Abstract: Hydrogels are three-dimensional, hydrophilic,
polymeric networks composed of homopolymers or copolymers and
are insoluble in water due to the presence of chemical or physical
cross-links. When hydrogels come in contact with aqueous solutions,
they can effectively sorb and retain the dissolved substances,
depending on the nature of the monomeric units comprising the
hydrogel. For this reason, hydrogels have been proposed in several
studies as water purification agents. At the present work anionic
hydrogels bearing negatively charged –COO- groups were prepared
and investigated. These gels are based on sodium acrylate (ANa),
either homopolymerized (poly(sodiumacrylate), PANa) or
copolymerized (P(DMAM-co-ANa)) with N,N Dimethylacrylamide
(DMAM). The hydrogels were used to extract some model organic
dyes from water. It is found that cationic dyes are strongly sorbed and
retained by the hydrogels, while sorption of anionic dyes was
negligible. In all cases it was found that both maximum sorption
capacity and equilibrium binding constant varied from one dye to the
other depending on the chemical structure of the dye, the presence of
functional chemical groups and the hydrophobic-hydrophilic balance.
Finally, the nonionic hydrogel of the homopolymer poly(N,Ndimethylacrylamide),
PDMAM, was also used for reasons of
comparison.
Abstract: Revenue leakages are one of the major challenges
manufacturers face in production processes, as most of the input
materials that should emanate as products from the lines are lost as
waste. Rather than generating income from material input which is
meant to end-up as products, losses are further incurred as costs in
order to manage waste generated. In addition, due to the lack of a
clear view of the flow of resources on the lines from input to output
stage, acquiring information on the true cost of waste generated have
become a challenge. This has therefore given birth to the
conceptualization and implementation of waste minimization
strategies by several manufacturing industries. This paper reviews the
principles and applications of three environmental management
accounting tools namely Activity-based Costing (ABC), Life-Cycle
Assessment (LCA) and Material Flow Cost Accounting (MFCA) in
the manufacturing industry and their effectiveness in curbing revenue
leakages. The paper unveils the strengths and limitations of each of
the tools; beaming a searchlight on the tool that could allow for
optimal resource utilization, transparency in production process as
well as improved cost efficiency. Findings from this review reveal
that MFCA may offer superior advantages with regards to the
provision of more detailed information (both in physical and
monetary terms) on the flow of material inputs throughout the
production process compared to the other environmental accounting
tools. This paper therefore makes a case for the adoption of MFCA as
a viable technique for the identification and reduction of waste in
production processes, and also for effective decision making by
production managers, financial advisors and other relevant
stakeholders.
Abstract: In this numerical study, effects of using Al2O3-water
nanofluid on the rate of heat transfer have been investigated. Physical
model is a square enclosure with insulated top and bottom horizontal
walls, while the vertical walls are kept at different constant
temperatures. Two appropriate models are used to evaluate the
viscosity and thermal conductivity of nanofluid. The governing
stream-vorticity equations are solved using a second order central
finite difference scheme, coupled to the conservation of mass and
energy. The study has been carried out for the nanoparticle diameter
30, 60 and 90 nm and the solid volume fraction 0 to 0.04. Results are
presented by average Nusselt number and normalized Nusselt number
in different range of φ and D for mixed convection dominated
regime. It is found that different heat transfer rate is predicted when
the effect of nanoparticle diameter is taken into account.
Abstract: This study aims to assess the students' needs for the
tour planning e-guide. The study is developing on the contribution
and importance of the Educational Tour Planning Guide (ETP) is a
multimedia course ware as one of the effective methods in teaching
and learning of environmental science among the students in primary
schools of the Ministry of Education, Malaysia. It is to provide the
student with knowledge and experience about tourism, environmental
science activities and process. E-guide to ETP also hopes to
strengthen the student understanding toward the subject learn in the
tourism environmental science. In order to assess the student's needs
on the e-Guide to Educational Tour Planning in Environmental
Science, the study has produced a similar e-Guide to ETP in the form
as a course ware to be tested during the study. The study has involved
several steps in order to be completed. It is such as the formulation of
the problem, the review of the literature, the formulation of the study
methodology, the production of the e-Guide to ETP, field survey and
finally the analyses and discussion made on the data gathered during
the study. The survey has involved 100 respondents among the
students in standard six primary schools in Kluang Johor. Through
the findings, the study indicates that the current tested product is
acceptable among the students in learning environmental science as a
guide to plan for the tour. The findings also show a slight difference
between the respondents who are using the e-Guide to ETP, and those
who are not on the basis of the e-Guide to ETP results. Due the
important for the study, the researcher hopes to be having a fair
discussion and excellence, recommendation for the development of
the product of the current study. This report is written also important
to provide a written reference for the future related study.
