Abstract: Strong anion exchange resins with QN+OH-, have the
potential to be developed and employed as heterogeneous catalyst for
transesterification, as they are chemically stable to leaching of the
functional group. Nine different SIERs (SIER1-9) with QN+OH-were
prepared by suspension polymerization of vinylbenzyl chloridedivinylbenzene
(VBC-DVB) copolymers in the presence of n-heptane
(pore-forming agent). The amine group was successfully grafted into
the polymeric resin beads through functionalization with
trimethylamine. These SIERs are then used as a catalyst for the
transesterification of triacetin with methanol. A set of differential
equations that represents the Langmuir-Hinshelwood-Hougen-
Watson (LHHW) and Eley-Rideal (ER) models for the
transesterification reaction were developed. These kinetic models of
LHHW and ER were fitted to the experimental data. Overall, the
synthesized ion exchange resin-catalyzed reaction were welldescribed
by the Eley-Rideal model compared to LHHW models,
with sum of square error (SSE) of 0.742 and 0.996, respectively.
Abstract: Medulloblastoma (MB) is one of the most prevalent
brain tumours among paediatrics. Although its management has
evolved over time still there is need to find new therapeutic targets
for MB that can result in less normal tissue toxicity while improving
survival and reducing recurrence. This literature review is aimed at
finding new potential therapeutic targets for MB focusing on viruses
that can be used as potential targets for MB. The review also gives an
over-view of management of paediatric Medulloblastoma focusing on
Radiotherapy management.
Abstract: Rhodamine B (RB) is a toxic dye used extensively in
textile industry, which must be remediated before its drainage to
environment. In the present study, supported gold nanoparticles on
commercially available titania and zincite were successfully prepared
and then their activity on the photodegradation of RB under UV A
light irradiation were evaluated. The synthesized photocatalysts were
characterized by ICP, BET, XRD, and TEM. Kinetic results showed
that Au/TiO2 was an inferior photocatalyst to Au/ZnO. This
observation could be attributed to the strong reflection of UV
irradiation by gold nanoparticles over TiO2 support.
Abstract: In this study, microcrystalline cellulose (MCC) was
extracted from oil palm empty fruit bunch (EFB) cellulose which was
earlier isolated from oil palm EFB fibre. In order to isolate the
cellulose, the chlorination method was carried out. Then, the MCC
was prepared by simultaneous ultrasonic and alkali treatment from
the isolated α-cellulose. Based on mass balance calculation, the yields
for MCC obtained from EFB was 44%. For fiber characterization, it
is observed that the chemical composition of the hemicellulose and
lignin for all samples decreased while composition for cellulose
increased. The structural property of the MCC was studied by X-ray
diffraction (XRD) method and the result shows that the MCC
produced is a cellulose-I polymorph, with 73% crystallinity.
Abstract: Domestic goats (Capra hircus) are extremely diverse
species and principal animal genetic resource of the developing
world. These facilitate a persistent supply of meat, milk, fibre, and
skin and are considered as important revenue generators in small
pastoral environments. This study aimed to fingerprint β-LG gene at
PCR-RFLP level in native Saudi goat breeds (Ardi, Habsi and Harri)
in an attempt to have a preliminary image of β-LG genotypic patterns
in Saudi breeds as compared to other foreign breeds such as Indian
and Egyptian. Also, the Phylogenetic analysis was done to investigate
evolutionary trends and similarities among the caprine β-LG gene
with that of the other domestic specie, viz. cow, buffalo and sheep.
Blood samples were collected from 300 animals (100 for each breed)
and genomic DNA was extracted. A fragment of the β-LG gene
(427bp) was amplified using specific primers. Subsequent digestion
with Sac II restriction endonuclease revealed two alleles (A and B)
and three different banding patterns or genotypes i.e. AA, AB and
BB. The statistical analysis showed a general trend that β-LG AA
genotype had higher milk yield than β-LG AB and β-LG BB
genotypes. Nucleotide sequencing of the selected β-LG fragments
was done and submitted to GenBank NCBI (Accession No.
KJ544248, KJ588275, KJ588276, KJ783455, KJ783456 and
KJ874959). Phylogenetic analysis on the basis of nucleotide
sequences of native Saudi goats indicated evolutional similarity with
the GenBank reference sequences of goat, Bubalus bubalis and Bos
taurus. However, the origin of sheep which is the most closely
related from the evolutionary point of view, was located some
distance away.
