Abstract: Alkylated silicon nanocrystals (C11-SiNCs) were
prepared successfully by galvanostatic etching of p-Si(100) wafers
followed by a thermal hydrosilation reaction of 1-undecene in
refluxing toluene in order to extract C11-SiNCs from porous silicon.
Erbium trichloride was added to alkylated SiNCs using a simple
mixing chemical route. To the best of our knowledge, this is the first
investigation on mixing SiNCs with erbium ions (III) by this
chemical method. The chemical characterization of C11-SiNCs and
their mixtures with Er3+(Er/C11-SiNCs) were carried out using X-ray
photoemission spectroscopy (XPS). The optical properties of C11-
SiNCs and their mixtures with Er3+ were investigated using Raman
spectroscopy and photoluminescence (PL). The erbium mixed
alkylated SiNCs shows an orange PL emission peak at around 595
nm that originates from radiative recombination of Si. Er/C11-SiNCs
mixture also exhibits a weak PL emission peak at 1536 nm that
originates from the intra-4f transition in erbium ions (Er3+). The PL
peak of Si in Er/C11-SiNCs mixture is increased in the intensity up to
three times as compared to pure C11-SiNCs. The collected data
suggest that this chemical mixing route leads instead to a transfer of
energy from erbium ions to alkylated SiNCs.
Abstract: Modular structural systems are constructed using a
method that they are assembled with prefabricated unit modular
frames on-site. This provides a benefit that can significantly reduce
building construction time. The structural design is usually carried out
under the assumption that their load-carrying mechanism is similar to
that of traditional steel moment-resisting systems. However, both
systems are different in terms of beam-column connection details
which may strongly influence the lateral structural behavior. Specially,
the presence of access holes in a beam-column joint of a unit modular
frame could cause undesirable failure during strong earthquakes.
Therefore, this study carried out finite element analyses (FEMs) of
unit modular frames to investigate the cyclic behavior of beam-column
joints with the access holes. Analysis results show that the unit
modular frames present stable cyclic response with large deformation
capacities and their joints are classified into semi-rigid connections
even if there are access holes.
Abstract: Starting in 2020, an EU-wide CO2-limitation of
95 g/km is scheduled for the average of an OEMs passenger car fleet.
Taking that into consideration additional improvement measures of
the Diesel cycle are necessary in order to reduce fuel consumption
and emissions while boosting, or at the least, keeping performance
values at the same time.
The present article deals with the possibilities of an optimized
air/water charge air cooler, also called iCAC (indirect Charge Air
Cooler) for a Diesel passenger car amongst extreme-boundary
conditions. In this context, the precise objective was to show the
impact of improved intercooling with reference to the engine working
process (fuel consumption and NOx-emissions). Several extremeboundaries
- e.g. varying ambient temperatures or mountainous
routes - that will become very important in the near future regarding
RDE (Real Driving emissions) were subject of the investigation.
With the introduction of RDE in 2017 (EU6c measure), the
controversial NEDC (New European Driving Cycle) will belong to
the past and the OEMs will have to avoid harmful emissions in any
conceivable real life situation.
This is certainly going to lead to optimization-measurements at the
powertrain, which again is going to make the implementation of
iCACs, presently solely used for the premium class, more and more
attractive for compact class cars. The investigations showed a benefit
in FC between 1 and 3% for the iCAC in real world conditions.
Abstract: Strong anion exchange resins with QN+OH-, have the
potential to be developed and employed as heterogeneous catalyst for
transesterification, as they are chemically stable to leaching of the
functional group. Nine different SIERs (SIER1-9) with QN+OH-were
prepared by suspension polymerization of vinylbenzyl chloridedivinylbenzene
(VBC-DVB) copolymers in the presence of n-heptane
(pore-forming agent). The amine group was successfully grafted into
the polymeric resin beads through functionalization with
trimethylamine. These SIERs are then used as a catalyst for the
transesterification of triacetin with methanol. A set of differential
equations that represents the Langmuir-Hinshelwood-Hougen-
Watson (LHHW) and Eley-Rideal (ER) models for the
transesterification reaction were developed. These kinetic models of
LHHW and ER were fitted to the experimental data. Overall, the
synthesized ion exchange resin-catalyzed reaction were welldescribed
by the Eley-Rideal model compared to LHHW models,
with sum of square error (SSE) of 0.742 and 0.996, respectively.
