Abstract: Geopolymer composites reinforced with flax fabrics
and nanoclay are fabricated and studied for physical and mechanical
properties using X-Ray Diffraction (XRD), Fourier Transform
Infrared Spectroscopy (FTIR), and Scanning Electron Microscope
(SEM). Nanoclay platelets at a weight of 1.0%, 2.0%, and 3.0% were
added to geopolymer pastes. Nanoclay at 2.0 wt.% was found to
improve density and decrease porosity while improving flexural
strength and post-peak toughness. A microstructural analysis
indicated that nanoclay behaves as filler and as an activator
supporting geopolymeric reaction while producing a higher content
geopolymer gel improving the microstructure of binders. The process
enhances adhesion between the geopolymer matrix and flax fibres.
Abstract: In this study, the effects and interactions of reaction
time and capping agent assistance during sol-gel synthesis of
magnesium substituted hydroxyapatite nanopowder (MgHA) on
hydroxyapatite (HA) to β-tricalcium phosphate (β-TCP) ratio, Ca/P
ratio and mean crystallite size was examined experimentally as well
as through statistical analysis. MgHA nanopowders were synthesized
by sol-gel technique at room temperature using aqueous solution of
calcium nitrate tetrahydrate, magnesium nitrate hexahydrate and
potassium dihydrogen phosphate as starting materials. The reaction
time for sol-gel synthesis was varied between 15 to 60 minutes. Two
process routes were followed with and without addition of
triethanolamine (TEA) in the solutions. The elemental compositions
of as-synthesized powders were determined using X-ray fluorescence
(XRF) spectroscopy. The functional groups present in the assynthesized
MgHA nanopowders were established through Fourier
Transform Infrared Spectroscopy (FTIR). The amounts of phases
present, Ca/P ratio and mean crystallite sizes of MgHA nanopowders
were determined using X-ray diffraction (XRD). The HA content in
biphasic mixture of HA and β-TCP and Ca/P ratio in as-synthesized
MgHA nanopowders increased effectively with reaction time of sols
(p0.15, two way ANOVA). The MgHA nanopowders
synthesized with TEA assistance exhibited 14 nm lower crystallite
size (p
Abstract: Mechanical behavior of 6082T6 aluminum is
investigated at different temperatures. The strain rate sensitivity is
investigated at different temperatures on the grain size variants. The
sensitivity of the measured grain size variants on 3-D grain is
discussed. It is shown that the strain rate sensitivities are negative for
the grain size variants during the deformation of nanostructured
materials. It is also observed that the strain rate sensitivities vary in
different ways with the equivalent radius, semi minor axis radius,
semi major axis radius and major axis radius. From the obtained
results, it is shown that the variation of strain rate sensitivity with
temperature suggests that the strain rate sensitivity at the low and the
high temperature ends of the 6082T6 aluminum range is different.
The obtained results revealed transition at different temperature from
negative strain rate sensitivity as temperature increased on the grain
size variants.
Abstract: In this work, our goal is to optimize the nitriding treatment at a low-temperature of the steel 32CrMoV13 using gas mixtures of ammonia, nitrogen and hydrogen to improve the mechanical properties of the surface (good wear resistance, friction and corrosion), and of the diffusion layer of the nitrogen (good resistance to fatigue and good tenacity with heart). By limiting our work to the pure iron and to the alloys iron-chromium and iron-chromium-carbon, we have studied the various parameters which manage the nitriding: flow rate and composition of the gaseous phase, the interaction chromium-nitrogen and chromium-carbon by the help of experiments of nitriding realized in the laboratory by thermogravimetry. The acquired knowledge has been applied by the mastery of the growth of the γ' combination layer on the α diffusion layer in the case of the industrial steel 32CrMoV13.
Abstract: The transesterification of dimethyl malonate (DMM)
with phenol has been studied in vapour phase over cordierite
honeycomb coated with solid acid catalysts such as ZrO2,
Mo(VI)/ZrO2 and SO42-/ZrO2. The catalytic materials were prepared
honeycomb coated, powder forms, and characterized for their total
surface acidity by NH3-TPD and crystalinity by powder XRD
methods. Phenyl methyl malonate (PMM) and diphenyl malonate
(DPM) were obtained as the reaction products. A good conversion of
DMM (up to 82%) of MPM with 95% selectivity was observed when
the reactions were carried out at a catalyst bed temperature of 200 °C
and flow-rate of 10 mL/h in presence of Mo(VI)/ZrO2 as catalyst.
