Abstract: In this study, the possibility of using unground oil palm ash (UOPA) for producing foamed concrete is investigated. The UOPA used in this study is produced by incinerating palm oil biomass at a temperature exceeding 1000ºC. A semi-structural density of 1300kg/m3 was used with filler to binder ratio of 1.5 and preliminary water to binder ratio of 0.45. Cement was replaced by UOPA at replacement levels of 0, 25, 35, 45, 55 and 65% by weight of binder. Properties such as density, compressive strength, drying shrinkage and water absorption were investigated to the age of 90 days. The mix with a 35% of UOPA content was chosen to be used as the base material of a newly designed interlocking, mortar-less block system.
Abstract: In the present research, whole meal barley flour
(WBF) was supplemented with gelatinized corn flour (GCF) in 0 and
30%. Whole meal wheat flour (WWF) was mixed with defatted rice
bran (DRB) to produce 0, 20, 25, and 30% replacement levels.
Rheological properties of dough were studied. Thermal properties
and starch crystallinity of flours were evaluated. Flat bread, balady
bread and pie were prepared from the different flour blends. The
different bakeries were sensory evaluated. Color of raw materials and
crust of bakery products were determined. Nutrients contents of raw
flours and food products were assessed. Results showed that addition
of GCF to WBF increased the viscosity and falling number of the
produced dough. Water absorption, dough development time and
dough stability increased with increasing the level of DRB in dough
while, weakening and mixing tolerance index decreased.
Extensibility and energy decreased, while, resistance to extension
increased as DRB level increased. Gelatinized temperature of WWF,
WBF, GCF, and DRB were 13.26, 35.09, 28.33, and 39.63,
respectively. Starch crystallinity was affected when DRB was added
to WWF. The highest protein content was present in balady bread
made from 70% WWF and 30% DRB. The highest calcium,
phosphorus, and potassium levels were present in products made
from 100% WBF. Sensory attributes of the products were slightly
affected by adding DRB and GCF. Conclusion: Addition of DRB or
GCF to WWF or WBF, respectively affect the physical, chemical,
rheological and sensory properties of balady bread, flat bread, and pie
while improved their nutritive values.
Abstract: Coal fly ash, an industrial by product of coal
combustion thermal power plants is considered as a hazardous
material and its improper disposal has become an environmental
issue. On the other hand, manufacturing conventional clay bricks
involves on consumption of large amount of clay and leads
substantial depletion of topsoil. This paper unveils the possibility of
using fly ash as a partial replacement of clay for brick manufacturing
considering the local technology practiced in Bangladesh. The effect
of fly ash with different replacing ratio (0%, 20%, 30%, 40%, and
50% by volume) of clay on properties of bricks was studied. Bricks
were made in the field parallel to ordinary bricks marked with
specific number for different percentage to identify them at time of
testing. No physical distortion is observed in fly ash brick after
burning in the kiln. Results from laboratory test show that
compressive strength of brick is decreased with the increase of fly
ash and maximum compressive strength is found to be 19.6 MPa at
20% of fly ash. In addition, water absorption of fly ash brick is
increased with the increase of fly ash. The abrasion value and
Specific gravity of coarse aggregate prepared from brick with fly ash
also studied and the results of this study suggests that 20% fly ash
can be considered as the optimum fly ash content for producing good
quality bricks utilizing present practiced technology.
Abstract: The purpose of the present work was to develop an innovative food product with good textural and sensorial characteristics. The product, a new type of bread, was prepared with wheat (90%) and lupin (10%) flours, without the addition of any conservatives. Several experiences were also done to find the most appropriate proportion of lupin flour. The optimized product was characterized considering the rheological, physical-chemical and sensorial properties. The water absorption of wheat flour with 10% of lupin was higher than that of the normal wheat flours, and Wheat Ceres flour presented the lower value, with lower dough development time and high stability time. The breads presented low moisture but a considerable water activity. The density of bread decreased with the introduction of lupin flour. The breads were quite white, and during storage the colour parameters decreased. The lupin flour clearly increased the number of alveolus, but the total area increased significantly just for the Wheat Cerealis bread. The addition of lupin flour increased the hardness and chewiness of breads, but the elasticity did not vary significantly. Lupin bread was sensorially similar to wheat bread produced with WCerealis flour, and the main differences are the crust rugosity, colour and alveolus characteristics.