Abstract: The influence of three different types of halloysite
nanotubes (HNTs) with different dimensions, namely as camel lake
(CLA), Jarrahdale (JA) and Matauri Bay (MB), on their reinforcing
ability of ethylene propylene dine monomer (EPDM) were
investigated by varying the HNTs loading (from 0-15 phr).
Mechanical properties of the nanocomposites improved with addition
of all three HNTs, but CLA based nanocomposites exhibited a
significant enhancement compared to the other HNTs. For instance,
tensile properties of EPDM nanocomposites increased by 120%,
256% and 340% for MB, JA and CLA, respectively, with addition of
15 phr of HNTs. This could be due to the higher aspect ratio and
higher surface area of CLA compared to others. Scanning electron
microscopy (SEM) of nanocomposites at 15 phr of HNT loadings
showed low amounts of pulled-out nanotubes which confirmed the
presence of more embedded nanotubes inside the EPDM matrix, as
well as aggregates within the fracture surface of EPDM/HNT
nanocomposites
Abstract: This paper present the experimental work of double
unit tunnel form building (TFB) subjected to in-plane lateral cyclic
loading. A one third scale of 3-storey double unit of TFB is tested
until its strength degradation. Then, the TFB is repaired and
retrofitted using additional shear wall, steel angle and CFRP sheet.
The crack patterns, lateral strength, stiffness, ductility and equivalent
viscous damping (EVD) were analyzed and compared before and
after repair and retrofit. The result indicates that the lateral strength
increases by 22% in pushing and 27% in pulling direction. Moreover,
the stiffness and ductility obtained before and after retrofit increase
tremendously by 87.87% and 39.66%, respectively. Meanwhile, the
energy absorption measured by equivalent viscous damping obtained
after retrofit increase by 12.34% in pulling direction. It can be
concluded that the proposed retrofit method is capable to increase the
lateral strength capacity, stiffness and energy absorption of double
unit TFB.
Abstract: Due to the large amount of information in the World
Wide Web (WWW, web) and the lengthy and usually linearly
ordered result lists of web search engines that do not indicate
semantic relationships between their entries, the search for topically
similar and related documents can become a tedious task. Especially,
the process of formulating queries with proper terms representing
specific information needs requires much effort from the user. This
problem gets even bigger when the user's knowledge on a subject and
its technical terms is not sufficient enough to do so. This article
presents the new and interactive search application DocAnalyser that
addresses this problem by enabling users to find similar and related
web documents based on automatic query formulation and state-ofthe-
art search word extraction. Additionally, this tool can be used to
track topics across semantically connected web documents.
Abstract: Cement-based grouts has been used successfully to
repair cracks in many concrete structures such as bridges, tunnels,
buildings and to consolidate soils or rock foundations. In the present
study the rheological characterization of cement grout with
water/binder ratio (W/B) is fixed at 0.5. The effect of the replacement
of cement by bentonite (2 to 10% wt) in presence of superplasticizer
(0.5% wt) was investigated. Several rheological tests were carried out
by using controlled-stress rheometer equipped with vane geometry in
temperature of 20°C. To highlight the influence of bentonite and
superplasticizer on the rheological behavior of grout cement, various
flow tests in a range of shear rate from 0 to 200 s-1 were observed.
Cement grout showed a non-Newtonian viscosity behavior at all
concentrations of bentonite. Three parameter model Herschel-
Bulkley was chosen for fitting of experimental data. Based on the
values of correlation coefficients of the estimated parameters, The
Herschel-Bulkley law model well described the rheological behavior
of the grouts. Test results showed that the dosage of bentonite
increases the viscosity and yield stress of the system and introduces
more thixotropy. While the addition of both bentonite and
superplasticizer with cement grout improve significantly the fluidity
and reduced the yield stress due to the action of dispersion of SP.
Abstract: In this paper family of multilevel inverter topology
with reduced number of power switches is presented. The proposed
inverter can generate both even and odd level. The proposed topology
is suitable for symmetric structure. The proposed symmetric inverter
results in reduction of power switches, power diode and gate driver
circuits and also it may further minimize the installation area and
cost. To prove the superiority of proposed topology is compared with
conventional topologies. The performance of this symmetric
multilevel inverter has been tested by computer based simulation and
prototype based experimental setup for nine-level inverter is
developed and results are verified.
Abstract: Lately, asynchronous discussion forum is integrated in
higher educational institutions as it may increase learning process,
learners’ understanding, achievement and knowledge construction.
The asynchronous discussion forum is used to complement the
traditional, face-to-face learning session in hybrid learning courses.
