Abstract: We succeeded to produce a high performance and flexible graphene/Manganese dioxide (G/MnO2) electrode coated on flexible polyethylene terephthalate (PET) substrate. The graphene film is initially synthesized by drop-casting the graphene oxide (GO) solution on the PET substrate, followed by simultaneous reduction and patterning of the dried film using carbon dioxide (CO2) laser beam with power of 1.8 W. Potentiostatic Anodic Deposition method was used to deposit thin film of MnO2 with different loading mass 10 – 50 and 100 μg.cm-2 on the pre-prepared graphene film. The electrodes were fully characterized in terms of structure, morphology, and electrochemical performance. A maximum specific capacitance of 973 F.g-1 was attributed when depositing 50μg.cm-2 MnO2 on the laser reduced graphene oxide rGO (or G/50MnO2) and over 92% of its initial capacitance was retained after 1000 cycles. The good electrochemical performance and long-term cycling stability make our proposed approach a promising candidate in the supercapacitor applications.
Abstract: The presented paper is related to the design methods and neutronic characterization of the reactivity control system in the large power unit of Generation IV Gas cooled Fast Reactor – GFR2400. The reactor core is based on carbide pin fuel type with the application of refractory metallic liners used to enhance the fission product retention of the SiCcladding. The heterogeneous design optimization of control rod is presented and the results of rods worth and their interferences in a core are evaluated. In addition, the idea of reflector removal as an additive reactivity management option is investigated and briefly described.
Abstract: Identifying the nature of protein-nanoparticle
interactions and favored binding sites is an important issue in
functional characterization of biomolecules and their physiological
responses. Herein, interaction of silver nanoparticles with lysozyme
as a model protein has been monitored via fluorescence spectroscopy.
Formation of complex between the biomolecule and silver
nanoparticles (AgNPs) induced a steady state reduction in the
fluorescence intensity of protein at different concentrations of
nanoparticles. Tryptophan fluorescence quenching spectra suggested
that silver nanoparticles act as a foreign quencher, approaching the
protein via this residue. Analysis of the Stern-Volmer plot showed
quenching constant of 3.73 μM−1. Moreover, a single binding site in
lysozyme is suggested to play role during interaction with AgNPs,
having low affinity of binding compared to gold nanoparticles.
Unfolding studies of lysozyme showed that complex of lysozyme-
AgNPs has not undergone structural perturbations compared to the
bare protein. Results of this effort will pave the way for utilization of
sensitive spectroscopic techniques for rational design of
nanobiomaterials in biomedical applications.
Abstract: This paper present some preliminary work on the
preparation and physicochemical caracterization of nanocomposite
MFI-alumina structures based on alumina hollow fibres. The fibers
are manufactured by a wet spinning process. α-alumina particles were
dispersed in a solution of polysulfone in NMP. The resulting slurry is
pressed through the annular gap of a spinneret into a precipitation
bath. The resulting green fibres are sintered. The mechanical strength
of the alumina hollow fibres is determined by a three-point-bending
test while the pore size is characterized by bubble-point testing. The
bending strength is in the range of 110 MPa while the average pore
size is 450 nm for an internal diameter of 1 mm and external diameter
of 1.7 mm. To characterize the MFI membranes various techniques
were used for physicochemical characterization of MFI–ceramic
hollow fibres membranes: The nitrogen adsorption, X-ray
diffractometry, scanning electron microscopy combined with X
emission microanalysis. Scanning Electron Microscopy (SEM) and
Energy Dispersive Microanalysis by the X-ray were used to observe
the morphology of the hollow fibre membranes (thickness,
infiltration into the carrier, defects, homogeneity). No surface film,
has been obtained, as observed by SEM and EDX analysis and
confirmed by high temperature variation of N2 and CO2 gas
permeances before cation exchange. Local analysis and characterise
(SEM and EDX) and overall (by ICP elemental analysis) were
conducted on two samples exchanged to determine the quantity and
distribution of the cation of cesium on the cross section fibre of the
zeolite between the cavities.
