Abstract: Poly bag and mulch films for agricultural field caused
pose environmental problem due to the non-degradable plastics
wastes upon disposal. Thus, a degradable poly bag was designed with
hybrid sago starch (SS) and polyvinyl alcohol (PVA). Two Different
blended compositions of SS and PVA hybrid have been compounded.
Then, the hybrids blended are mixed with linear line density
polyethylene (LLDPE) resin to fabricate poly bag film through
conventional film blowing process. Samples of LLDPE, SS and PVA
hybrid film were exposed to UV light and soil burial. The weight
losses were determined during degradation process. Hybrid film by
degradation of starch was found to hydrolyze and hydroxyl groups
decrease on esterification upon exposure to soil burial and uv
radiation. It was found out that, the hybrid film for 60% of SS
composition showed greatest degradation in soil and UV radiation.
Abstract: Polybag and mulch film in agricultural field are used plastics which caused environmental problems after transplantation and planting processes due to the discarded wastes. Thus a degradable polybag was designed in this study to replace non degradable polybag with natural biodegradable resin that is widely available, namely sago starch (SS) and polyvinyl alcohol (PVA). Hybrid blend consists of SS, PVA and linear low density polyethylene (LLDPE) was compounded at different ratios. The thermal and mechanical properties of the blends were investigated. Hybrid films underwent landfill degradation tests for up to 2 months. The films showed gelation and melting transition existed for all three systems with significant melting peaks by LLDPE and PVA. All hybrid blends loses its LLDPE semi crystalline characteristics as PVA and SS systems had disrupted crystallinity and enhanced the amorphosity of the hybrid system. Generally, blending SS with PVA improves the mechanical properties of the SS based materials. Tensile strength of each film was also decreased with the increase of SS contents while its modulus had increased with SS content.