Abstract: This study was conducted to investigate the extent
with which knowledge of results influences the performance of
cricket players. A sample of 160 fresh students in the Department of
Physical and Health Education who are novice in the game were
randomly assigned into two groups. The first group of eighty (80)
subjects was classified as experimental group while the second group
of eighty (80) subjects was the control group. Subjects in both groups
were asked to bowl and bat ten times each for a period of six weeks.
After the first round, the subjects in the experimental group were
allowed feedback on their performance in the first trial while those in
the control group were denied feedback. Two null hypotheses
generated for the study were tested using percentages and chi-square
statistical analysis at 0.05 level of significance. Analysis of data
showed that knowledge of results influenced the performance of
cricket players. It was concluded that knowledge of results is
pertinent for effective skill acquisition and could enhance better
performance among unskilled cricket players. Hence, it is suggested
that immediate feedback on the level of skill acquisition by the
prospective and unskilled cricket players would inspire them for
better performance in cricket tournaments.
Abstract: Polylactic acid (PLA) is the most commercially
available bio-based and biodegradable plastic at present. PLA has
been used in plastic related industries including single-used
containers, disposable and environmentally friendly packaging owing
to its renewability, compostability, biodegradability, and safety.
Although PLA demonstrates reasonably good optical, physical,
mechanical and barrier properties comparable to the existing
petroleum-based plastics, its brittleness and mold shrinkage as well as
its price are the points to be concerned for the production of rigid and
semi-rigid packaging. Blending PLA with other bio-based polymers
including thermoplastic starch (TPS) is an alternative not only to
achieve a complete bio-based plastic, but also to reduce the
brittleness, shrinkage during molding and production cost of the
PLA-based products. TPS is a material produced mainly from starch
which is cheap, renewable, biodegradable, compostable, and nontoxic.
It is commonly prepared by a plasticization of starch under
applying heat and shear force. Although glycerol has been reported as
one of the most plasticizers used for preparing TPS, its migration
caused the surface stickiness of the TPS products. In some cases,
mixed plasticizers or natural fibers have been applied to impede the
retrogradation of starch or reduce the migration of glycerol. The
introduction of fibers into TPS-based materials could reinforce the
polymer matrix as well. Therefore, the objective of the present
research is to study the effect of starch type (i.e. native starch and
phosphate starch), plasticizer type (i.e. glycerol and xylitol with a
weight ratio of glycerol to xylitol of 100:0, 75:25, 50:50, 25:75 and
0:100) and fiber content (i.e. in the range of 1-25 %wt) on properties
of PLA/TPS blend and composite. PLA/TPS blends and composites
were prepared using a twin-screw extruder and then converted into
dumbbell-shaped specimens using an injection molding machine. The
PLA/TPS blends prepared by using phosphate starch showed higher
tensile strength and stiffness than the blends prepared by using native
one. In contrast, the blends from native starch exhibited higher
extensibility and heat distortion temperature (HDT) than those from
the modified starch. Increasing xylitol content resulted in enhanced
tensile strength, stiffness and water resistance, but decreased
extensibility and HDT of the PLA/TPS blend. Tensile properties and
hydrophobicity of the blend could be improved by incorporating
silane treated-jute fibers.
Abstract: Household waste form a larger proportion of waste
generated across the state, accumulation of organic waste is an
apparent problem and the existing dump sites could be overstress.
Niger state has abundant arable land and water resources thus should
be one of the highest producers of agricultural crops in the country.
However, the major challenge to agricultural sector today is loss of
soil nutrient coupled with high cost of fertilizer. These have
continued to increase the use of fertilizer and decomposed solid waste
for enhance agricultural yield, which have varying effects on the soil
as well a threat to human livelihood. Consequently, vegetable yield
samples from poultry droppings, decomposed household waste
manure, NPK treatments and control from each replication were
subjected to proximate analysis to determine the nutritional and antinutritional
component as well as heavy metal concentration. Data
collected was analyzed using SPSS software and Randomized
complete Block Design means were compared. The result shows that
the treatments do not devoid the concentrations of any nutritional
components while the anti-nutritional analysis proved that NPK had
higher oxalate content than control and organic treats. The
concentration of lead and cadmium are within safe permissible level
while the mercury level exceeded the FAO/WHO maximum
permissible limit for the entire treatments depicts the need for urgent
intervention to minimize mercury levels in soil and manure in order
to mitigate its toxic effect. Thus, eco-agriculture should be widely
accepted and promoted by the stakeholders for soil amendment,
higher yield, strategies for sustainable environmental protection, food
security, poverty eradication, attainment of sustainable development
and healthy livelihood.