Abstract: Currently, thorium fuel has been especially noticed
because of its proliferation resistance than long half-life alpha emitter
minor actinides, breeding capability in fast and thermal neutron flux
and mono-isotopic naturally abundant. In recent years, efficiency of
minor actinide burning up in PWRs has been investigated. Hence, a
minor actinide-contained thorium based fuel matrix can confront both
proliferation resistance and nuclear waste depletion aims. In the
present work, minor actinide depletion rate in a CANDU-type nuclear
core modeled using MCNP code has been investigated. The obtained
effects of minor actinide load as mixture of thorium fuel matrix on
the core neutronics has been studied with comparing presence and
non-presence of minor actinide component in the fuel matrix.
Depletion rate of minor actinides in the MA-contained fuel has been
calculated using different power loads. According to the obtained
computational data, minor actinide loading in the modeled core
results in more negative reactivity coefficients. The MA-contained
fuel achieves less radial peaking factor in the modeled core. The
obtained computational results showed 140 kg of 464 kg initial load
of minor actinide has been depleted in during a 6-year burn up in 10
MW power.
Abstract: Developing young people’s employability is a key
policy issue for ensuring their successful transition to the labour
market and their access to career oriented employment. The youths of
today irrespective of their gender need to acquire the knowledge,
skills and attitudes that will enable them to create or find jobs as well
as cope with unpredictable labour market changes throughout their
working lives. In a study carried out to determine the influence of
gender on job-competencies requirements of chemical-based
industries and undergraduate-competencies acquisition by chemists
working in the industries, all chemistry graduates working in twenty
(20) chemical-based industries that were randomly selected from six
sectors of chemical-based industries in Lagos and Ogun States of
Nigeria were administered with Job-competencies required and
undergraduate-competencies acquired assessment questionnaire. The
data were analysed using means and independent sample t-test. The
findings revealed that the population of female chemists working in
chemical-based industries is low compared with the number of male
chemists; furthermore, job-competencies requirements are found not
to be gender biased while there is no significant difference in
undergraduate-competencies acquisition of male and female
chemists. This suggests that females should be given the same
opportunity of employment in chemical-based industries as their male
counterparts. The study also revealed the level of acquisition of
undergraduate competencies as related to the needs of chemicalbased
industries.
Abstract: e-Service has moved from the usual manual and
traditional way of rendering services to electronic service provision
for the public and there are several reasons for implementing these
services, Airline ticketing have gone from its manual traditional way
to an intelligent web-driven service of purchasing. Many companies
have seen their profits doubled through the use of online services in
their operation and a typical example is Hewlett Packard (HP) which
is rapidly transforming their after sales business into a profit
generating e-service business unit.
This paper will examine the various challenges confronting e-
Service adoption and implementation in Nigeria and also analyse
lessons learnt from e-Service adoption and implementation in Asia to
see how it could be useful in Nigeria which is a lower middle income
country. From the analysis of the online survey data, it has been
identified that the public in Nigeria are much aware of e-Services but
successful adoption and implementation have been the problems
faced.
Abstract: Liposome plays an important role in medical and
pharmaceutical science as e.g. nano scale drug carriers. Liposomes
are vesicles of varying size consisting of a spherical lipid bilayer and
an aqueous inner compartment. Magnet-driven liposome used for the
targeted delivery of drugs to organs and tissues. These liposome
preparations contain encapsulated drug components and finely
dispersed magnetic particles.
Liposomes are vesicles of varying size consisting of a spherical
lipid bilayer and an aqueous inner compartment that are generated in
vitro. These are useful in terms of biocompatibility, biodegradability,
and low toxicity, and can control biodistribution by changing the size,
lipid composition, and physical characteristics. Furthermore,
liposomes can entrap both hydrophobic and hydrophilic drugs and are
able to continuously release the entrapped substrate, thus being useful
drug carriers. Magnetic liposomes (MLs) are phospholipid vesicles
that encapsulate magneticor paramagnetic nanoparticles. They are
applied as contrast agents for magnetic resonance imaging (MRI).
The biological synthesis of nanoparticles using plant extracts plays
an important role in the field of nanotechnology. Green-synthesized
magnetite nanoparticles-protein hybrid has been produced by treating
Iron (III) / Iron (II) chloride with the leaf extract of Datura inoxia.