Abstract: When acid is pumped into damaged reservoirs for
damage removal/stimulation, distorted inflow of acid into the
formation occurs caused by acid preferentially traveling into highly
permeable regions over low permeable regions, or (in general) into
the path of least resistance. This can lead to poor zonal coverage and
hence warrants diversion to carry out an effective placement of acid.
Diversion is desirably a reversible technique of temporarily reducing
the permeability of high perm zones, thereby forcing the acid into
lower perm zones.
The uniqueness of each reservoir can pose several challenges to
engineers attempting to devise optimum and effective diversion
strategies. Diversion techniques include mechanical placement and/or
chemical diversion of treatment fluids, further sub-classified into ball
sealers, bridge plugs, packers, particulate diverters, viscous gels,
crosslinked gels, relative permeability modifiers (RPMs), foams,
and/or the use of placement techniques, such as coiled tubing (CT)
and the maximum pressure difference and injection rate (MAPDIR)
methodology.
It is not always realized that the effectiveness of diverters greatly
depends on reservoir properties, such as formation type, temperature,
reservoir permeability, heterogeneity, and physical well
characteristics (e.g., completion type, well deviation, length of
treatment interval, multiple intervals, etc.). This paper reviews the
mechanisms by which each variety of diverter functions and
discusses the effect of various reservoir properties on the efficiency
of diversion techniques. Guidelines are recommended to help
enhance productivity from zones of interest by choosing the best
methods of diversion while pumping an optimized amount of
treatment fluid. The success of an overall acid treatment often
depends on the effectiveness of the diverting agents.
Abstract: The improvement of a filer case utilized to purify the
let-out smoke and smell in the production of Benjarong Ceramic is
studied through Participatory Action Research (PAR). This research
is aimed to protect smell, dirty smoke, and air pollution which are
effects of incomplete combustion in the production of Benjarong
ceramic. This research was conducted at Jongjint Benjarong Ceramic
Factory in Plai Bang, Bang Kruai, Nonthaburi Province,Thailand,
also 12 employees were interviewed for data collection. All collected
data were analyzed to develop and create solution to protect smoke
and smell pollution from Benjarong ceramic production.
The results revealed that the employees who have used the
developed filer cases are moderately satisfied. In addition to the
efficiency of developed smoke-and-smell filer cases, it was found
that Overall, the respondents were satisfied moderately with
efficiency of modified smoke and smell filter cases.
Abstract: Cs-type nanocomposite zeolite membrane was successfully synthesized on an alumina ceramic hollow fibre with a mean outer diameter of 1.7 mm; cesium cationic exchange test was carried out inside test module with mean wall thickness of 230 μm and an average crossing pore size smaller than 0.2 μm. Separation factor of n-butane/H2 obtained indicate that a relatively high quality closed to 20. Maxwell-Stefan modeling provides an equivalent thickness lower than 1 µm. To compare the difference an application to CO2/N2 separation has been achieved, reaching separation factors close to (4,18) before and after cation exchange on H-zeolite membrane formed within the pores of a ceramic alumina substrate.
Abstract: The major objective of this study is to understand the
potential of a newly fabricated equipment to study the thermal
properties of nonwoven textile fabrics treated with aerogel at subzero
temperatures. Thermal conductivity was calculated by using the
empirical relation Fourier’s law, The relationship between the
thermal conductivity and thermal resistance of the samples were
studied at various environmental temperatures (which was set in the
clima temperature system between +25oC to -25oC). The newly
fabricated equipment was found to be a suitable for measuring at
subzero temperatures. This field of measurements is being developed
and will be the subject of further research which will be more suitable
for measurement of the various thermal characteristics.
Abstract: Science and technology of ultrasonic is widely used in
recent years for industrial and medicinal application. The acoustical
properties of 2-mercapto substituted pyrimidines viz.,2- Mercapto-4-
(2’,4’ –dichloro phenyl) – 6-(2’ – hydroxyl -4’ –methyl-5’ –
chlorophenyl) pyrimidine and 2 –Mercapto – 4-(4’ –chloro phenyl) –
6-(2’ – hydroxyl -4’ –methyl-5’ –chlorophenyl) pyrimidine have been
investigated from the ultrasonic velocity and density measurements at
different concentration and different % in dioxane-water mixture at
305K. The adiabatic compressibility (βs), acoustic impedance (Z),
intermolecular free length (Lf), apparent molar volume(ϕv) and
relative association (RA) values have been calculated from the
experimental data of velocity and density measurement at
concentration range of 0.01- 0.000625 mol/lit and 70%,75% and 80%
dioxane water mixture. These above parameters are used to discuss
the structural and molecular interactions.