Abstract: Nowadays, illegal logging has been causing many
effects including flash flood, avalanche, global warming, and etc. The
purpose of this study was to maintain the earth ecosystem by keeping
and regulate Malaysia’s treasurable rainforest by utilizing a new
technology that will assist in real-time alert and give faster response
to the authority to act on these illegal activities. The methodology of
this research consisted of design stages that have been conducted as
well as the system model and system architecture of the prototype in
addition to the proposed hardware and software that have been
mainly used such as microcontroller, sensor with the implementation
of GSM, and GPS integrated system. This prototype was deployed at
Royal Belum forest in December 2014 for phase 1 and April 2015 for
phase 2 at 21 pinpoint locations. The findings of this research were
the capture of data in real-time such as temperature, humidity,
gaseous, fire, and rain detection which indicate the current natural
state and habitat in the forest. Besides, this device location can be
detected via GPS of its current location and then transmitted by SMS
via GSM system. All of its readings were sent in real-time for further
analysis. The data that were compared to meteorological department
showed that the precision of this device was about 95% and these
findings proved that the system is acceptable and suitable to be used
in the field.
Abstract: The Greater Athens Area (GAA) faces photochemical
and particulate pollution episodes as a result of the combined effects
of local pollutant emissions, regional pollution transport, synoptic
circulation and topographic characteristics. The area has undergone
significant changes since the Athens 2004 Olympic Games because
of large scale infrastructure works that lead to the shift of population
to areas previously characterized as rural, the increase of the traffic
fleet and the operation of highways. However, few recent modelling
studies have been performed due to the lack of an accurate, updated
emission inventory. The photochemical modelling system
MM5/CAMx was applied in order to study the photochemical and
particulate pollution characteristics above the GAA for two distinct
ten-day periods in the summer of 2006 and 2010, where air pollution
episodes occurred. A new updated emission inventory was used
based on official data. Comparison of modeled results with
measurements revealed the importance and accuracy of the new
Athens emission inventory as compared to previous modeling
studies. The model managed to reproduce the local meteorological
conditions, the daily ozone and particulates fluctuations at different
locations across the GAA. Higher ozone levels were found at
suburban and rural areas as well as over the sea at the south of the
basin. Concerning PM10, high concentrations were computed at the
city centre and the southeastern suburbs in agreement with measured
data. Source apportionment analysis showed that different sources
contribute to the ozone levels, the local sources (traffic, port
activities) affecting its formation.
Abstract: The present study deals with the characterization of
CrSiN coatings obtained by PVD magnetron sputtering systems.
CrSiN films were deposited with different Si contents, in order to
check the effect of at.% variation on the different properties of the
Cr–N system. Coatings were characterized by scanning electron
microscopy (SEM) for thickness measurements, X-ray diffraction.
Surface morphology and the roughness characteristics were explored
using AFM, Mechanicals properties, elastic and plastic deformation
resistance of thin films were investigated using nanoindentation test. We observed that the Si addition improved the hardness and the
Young’s modulus of the Cr–N system. Indeed, the hardness value is
18,56 GPa for CrSiN coatings. Besides, the Young’s modulus value
is 224,22 GPa for CrSiN coatings for Si content of 1.2 at.%.
Abstract: In the present study, analysis of heat transfer is carried
out in the slip flow region for the fluid flowing between two parallel
plates by employing the asymmetric heat fluxes at surface of the
plates. The flow is assumed to be hydrodynamically and thermally
fully developed for the analysis. The second order velocity slip and
viscous dissipation effects are considered for the analysis. Closed
form expressions are obtained for the Nusselt number as a function of
Knudsen number and modified Brinkman number. The limiting
condition of the present prediction for Kn = 0, Kn2 = 0, and Brq1 = 0
is considered and found to agree well with other analytical results.
Abstract: The advancements in technology allow the
development of a new system that can continuously measure surface
soil erosion. Continuous soil erosion measurements are required in
order to comprehend the erosional processes and propose effective
and efficient conservation measures to mitigate surface erosion.