The phytochemicals present in the leaf extracts act as a reducing as
well stabilizing agents preventing agglomeration, which include
flavonoids, phenolic compounds, cardiac glycosides, proteins and
sugars.
The magnetite nanoparticles-protein hybrid has been trapped
inside the aqueous core of the liposome prepared by reversed phase
evaporation (REV) method using oleic and linoleic acid which has
been shown to be driven under magnetic field confirming the
formation magnetic liposome (ML). Chemical characterization of
stealth magnetic liposome has been performed by breaking the
liposome and release of magnetic nanoparticles. The presence iron
has been confirmed by colour complex formation with KSCN and
UV-Vis study using spectrophotometer Cary 60, Agilent.
This magnet driven liposome using nanoparticles-protein hybrid
can be a smart vesicles for the targeted drug delivery.
Abstract: Over the last few decades, oilfield service rolling
equipment has significantly increased in weight, primarily because of
emissions regulations, which require larger/heavier engines, larger
cooling systems, and emissions after-treatment systems, in some
cases, etc. Larger engines cause more vibration and shock loads,
leading to failure of electronics and control systems.
If the vibrating frequency of the engine matches the system
frequency, high resonance is observed on structural parts and mounts.
One such existing automated control equipment system comprising
wire rope mounts used for mounting computers was designed
approximately 12 years ago. This includes the use of an industrialgrade
computer to control the system operation. The original
computer had a smaller, lighter enclosure. After a few years, a newer
computer version was introduced, which was 10 lbm heavier. Some
failures of internal computer parts have been documented for cases in
which the old mounts were used. Because of the added weight, there
is a possibility of having the two brackets impact each other under
off-road conditions, which causes a high shock input to the computer
parts. This added failure mode requires validating the existing mount
design to suit the new heavy-weight computer.
This paper discusses the modal finite element method (FEM)
analysis and experimental modal analysis conducted to study the
effects of vibration on the wire rope mounts and the computer. The
existing mount was modelled in ANSYS software, and resultant
mode shapes and frequencies were obtained. The experimental modal
analysis was conducted, and actual frequency responses were
observed and recorded.
Results clearly revealed that at resonance frequency, the brackets
were colliding and potentially causing damage to computer parts. To
solve this issue, spring mounts of different stiffness were modeled in
ANSYS software, and the resonant frequency was determined.
Increasing the stiffness of the system increased the resonant
frequency zone away from the frequency window at which the engine
showed heavy vibrations or resonance. After multiple iterations in
ANSYS software, the stiffness of the spring mount was finalized,
which was again experimentally validated.
Abstract: Nowadays social media information, such as news,
links, images, or VDOs, is shared extensively. However, the
effectiveness of disseminating information through social media
lacks in quality: less fact checking, more biases, and several rumors.
Many researchers have investigated about credibility on Twitter, but
there is no the research report about credibility information on
Facebook. This paper proposes features for measuring credibility on
Facebook information. We developed the system for credibility on
Facebook. First, we have developed FB credibility evaluator for
measuring credibility of each post by manual human’s labelling. We
then collected the training data for creating a model using Support
Vector Machine (SVM). Secondly, we developed a chrome extension
of FB credibility for Facebook users to evaluate the credibility of
each post. Based on the usage analysis of our FB credibility chrome
extension, about 81% of users’ responses agree with suggested
credibility automatically computed by the proposed system.
Abstract: The recommended limit for cadmium concentration in
potable water is less than 0.005 mg/L. A continuous biosorption
process using indigenous red seaweed, Gracilaria corticata, was
performed to remove cadmium from the potable water. The process
was conducted under fixed conditions and the breakthrough curves
were achieved for three consecutive sorption-desorption cycles. A
modeling based on Artificial Neural Network (ANN) was employed
to fit the experimental breakthrough data. In addition, a simplified
semi empirical model, Thomas, was employed for this purpose. It
was found that ANN well described the experimental data (R2>0.99)
while the Thomas prediction were a bit less successful with R2>0.97.
The adjusted design parameters using the nonlinear form of Thomas
model was in a good agreement with the experimentally obtained
ones. The results approve the capability of ANN to predict the
cadmium concentration in potable water.