Abstract: In most existing buildings in hot climate, cooling
loads lead to high primary energy consumption and consequently
high CO2 emissions. These can be substantially decreased with
integrated renewable energy systems. Kuwait is characterized by its
dry hot long summer and short warm winter. Kuwait receives annual
total radiation more than 5280 MJ/m2 with approximately 3347 h of
sunshine. Solar energy systems consist of PV modules and parabolic
trough collectors are considered to satisfy electricity consumption,
domestic water heating, and cooling loads of an existing building.
This paper presents the results of an extensive program of energy
conservation and energy generation using integrated photovoltaic
(PV) modules and Parabolic Trough Collectors (PTC). The program
conducted on an existing institutional building intending to convert it
into a Net-Zero Energy Building (NZEB) or near net Zero Energy
Building (nNZEB). The program consists of two phases; the first
phase is concerned with energy auditing and energy conservation
measures at minimum cost and the second phase considers the
installation of photovoltaic modules and parabolic trough collectors.
The 2-storey building under consideration is the Applied Sciences
Department at the College of Technological Studies, Kuwait. Single
effect lithium bromide water absorption chillers are implemented to
provide air conditioning load to the building. A numerical model is
developed to evaluate the performance of parabolic trough collectors
in Kuwait climate. Transient simulation program (TRNSYS) is
adapted to simulate the performance of different solar system
components. In addition, a numerical model is developed to assess
the environmental impacts of building integrated renewable energy
systems. Results indicate that efficient energy conservation can play
an important role in converting the existing buildings into NZEBs as
it saves a significant portion of annual energy consumption of the
building. The first phase results in an energy conservation of about
28% of the building consumption. In the second phase, the integrated
PV completely covers the lighting and equipment loads of the
building. On the other hand, parabolic trough collectors of optimum
area of 765 m2 can satisfy a significant portion of the cooling load,
i.e about73% of the total building cooling load. The annual avoided
CO2 emission is evaluated at the optimum conditions to assess the
environmental impacts of renewable energy systems. The total annual
avoided CO2 emission is about 680 metric ton/year which confirms
the environmental impacts of these systems in Kuwait.
Abstract: The composite flour blend consisting of corn, pearl
millet, black gram and wheat bran in the ratio of 80:5:10:5 was taken
to prepare the extruded product and their effect on physical properties
of extrudate was studied. The extrusion process was conducted in
laboratory by using twin screw extruder. The physical characteristics
evaluated include lateral expansion, bulk density, water absorption
index, water solubility index, and rehydration ratio and moisture
retention. The Central Composite Rotatable Design (CCRD) was
used to decide the level of processing variables i.e. feed moisture
content (%), screw speed (rpm), and barrel temperature (oC) for the
experiment. The data obtained after extrusion process were analyzed
by using response surface methodology. A second order polynomial
model for the dependent variables was established to fit the
experimental data. The numerical optimization studies resulted in
127°C of barrel temperature, 246 rpm of screw speed, and 14.5% of
feed moisture as optimum variables to produce acceptable extruded
product. The responses predicted by the software for the optimum
process condition resulted in lateral expansion 126%, bulk density
0.28 g/cm3, water absorption index 4.10 g/g, water solubility index
39.90%, rehydration ratio 544% and moisture retention 11.90% with
75% desirability.
Abstract: This paper presents results of compressive strength,
capillary water absorption, and density tests conducted on concrete
containing recycled aggregate (RCA) which is obtained from
structural waste generated by the construction industry in Turkey. In
the experiments, 0%, 15%, 30%, 45% and 60% of the normal
(natural) coarse aggregate was replaced by the recycled aggregate.
Maximum aggregate particle sizes were selected as 16 mm, 22,4 mm
and 31,5 mm; and 0,06%, 0,13% and 0,20% of air-entraining agent
(AEA) were used in mixtures. Fly ash and superplasticizer were used
as a mineral and chemical admixture, respectively. The same type
(CEM I 42.5) and constant dosage of cement were used in the study.
Water/cement ratio was kept constant as 0.53 for all mixture. It was
concluded that capillary water absorption, compressive strength, and
density of concrete decreased with increasing RCA ratio. Increasing
in maximum aggregate particle size and amount of AEA also affect
the properties of concrete significantly.