However, over SO4^2-/ZrO2 catalyst, the yield of DPM was found to be
higher. The results have been interpreted based on the variation of
acidic properties and powder XRD phases of zirconia on
incorporation of Mo(VI) or SO42– ions. Transesterification reactions
were also carried out over powder forms of the catalytic materials
and the yield of the desired phenyl ester products were compared
with that of the HC coated catalytic materials. The solid acids were
found to be reusable when used for at least 5 reaction cycles.
Abstract: Durian skin is a newly explores natural fibre
potentially reinforced polyolefin for diverse applications. In this
work, investigation on the effect of coupling agent, maleic anhydride
polypropylene (MAPP) on the mechanical, morphological, and
thermal properties of polypropylene (PP) reinforced with durian skin
fibre (DSF) was conducted. The presence of 30 wt% DSF
significantly reduced the tensile strength of PP-DSF composite.
Interestingly, even though the same trend goes to PP-DSF with the
presence of MAPP, the reduction is only about 4% relative to
unreinforced PP and 18% higher than PP-DSF without MAPP
(untreated composite or UTC). The used of MAPP in treated
composite (TC) also increased the tensile modulus, flexural
properties and degradation temperature. The enhanced mechanical
properties are consistent with good interfacial interaction as
evidenced under scanning electron microscopy.
Abstract: The purpose of this study is to propose an effective method to improve frictional coefficient between shoe rubber soles with added glass fibers and the surfaces of icy and snowy road in order to prevent slip-and-fall accidents by the users. The additional fibers into the rubber were uniformly tilted to the perpendicular direction of the frictional surface, where tilting angles were -60, -30, +30, +60, 90 degrees and 0 (as normal specimen), respectively. It was found that parallel arraignment was effective to improve the frictional coefficient when glass fibers were embedded in the shoe rubber, while perpendicular to normal direction of the embedded glass fibers on the shoe surface was also effective to do that once after they were exposed from the shoe rubber with its abrasion. These improvements were explained by the increase of stiffness against the shear deformation of the rubber at critical frictional state and adequate scratching of fibers when fibers were protruded in perpendicular to frictional direction, respectively. Most effective angle of tilting of frictional coefficient between rubber specimens and a stone was perpendicular (= 0 degree) to frictional direction. Combinative modified rubber specimen having 2 layers was fabricated where tilting angle of protruded fibers was 0 degree near the contact surface and tilting angle of embedded fibers was 90 degrees near back surface in thickness direction to further improve the frictional coefficient. Current study suggested that effective arraignments in tilting angle of the added fibers should be applied in designing rubber shoe soles to keep the safeties for users in regions of cold climates.
Abstract: Rotary entrainment is a phenomenon in which the
interface of two immiscible fluids are subjected to external flux by
means of rotation. Present work reports the experimental study on
rotary motion of a horizontal cylinder between the interface of air and
water to observe the penetration of gas inside the liquid. Experiments
have been performed to establish entrainment of air mass in water
alongside the cylindrical surface. The movement of tracer and seeded
particles has been tracked to calculate the speed and path of the
entrained air inside water. Simplified particle image velocimetry
technique has been used to trace the movement of particles/tracers at
the moment they are injected inside the entrainment zone and
suspended beads have been used to replicate the particle movement
with respect to time in order to determine the flow dynamics of the
fluid along the cylinder. Present paper establishes a thorough experimental analysis of the
rotary entrainment phenomenon between air and water keeping in
interest the extent to which we can intermix the two and also to study
its entrainment trajectories.
Abstract: This study investigates the influence of low
temperature thermo-chemical pretreatment of organic food waste on
performance of COD solubilisation. Both temperature and alkaline
agent were reported to have effect on solubilizing any possible
biomass including organic food waste. The three independent
variables considered in this pretreatment were temperature (50-90oC),
pretreatment time (30-120 minutes) and alkaline concentration,
sodium hydroxide, NaOH (0.7-15 g/L). The maximal condition
obtained were 90oC, 15 g/L NaOH for 2 hours. Solubilisation has
potential in enhancing methane production by providing high amount
of soluble components at early stage during anaerobic digestion.
