Abstract: This research study the application of the immobilized
TiO2 layer and Cu-TiO2 layer on graphite substrate as a negative
electrode or anode for Li-ion battery. The titania layer was produced
through chemical bath deposition method, meanwhile Cu particles
were deposited electrochemically. A material can be used as an
electrode as it has capability to intercalates Li ions into its crystal
structure. The Li intercalation into TiO2/Graphite and Cu-
TiO2/Graphite were analyzed from the changes of its XRD pattern
after it was used as electrode during discharging process. The XRD
patterns were refined by Le Bail method in order to determine the
crystal structure of the prepared materials. A specific capacity and the
cycle ability measurement were carried out to study the performance
of the prepared materials as negative electrode of the Li-ion battery.
The specific capacity was measured during discharging process from
fully charged until the cut off voltage. A 300 was used as a load.
The result shows that the specific capacity of Li-ion battery with
TiO2/Graphite as negative electrode is 230.87 ± 1.70mAh.g-1 which is
higher than the specific capacity of Li-ion battery with pure graphite
as negative electrode, i.e 140.75 ±0.46mAh.g-1. Meanwhile
deposition of Cu onto TiO2 layer does not increase the specific
capacity, and the value even lower than the battery with
TiO2/Graphite as electrode. The cycle ability of the prepared battery
is only two cycles, due to the Li ribbon which was used as cathode
became fragile and easily broken.
Abstract: In this paper, a theoretical formula is presented to
predict the instantaneous folding force of the first fold creation in a
square column under axial loading. Calculations are based on analysis
of “Basic Folding Mechanism" introduced by Wierzbicki and
Abramowicz. For this purpose, the sum of dissipated energy rate under
bending around horizontal and inclined hinge lines and dissipated
energy rate under extensional deformations are equated to the work rate
of the external force on the structure. Final formula obtained in this
research, reasonably predicts the instantaneous folding force of the first
fold creation versus folding distance and folding angle and also predicts
the instantaneous folding force instead of the average value. Finally,
according to the calculated theoretical relation, instantaneous folding
force of the first fold creation in a square column was sketched
versus folding distance and was compared to the experimental results
which showed a good correlation.
Abstract: In this paper, an inventory model with finite and
constant replenishment rate, price dependant demand rate, time
value of money and inflation, finite time horizon, lead time and
exponential deterioration rate and with the objective of maximizing
the present worth of the total system profit is developed. Using a
dynamic programming based solution algorithm, the optimal
sequence of the cycles can be found and also different optimal
selling prices, optimal order quantities and optimal maximum
inventories can be obtained for the cycles with unequal lengths,
which have never been done before for this model. Also, a
numerical example is used to show accuracy of the solution
procedure.
Abstract: Passive systems were born with the purpose of the
greatest exploitation of solar energy in cold climates and high
altitudes. They spread themselves until the 80-s all over the world
without any attention to the specific climate and the summer
behavior; this caused the deactivation of the systems due to a series
of problems connected to the summer overheating, the complex
management and the rising of the dust.
Until today the European regulation limits only the winter
consumptions without any attention to the summer behavior but, the
recent European EN 15251 underlines the relevance of the indoor
comfort, and the necessity of the analytic studies validation by
monitoring case studies.
In the porpose paper we demonstrate that the solar wall is an
efficient system both from thermal comfort and energy saving point
of view and it is the most suitable for our temperate climates because
it can be used as a passive cooling sistem too. In particular the paper
present an experimental and numerical analisys carried out on a case
study with nine different solar passive systems in Ancona, Italy.
We carried out a detailed study of the lodging provided by the
solar wall by the monitoring and the evaluation of the indoor
conditions.
Analyzing the monitored data, on the base of recognized models
of comfort (ISO, ASHRAE, Givoni-s BBCC), is emerged that the
solar wall has an optimal behavior in the middle seasons. In winter
phase this passive system gives more advantages in terms of energy
consumptions than the other systems, because it gives greater heat
gain and therefore smaller consumptions. In summer, when outside
air temperature return in the mean seasonal value, the indoor comfort
is optimal thanks to an efficient transversal ventilation activated from
the same wall.