Abstract: Fibre cement plates, often used in construction,
generally are made using quartz as an inert material, cement as a
binder and cellulose as a fibre. This paper, first of all, investigates the
mechanical properties and durability of fibre cement plates when
quartz is both partly and fully replaced with diatomite. Diatomite
does not only have lower density compared to quartz but also has
high pozzolanic activity. The main objective of this paper is the
investigation of the effects of supplementary cementing materials
(SCMs) on the short and long term mechanical properties and
durability characteristics of fibre cement plates prepared using
diatomite. Supplementary cementing materials such as ground
granulated blast furnace slug (GGBS) and fly ash (FA) are used in
this study. Volume proportions of 10, 20, 30 and 40% of GGBS and
FA are used as partial replacement materials to cement. Short and
long term mechanical properties such as compressive and flexural
strengths as well as sorptivity characteristics and mass were
investigated. Consistency and setting time at each replacement levels
of SCMs were also recorded. The effects of using supplementary
cementing materials on the carbonation and sulphate resistance of
fibre cement plates were then experimented. The results, first of all,
show that the use of diatomite as a full or partial replacement to
quartz resulted in a systematic decrease in total mass of the fibre
cement plates. The reduction of mass was largely due to the lower
density and finer particle size of diatomite compared to quartz. The
use of diatomite did not only reduce the mass of these plates but also
increased the compressive strength significantly as a result of its high
pozzolanic activity. The replacement levels of both GGBS and FA
resulted in a systematic decrease in short term compressive strength
with increasing replacement levels. This was essentially expected as
the total rate of hydration is much lower in GGBS and FA than that
of cement. Long term results however, indicated that the compressive
strength of fibre cement plates prepared using both GGBS and FA
increases with time and hence the compressive strength of plates
prepared using SCMs is either equivalent or more than the
compressive strength of plates prepared using cement alone.
Durability characteristics of fibre cement plates prepared using SCMs
were enhanced significantly. Measurements of sopritivty
characteristics were also indicated that the plates prepared using
SCMs has much lower water absorption capacities compared to
plates prepared cement alone. Much higher resistance to carbonation
and sulphate attach were observed with plates prepared using SCMs.
The results presented in this paper show that the use of SCMs does
not only support the production of more sustainable construction
materials but also enhances the mechanical properties and durability
characteristics of fibre cement plates.
Abstract: Rice husk and kenaf filled with calcium carbonate
(CaCO3) and high density polyethylene (HDPE) composite were
prepared separately using twin-screw extruder at 50rpm. Different
filler loading up to 30 parts of rice husk particulate and kenaf fiber
were mixed with the fixed 30% amount of CaCO3 mineral filler to
produce rice husk/CaCO3/HDPE and kenaf/CaCO3/HDPE hybrid
composites. In this study, the effects of natural fiber for both rice
husk and kenaf in CaCO3/HDPE composite on physical, mechanical
and morphology properties were investigated. Field Emission
Scanning Microscope (FeSEM) was used to investigate the impact
fracture surfaces of the hybrid composite. The property analyses
showed that water absorption increased with the presence of kenaf
and rice husk fillers. Natural fibers in composite significantly
influence water absorption properties due to natural characters of
fibers which contain cellulose, hemicellulose and lignin structures.
The result showed that 10% of additional natural fibers into hybrid
composite had caused decreased flexural strength, however additional
of high natural fiber (>10%) filler loading has proved to increase its
flexural strength.
Abstract: In the present work, fly ash geopolymer based
composites including polyester (PES) waste were studied. Specimens
of three compositions were prepared: (a) fly ash geopolymer with 5%
PES waste; (b) fly ash geopolymer mortar with 5% PES waste; (c) fly
ash geopolymer mortar with 6.25% PES waste. Compressive and
bending strength measurements, water absorption test and
determination of thermal conductivity coefficient were performed.
The results showed that the addition of sand in a mixture of
geopolymer with 5% PES content led to higher compressive strength,
while it increased water absorption and reduced thermal conductivity
coefficient. The increase of PES addition in geopolymer mortars
resulted in a more dense structure, indicated by the increase of
strength and thermal conductivity and the decrease of water
absorption.
Abstract: The objective of this study was to identify the optimal
level of partial replacement of Portland cement by the ashes
originating from burning straw and bagasse from sugar cane (ASB).
Order to this end, were made five series of flat plates and cylindrical
bodies: control and others with the partial replacement in 20, 30, 40
and 50% of ASB in relation to the mass of the Ordinary Portland
cement, and conducted a mechanical testing of simple axial
compression (cylindrical bodies) and the four-point bending (flat
plates) and determined water absorption (WA), bulk density (BD)
and apparent void volume (AVV) on both types of specimens. Based
on the data obtained, it may be noted that the control treatment
containing only Portland cement, obtained the best results. However,
the cylindrical bodies with 20% ashes showed better results
compared to the other treatments. And in the formulations plates, the
treatment which showed the best results was 30% cement
replacement by ashes.
