Abstract: The removal efficiency of 4-chlorophenol with
different advanced oxidation processes have been studied. Oxidation
experiments were carried out using two 4-chlorophenol
concentrations: 100 mg L-1 and 250 mg L-1 and UV generated from a
KrCl excilamp with (molar ratio H2O2: 4-chlorophenol = 25:1) and
without H2O2, and, with Fenton process (molar ratio H2O2:4-
chlorophenol of 25:1 and Fe2+ concentration of 5 mg L-1).
The results show that there is no significant difference in the 4-
chlorophenol conversion when using one of the three assayed
methods. However, significant concentrations of the photoproductos
still remained in the media when the chosen treatment involves UV
without hydrogen peroxide. Fenton process removed all the
intermediate photoproducts except for the hydroquinone and the
1,2,4-trihydroxybenzene. In the case of UV and hydrogen peroxide
all the intermediate photoproducts are removed.
Microbial bioassays were carried out utilising the naturally
luminescent bacterium Vibrio fischeri and a genetically modified
Pseudomonas putida isolated from a waste treatment plant receiving
phenolic waste. The results using V. fischeri show that with samples
after degradation, only the UV treatment showed toxicity (IC50 =38)
whereas with H2O2 and Fenton reactions the samples exhibited no
toxicity after treatment in the range of concentrations studied. Using
the Pseudomonas putida biosensor no toxicity could be detected for
all the samples following treatment due to the higher tolerance of the
organism to phenol concentrations encountered.
Abstract: Sampling and analysis of leachate from Bhalaswa
landfill and groundwater samples from nearby locations, clearly
indicated the likely contamination of groundwater due to landfill
leachate. The results of simulation studies carried out for the
migration of Chloride from landfill shows that the simulation results
are in consonance with the observed concentration of Chloride in the
vicinity of landfill facility. The solid waste disposal system presently
being practiced in Delhi consists of mere dumping of wastes
generated, at three locations Bhalaswa, Ghazipur, and Okhla without
any regard to proper care for the protection of surrounding
environment. Bhalaswa landfill site in Delhi, which is being operated
as a dump site, is expected to become cause of serious groundwater
pollution in its vicinity. The leachate from Bhalaswa landfill was
found to be having a high concentration of chlorides, as well as DOC,
COD. The present study was undertaken to determine the likely
concentrations of principle contaminants in the groundwater over a
period of time due to the discharge of such contaminants from
landfill leachates to the underlying groundwater. The observed
concentration of chlorides in the groundwater within 75m of the
radius of landfill facility was found to be in consonance with the
simulated concentration of chloride in groundwater considering one
dimensional transport model, with finite mass of contaminant source.
Governing equation of contaminant transport involving advection and
diffusion-dispersion was solved in matlab7.0 using finite difference
method.
Abstract: In an assessment of the extractability of metals in
green liquor dregs from the chemical recovery circuit of semichemical
pulp mill, extractable concentrations of heavy metals in
artificial gastric fluid were between 10 (Ni) and 717 (Zn) times
higher than those in artificial sweat fluid. Only Al (6.7 mg/kg; d.w.),
Ni (1.2 mg/kg; d.w.) and Zn (1.8 mg/kg; d.w.) showed extractability
in the artificial sweat fluid, whereas Al (730 mg/kg; d.w.), Ba (770
mg/kg; d.w.) and Zn (1290 mg/kg; d.w.) showed clear extractability
in the artificial gastric fluid. As certain heavy metals were clearly
soluble in the artificial gastric fluid, the careful handling of this
residue is recommended in order to prevent the penetration of green
liquor dregs across the human gastrointestinal tract.
Abstract: The paper attempts a synthesis of problems relating to
municipal waste management in Nigeria and proposes a conceptual
knowledge management approach for tackling municipal waste
problems in cities across Nigeria. The application of knowledge
management approach and strategy is crucial for inculcating a change
of attitude towards improving the management of waste. The paper is
a review of existing literatures, information, policies and data on
municipal waste management in Nigeria. The inefficient management
of waste by individuals, households, consumers and waste
management companies can be attributed to inadequate information
on waste management benefits, lack of producers- involvement in
waste management as well as poor implementation of government
policies. The paper presents an alternative approach providing
solutions promoting efficient municipal waste management.
Abstract: Proper management of residues originated from
industrial activities is considered as one of the serious challenges
faced by industrial societies due to their potential hazards to the
environment. Common disposal methods for industrial solid wastes
(ISWs) encompass various combinations of solely management
options, i.e. recycling, incineration, composting, and sanitary
landfilling. Indeed, the procedure used to evaluate and nominate the
best practical methods should be based on environmental, technical,
economical, and social assessments. In this paper an environmentaltechnical
assessment model is developed using analytical network
process (ANP) to facilitate the decision making practice for ISWs
generated at Gilan province, Iran. Using the results of performed
surveys on industrial units located at Gilan, the various groups of
solid wastes in the research area were characterized, and four
different ISW management scenarios were studied. The evaluation
process was conducted using the above-mentioned model in the
Super Decisions software (version 2.0.8) environment. The results
indicates that the best ISW management scenario for Gilan province
is consist of recycling the metal industries residues, composting the
putrescible portion of ISWs, combustion of paper, wood, fabric and
polymeric wastes as well as energy extraction in the incineration
plant, and finally landfilling the rest of the waste stream in addition
with rejected materials from recycling and compost production plants
and ashes from the incineration unit.
