in dry conditions, and elevated temperatures up to 80°C in the laboratory. The tests were conducted by visual inspection, microscopy, Dynamic Mechanical Analysis (DMA), Differential Scanning Calorimetry (DSC) as well as mechanical testing, three point bending and tensile testing.
Abstract: This paper outlines the development of an
experimental technique in quantifying supersonic jet flows, in an
attempt to avoid seeding particle problems frequently associated with
particle-image velocimetry (PIV) techniques at high Mach numbers.
Based on optical flow algorithms, the idea behind the technique
involves using high speed cameras to capture Schlieren images of the
supersonic jet shear layers, before they are subjected to an adapted
optical flow algorithm based on the Horn-Schnuck method to
determine the associated flow fields. The proposed method is capable
of offering full-field unsteady flow information with potentially
higher accuracy and resolution than existing point-measurements or
PIV techniques. Preliminary study via numerical simulations of a
circular de Laval jet nozzle successfully reveals flow and shock
structures typically associated with supersonic jet flows, which serve
as useful data for subsequent validation of the optical flow based
experimental results. For experimental technique, a Z-type Schlieren
setup is proposed with supersonic jet operated in cold mode,
stagnation pressure of 4 bar and exit Mach of 1.5. High-speed singleframe
or double-frame cameras are used to capture successive
Schlieren images. As implementation of optical flow technique to
supersonic flows remains rare, the current focus revolves around
methodology validation through synthetic images. The results of
validation test offers valuable insight into how the optical flow
algorithm can be further improved to improve robustness and
accuracy. Despite these challenges however, this supersonic flow
measurement technique may potentially offer a simpler way to
identify and quantify the fine spatial structures within the shock shear
layer.
Abstract: We have aimed to produce a self-cleaning transparent
polymer coating with polyurethane (PU) matrix as the latter is highly
solvent, chemical and weather resistant having good mechanical
properties. Nano-silica modified by 1H, 1H, 2H, 2Hperflurooctyltriethoxysilane
was incorporated into the PU matrix for
attaining self-cleaning ability through hydrophobicity. The
modification was confirmed by particle size analysis and scanning
electron microscopy (SEM). Thermo-gravimetric (TGA) studies were
carried to ascertain the grafting of silane onto the silica. Several
coating formulations were prepared by varying the silica loading
content and compared to a commercial equivalent. The effect of
dispersion and the morphology of the coated films were assessed by
SEM analysis. All coating standardized tests like solvent resistance,
adhesion, flexibility, acid, alkali, gloss etc. have been performed as
per ASTM standards. Water contact angle studies were conducted to
analyze the hydrophobic character of the coating. In addition, the
coatings were also subjected to salt spray and accelerated weather
testing to analyze the durability of the coating.
Abstract: The present study investigates the effectiveness of
newly designed clayey pellets (fired clay pellets diameter sizes of 5
and 8 mm, and unfired clay pellets with the diameter size of 15 mm)
as the beds in the column adsorption process. The adsorption
experiments in the batch mode were performed before the column
experiment with the purpose to determine the order of adsorbent
package in the column which was to be designed in the investigation.
The column experiment was performed by using a known mass of the
clayey beds and the volume of the waste printing developer, which
was purified. The column was filled in the following order: fired clay
pellets of the diameter size of 5 mm, fired clay pellets of the diameter
size of 8 mm, and unfired clay pellets of the diameter size of 15 mm.
The selected order of the adsorbents showed a high removal
efficiency for zinc (97.8%) and copper (81.5%) ions. These
efficiencies were better than those in the case of the already existing
mode adsorption. The obtained experimental data present a good
basis for the selection of an appropriate column fill, but further
testing is necessary in order to obtain more accurate results.