Abstract: The purpose of this study is to compare Self
Compacting Concrete (SCC) and Conventional Concrete (CC) in
terms of their capillary water absorption. During the comparison of
SCC and CC, the effects of two different factors were also
investigated: concrete strength class and curing condition. In the
study, both SCC and CC were produced in three different concrete
classes (C25, C50 and C70) and the other parameter (i.e. curing
condition) was determined as two levels: moisture and air curing. It
was observed that, for both curing environments and all strength
classes of concrete, SCCs had lower capillary water absorption values
than that of CCs. It was also detected that, for both SCC and CC,
capillary water absorption values of samples kept in moisture curing
were significantly lower than that of samples stored in air curing.
Additionally, it was determined that capillary water absorption values
for both SCC and CC decrease with increasing strength class of
concrete for both curing environments.
Abstract: Stoneware clay, fired clay (as a grog), calcite waste and class C fly ash in various mixing rations were the basic raw materials for the mixture for production of dry pressed ceramic tiles. Mechanical properties (water absorption, bulk density, apparent porosity, flexural strength) as well as mineralogical composition were studied on samples with different source of calcium oxide after firing at 900, 1000, 1100 and 1200°C. It was found that samples with addition of calcite waste contain dmisteinbergit and anorthite. This minerals help to improve the strength of the body and reduce porosity fired at lower temperatures. Class C fly ash has not significantly influence on properties of the fired body as calcite waste.
Abstract: The acid attack on cement mortars modified with rubber aggregates and EVA polymer binder was studied. Mortar specimens were prepared using a type CEM I 42.5 Portland cement and siliceous sand, as well as by substituting 25% of sand with shredded used automobile tires, and by adding EVA polymer in two percentages (5% and 10% of cement mass). Some specimens were only air cured, at laboratory conditions, and their compressive strength and water absorption were determined. The rest specimens were stored in acid solutions (HCl, H2SO4, HNO3) after 28 days of initial curing, and stored at laboratory temperature. Compressive strength tests, mass measurements and visual inspection took place for 28 days. Compressive strength and water absorption of the air-cured specimens were significantly decreased when rubber aggregates are used. The addition of EVA polymer further reduced water absorption, while had no important impact on strength. Compressive strength values were affected in a greater extent by hydrochloric acid solution, followed by sulfate and nitric acid solutions. The addition of EVA polymer decreased compressive strength loss for the specimens with rubber aggregates stored in hydrochloric and nitric acid solutions. The specimens without polymer binder showed similar mass loss, which was higher in sulfate acid solution followed by hydrochloric and nitric acid solutions. The use of EVA polymer delayed mass loss, while its content did not affect it significantly.
Abstract: Construction industry in Greece consumes annually
more than 25 million tons of natural aggregates originating mainly
from quarries. At the same time, more than 2 million tons of
construction and demolition waste are deposited every year, usually
without control, therefore increasing the environmental impact of this
sector. A potential alternative for saving natural resources and
minimize landfilling, could be the recycling and re-use of Concrete
and Demolition Waste (CDW) in concrete production. Moreover, in
order to conform to the European legislation, Greece is obliged to
recycle non-hazardous construction and demolition waste to a
minimum of 70% by 2020. In this paper characterization of recycled
materials - commercially and laboratory produced, coarse and fine,
Recycled Concrete Aggregates (RCA) - has been performed. Namely,
X-Ray Fluorescence and X-ray diffraction (XRD) analysis were used
for chemical and mineralogical analysis respectively. Physical
properties such as particle density, water absorption, sand equivalent
and resistance to fragmentation were also determined. This study,
first time made in Greece, aims at outlining the differences between
RCA and natural aggregates and evaluating their possible influence
in concrete performance. Results indicate that RCA’s chemical
composition is enriched in Si, Al, and alkali oxides compared to
natural aggregates. X-ray diffraction (XRD) analyses results
indicated the presence of calcite, quartz and minor peaks of mica and
feldspars. From all the evaluated physical properties of coarse RCA,
only water absorption and resistance to fragmentation seem to have a
direct influence on the properties of concrete. Low Sand Equivalent
and significantly high water absorption values indicate that fine
fractions of RCA cannot be used for concrete production unless
further processed. Chemical properties of RCA in terms of water
soluble ions are similar to those of natural aggregates. Four different
concrete mixtures were produced and examined, replacing natural
coarse aggregates with RCA by a ratio of 0%, 25%, 50% and 75%
respectively. Results indicate that concrete mixtures containing
recycled concrete aggregates have a minor deterioration of their
properties (3-9% lower compression strength at 28 days) compared to
conventional concrete containing the same cement quantity.