Mitigating soil erosion, especially in Mediterranean countries such as
Greece, is essential in order to maintain environmental and
agricultural sustainability. In this paper, we present the Automated
Soil Erosion Monitoring System (ASEMS) that measures surface soil
erosion along with other factors that impact erosional process.
Specifically, this system measures ground level changes (surface soil
erosion), rainfall, air temperature, soil temperature, and soil moisture.
Another important innovation is that the data will be collected by
remote communication. In addition, stakeholder’s awareness is a key
factor to help reduce any environmental problem. The different
dissemination activities that were utilized are described. The overall
outcomes were the development of a new innovative system that can
measure erosion very accurately. These data from the system help
study the process of erosion and find the best possible methods to
reduce erosion. The dissemination activities enhance the stakeholders
and public's awareness on surface soil erosion problems and will lead
to the adoption of more effective soil erosion conservation practices
in Greece.
Abstract: The development of composite materials and the
related design and manufacturing technologies is one of the most
important advances in the history of materials. Composites are
multifunctional materials having unprecedented mechanical and
physical properties that can be tailored to meet the requirements of a
particular application. Some composites also exhibit great resistance
to high-temperature corrosion, oxidation, and wear. Polymers are
widely used indoors and outdoors, therefore they are exposed to a
chemical environment which may include atmospheric oxygen, acidic
fumes, acidic rain, moisture heat and thermal shock, ultra-violet light,
high energy radiation, etc. Different polymers are affected differently
by these factors even though the amorphous polymers are more
sensitive. Ageing is also important and it is defined as the process of
deterioration of engineering materials resulting from the combined
effects of atmospheric radiation, heat, oxygen, water, microorganisms
and other atmospheric factors.
Abstract: Analytical techniques for measuring and planning
railway capacity expansion activities have been considered in this
article. A preliminary mathematical framework involving track
duplication and section sub divisions is proposed for this task. In
railways, these features have a great effect on network performance
and for this reason they have been considered. Additional motivations
have also arisen from the limitations of prior models that have not
included them.
Abstract: This article presents the main results of a numerical
investigation on the uncertainty of dynamic response of structures
with statistically correlated random damping Gamma distributed. A
computational method based on a Linear Statistical Model (LSM) is
implemented to predict second order statistics for the response of a
typical industrial building structure. The significance of random
damping with correlated parameters and its implications on the
sensitivity of structural peak response in the neighborhood of a
resonant frequency are discussed in light of considerable ranges of
damping uncertainties and correlation coefficients. The results are
compared to those generated using Monte Carlo simulation
techniques. The numerical results obtained show the importance of
damping uncertainty and statistical correlation of damping
coefficients when obtaining accurate probabilistic estimates of
dynamic response of structures. Furthermore, the effectiveness of the
LSM model to efficiently predict uncertainty propagation for
structural dynamic problems with correlated damping parameters is
demonstrated.
Abstract: The present study focused on the investigation of the
effects of roughness elements on heat transfer during natural
convection in a rectangular cavity using numerical technique.
Roughness elements were introduced on the bottom hot wall with a
normalized amplitude (A*/H) of 0.1. Thermal and hydrodynamic
behaviors were studied using computational method based on Lattice
Boltzmann method (LBM). Numerical studies were performed for a
laminar flow in the range of Rayleigh number (Ra) from 103 to 106
for a rectangular cavity of aspect ratio (L/H) 2.0 with a fluid of
Prandtl number (Pr) 1.0. The presence of the sinusoidal roughness
elements caused a minimum to maximum decrease in the heat
transfer as 7% to 17% respectively compared to smooth enclosure.
The results are presented for mean Nusselt number (Nu), isotherms
and streamlines.
Abstract: The study conducted a simulation of the effect of sea
water to the bonding capacity of GFRP sheet on the concrete beams
using a simulation tank. Fiber reinforced polymer (FRP) has been
developed and applied in many fields civil engineering structures on
the new structures and also for strengthening of the deteriorated
structures. The FRP has advantages such as its corrosion resistance as
well as high tensile strength to weight ratio. Compared to the other
FRP materials, Glass composed FRP (GFRP) is relatively cheaper.
GFRP sheet is applied externally by bonding it on the concrete surface.