Abstract: As the data-driven economy is growing faster than
ever and the demand for energy is being spurred, we are facing
unprecedented challenges of improving energy efficiency in data
centers. Effectively maximizing energy efficiency or minimising the
cooling energy demand is becoming pervasive for data centers. This
paper investigates overall energy consumption and the energy
efficiency of cooling system for a data center in Finland as a case
study. The power, cooling and energy consumption characteristics
and operation condition of facilities are examined and analysed.
Potential energy and cooling saving opportunities are identified and
further suggestions for improving the performance of cooling system
are put forward. Results are presented as a comprehensive evaluation
of both the energy performance and good practices of energy
efficient cooling operations for the data center. Utilization of an
energy recovery concept for cooling system is proposed. The
conclusion we can draw is that even though the analysed data center
demonstrated relatively high energy efficiency, based on its power
usage effectiveness value, there is still a significant potential for
energy saving from its cooling systems.
Abstract: New nondestructive technique, namely an inverse technique based on vibration tests, to characterize nonlinear mechanical properties of adhesive layers in sandwich composites is developed. An adhesive layer is described as a viscoelastic isotropic material with storage and loss moduli which are both frequency dependent values in wide frequency range. An optimization based on the planning of experiments and response surface technique to minimize the error functional is applied to decrease considerably the computational expenses. The developed identification technique has been tested on aluminum panels and successfully applied to characterize viscoelastic material properties of 3M damping polymer ISD-112 used as a core material in sandwich panels.
Abstract: Explosion occurs due to sudden release of energy.
Common examples of explosion include chemical, atomic, heat, and
pressure tank (due to ignition) explosions. Petroleum, gas, and
petrochemical industries operations are threatened by natural risks
and processes. Fires and explosions are the greatest process risks
which cause financial damages.
This study aims at designing a single-floor structure for the control
room of a petroleum refinery to be resistant against gas explosion
loads, and the information related to the structure specifications have
been provided regarding the fact that the structure is made on the
ground's surface. In this research, the lateral stiffness of single pile is
calculated by SPPLN.FOR computer program, and its value for
13624 KN/m single pile has been assessed. The analysis used due to
the loading conditions, is dynamic nonlinear analysis with direct
integration method.
Abstract: In this paper, our focus is to assure a global frequency synchronization in OFDMA-based wireless mesh networks with local information. To acquire the global synchronization in distributed manner, we propose a novel distributed frequency synchronization (DFS) method. DFS is a method that carrier frequencies of distributed nodes converge to a common value by repetitive estimation and averaging step and sharing step. Experimental results show that DFS achieves noteworthy better synchronization success probability than existing schemes in OFDMA-based mesh networks where the estimation error is presented.
Abstract: Silver nanoparticles were prepared by chemical reduction method. Silver nitrate was taken as the metal precursor and hydrazine hydrate as a reducing agent. The formation of the silver nanoparticles was monitored using UV-Vis absorption spectroscopy. The UV-Vis spectroscopy revealed the formation of silver nanopart├¡cles by exhibing the typical surface plasmon absorption maxima at 418-420 nm from the UV–Vis spectrum. Comparison of theoretical (Mie light scattering theory) and experimental results showed that diameter of silver nanoparticles in colloidal solution is about 60 nm. We have used energy-dispersive spectroscopy (EDX), X-ray diffraction (XRD), transmission electron microscopy (TEM) and, UV–Vis spectroscopy to characterize the nanoparticles obtained. The energy-dispersive spectroscopy (EDX) of the nanoparticles dispersion confirmed the presence of elemental silver signal no peaks of other impurity were detected. The average size and morphology of silver nanoparticles were determined by transmission electron microscopy (TEM). TEM photographs indicate that the nanopowders consist of well dispersed agglomerates of grains with a narrow size distribution (40 and 60 nm), whereas the radius of the individual particles are between 10 and 20 nm. The synthesized nanoparticles have been structurally characterized by X-ray diffraction and transmission high-energy electron diffraction (HEED). The peaks in the XRD pattern are in good agreement with the standard values of the face-centered-cubic form of metallic silver (ICCD-JCPDS card no. 4-0787) and no peaks of other impurity crystalline phases were detected. Additionally, the antibacterial activity of the nanopart├¡culas dispersion was measured by Kirby-Bauer method. The nanoparticles of silver showed high antimicrobial and bactericidal activity against gram positive bacteria such as Escherichia Coli, Pseudimonas aureginosa and staphylococcus aureus which is a highly methicillin resistant strain.