Abstract: This paper presents a study on use of alkali activated bottom ash (BA) and ground granulated blast furnace slag (GGBS) blend in paver blocks. A preliminary effort on alkali-activated bottom ash, blast furnace slag based geopolymer (BA-GGBS-GP) mortar with river sand was carried out to identify the suitable mix for paver block. Several mixes were proposed based on the combination of BA-GGBS. The percentage ratio of BA: GGBS was selected as 100:0, 75:25, 50:50, 25:75 and 0:100 for the source material. Sodium based alkaline activators were used for activation. The molarity of NaOH was considered as 8M. The molar ratio of SiO2 to Na2O was varied from 1 to 4. Two curing mode such as ambient and steam curing 60°C for 24 hours were selected. The properties of paver block such as compressive strength split tensile strength, flexural strength and water absorption were evaluated as per IS15658:2006. Based on the preliminary study on BA-GGBS-GP mortar, the combinations of 25% BA with 75% GGBS mix for M30 and 75% BA with 25% GGBS mix for M35 grade were identified for paver block. Test results shows that the combination of BA-GGBS geopolymer paver blocks attained remarkable compressive strength under steam curing as well as in ambient mode at 3 days. It is noteworthy to know BA-GGBS-GP has promising future in the construction industry.
Abstract: An experimental study was conducted on foamed concrete with synthetic and natural fibres consisting of AR-glas, polypropylene, steel, kenaf and oil palm fibre. The foamed concrete mixtures produced had a target density of 1000kg/m3 and a mix ratio of (1:1.5:0.45). The fibres were used as additives. The inclusion of fibre was maintained at a volumetric fraction of 0.25 and 0.4%. The water absorption, thermal and shrinkage were determined to study the effect of the fibre on the durability properties of foamed concrete. The results showed that AR-glass fibre has the lowest percentage value of drying shrinkage compared to others.
Abstract: The Proton Exchange Membranes (PEM) are largely studied because they operate at low temperatures and they are suitable for mobile applications. However, there are some deficiencies in their operation, mainly those that use ethanol as a hydrogen source, that require a certain attention. Therefore, this research aimed to develop Nafion® composite membranes, mixing clay minerals, kaolin and halloysite to the polymer matrix in order to improve the ethanol molecule retentions and, at the same time, to keep the system’s protonic conductivity. The modified Nafion/Kaolin, Nafion/Halloysite composite membranes were prepared in weight proportion of 0.5, 1.0 and 1.5. The membranes obtained were characterized as to their ethanol permeability, protonic conductivity and water absorption. The composite morphology and structure are characterized by SEM and EDX and the thermal behavior is determined by TGA and DSC. The analysis of the results shows ethanol permeability reduction from 48% to 63%. However, the protonic conductivity results are lower in relation to pure Nafion®. As to the thermal behavior, the Nafion® composite membranes were stable up to a temperature of 325ºC.
Abstract: This study examined the properties of fresh and hardened concretes as influenced by the moisture state of the coarse recycled concrete aggregates (RCA) after surface treatment. Surface treatment was performed by immersing the coarse RCA in a calcium metasilicate (CM) solution. The treated coarse RCA was maintained in three controlled moisture states, namely, air-dried, oven-dried, and saturated surface-dried (SSD), prior to its use in a concrete mix. The physical properties of coarse RCA were evaluated after surface treatment during the first phase of the experiment to determine the density and the water absorption characteristics of the RCA. The second phase involved the evaluation of the slump, slump loss, density, and compressive strength of the concretes that were prepared with different proportions of natural and treated coarse RCA. Controlling the moisture state of the coarse RCA after surface treatment was found to significantly influence the properties of the fresh and hardened concretes.
Abstract: In this study, tapioca starch, which acts as natural polymer, was added in the blend in order to produce biodegradable product. Low density polyethylene (LDPE) and tapioca starch blends were prepared by extrusion and the test sample by injection moulding process. Ethylene vinyl acetate (EVA) acts as compatibilizer while glycerol as processing aid was added in the blend. The blends were characterized by using melt flow index (MFI), fourier transform infrared (FTIR) and the effects of water absorption to the sample. As the starch content increased, MFI of the blend was decreased. Tensile testing were conducted shows the tensile strength and elongation at break decreased while the modulus increased as the starch increased. For the biodegradation, soil burial test was conducted and the loss in weight was studied as the starch content increased. Morphology studies were conducted in order to show the distribution between LDPE and starch.