Abstract: In the paper we submit the modification of kinetic Smoluchowski equation for binary aggregation applying to systems with chemical reactions of first and second orders in which the main product is insoluble. The goal of this work is to create theoretical foundation and engineering procedures for calculating the chemical apparatuses in the conditions of joint course of chemical reactions and processes of aggregation of insoluble dispersed phases which are formed in working zones of the reactor.
Abstract: The purpose of this work is to establish the theoretical
foundations for calculating and designing the sublimationcondensation
processes in chemical apparatuses which are intended
for production of ultrafine powders of crystalline and amorphous
materials with controlled fractional composition. Theoretic analysis
of the primary processes of nucleation and growth kinetics of the
clusters according to the degree of super-saturation and the
homogeneous or heterogeneous nature of nucleation has been carried
out. The engineering design procedures of desublimation processes
have been offered and tested for modification of the Claus process.
Abstract: In the paper we submit the non-local modification of
kinetic Smoluchowski equation for binary aggregation applying to
dispersed media having memory. Our supposition consists in that that
intensity of evolution of clusters is supposed to be a function of the
product of concentrations of the lowest orders clusters at different
moments. The new form of kinetic equation for aggregation is
derived on the base of the transfer kernels approach. This approach
allows considering the influence of relaxation times hierarchy on
kinetics of aggregation process in media with memory.