The studies regarding the application of GFRP sheet have been
conducted such as strengthening system, bonding behavior of GFRP
sheet including the application as reinforcement in new structures. For
application to the structures with direct contact to sea environment, a
study regarding the effect of sea water to the bonding capacity of
GFRP sheet is important to be clarified. To achieve the objective of the
study, a series of concrete beams strengthened with GFRP sheet on
extreme tension surface were prepared. The beams then were stored on
the sea water tank for six months. Results indicated the bonding
capacity decreased after six month exposed to the sea water.
Abstract: In the last decade the emergence of new social needs
as an effect of the economic crisis has stimulated the flourishing of
business endeavours characterised by explicit social goals. Social
start-ups, social enterprises or Corporate Social Responsibility
operations carried out by traditional companies are quintessential
examples in this regard. This paper analyses these kinds of initiatives
in order to discover the main characteristics of social business models
and to provide insights to social entrepreneurs for developing or
improving their strategies. The research is conducted through the
integration of literature review and case study analysis and, thanks to
the recognition of the importance of both profits and social impacts
as the key success factors for a social business model, proposes a
framework for identifying indicators suitable for measuring the social
impacts generated.
Abstract: Carbon Fiber Reinforced Plastics (CFRPs) are widely
used for advanced applications, in particular in aerospace, automotive
and wind energy industries. Once cured to near net shape, CFRP
parts need several finishing operations such as trimming, milling or
drilling in order to accommodate fastening hardware and meeting the
final dimensions. The present research aims to study the effect of the
cutting temperature in trimming on the mechanical strength of high
performance CFRP laminates used for aeronautics applications. The
cutting temperature is of great importance when dealing with
trimming of CFRP. Temperatures higher than the glass-transition
temperature (Tg) of the resin matrix are highly undesirable: they
cause degradation of the matrix in the trimmed edges area, which can
severely affect the mechanical performance of the entire component.
In this study, a 9.50mm diameter CVD diamond coated carbide tool
with six flutes was used to trim 24-plies CFRP laminates. A
300m/min cutting speed and 1140mm/min feed rate were used in the
experiments. The tool was heated prior to trimming using a
blowtorch, for temperatures ranging from 20°C to 300°C. The
temperature at the cutting edge was measured using embedded KType
thermocouples. Samples trimmed for different cutting
temperatures, below and above Tg, were mechanically tested using
three-points bending short-beam loading configurations. New cutting
tools as well as worn cutting tools were utilized for the experiments.
The experiments with the new tools could not prove any correlation
between the length of cut, the cutting temperature and the mechanical
performance. Thus mechanical strength was constant, regardless of
the cutting temperature. However, for worn tools, producing a cutting
temperature rising up to 450°C, thermal damage of the resin was
observed. The mechanical tests showed a reduced mean resistance in
short beam configuration, while the resistance in three point bending
decreases with increase of the cutting temperature.
Abstract: In recent years, the power system has been changed
and a flexible power pricing system such as demand response has been
sought in Japan. The demand response system works simply in the
household sector and the owner as the decision-maker, can benefit
from power saving. On the other hand, the execution of demand
response in the office building is more complex than in the household
because various people such as owners, building administrators and
occupants are involved in the decision-making process. While the
owners benefit from demand saving, the occupants are exposed to
restricted benefits of a demand-saved environment. One of the reasons
is that building systems are usually under centralized management and
each occupant cannot choose freely whether to participate in demand
response or not. In addition, it is unclear whether incentives give
occupants the motivation to participate. However, the recent
development of IT and building systems enables the personalized
control of the office environment where each occupant can control the
lighting level or temperature individually. Therefore, it can be possible
to have a system which each occupant can make a decision of whether
or not to participate in demand response in the office building. This study investigates personal responses to demand response
requests, under the condition where each occupant can adjust their
brightness individually in their workspace. Once workers participate
in the demand response, their desk-lights are automatically turned off.
The participation rates in the demand response events are compared
among four groups, which are divided by different motivation, the
presence, or absence of incentives and the method of participation. The
result shows that there are significant differences of participation rates
in demand response event between four groups. The method of
participation has a large effect on the participation rate. The “Opt-out”
groups where the occupants are automatically enrolled in a demand
response event if they do not express non-participation have the
highest participation rate in the four groups. Incentives also have an
effect on the participation rate. This study also reports on the impact of low illumination office
environment on the occupants, such as stress or fatigue. The
electrocardiogram and the questionnaire are used to investigate the
autonomic nervous activity and subjective fatigue symptoms of the
occupants. There is no big difference between dim workspace during
demand response event and bright workspace in autonomic nervous
activity and fatigue.