Abstract: Landfill waste is a common problem as it has an
economic and environmental impact even if it is closed. Landfill
waste contains a high density of various persistent compounds such
as heavy metals, organic and inorganic materials. As persistent
compounds are slowly-degradable or even non-degradable in the
environment, they often produce sublethal or even lethal effects on
aquatic organisms. The aims of the present study were to estimate
sublethal effects of the Kairiai landfill (WGS: 55°55‘46.74“,
23°23‘28.4“) leachate on the locomotor activity of rainbow trout
Oncorhynchus mykiss juveniles using the original system package
developed in our laboratory for automated monitoring, recording and
analysis of aquatic organisms’ activity, and to determine patterns of
fish behavioral response to sublethal effects of leachate. Four
different concentrations of leachate were chosen: 0.125; 0.25; 0.5 and
1.0 mL/L (0.0025; 0.005; 0.01 and 0.002 as part of 96-hour LC50,
respectively). Locomotor activity was measured after 5, 10 and 30
minutes of exposure during 1-minute test-periods of each fish (7 fish
per treatment). The threshold-effect-concentration amounted to 0.18
mL/L (0.0036 parts of 96-hour LC50). This concentration was found
to be even 2.8-fold lower than the concentration generally assumed to
be “safe” for fish. At higher concentrations, the landfill leachate
solution elicited behavioral response of test fish to sublethal levels of
pollutants. The ability of the rainbow trout to detect and avoid
contaminants occurred after 5 minutes of exposure. The intensity of
locomotor activity reached a peak within 10 minutes, evidently
decreasing after 30 minutes. This could be explained by the
physiological and biochemical adaptation of fish to altered
environmental conditions. It has been established that the locomotor
activity of juvenile trout depends on leachate concentration and
exposure duration. Modeling of these parameters showed that the
activity of juveniles increased at higher leachate concentrations, but
slightly decreased with the increasing exposure duration. Experiment
results confirm that the behavior of rainbow trout juveniles is a
sensitive and rapid biomarker that can be used in combination with
the system for fish behavior monitoring, registration and analysis to
determine sublethal concentrations of pollutants in ambient water.
Further research should be focused on software improvement aimed
to include more parameters of aquatic organisms’ behavior and to
investigate the most rapid and appropriate behavioral responses in
different species. In practice, this study could be the basis for the
development and creation of biological early-warning systems
(BEWS).
Abstract: At the Savonia University of Applied Sciences (UAS),
curriculum and studies have been improved by applying an Open
Innovation Space approach (OIS). It is based on multidisciplinary
action learning. The key elements of OIS-ideology are work-life
orientation, and student-centric communal learning. In this approach,
every participant can learn from each other and innovations will be
created. In this social innovation educational approach, all practices
are carried out in close collaboration with enterprises in real-life
settings, not in classrooms. As an example, in this paper, Savonia
UAS’s Future Food RDI hub (FF) shows how OIS practices are
implemented by providing food product development and consumer
research services for enterprises in close collaboration with
academicians, students and consumers. In particular one example of
OIS experimentation in the field is provided by a consumer research
carried out utilizing verbal analysis protocol combined with audiovisual
observation (VAP-WAVO). In this case, all co-learners were
acting together in supermarket settings to collect the relevant data for
a product development and the marketing department of a company.
The company benefitted from the results obtained, students were
more satisfied with their studies, educators and academicians were
able to obtain good evidence for further collaboration as well as
renewing curriculum contents based on the requirements of working
life. In addition, society will benefit over time as young university
adults find careers more easily through their OIS related food science
studies. Also this knowledge interaction model re-news education
practices and brings working-life closer to educational research
institutes.
Abstract: Purpose: The key aim of the research was to identify
the secondary stressors experienced by businesses affected by single
or repeated flooding and to determine to what extent businesses were
affected by these stressors, along with any resulting impact on health.