Abstract: The volume of biosolids produced in Malaysia
nowadays had increased proportionally to its population size. The end
products from the waste treatments were mounting, thus inevitable
that in the end the environment will be surrounded by the waste. This
study was conducted to investigate the suitability of biosolids to be
reused as fertilizer for non-food crop. By varying the concentration of
biosolids applied onto the soil, growth of five ornamental plant
samples were tested for eight consecutive weeks. The results show
that the pH of the soil after the addition of biosolids ranges from 6.45
to 6.56 which is suitable for the plant growth. The soil samples that
contains biosolid also show higher amount of macronutrients (N, P,
K) and the heavy metals content are significantly increased in the
plant however it does not exceed the guidelines drawn by the
Environmental Protection Agency. It is also proven that there was
only small significant different in the performance of plant growth
between biosolids and commercial fertilizer. It can be seen that
biosolids was able to perform just as well as commercial fertilizer.
Abstract: The presented article deals with the description of a
numerical model of a corridor at a Central Interim Spent Fuel Storage
Facility (hereinafter CISFSF). The model takes into account the
effect of air flows on the temperature of stored waste. The
computational model was implemented in the ANSYS/CFX
programming environment in the form of a CFD task solution, which
was compared with an approximate analytical calculation. The article
includes a categorization of the individual alternatives for the
ventilation of such underground systems. The aim was to evaluate a
ventilation system for a CISFSF with regard to its stability and
capacity to provide sufficient ventilation for the removal of heat
produced by stored casks with spent nuclear fuel.
Abstract: The aim of this work is to study the possible use of
stone cutting sludge waste in concrete production, which would
reduce both the environmental impact and the production cost .Slurry
sludge was used a source of water in concrete production, which was
obtained from Samara factory/Jordan, The physico-chemical and
mineralogical characterization of the sludge was carried out to
identify the major components and to compare it with the typical
sand used to produce concrete. Samples analysis showed that 96% of
slurry sludge volume is water, so it should be considered as an
important source of water. Results indicated that the use of slurry
sludge as water source in concrete production has insignificant effect
on compression strength, while it has a sharp effect on the slump
values. Using slurry sludge with a percentage of 25% of the total
water content obtained successful concrete samples regarding slump
and compression tests. To clarify slurry sludge, settling process can
be used to remove the suspended solid. A settling period of 30 min.
obtained 99% removal efficiency. The clarified water is suitable for
using in concrete mixes, which reduce water consumption, conserve
water recourses, increase the profit, reduce operation cost and save
the environment. Additionally, the dry sludge could be used in the
mix design instead of the fine materials with sizes < 160 um. This
application could conserve the natural materials and solve the
environmental and economical problem caused by sludge
accumulation.
Abstract: This paper reviews the objectives, methods and results of previous studies on biodrying of solid waste in several countries. Biodrying of solid waste is a novel technology in developing countries such as in Malaysia where high moisture content in organic waste makes the segregation process for recycling purposes complicated and diminishes the calorific value for the use of fuel source. In addition, the high moisture content also encourages the breeding of vectors and disease-bearing animals. From the laboratory results, the average moisture content of organic waste, paper, plastics and metals are 58.17%, 37.93%, 29.79% and 1.03% respectively for UKM campus. Biodrying of solid waste is a simple method of waste treatment as well as a cost-efficient technology to dry the solid waste. The process depends on temperature monitoring and air flow control along with the natural biodegradable process of organic waste. This review shows that the biodrying of solid waste method has high potential in treatment and recycling of solid waste, be useful for biodrying study and implementation in Malaysia.
Abstract: Waste corn pulp was investigated as a potential feedstock during vermicomposting using Eisenia fetida. Corn pulp is the major staple food in Southern Africa and constitutes about 25% of the total organic waste. Wastecooked corn pulp was blended with cow dung in the ratio 6:1 respectively to optimize the vermicomposting process. The feedstock was allowed to vermicompost for 30 days. The vermicomposting took place in a 3- tray plastic worm bin. Moisture content, temperature, pH, and electrical conductivity were monitoreddaily. The NPK content was determined at day 30. During vermicomposting, moisture content increased from 27.68% to 52.41%, temperature ranged between 19- 25◦C, pH increased from 5.5 to 7.7, and electrical conductivity decreased from 80000μS/cm to 60000μS/cm. The ash content increased from 11.40% to 28.15%; additionally the volatile matter increased from 1.45% to 10.02%. An odorless, dark brown vermicompost was obtained. The vermicompost NPK content was 4.19%, 1.15%, and 6.18% respectively.
Abstract: In this research, an aerobic composting method is
studied to reuse organic waste from rubber factory waste as soil fertilizer and to study the effect of cellulolytic microbial activator
(CMA) as the activator in the rubber factory waste composting. The
performance of the composting process was monitored as a function
of carbon and organic matter decomposition rate, temperature and
moisture content. The results indicate that the rubber factory waste is best composted with water hyacinth and sludge than composted
alone. In addition, the CMA is more affective when mixed with the rubber factory waste, water hyacinth and sludge since a good fertilizer is achieved. When adding CMA into the rubber factory
waste composted alone, the finished product does not achieve a
standard of fertilizer, especially the C/N ratio.
Finally, the finished products of composting rubber factory waste and water hyacinth and sludge (both CMA and without CMA), can be an environmental friendly alternative to solve the disposal problems of rubber factory waste. Since the C/N ratio, pH, moisture
content, temperature, and nutrients of the finished products are acceptable for agriculture use.