Abstract: A phase diagram of the Ag2SO4 - CaSO4 (Silver sulphate – Calcium Sulphate) binaries system using conductivity, XRD (X-Ray Diffraction Technique) and DTA (Differential Thermal Analysis) data is constructed. The eutectic reaction (liquid -» a-Ag2SO4 + CaSO4) is observed at 10 mole% CaSO4 and 645°C. Room temperature solid solubility limit up to 5.27 mole % of Ca 2+ in Ag2SO4 is set using X-ray powder diffraction and scanning electron microscopy results. All compositions beyond this limit are two-phase mixtures below and above the transition temperature (≈ 416°C). The bulk conductivity, obtained following complex impedance spectroscopy, is found decreasing with increase in CaSO4 content. Amongst other binary compositions, the 80AgSO4-20CaSO4 gave improved sinterability/packing density.
Abstract: Science and technology of ultrasonic is widely used in
recent years for industrial and medicinal application. The acoustical
properties of 2-mercapto substituted pyrimidines viz.,2- Mercapto-4-
(2’,4’ –dichloro phenyl) – 6-(2’ – hydroxyl -4’ –methyl-5’ –
chlorophenyl) pyrimidine and 2 –Mercapto – 4-(4’ –chloro phenyl) –
6-(2’ – hydroxyl -4’ –methyl-5’ –chlorophenyl) pyrimidine have been
investigated from the ultrasonic velocity and density measurements at
different concentration and different % in dioxane-water mixture at
305K. The adiabatic compressibility (βs), acoustic impedance (Z),
intermolecular free length (Lf), apparent molar volume(ϕv) and
relative association (RA) values have been calculated from the
experimental data of velocity and density measurement at
concentration range of 0.01- 0.000625 mol/lit and 70%,75% and 80%
dioxane water mixture. These above parameters are used to discuss
the structural and molecular interactions.