Additionally the research aimed to establish the likelihood of
businesses being re-exposed to the secondary stressors through
assessing awareness of flood risk, implementation of property
protection measures and level of community resilience. Design/methodology/approach: The chosen research method
involved the distribution of a questionnaire survey to businesses
affected by either single or repeated flood events. The questionnaire
included the Impact of Event Scale (a 15-item self-report measure
which assesses subjective distress caused by traumatic events). Findings: 55 completed questionnaires were returned by flood
impacted businesses. 89% of the businesses had sustained internal
flooding, while 11% had experienced external flooding. The results
established that the key secondary stressors experienced by
businesses, in order of priority, were: flood damage, fear of
reoccurring flooding, prevention of access to the premise/closure,
loss of income, repair works, length of closure and insurance issues.
There was a lack of preparedness for potential future floods and
consequent vulnerability to the emergence of secondary stressors
among flood affected businesses, as flood resistance or flood
resilience measures had only been implemented by 11% and 13%
respectively. In relation to the psychological repercussions, the
Impact of Event scores suggested that potential prevalence of posttraumatic
stress disorder (PTSD) was noted among 8 out of 55
respondents (l5%). Originality/value: The results improve understanding of the
enduring repercussions of flood events on businesses, indicating that
not only residents may be susceptible to the detrimental health
impacts of flood events and single flood events may be just as likely
as reoccurring flooding to contribute to ongoing stress. Lack of
financial resources is a possible explanation for the lack of
implementation of property protection measures among businesses,
despite 49% experiencing flooding on multiple occasions. Therefore
it is recommended that policymakers should consider potential
sources of financial support or grants towards flood defences for
flood impacted businesses. Any form of assistance should be made
available to businesses at the earliest opportunity as there was no
significant association between the time of the last flood event and
the likelihood of experiencing PTSD symptoms.
Abstract: The rheological response of blends obtained from
quaternized polysulfone and polyvinyl alcohol in N-methyl-2-
pyrrolidone as against structural peculiarity of polymers from the
blend, composition of polymer mixtures, as well as the types of
interactions were investigated. Results show that the variation of
polyvinyl alcohol composition in the studied system determines
changes of the rheological properties, suggesting that the PVA acts as
a plasticizer. Consequently, rheological behavior of complex system,
described by the nonlinear flow curve, indicates the impact of
polyvinil alcohol content to polysulfone solution, in order to facilitate
the subsequently preparation of bioactive membranes.
Abstract: An Energetic and exergetic analysis is conducted on a
Steam Turbine Power Plant of an existing Phosphoric Acid Factory.
The heat recovery systems used in different parts of the plant are also
considered in the analysis. Mass, thermal and exergy balances are
established on the main compounds of the factory. A numerical code
is established using EES software to perform the calculations
required for the thermal and exergy plant analysis. The effects of the
key operating parameters such as steam pressure and temperature,
mass flow rate as well as seawater temperature, on the cycle
performances are investigated. A maximum Exergy Loss Rate of about 72% is obtained for the
melters, followed by the condensers, heat exchangers and the pumps.
The heat exchangers used in the phosphoric acid unit present
exergetic efficiencies around 33% while 60% to 72% are obtained for
steam turbines and blower. For the explored ranges of HP steam
temperature and pressure, the exergy efficiencies of steam turbine
generators STGI and STGII increase of about 2.5% and 5.4%
respectively. In the same way optimum HP steam flow rate values,
leading to the maximum exergy efficiencies are defined.
Abstract: Concrete is an essential building material which is
widely used in construction industry all over the world due to its
compressible strength. Curing of concrete plays a vital role in
durability and other performance necessities. Improper curing can
affect the concrete performance and durability easily. When areas
like scarcity of water, structures is not accessible by humans external
curing cannot be performed, so we opt for internal curing. Internal
curing (or) self curing plays a major role in developing the concrete
pore structure and microstructure. The concept of internal curing is to
enhance the hydration process to maintain the temperature uniformly.