However, studies have proven that students’ engagement in online
forums is still unconvincing. Thus, the aim of this study is to
investigate the motivating factors and obstacles that affect the
learners’ engagement in asynchronous discussion forum. This study
is carried out in one of the public higher educational institutions in
Malaysia with 18 postgraduate students as samples. The authors have
developed a 40-items questionnaire based on literature review. The
results indicate several factors that have encouraged or limited
students’ engagement in asynchronous discussion forum: (a) the
practices or behaviors of peers, or instructors, (b) the needs for the
discussions, (c) the learners’ personalities, (d) constraints in
continuing the discussion forum, (e) lack of ideas, (f) the level of
thoughts, (g) the level of knowledge construction, (h) technical
problems, (i) time constraints and (j) misunderstanding. This study
suggests some recommendations to increase the students’
engagement in online forums. Finally, based upon the findings, some
implications are proposed for further research.
Abstract: Mech-Degla, Degla-Beida and Frezza are the date
(Phoenix dactylifera L.) common varieties with a more or less good
availability and feeble trade value. Some morphologic and
physicochemical factors were determined. Results show that the
whole date weight is significantly different (P= 95%) concerning
Mech-Degla and Degla-Beida which are more commercialized than
Frezza whereas the pulp mass proportion in relation to whole fruits is
highest for Frezza (88.28%). Moreover, there is a large variability
concerning the weights and densities of constitutive tissues in each
variety. The white tissue is dominant in Mech-Degla in opposite to
the two other varieties. The variance analyze showed that the
difference in weights between brown and white tissues is significant
(P = 95%) for all studied varieties. Some other morphologic and
chemical proprieties of the whole pulps and their two constitutive
parts (brown or pigmented and white) are also investigated. The
predominance of phenolics in Mech-Degla (4.01g/100g, w.b) and
Frezza (4.96 g/100g, w.b) pulps brown part is the main result
revealed in this study.
Abstract: In this study, we develop a performance evaluation
model based on a multi-attribute utility approach aiming at reaching
the sustainable banking (SB) status. This model is built accounting
for various banks’ stakeholders in a win-win paradigm. In addition, it
offers the opportunity for adopting a global measure of performance
as an indication of a bank’s sustainability degree. This measure is
referred to as banking sustainability performance index (BSPI). This
index may constitute a basis for ranking banks. Moreover, it may
constitute a bridge between the assessment types of financial and
extra-financial rating agencies. A real application is performed on
three French banks.
Abstract: In the present work, the effects of additives, including
contents of the added antioxidants and type of the selected metallic
stearates (either calcium stearate (CaSt) or zinc stearate (ZnSt)), on
the thermal stabilities of carbon black (CB)/high density polyethylene
(HDPE) compounds were studied. The results showed that the AO
contents played a key role in the thermal stabilities of the CB/HDPE
compounds — the higher the AO content, the higher the thermal
stabilities. Although the CaSt-containing compounds were slightly
superior to those with ZnSt in terms of the thermal stabilities, the
remaining solid residue of CaSt after heated to the temperature of 600
°C (mainly calcium carbonate (CaCO3) as characterized by the X-ray
diffraction (XRD) technique) seemed to catalyze the decomposition
of CB in the HDPE-based compounds. Hence, the quantification of
CB in the CaSt-containing compounds with a muffle furnace gave an
inaccurate CB content — much lower than actual value. However,
this phenomenon was negligible in the ZnSt-containing system.
Abstract: This paper presents a model predictive control (MPC)
of a utility interactive (UI) single phase inverter (SPI) for a
photovoltaic (PV) system at residential/distribution level. The
proposed model uses single-phase phase locked loop (PLL) to
synchronize SPI with the grid and performs MPC control in a dq
reference frame. SPI model consists of boost converter (BC),
maximum power point tracking (MPPT) control, and a full bridge
(FB) voltage source inverter (VSI). No PI regulators to tune and
carrier and modulating waves are required to produce switching
sequence. Instead, the operational model of VSI is used to synthesize
sinusoidal current and track the reference. Model is validated using a
three kW PV system at the input of UI-SPI in Matlab/Simulink.
Implementation and results demonstrate simplicity and accuracy, as
well as reliability of the model.
Abstract: The use of permanent magnets (PM) is increasing in
permanent magnet synchronous machines (PMSM) to fulfill the
requirements of high efficiency machines in modern industry. PMSM
are widely used in industrial applications, wind power plants and the
automotive industry. Since PMSM are used in different
environmental conditions, the long-term effect of NdFeB-based
magnets at high temperatures and their corrosion behavior have to be
studied due to the irreversible loss of magnetic properties.