Abstract: The paper examines the interaction between the
environmental taxation, size of government spending on
environmental protection and greenhouse gas emissions and gross
inland energy consumption. The aim is to analyze the effects of
environmental taxation and government spending on environmental
protection as an environmental policy instruments on greenhouse gas
emissions and gross inland energy consumption in the EU15. The
empirical study is performed using a VAR approach with the
application of aggregated data of EU15 over the period 1995 to 2012.
The results provide the evidence that the reactions of greenhouse gas
emission and gross inland energy consumption to the shocks of
environmental policy instruments are strong, mainly in the short term
and decay to zero after about 8 years. Further, the reactions of the
environmental policy instruments to the shocks of greenhouse gas
emission and gross inland energy consumption are also strong in the
short term, however with the deferred effects. In addition, the results
show that government spending on environmental protection together
with gross inland energy consumption has stronger effect on
greenhouse gas emissions than environmental taxes in EU15 over the
examined period.
Abstract: Systems Engineering plays a key role during industrial
product development of complex technical systems. The need for
systems engineers in industry is growing. But there is a gap between
the industrial need and the academic education. Normally the
academic education is focused on the domain specific design,
implementation and testing of technical systems. Necessary systems
engineering expertise like knowledge about requirements analysis,
product cost estimation, management or social skills are poorly
taught. Thus there is the need of new academic concepts for teaching
systems engineering skills. This paper presents a project-orientated
training concept to prepare students from different technical degree
programs for systems engineering activities. The training concept has
been initially implemented and applied in the industrial engineering
master program of the University of Applied Sciences Offenburg.
Abstract: The problematic of gender and socioeconomic status
biased differences in academic motivation patterns is discussed.
Gender identity is understood according to symbolic interactionism
perspective: as a result of reflected appraisals, social comparisons,
self-attributions, and identifications, shaped by social environment
and family context. The effects of socioeconomic status on academic
motivation are conceptualized according to Bourdieu’s habitus
concept, reflecting the role of unconscious and internalized cultural
signals, proper to low and high socioeconomic status family contexts.
Since families differ by various socioeconomic features, the
hypothesis about possible impact of parents’ socioeconomic status on
their children’s academic motivation interfering with gender
socialization effects is held. The survey, aiming to seize gender
differences in academic motivation and self-recorded improvementoriented
efforts as a result of socialization processes operating in the
families of low and high socioeconomic status, was designed. The
results of Lithuanian higher education students’ survey are presented
and discussed.
Abstract: The use of eXtensible Markup Language (XML) in
web, business and scientific databases lead to the development of
methods, techniques and systems to manage and analyze XML data.
Semi-structured documents suffer due to its heterogeneity and
dimensionality. XML structure and content mining represent
convergence for research in semi-structured data and text mining. As
the information available on the internet grows drastically, extracting
knowledge from XML documents becomes a harder task. Certainly,
documents are often so large that the data set returned as answer to a
query may also be very big to convey the required information. To
improve the query answering, a Semantic Tree Based Association
Rule (STAR) mining method is proposed. This method provides
intentional information by considering the structure, content and the
semantics of the content. The method is applied on Reuter’s dataset
and the results show that the proposed method outperforms well.
Abstract: In this research, waterglass based aerogel powder was
prepared by sol–gel process and ambient pressure drying. Inspired by
limited dust releasing, aerogel powder was introduced to the PET
electrospinning solution in an attempt to create required bulk and
surface structure for the nanofibers to improve their hydrophobic and
insulation properties. The samples evaluation was carried out by
measuring density, porosity, contact angle, heat transfer, FTIR, BET,
and SEM. According to the results, porous silica aerogel powder was
fabricated with mean pore diameter of 24 nm and contact angle of
145.9º. The results indicated the usefulness of the aerogel powder
confined into nanofibers to control surface roughness for
manipulating superhydrophobic nanowebs with water contact angle
of 147º. It can be due to a multi-scale surface roughness which was
created by nanowebs structure itself and nanofibers surface
irregularity in presence of the aerogels while a layer of fluorocarbon
created low surface energy. The wettability of a solid substrate is an
important property that is controlled by both the chemical
composition and geometry of the surface. Also, a decreasing trend in
the heat transfer was observed from 22% for the nanofibers without
any aerogel powder to 8% for the nanofibers with 4% aerogel
powder. The development of thermal insulating materials has become
increasingly more important than ever in view of the fossil energy
depletion and global warming that call for more demanding energysaving
practices.
