Abstract: Ambient hydrolysis products in moist air and
hydrolysis kinetics in argon with humidity of RH1.5% for
polycrystalline LiH powders and sintered bulks were investigated by
X-ray diffraction, Raman spectroscopy and gravimetry. The results
showed that the hydrolysis products made up a layered structure of
LiOH•H2O/LiOH/Li2O from surface of the sample to inside. In low
humid argon atmosphere, the primary hydrolysis product was Li2O
rather than LiOH. The hydrolysis kinetic curves of LiH bulks present a
paralinear shape, which could be explained by the “Layer Diffusion
Control" model. While a three-stage hydrolysis kinetic profile was
observed for LiH powders under the same experimental conditions.
The first two sections were similar to that of the bulk samples, and the
third section also presents a linear reaction kinetics but with a smaller
reaction rate compared to the second section because of a larger
exothermic effect for the hydrolysis reaction of LiH powder.