Abstract: The 1:1 cocrystal of 2-amino-4-chloro-6-
methylpyrimidine (2A4C6MP) with 4-methylbenzoic acid (4MBA)
(I) has been prepared by slow evaporation method in methanol,
which was crystallized in monoclinic C2/c space group, Z = 8, and a
= 28.431 (2) Å, b = 7.3098 (5) Å, c = 14.2622 (10) Å and β =
109.618 (3)°. The presence of unionized –COOH functional group in
cocrystal I was identified both by spectral methods (1H and 13C
NMR, FTIR) and X-ray diffraction structural analysis. The
2A4C6MP molecule interact with the carboxylic group of the
respective 4MBA molecule through N—H⋯O and O—H⋯N
hydrogen bonds, forming a cyclic hydrogen–bonded motif R2
2(8).
The crystal structure was stabilized by Npyrimidine—H⋯O=C and
C=O—H⋯Npyrimidine types hydrogen bonding interactions.
Theoretical investigations have been computed by HF and density
function (B3LYP) method with 6–311+G (d,p)basis set. The
vibrational frequencies together with 1H and 13C NMR chemical
shifts have been calculated on the fully optimized geometry of
cocrystal I. Theoretical calculations are in good agreement with the
experimental results. Solvent–free formation of this cocrystal I is
confirmed by powder X-ray diffraction analysis.
Abstract: Chatter vibrations, occurring during cutting process,
cause vibration between the cutting tool and workpiece, which
deteriorates surface roughness and reduces tool life. The purpose of
this study is to investigate the influence of cutting parameters and
tool construction on surface roughness and vibration in turning of
aluminum alloy AA2024. A new design of cutting tool is proposed,
which is filled up with epoxy granite in order to improve damping
capacity of the tool. Experiments were performed at the lathe using
carbide cutting insert coated with TiC and two different cutting tools
made of AISI 5140 steel. Taguchi L9 orthogonal array was applied to
design of experiment and to optimize cutting conditions. By the help
of signal-to-noise ratio and analysis of variance the optimal cutting
condition and the effect of the cutting parameters on surface
roughness and vibration were determined. Effectiveness of Taguchi
method was verified by confirmation test. It was revealed that new
cutting tool with epoxy granite has reduced vibration and surface
roughness due to high damping properties of epoxy granite in
toolholder.
Abstract: The fundamental issue in understanding the origin and
growth mechanism of nanomaterials, from a fundamental unit is a big
challenging problem to the scientists. Recently, an immense attention
is generated to the researchers for prediction of exceptionally stable
atomic cluster units as the building units for future smart materials.
The present study is a systematic investigation on the stability and
electronic properties of a series of bimetallic (semiconductor-alkaline
earth) clusters, viz., BxMg3 (x=1-5) is performed, in search for
exceptional and/ or unusual stable motifs. A very popular hybrid
exchange-correlation functional, B3LYP along with a higher basis
set, viz., 6-31+G[d,p] is employed for this purpose under the density
functional formalism. The magic stability among the concerned
clusters is explained using the jellium model. It is evident from the
present study that the magic stability of B4Mg3
cluster arises due to
the jellium shell closure.
Abstract: Cryosorption pumps are considered safe, quiet, and
ultra-high vacuum production pumps which have their application
from Semiconductor industries to ITER [International Thermonuclear
Experimental Reactor] units. The principle of physisorption of gases
over highly porous materials like activated charcoal at cryogenic
temperatures (below -1500°C) is involved in determining the
pumping speed of gases like Helium, Hydrogen, Argon, and
Nitrogen. This paper aims at providing detailed overview of
development of Cryosorption pump and characterization of different
activated charcoal materials that optimizes the performance of the
pump. Different grades of charcoal were tested in order to determine
the pumping speed of the pump and were compared with
commercially available Varian cryopanel. The results for bare panel,
bare panel with adhesive, cryopanel with pellets, and cryopanel with
granules were obtained and compared. The comparison showed that
cryopanel adhered with small granules gave better pumping speeds
than large sized pellets.