In this paper, the effect of magnetic properties due to corrosion
and increasing temperature in a climatic chamber has been presented.
The magnetic moment and magnetic field of the magnets were
studied experimentally.
Abstract: The lactic acid bacteria (LAB) were isolated from
10 samples of fermented foods (Sa-tor-dong and Bodo) in South
locality of Thailand. The 23 isolates of lactic acid bacteria were
selected, which were exhibited a clear zone and growth on MRS
agar supplemented with CaCO3. All of lactic acid bacteria were
tested on morphological and biochemical. The result showed that
all isolates were Gram’s positive, non-spore forming but only
10 isolates displayed catalase negative. The 10 isolates including
BD1 .1, BD 1.2, BD 2.1, BD2.2, BD 2.3, BD 3.1, BD 4.1, BD 5.2,
ST 4.1 and ST 5.2 were selected for inhibition activity
determination. Only 2 strains (ST 4.1 and BD 2.3) showed
inhibition zone on agar, when using Escherichia coli sp. as target
strain. The ST 4.1 showed highest inhibition zone on agar, which
was selected for probiotic property testing. The ST4.1 isolate
could grow in MRS broth containing a high concentration of
sodium chloride 6%, bile salts 7%, pH 4-10 and vary temperature
at 15-45°C.
Abstract: It is well known, that any interpolating polynomial
p (x, y) on the vector space Pn,m of two-variable polynomials with
degree less than n in terms of x and less than m in terms of y, has
various representations that depends on the basis of Pn,m that we
select i.e. monomial, Newton and Lagrange basis e.t.c.. The aim of
this short note is twofold : a) to present transformations between the
coordinates of the polynomial p (x, y) in the aforementioned basis
and b) to present transformations between these bases.
Abstract: One of the major goals of Spoken Dialog Systems
(SDS) is to understand what the user utters.
In the SDS domain, the Spoken Language Understanding (SLU)
Module classifies user utterances by means of a pre-definite
conceptual knowledge. The SLU module is able to recognize only the
meaning previously included in its knowledge base. Due the vastity
of that knowledge, the information storing is a very expensive
process.
Updating and managing the knowledge base are time-consuming
and error-prone processes because of the rapidly growing number of
entities like proper nouns and domain-specific nouns. This paper
proposes a solution to the problem of Name Entity Recognition
(NER) applied to a SDS domain. The proposed solution attempts to
automatically recognize the meaning associated with an utterance by
using the PANKOW (Pattern based Annotation through Knowledge
On the Web) method at runtime.
The method being proposed extracts information from the Web to
increase the SLU knowledge module and reduces the development
effort. In particular, the Google Search Engine is used to extract
information from the Facebook social network.
Abstract: Three dimensional non-Interlaced carbon fibre
reinforced silicon carbide (3-D-Cf/SiC) composites with pyrocarbon
interphase were fabricated using isothermal chemical vapor
infiltration (ICVI) combined with polymer impregnation pyrolysis
(PIP) process. Polysilazane (PSZ) is used as a preceramic polymer to
obtain silicon carbide matrix. Thermo gravimetric analysis (TGA),
Infrared spectroscopic analysis (IR) and X-ray diffraction (XRD)
analysis were carried out on PSZ pyrolysed at different temperatures
to understand the pyrolysis and obtaining the optimum pyrolysing
condition to yield β-SiC phase. The density of the composites was
1.94 g cm-3 after the 3-D carbon preform was SiC infiltrated for 280 h
with one intermediate polysilazane pre-ceramic PIP process.
Mechanical properties of the composite materials were investigated
under tensile, flexural, shear and impact loading. The values of
tensile strength were 200 MPa at room temperature (RT) and 195
MPa at 500°C in air. The average RT flexural strength was 243 MPa.
The lower flexural strength of these composites is because of the
porosity. The fracture toughness obtained from single edge notched
beam (SENB) technique was 39 MPa.m1/2. The work of fracture
obtained from the load-displacement curve of SENB test was 22.8
kJ.m-2. The composites exhibited excellent impact resistance and the
dynamic fracture toughness of 44.8 kJ.m-2 is achieved as determined
from instrumented Charpy impact test. The shear strength of the
composite was 93 MPa, which is significantly higher compared 2-D
Cf/SiC composites. Microstructure evaluation of fracture surfaces
revealed the signatures of fracture processes and showed good
support for the higher toughness obtained.