The evaporation of water in the concrete is reduced by self curing
agent (Super Absorbing Polymer – SAP) there by increasing the
water retention capacity of the concrete. The research work was
carried out to reduce water, which is prime material used for concrete
in the construction industry. Concrete curing plays a major role in
developing hydration process. Concept of self curing will reduce the
evaporation of water from concrete. Self curing will increase water
retention capacity as compared to the conventional concrete. Proper
self curing (or) internal curing increases the strength, durability and
performance of concrete. Super absorbing Polymer (SAP) used as
internal curing agent. In this study 0.2% to 0.4% of SAP was varied
in different grade of high strength concrete. In the experiment
replacement of cement by silica fumes with 5%, 10% and 15% are
studied. It is found that replacement of silica fumes by 10 % gives
more strength and durability when compared to others.
Abstract: In this current contribution, authors are dedicated to
investigate influence of the crystal lamellae orientation on
electromechanical behaviors of relaxor ferroelectric Poly
(vinylidene fluoride –trifluoroethylene -chlorotrifluoroethylene)
(P(VDF-TrFE-CTFE)) films by control of polymer microstructure,
aiming to picture the full map of structure-property relationship. In
order to define their crystal orientation films, terpolymer films were
fabricated by solution-casting, stretching and hot-pressing process.
Differential scanning calorimetry, impedance analyzer, and tensile
strength techniques were employed to characterize crystallographic
parameters, dielectric permittivity, and elastic Young’s modulus
respectively. In addition, large electrical induced out-of-plane
electrostrictive strain was obtained by cantilever beam mode.
Consequently, as-casted pristine films exhibited surprisingly high
electrostrictive strain 0.1774% due to considerably small value of
elastic Young’s modulus although relatively low dielectric
permittivity. Such reasons contributed to large mechanical elastic
energy density. Instead, due to 2 folds increase of elastic Young’s
modulus and less than 50% augmentation of dielectric constant, fullycrystallized
film showed weak electrostrictive behavior and
mechanical energy density as well. And subjected to mechanical
stretching process, Film C exhibited stronger dielectric constant and
out-performed electrostrictive strain over Film B because edge-on
crystal lamellae orientation induced by uniaxially mechanical stretch.
Hot-press films were compared in term of cooling rate. Rather large
electrostrictive strain of 0.2788% for hot-pressed Film D in
quenching process was observed although its dielectric permittivity
equivalent to that of pristine as-casted Film A, showing highest
mechanical elastic energy density value of 359.5 J/m3. In hot-press
cooling process, dielectric permittivity of Film E saw values at 48.8
concomitant with ca.100% increase of Young’s modulus. Films with
intermediate mechanical energy density were obtained.
Abstract: In language learning, second language learners as well
as Native speakers commit errors in their attempt to achieve
competence in the target language. The realm of collocation has to do
with meaning relation between lexical items. In all human language,
there is a kind of ‘natural order’ in which words are arranged or relate
to one another in sentences so much so that when a word occurs in a
given context, the related or naturally co-occurring word will
automatically come to the mind. It becomes an error, therefore, if
students inappropriately pair or arrange such ‘naturally’ co–occurring
lexical items in a text. It has been observed that most of the second
language learners in this research group commit collocation errors. A
study of this kind is very significant as it gives insight into the kinds
of errors committed by learners. This will help the language teacher
to be able to identify the sources and causes of such errors as well as
correct them thereby guiding, helping and leading the learners
towards achieving some level of competence in the language. The
aim of the study is to understand the nature of these errors as
stumbling blocks to effective essay writing. The objective of the
study is to identify the errors, analyze their structural compositions so
as to determine whether there are similarities between students in this
regard and to find out whether there are patterns to these kinds of
errors which will enable the researcher to understand their sources
and causes. As a descriptive research, the researcher samples some
nine hundred essays collected from three hundred undergraduate
learners of English as a second language in the Federal College of
Education, Kano, North- West Nigeria, i.e. three essays per each
student. The essays which were given on three different lecture times
were of similar thematic preoccupations (i.e. same topics) and length
(i.e. same number of words). The essays were written during the
lecture hour at three different lecture occasions. The errors were
identified in a systematic manner whereby errors so identified were
recorded only once even if they occur severally in students’ essays.