Abstract: The objectives of this research are to produce
prototype coconut oil based solvent offset printing inks and to
analyze a basic quality of printing work derived from coconut oil
based solvent offset printing inks, by mean of bringing coconut oil
for producing varnish and bringing such varnish to produce black
offset printing inks. Then, analysis of qualities i.e. CIELAB value,
density value, and dot gain value of printing work from coconut oil
based solvent offset printing inks which printed on gloss-coated
woodfree paper weighs 130 grams were done. The research result of
coconut oil based solvent offset printing inks indicated that the
suitable varnish formulation is using 51% of coconut oil, 36% of
phenolic resin, and 14% of solvent oil 14%, while the result of
producing black offset ink displayed that the suitable formula of
printing ink is using varnish mixed with 20% of coconut oil, and the
analyzing printing work of coconut oil based solvent offset printing
inks which printed on paper, the results were as follows: CIELAB
value of black offset printing ink is at L* = 31.90, a* = 0.27, and b* =
1.86, density value is at 1.27 and dot gain value was high at mid tone
area of image area.
Abstract: Using a texture database, a statistical estimation of
spring-back was conducted in this study on the basis of statistical
analysis. Both spring-back in bending deformation and experimental
data related to the crystal orientation show significant dispersion.
Therefore, a probabilistic statistical approach was established for the
proper quantification of these values. Correlation was examined
among the parameters F(x) of spring-back, F(x) of the buildup fraction
to three orientations after 92° bending, and F(x) at an as-received part
on the basis of the three-parameter Weibull distribution. Consequent
spring-back estimation using a texture database yielded excellent
estimates compared with experimental values.
Abstract: Sport is one of the sectors in which the largest
technical projections regarding the functions of textiles can be found.
He is a large consumer of high performance composite materials and
new fibers. It is one of the sectors where the innovation is the most
important when the greatest numbers of spectacular developments are
aimed at increasing performance. In medicine, textile innovation is
used and contributes in the amelioration of different materials such as
dressing, orthosis, bandages, etc. The hygienic textiles in non-woven
materials record a strong growth. The objective of this study is to
show the different advances of development we obtained in the both
ways (sport and medicine). Polyamide fibers where developed
tacking into account the specification of the high level athlete’s
performance like swimming and triathlon (Olympic Games, Brazil
2016). The first textile utilization was for skiing (Olympic Games,
Sotchi 2014). The different textiles technologies where adapted for
medicine.
Abstract: Sol-gel method has been used to fabricate
nanocomposite films on glass substrates composed halloysite clay
mineral and nanocrystalline TiO2. The methodology for the synthesis
involves a simple chemistry method utilized nonionic surfactant
molecule as pore directing agent along with the acetic acid-based solgel
route with the absence of water molecules. The thermal treatment
of composite films at 450oC ensures elimination of organic material
and lead to the formation of TiO2 nanoparticles onto the surface of
the halloysite nanotubes. Microscopy techniques and porosimetry
methods used in order to delineate the structural characteristics of the
materials. The nanocomposite films produced have no cracks and
active anatase crystal phase with small crystallite size were deposited
on halloysite nanotubes. The photocatalytic properties for the new
materials were examined for the decomposition of the Basic Blue 41
azo dye in solution. These, nanotechnology based composite films
show high efficiency for dye’s discoloration in spite of different
halloysite quantities and small amount of halloysite/TiO2 catalyst
immobilized onto glass substrates. Moreover, we examined the
modification of the halloysite/TiO2 films with silver particles in order
to improve the photocatalytic properties of the films. Indeed, the
presence of silver nanoparticles enhances the discoloration rate of the
Basic Blue 41 compared to the efficiencies obtained for unmodified
films.