Abstract: The tomato is a very important crop, whose
cultivation in the Mediterranean basin is severely affected by the
phytoparasitic weed Phelipanche ramosa. The semiarid regions of
the world are considered the main areas where this parasitic weed is
established causing heavy infestation as it is able to produce high
numbers of seeds (up to 500,000 per plant), which remain viable for
extended period (more than 20 years). In this paper the results
obtained from eleven treatments in order to control this parasitic
weed including chemical, agronomic, biological and biotechnological
methods compared with the untreated test under two plowing depths
(30 and 50 cm) are reported. The split-plot design with 3 replicates
was adopted. In 2014 a trial was performed in Foggia province
(southern Italy) on processing tomato (cv Docet) grown in the field
infested by Phelipanche ramosa. Tomato seedlings were transplant
on May 5, on a clay-loam soil. During the growing cycle of the
tomato crop, at 56-78 and 92 days after transplantation, the number
of parasitic shoots emerged in each plot was detected. At tomato
harvesting, on August 18, the major quantity-quality yield parameters
were determined (marketable yield, mean weight, dry matter, pH,
soluble solids and color of fruits). All data were subjected to analysis
of variance (ANOVA) and the means were compared by Tukey's test.
Each treatment studied did not provide complete control against
Phelipanche ramosa. However, among the different methods tested,
some of them which Fusarium, gliphosate, radicon biostimulant and
Red Setter tomato cv (improved genotypes obtained by Tilling
technology) under deeper plowing (50 cm depth) proved to mitigate
the virulence of the Phelipanche ramose attacks. It is assumed that
these effects can be improved combining some of these treatments
each other, especially for a gradual and continuing reduction of the
“seed bank” of the parasite in the soil.
Abstract: Learning through creation of contextual games is a
very promising approach when undertaking interdisciplinary and
international group projects. During 2013 and 2014 the authors
organized two intensive student projects. The two projects were in
different countries and different conditions. Between them, the two
projects involved 68 students and 12 mentors from five EU countries
and from various academic disciplines. In this paper we share our
experience of these two projects and we suggest approaches that can
be utilized to strengthen the chances of succeeding in short (12-15
days long) intensive student projects.
Abstract: This paper presents nonlinear pulse propagation characteristics for different input optical pulse shapes with various input pulse energy levels in semiconductor optical amplifiers. For simulation of nonlinear pulse propagation, finite-difference beam propagation method is used to solve the nonlinear Schrödinger equation. In this equation, gain spectrum dynamics, gain saturation are taken into account which depends on carrier depletion, carrier heating, spectral-hole burning, group velocity dispersion, self-phase modulation and two photon absorption. From this analysis, we obtained the output waveforms and spectra for different input pulse shapes as well as for different input energies. It shows clearly that the peak position of the output waveforms are shifted toward the leading edge which due to the gain saturation of the SOA for higher input pulse energies. We also analyzed and compared the normalized difference of full-width at half maximum for different input pulse shapes in the SOA.
Abstract: Cloud computing has provided the impetus for change
in the demand, sourcing, and consumption of IT-enabled services.
The technology developed from an emerging trend towards a ‘musthave’.
Many organizations harnessed on the quick-wins of cloud
computing within the last five years but nowadays reach a plateau
when it comes to sustainable savings and performance. This study
aims to investigate what is needed from an organizational perspective
to make cloud computing a sustainable success. The study was
carried out in Germany among senior IT professionals, both in
management and delivery positions. Our research shows that IT
executives must be prepared to realign their IT workforce to sustain
the advantage of cloud computing for today and the near future.
While new roles will undoubtedly emerge, roles alone cannot ensure
the success of cloud deployments. What is needed is a change in the
IT workforce’s business behaviour, or put more simply, the ways in
which the IT personnel works. It gives clear guidance on which
dimensions of an employees’ working behaviour need to be adapted.
The practical implications are drawn from a series of semi-structured
interviews, resulting in a high-level workforce enablement plan.
Lastly, it elaborates on tools and gives clear guidance on which
pitfalls might arise along the proposed workforce enablement
process.