The data was collated using percentages in which the identified
numbers of occurrences were converted accordingly in percentages.
The findings from the study indicate that there are similarities as well
as regular and repeated errors which provided a pattern. Based on the
pattern identified, the conclusion is that students’ collocation errors
are attributable to poor teaching and learning which resulted in wrong
generalization of rules.
Abstract: The most crucial aspect that is closely related to vocabulary and the one that needs to be emphasized and investigated more than it has been up until now, is the ability to combine words that co-occur frequently in the language. Pedagogically, collocation is one of the error-provoking aspects in foreign language learning. This is indicative of the dire need to provide L2 learners with tools to help them improve their collocational knowledge. This paper pinpoints the role that collocations play in the English language. Furthermore, it presents pedagogical implications for ESL/EFL learners.
Abstract: A combined heat and power (CHP) system is an efficient and clean way to generate power (electricity). Heat produced by the CHP system can be used for water and space heating. The CHP system which uses hydrogen as fuel produces zero carbon emission. Its’ efficiency can reach more than 80% whereas that of a traditional power station can only reach up to 50% because much of the thermal energy is wasted. The other advantages of CHP systems include that they can decentralize energy generation, improve energy security and sustainability, and significantly reduce the energy cost to the users. This paper presents the economic benefits of using a CHP system in the domestic environment. For this analysis, natural gas is considered as potential fuel as the hydrogen fuel cell based CHP systems are rarely used. UK government incentives for CHP systems are also considered as the added benefit. Results show that CHP requires a significant initial investment in returns it can reduce the annual energy bill significantly. Results show that an investment may be paid back in 7 years. After the back period, CHP can run for about 3 years as most of the CHP manufacturers provide 10 year warranty.
Abstract: The paper presents an additive manufacturing process for the production of metal and composite parts. It is termed as composite metal foil manufacturing and is a combination of laminated object manufacturing and brazing techniques. The process has been described in detail and is being used to produce dissimilar aluminum to copper foil single lap joints. A three dimensional finite element model has been developed to study the thermo-mechanical characteristics of the dissimilar Al/Cu single lap joint. The effects of thermal stress and strain have been analyzed by carrying out transient thermal analysis on the heated plates used to join the two 0.1mm thin metal foils. Tensile test has been carried out on the foils before joining and after the single Al/Cu lap joints are made, they are subjected to tensile lap-shear test to analyze the effect of heat on the foils. The analyses are designed to assess the mechanical integrity of the foils after the brazing process and understand whether or not the heat treatment has an effect on the fracture modes of the produced specimens.
Abstract: E-government has been adopted and used by many governments/countries around the world including Ghana to provide citizens and businesses with more accurate, real-time, and high quality services and information. The objective of this paper is to present an overview of the Government of Ghana’s (GoG) adoption and implement of e-government and its usage by the Ministries, Departments and its agencies (MDAs) as well as other public sector institutions to deliver efficient public service to the general public i.e. citizens, business etc. Government implementation of e-government focused on facilitating effective delivery of government service to the public and ultimately to provide efficient government-wide electronic means of sharing information and knowledge through a network infrastructure developed to connect all major towns and cities, Ministries, Departments and Agencies and other public sector organizations in Ghana. One aim for the Government of Ghana use of ICT in public administration is to improve productivity in government administration and service by facilitating exchange of information to enable better interaction and coordination of work among MDAs, citizens and private businesses. The study was prepared using secondary sources of data from government policy documents, national and international published reports, journal articles, and web sources. This study indicates that through the e-government initiative, currently citizens and businesses can access and pay for services such as renewal of driving license, business registration, payment of taxes, acquisition of marriage and birth certificates as well as application for passport through the GoG electronic service (eservice) and electronic payment (epay) portal. Further, this study shows that there is enormous commitment from GoG to adopt and implement e-government as a tool not only to transform the business of government but also to bring efficiency in public services delivered by the MDAs. To ascertain this, a further study need to be carried out to determine if the use of e-government has brought about the anticipated improvements and efficiency in service delivery of MDAs and other state institutions in Ghana.