Abstract: In present work are considered the scheme of
evaluation the transition probability in quantum system. It is based on
path integral representation of transition probability amplitude and its
evaluation by means of a saddle point method, applied to the part of
integration variables. The whole integration process is reduced to
initial value problem solutions of Hamilton equations with a random
initial phase point. The scheme is related to the semiclassical initial
value representation approaches using great number of trajectories. In
contrast to them from total set of generated phase paths only one path
for each initial coordinate value is selected in Monte Karlo process.
Abstract: In this paper, an analytical approach for free vibration
analysis of rectangular and circular membranes is presented. The
method is based on wave approach. From wave standpoint vibration
propagate, reflect and transmit in a structure. Firstly, the propagation
and reflection matrices for rectangular and circular membranes are
derived. Then, these matrices are combined to provide a concise and
systematic approach to free vibration analysis of membranes.
Subsequently, the eigenvalue problem for free vibration of membrane
is formulated and the equation of membrane natural frequencies is
constructed. Finally, the effectiveness of the approach is shown by
comparison of the results with existing classical solution.
Abstract: There has been a growing emphasis in
communication management from simple coordination of
promotional tools to a complex strategic process. This study will
examine the current marketing communications and engagement
strategies used in addressing the key stakeholders. In the case of
fertilizer industry in Malaysia, there has been little empirical
research on stakeholder communication when major challenges
facing the modern corporation is the need to communicate its
identity, its values and products in order to distinguish itself from
competitors. The study will employ both quantitative and qualitative
methods and the use of Structural Equation Modeling (SEM) to
establish a causal relationship amongst the key factors of stakeholder
communication strategies and increment in consumers-
choice/acceptance and impact on financial performance. One of the
major contributions is a conceptual framework for communication
strategies and engagement in increasing consumers- acceptance level
and the firm-s financial performance.
Abstract: This paper describes topology of business models in market ecosystem of the emerging electric mobility industry. The business model topology shows that firm-s participation in the ecosystem is associated with different requirements on resources and capabilities, and different levels of risk. Business model concept is used together with concepts of networked value creation and shows that firms can achieve higher levels of sustainable advantage by cooperation, not competition. Hybrid business models provide companies a viable alternative possibility for participation in the market ecosystem.
Abstract: The Build-Then-Sell (BTS) is a novel system
implemented in Malaysia after a number of complaints have been
received from buyers in the preceding Sell-Then-Build (STB) system.
When the government announced the implementation of the BTS in
2007, proponents of BTS have asserted that the new system will
provide houses with low level of defects. Their argument however is
not supported by any empirical data. Hence, this study is conducted
to evaluate the housing defects in BTS houses. Six BTS residential
areas have been surveyed to collect the defects data. Questionnaires
were administered directly to the occupiers in each of the BTS houses
through door-to-door visits. The result has shown that the rate of
defects for the six residential areas is ranged from minor to slight,
which only affect the aesthetic value of the house.
Abstract: In this study, the dispersion of heavy particles line in
an isotropic and incompressible three-dimensional turbulent flow has
been studied using the Kinematic Simulation techniques to find out
the evolution of the line fractal dimension. The fractal dimension of
the line is found in the case of different particle gravity (in practice,
different values of particle drift velocity) in the presence of small
particle inertia with a comparison with that obtained in the diffusion
case of material line at the same Reynolds number. It can be
concluded for the dispersion of heavy particles line in turbulent flow
that the particle gravity affect the fractal dimension of the line for
different particle gravity velocities in the range 0.2 < W < 2. With
the increase of the particle drift velocity, the fractal dimension of the
line decreases which may be explained as the particles pass many
scales in their journey in the direction of the gravity and the particles
trajectories do not affect by these scales at high particle drift
velocities.
Abstract: In inspection and workpiece localization, sampling point data is an important issue. Since the devices for sampling only sample discrete points, not the completely surface, sampling size and location of the points will be taken into consideration. In this paper a method is presented for determining the sampled points size and location for achieving efficient sampling. Firstly, uncertainty analysis of the localization parameters is investigated. A localization uncertainty model is developed to predict the uncertainty of the localization process. Using this model the minimum size of the sampled points is predicted. Secondly, based on the algebra theory an eigenvalue-optimal optimization is proposed. Then a freeform surface is used in the simulation. The proposed optimization is implemented. The simulation result shows its effectivity.
Abstract: This paper provides an exergy analysis of the multistage refrigeration cycle used for C2+ recovery plant. The behavior of an industrial refrigeration cycle with refrigerant propane has been investigated by the exergy method. A computational model based on the exergy analysis is presented for the investigation of the effects of the valves on the exergy losses, the second law of efficiency, and the coefficient of performance (COP) of a vapor compression refrigeration cycle. The equations of exergy destruction and exergetic efficiency for the main cycle components such as evaporators, condensers, compressors, and expansion valves are developed. The relations for the total exergy destruction in the cycle and the cycle exergetic efficiency are obtained. An ethane recovery unit with its refrigeration cycle has been simulated to prepare the exergy analysis. Using a typical actual work input value; the exergetic efficiency of the refrigeration cycle is determined to be 39.90% indicating a great potential for improvements. The simulation results reveal that the exergetic efficiencies of the heat exchanger and expansion sections get the lowest rank among the other compartments of refrigeration cycle. Refrigeration calculations have been carried out through the analysis of T–S and P–H diagrams where coefficient of performance (COP) was obtained as 1.85. The novelty of this article includes the effect and sensitivity analysis of molar flow, pressure drops and temperature on the exergy efficiency and coefficient of performance of the cycle.
Abstract: Ciprofloxacin (CIP) and Carbamazepine (CBZ), nonbiodegradable pharmaceutical residues, were become emerging pollutants in several aquatic environments. The objectives of this research were to study the possibility to recover these pharmaceuticals residues from pharmaceutical wastewater by increasing the selective adsorption on synthesized functionalized porous silicate, comparing with powdered activated carbon (PAC). Hexagonal mesoporous silicate (HMS), functionalized HMSs (3- aminopropyltriethoxy, 3- mercaptopropyltrimethoxy and noctyldimethyl) were synthesized and characterized physico-chemical characteristics. Obtained adsorption kinetics and isotherms showed that 3-mercaptopropyltrimethoxy functional groups grafted on HMS provided highest CIP and CBZ adsorption capacities; however, it was still lower than that of PAC. The kinetic results were compatible with pseudo-second order. The hydrophobicity and hydrogen bonding might play a key role on the adsorption. Furthermore, the capacities were affected by varying pH values due to the strength of hydrogen bonding between targeted compounds and adsorbents. Electrostatic interaction might not affect the adsorption capacities.
Abstract: The whole work is based on possibility to use Lego Mindstorms robotics systems to reduce costs. Lego Mindstorms consists of a wide variety of hardware components necessary to simulate, programme and test of robotics systems in practice. To programme algorithm, which simulates space using the ultrasonic sensor, was used development environment supplied with kit. Software Matlab was used to render values afterwards they were measured by ultrasonic sensor. The algorithm created for this paper uses theoretical knowledge from area of signal processing. Data being processed by algorithm are collected by ultrasonic sensor that scans 2D space in front of it. Ultrasonic sensor is placed on moving arm of robot which provides horizontal moving of sensor. Vertical movement of sensor is provided by wheel drive. The robot follows map in order to get correct positioning of measured data. Based on discovered facts it is possible to consider Lego Mindstorm for low-cost and capable kit for real-time modelling.
Abstract: With the presence of a uniform vertical magnetic field and suspended particles, thermocapillary instability in a horizontal liquid layer is investigated. The resulting eigenvalue is solved by the Galerkin technique for various basic temperature gradients. It is found that the presence of magnetic field always has a stability effect of increasing the critical Marangoni number.