Abstract: Energy has a prominent role for development of
nations. Countries which have energy resources also have strategic
power in the international trade of energy since it is essential for all
stages of production in the economy. Thus, it is important for
countries to analyze the weaknesses and strength of the system. On
the other side, international trade is one of the fields that are analyzed
as a complex network via network analysis. Complex network is one
of the tools to analyze complex systems with heterogeneous agents
and interaction between them. A complex network consists of nodes
and the interactions between these nodes. Total properties which
emerge as a result of these interactions are distinct from the sum of
small parts (more or less) in complex systems. Thus, standard
approaches to international trade are superficial to analyze these
systems. Network analysis provides a new approach to analyze
international trade as a network. In this network, countries constitute
nodes and trade relations (export or import) constitute edges. It
becomes possible to analyze international trade network in terms of
high degree indicators which are specific to complex networks such
as connectivity, clustering, assortativity/disassortativity, centrality,
etc. In this analysis, international trade of crude oil and coal which
are types of fossil fuel has been analyzed from 2005 to 2014 via
network analysis. First, it has been analyzed in terms of some
topological parameters such as density, transitivity, clustering etc.
Afterwards, fitness to Pareto distribution has been analyzed via
Kolmogorov-Smirnov test. Finally, weighted HITS algorithm has
been applied to the data as a centrality measure to determine the real
prominence of countries in these trade networks. Weighted HITS
algorithm is a strong tool to analyze the network by ranking countries
with regards to prominence of their trade partners. We have
calculated both an export centrality and an import centrality by
applying w-HITS algorithm to the data. As a result, impacts of the
trading countries have been presented in terms of high-degree
indicators.
Abstract: This paper explored the challenges faced by the
management of a Ghanaian state enterprise in managing conflicts and
disturbances associated with its attempt to implement new work
practices to enhance its capability to operate as a commercial entity.
The purpose was to understand the extent to which organizational
involvement, consistency and adaptability influence employees’
consumption of new work practices in transforming the
organization’s organizational activity system. Using selfadministered
questionnaires, data were collected from one hundred
and eighty (180) employees and analyzed using both descriptive and
inferential statistics. The results showed that constraints in
organizational involvement and adaptability prevented the positive
consumption of new work practices by employees in the
organization. It is also found that the organization’s employees failed
to consume the new practices being implemented, because they
perceived the process as non-involving, and as such, did not
encourage the development of employee capability, empowerment,
and teamwork. The study concluded that the failure of the
organization’s management to create opportunities for organizational
learning constrained its ability to get employees consume the new
work practices, which situation could have facilitated the
organization’s capabilities of operating as a commercial entity.
Abstract: In order to retrieve images efficiently from a large
database, a unique method integrating color and texture features
using genetic programming has been proposed. Opponent color
histogram which gives shadow, shade, and light intensity invariant
property is employed in the proposed framework for extracting color
features. For texture feature extraction, fast discrete curvelet
transform which captures more orientation information at different
scales is incorporated to represent curved like edges. The recent
scenario in the issues of image retrieval is to reduce the semantic gap
between user’s preference and low level features. To address this
concern, genetic algorithm combined with relevance feedback is
embedded to reduce semantic gap and retrieve user’s preference
images. Extensive and comparative experiments have been conducted
to evaluate proposed framework for content based image retrieval on
two databases, i.e., COIL-100 and Corel-1000. Experimental results
clearly show that the proposed system surpassed other existing
systems in terms of precision and recall. The proposed work achieves
highest performance with average precision of 88.2% on COIL-100
and 76.3% on Corel, the average recall of 69.9% on COIL and 76.3%
on Corel. Thus, the experimental results confirm that the proposed
content based image retrieval system architecture attains better
solution for image retrieval.